• Title/Summary/Keyword: thermal activation

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Kinetics of Thermal Dehydration of Ha-dong Kaolin (하동카오린의 열분해속도에 관한 연구)

  • 박희찬;손명모
    • Journal of the Korean Ceramic Society
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    • v.18 no.1
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    • pp.35-40
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    • 1981
  • The kinetics of the dehydration of Ha-dong kaolin was studied isothermally at various temperatures. Dehydration rate was measured by thermogravimetry method in the temperature range of 440~50$0^{\circ}C$ and the particle size range of 170~325mesh. The general equation f($\alpha$)=kt, where $\alpha$ is the fraction reacted in the time and the function f($\alpha$) depends on the reaction mechanism, was applied to this reaction. The function, f($\alpha$) was obtained by application of reduced-time plot and plot of lnln (1-$\alpha$) vs. ln (time), and expressed as (1-$\alpha$) ln (1-$\alpha$)+$\alpha$=kt. The dehydration followed the diffusion-controlled reaction model and gave activation energy of 30Kcal/mole.

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Synthesis of Organo-montmorillonite by Intercalation Reaction and its Kinetic Study (Intercalation 반응에 의한 Organo-montmorillonite의 합성 및 반응속도 연구)

  • 김창은;최진호;형경우
    • Journal of the Korean Ceramic Society
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    • v.21 no.1
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    • pp.67-73
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    • 1984
  • A stable intercalation complex was formed by adsorption of alcanol (ROH, R; $C_{10}H_2$, $C_{12}H_{25}$, $C_{14}H_{29}$) on the surfaces of Yongil bentonite in which the interlayer cation had been exchanged by n-decylammonium ion $(C_{10}H_{21}NH_3^+)$ The layer charge density calculated from the increaments of basal spacings was 0.34 per unit chemical formula. Thermochemical properties of synthesized $C_{10}H_{21}NH_3^+$ montmorillonite were studied by means of DSC, TGA, DTG, Thermal analysis showed two steps of desoption behavior of $C_{10}H_{21}NH_3^+$ ion namely nonyl $(CH_3(CH_2)_8$ decomposition reaction of 40$0^{\circ}C$ and methyleneammonium decomposition reaction of 78$0^{\circ}C$ The activation energy of nonyl decomposition reaction of $C_{10}H_{21}NH_3^+$ -montmorillonite respectively.

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Thermal Behavior of Silver Paste to Improve Reliability and Image Quality of LCoS Panel

  • Chen, Yu-Hsien;Huang, I-Chen;Huang, Li-Chen;Wang, Jiun-Ming;Chen, Kun-Hong;Liu, Kuang-Hua;Li, Huai-An;Lo, Yu-Cheng;Liu, Pei-Yu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1398-1401
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    • 2006
  • Silver paste curing process is very important in LCoS panel manufacture because incomplete curing process will cause poor bonding strength and increase resistance. The imperfection situation results in poor reliability and the variation of the common voltage, respectively. The change of the common voltage causes image flicker. According to Kinetics, we acquire activation energy by using dynamic DSC and compare two kinds of silver paste. From the result of isothermal DSC, we get optimum curing parameters to solve the flicker problem caused of incomplete curing of the silver paste.

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Study on the Conversion of Ortho to Para Hydrogen (ORTHO/PARA 수소의 전환에의 연구)

  • Kim, Jong-Pal;Lee, Kwang-Hyun
    • Journal of Hydrogen and New Energy
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    • v.18 no.3
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    • pp.317-324
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    • 2007
  • The conversion reaction of ortho to para hydrogen was studied. The percentage of ortho and para hydrogen is mainly dependent on the equilibrium temperature. Because this reaction is known to be accelerated by the catalyst such as nickel-silicate and ruthenium on silica, we focused in the test and development of the catalysts. We studied metal-silicates because they provide high metal dispersion on support. Nickel-silicate, ruthenium-silicate and mixed-silicate were prepared by the coprecipitation method and used in the reaction at the temperature of liquid nitrogen. The conversion was measured by the difference of thermal conductivity between reference gas and sample gas. The activation condition was important and it affected the activities of the catalysts. Nickel-silicate showed high activities. Ruthenium-silicate also showed relative high activities but mixed-silicate showed poor activities.

Preparation of Composite Adsorbents by Activation of Water Plant Sludge and Phenolic Resin Mixtures

  • Myung, Heung-Sik;Kim, Dong-Pyo
    • Carbon letters
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    • v.1 no.3_4
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    • pp.154-157
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    • 2001
  • Composite adsorbents were prepared by mixing water plant sludge with phenolic resin having the ratio of 1 : 1, 1 : 2, and 1 : 3 respectively, curing from $100^{\circ}C$ to $170^{\circ}C$ under $N_2$ atmosphere, and then activating with $N_2$ at $700^{\circ}C$. Thermal property, specific surface area and morphology of the composite adsorbents as well as their precursors were measured by TGA, BET and SEM respectively. Removal efficiency of the composite adsorbents to ${NH_4}^+$ and TOC was compared with those of commercial zeolite and activated carbon. The adsorbents presented very promising TOC removal efficiency of 98%, which was identical level to that of commercial activated carbon while they displayed removal efficiency, only 32%, of ${NH_4}^+$. Therefore, this composite adsorbent considered as the alternative material of commercial activated carbon, used as an expensive removal agent of organic substances and THM in water treatment plant and it also suggested a possibility of practical application in other processes.

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Impact of Passivation and Reliability for Base-exposed InGaP/GaAs HBTs

  • Park, Jae-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.115-120
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    • 2007
  • Reliability between passivated and unpassivated process with the base-exposed InGaP/GaAs HBTs was studied. A passivation of HBT was attempted by $SiO_2$ thin film deposition at $300^{\circ}C$ by means of PECVD. Base-exposed InGaP/GaAs HBTs before and after passivation were investigated and compared in terms of DC and RF performance. Over a total period of 30 days, passivated HBTs show only 2% degradation of DC current gain for the high current density of $40KA/cm^2$. The measured thermal resistance of $2{\times}30{\mu}m^2$ single emitter InGaP/GaAs HBT passivated with PECVD $SiO_2$ devices can be extracted and was founded to be 1430 K/W. The estimated MTTF was $2{\times}10^7hr\;at\;T_j=125^{\circ}C$ with an activation energy $(E_a)$ of 1.37 eV.

Excimer Laser-Assisted In Situ Phosphorus Doped $Si_{(1-x)}Ge_x$ Epilayer Activation

  • Bae, Ji-Cheul;Lee, Young-Jae
    • ETRI Journal
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    • v.25 no.4
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    • pp.247-252
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    • 2003
  • This paper presents results from experiments on laser-annealed SiGe-selective epitaxial growth (LA-SiGe-SEG). The SiGe-SEG technology is attractive for devices that require a low band gap and high mobility. However, it is difficult to make such devices because the SiGe and the highly doped region in the SiGe layer limit the thermal budget. This results in leakage and transient enhanced diffusion. To solve these problems, we grew in situ doped SiGe SEG film and annealed it on an XMR5121 high power XeCl excimer laser system. We successfully demonstrated this LA-SiGe-SEG technique with highly doped Ge and an ultra shallow junction on p-type Si (100). Analyzing the doping profiles of phosphorus, Ge compositions, surface morphology, and electric characteristics, we confirmed that the LA-SiGe-SEG technology is suitable for fabricating high-speed, low-power devices.

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Anti-nociceptive Activity of Methanol Extracts from Ligularia stenocephala (곤달비 메탄올 추출물의 진통 효과)

  • Cha, Dong Seok;Jeon, Hoon
    • Korean Journal of Pharmacognosy
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    • v.44 no.1
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    • pp.70-74
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    • 2013
  • Ligularia stenocephala has been widely used as a traditional medicine for the treatment of lots of diseases such as asthma, arthritis, and jaundice. In this study, we evaluated the anti-nocicepitve activities of methanolic extract of L. stenocephala (MLS) using various pain models including thermal nociception as well as chemical nociception methods. MLS showed significant increase in latency time in the tail immersion test and hot-plate test. In addition, the number of acetic acid-induced abdominal constrictions was decreased by MLS. MLS also attenuated paw licking time in the formalin test. The combination test using naloxone revealed that the anti-nociceptive properties of MLS was not associated with opioid receptor activation. The present results demonstrate that MLS may possibly used as valuable analgesic agent for the treatment of nociceptive pain.

Thermal dissociation of excitons bound to neutral acceptors in CdTe single crystal (CdTe 단결정에서 중성 받게에 구속된 엑시톤의 열 해리)

  • 박효열
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.3
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    • pp.185-188
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    • 2000
  • The dissociation of excitons bounds to neutral accepter in CdTe single crystal was investigated by measurement of temperature dependence of the photoluminescence spectra. The binding energies of CdTe single crystal were determined by PL spectrum at 12K. The free exciton (X) binding energy, the exciton binding energy on neutral donor ($D^{\circ}$, X), and the exciton binding energy on neutral acceptor ($A^{\circ}$, X) were 10 meV, 3.49 meV, and 7.17 meV respectively. From the value of activation energy of ($A^{\circ}$, X), we could show that the dissociation of ($A^{\circ}$, X) is attributed to free exciton.

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Error Correction of the Activation Energy of Thermally Stimulated Current by using a Asymptotic Estimation Method (접근해법을 이용한 열자격전류의 활성화에너지 오차 보정)

  • Kim, Ki-Joon;Park, Seung-Hyub;Kim, Chung-Hyeok;Lee, Joon-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.118-122
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    • 1992
  • In this paper, the properties of Thermally Stimulated Current was studied to understand carrier's behavior of $PVF_2$ film, to be regarded as the excellent piezo and pyroelectricity. The complex relaxation curve of Thermally Stimulated Current was divided into single relaxation style using Thermal Cleaning method. As a result of Applying the numerical method of asymtotic estimation to the divided single relaxation peak, we could calculated the physical factors related to charged particles of the specimen, more accurately.

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