• Title/Summary/Keyword: theoretical yield

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Enhanced Anaerobic Degradation of Food Waste by Employing Rumen Microorganisms (Rumen 미생물을 이용한 주방폐기물 혐기성소화의 효율증진 방안)

  • Shin, Hang-Sik;Song, Young-Chae;Son, Sung-Sub;Bae, Byung-Uk
    • Journal of the Korea Organic Resources Recycling Association
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    • v.1 no.1
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    • pp.103-113
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    • 1993
  • Every year, over $3.37{\times}10^7$ ton of municipal solid waste is generated in Korea, of which about 28% is organic food waste from restaurant, dining halls and households etc. Methane conversion of the food waste by anaerobic digestion could be a viable approach for energy recovery as well as safe disposal of the waste. However, as food waste is composed of highmolecular complex polymers such as cellulose, lignin and protein, anaerobic digestion of food waste has not been efficient in terms of volumetric loading rate, solid retention time and extent of anaerobic degradation. In this research, the improved anaerobic degradation of food waste was attemped by applying rumen microorganisms to anaerobic digestion. Acidification efficiency of food waste by rumen microorganisms was compared with that of conventional acidogenesis. And optimum acidification conditions by rumen microorganisms were also determined. For the experiments, anaerobic batch reactors of 600 mL was fed with the processed (dried and milled) food waste obtained from a restaurant. Ultimate volatile fatty acid (VFA) yield produced by rumen microorganisms was about 8.4 meq VFA/g volatile solid (VS) that is 95% of the theoretical value. This yield was not much different from that of conventional acidogenesis, but hydrolysis rate was about twice faster. Cumulative VFA concentration increased from 66 meq/L to 480 meq/L, when the initial TS was increased from 1% to 15%. But VFA yield at 15% TS was half of that at 1% TS. This inhibition on the acidification might be caused by the rapid drop of pH and higher concentration of nonionized VFA. Optimal pH and temperature range for the acidification were about 6.0~7.5 and $35{\sim}45^{\circ}C$, respectively.

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Bioenergy and Material Production Potential by Life Cycle Assessment in Swine Waste Biomass (전과정 평가에 의한 양돈 바이오매스의 물질 및 에너지 자원화 잠재량 연구)

  • Kim, Seung-Hwan;Kim, Chang-Hyun;Yoon, Young-Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1245-1251
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    • 2011
  • As a result of the growing livestock industry, varieties of organic solid and waste biomass are be generated in swine breeding and slaughtering stages. Anaerobic digestion is a promising alternative for the treatment of livestock waste biomass, as well as for the material recovery and energy production. Objectives of this study were to analyze the biochemical methane potential of swine waste biomasses that were generated from swine pen and slaughterhouse and to investigate the material recovery and methane yield per head. As pig waste biomass, swine slurry, blood, intestine residue, and digestive tract content were collected for investigation from pig farmhouse and slaughterhouse. The $B_{th}$ (Theoretical methane potential) and $B_0$ (Biochemical methane potential) of swine slurry generating in swine breeding stage were 0.525 and $0.360Nm^3\;kg^{-1}-VS_{added}$, the ratio of degradation ($B_0/B_{th}$) was 68.6%. $B_{th}$ of blood, intestine residue, and digestive tract content were 0.539, 0.664, and $0.517Nm^3\;kg^{-1}-VS_{added}$, and $B_0$ were 0.405, 0.213, and $0.240Nm^3\;kg^{-1}-VS_{added}$, respectively. And the ratio of degradation showed 75.1, 32.1, and 46.4% in blood, intestine residue, and digestive tract content. Material yield of swine waste biomass was calculated as TS 73.79, VS 46.75, TN 5.58, $P_2O_5$ 1.94, and $K_2O$ $2.91kg\;head^{-1}$. And methane yield was $16.58Nm^3\;head^{-1}$. In the aspect that slaughterhouse is a large point source of waste biomass, while swine farmhouse is non-point source, the feasibility of an anaerobic digestion using the slaughtering waste biomass need to be assessed in the economical aspect between the waste treatment cost and the profitable effect by methane production.

Modification of Starch using Dextransucrase and Characterization of the Modified Starch. (덱스트란수크라제를 이용한 전분의 변형 및 특성 조사)

  • ;;;;;John E. Robyt
    • Microbiology and Biotechnology Letters
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    • v.26 no.2
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    • pp.143-150
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    • 1998
  • Many enzymes catalyze a primary reaction and/or secondary reaction. Dextransucrase usually synthesize dextran from sucrose as a primary reaction. The secondary reaction of dextransucrase is the transfer of glucose from sucrose to carbohydrate accepters. We have reacted dextransucrase from Leuconostoc mesenteroides B-742CB with sucrose and starches; granule or gelatinized starches, and Small or Potato starches. The yield of modified starch was ranged from 46% to 72%(s.d.<${pm}$5%) of theoretical depends on various reaction conditions. Modified products were more resistant against the hydrolysis of ${alpha}$-amylase, isoamylase, pullulanase and endo-dextranase than those of native starch. Based on the reactions from enzyme hydrolysis and methylation followed by acid hydrolysis modification of granule starch was more efficient than the modification of gelatinized starch. After modification of granule starch with dextransucrase, there produced a soluble modified starch. After modification the starch granules were fractionated to small size. The positions of glucose substitution of the modified products were determined by methylation followed by acid hydrolysis and analyzed by TLC. The products were modified by the addition of glucose to the position of C3, C4 and C6 free hydroxyl group of glucose residues in the starch.

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Study on Uncertainty Factors of Head Vibration Measurements (머리 진동 측정치의 불확도 인자들에 관한 연구)

  • Cheung, Wan-Sup;Kim, Young-Tae;Ryu, Je-Dam;Hong, Dong-Pyo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.15 no.1 s.94
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    • pp.20-28
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    • 2005
  • This paper addresses uncertainty issues encountered recently in measuring head vibration using the conventional 6-axis or 9-axis bite-bar model. Those conventional bite-bar models are shown to present insufficient information to evaluate a generalized motion of head vibration. In order to overcome such limit, a new theoretical measurement model that consists of four 3-axis linear accelerometers is suggested. It is shown to enable the measurement of three angular acceleration components and six second-order angular velocity-dependent terms. Those nine angular motion-related ones, in addition to the three linear acceleration terms at the origin, are found to make it possible to evaluate the generalized head vibration for a given position. To examine the feasibility of the proposed method, a newly designed 12-axis bite-bar was developed. Detailed experimental results obtained from the developed 12-axis bite-bar are demonstrated in this paper. They illustrate that the popular 6-axis bite-bar model yield about $4.0\%$ relative measurement uncertainty for the pitch component of head vibration, $14\%$ and $10\%$ relative measurement uncertainty for the roll and yaw components of head vibration, respectively. Furthermore, this paper proposes other uncertainty factors to be considered in the future.

Basic Study on the Production of Nd-Fe-B System Rare Earth Anisotropic bonded Magnet Materials by the R-D & HDDR Process(I) (R-D & HDDR Process에 의한 Nd-Fe-B계 희토류 이방성 본드자석재료의 제조에 관한 기초연구 (I))

  • Jo, Seon-Mi;Son, Chang-Bin;Jo, Tong-Rae
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.609-614
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    • 2001
  • This study was carried out to obtain a basic data on the production of the Nd-Fe-B system rare earth anisotropic bonded magnet by R-D & HDDR process. The reduction reaction of Nd$_2$O$_3$by metallic Ca and the diffusion reaction of Nd into Fe-B alloy powder were investigated for the production the Nd-Fe-B alloy powder. We concluded that a proper quantity of metallic Ca was about 1.3 times of theoretical equivalent from the yields of Nd and B after the R-D reaction at 100$0^{\circ}C$ for 1h. In the XRD analysis the diffusion reaction of Nd into the center of Fe-B alloy powder for the completed homogenization was required through about 45min at 110$0^{\circ}C$ for the R-D reaction, and also the maximum efficiency on the yield of Nd was obtained with such a condition. Residual Ca and oxygen contents of the final powder sample after washing were detected in 0.17wt% and 0.42wt% by ICP and oxygen analyzer, respectively.

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Behavior of Reinforced Concrete Slabs Connected with Hinge Joints of Remodelling Buildings (리모델링 건물의 활절점에 의하여 연결된 철근콘크리트 바닥판의 거동 평가)

  • Sim Kyu-Kwan;Kim Sang-Sik;Lee Jung-Yoon;Choi kwang-Ho;Im Juhyeuk
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.761-768
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    • 2005
  • Lately outmoded and functionally obsolete buildings constructed in 1960s and 1970s are often remodelled and restored. Even though there are not serious structural defects in the existing buildings, many old buildings have been reconstructed to improve residence quality or to extend residence area of the buildings. The experimental or theoretical research on plane expansion of RC apartments is quite scare. In this research, 12 specimens and 19 RC slabs connected by hinged joints were tested. The new slab was connected to the existing slab by hinge joints injecting dowel bars between two slabs. Main parameters of the slabs are types of the dowel bars (D13 and D19), spacing of the dowel bars (150mm, 300mm, and 450mm), and the locations of the steel bars in the existing slabs. The test results indicated that the shear strength of the RC test slabs having various types of dowel bars was about twice that calculated by the ACI 318-02 code. All slabs failed in concrete spatting and the dowel steel bars did not reach their yield strengths.

Earth Pressure Analysis of Tunnel Ceiling according to Tunnel Plastic Zone (터널 소성영역에 따른 터널 천단토압 해석)

  • Park, Shin-Young;Han, Heui-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.753-764
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    • 2020
  • In this study, the plastic zone and internal earth pressure of the tunnel were calculated using the following three methods: metal plasticity to analyze the deformation of metal during plastic processing, Terzaghi's earth pressure theory from the geotechnical perspective and modified Terzaghi's earth pressure theory, and slip line theory using Mohr-Coulomb yield conditions. All three methods are two-dimensional mathematical analysis models for analyzing the plane strain conditions of isotropic materials. Using the theory of metallurgical plastics, the plastic zone and the internal earth pressure of the ground were obtained by assuming that the internal pressure acts on the tunnel, so different results were derived that did not match the actual tunnel site, where only gravity was applied. An analysis of the plasticity zone and earth pressure via the slip-line method showed that a failure line is formed in a log-spiral, which was found to be similar to the real failure line by comparing the results of previous studies. The earth pressure was calculated using a theoretical method. Terzaghi's earth pressure was calculated to be larger than the earth pressure considering the dilatancy effect.

Production of 6-hydroxynicotinic acid by nicotinic acid-assimilating Pseudomonas sp. (Pseudomonas sp.에 의한 nicotinic acid로부터 6-hydroxynicotinic acid의 생산)

  • Hong, Jeong-Jin;Hwang, Ki-Chul;Bang, Won-Gi
    • Applied Biological Chemistry
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    • v.35 no.6
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    • pp.495-500
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    • 1992
  • For the production of 6-hydroxynicotinic acid from nicotinic acid, bacteria capable of assimilating nicotinic acid as a sole carbon, nitrogen and energy source were isolated from soils. Among them, SH-007, newly isolated strain having the best acitivity of nicotinic acid hydroxylase was selected and identified as Pseudomonas sp. The specific acitivity of nicotinic acid hydroxylase of Pseudomonas sp. was highest when the strain was cultured at $30^{\circ}C$ for 24 hrs in the medium (pH 7.5) containing 2 g nicotinic acid, 1 g $(NH_4)_2SO_4$, and 0.5 g peptone per liter. The addition of 1.5 g/l of nicotinic acid into the 24 hrs incubated culture medium resulted in the 12% higher specific acitivity of nicotinic acid hydroxylase than that of the non-added control after further 18 hrs incubation. In the 6-hydroxynicotinic acid production through the reaction with resting cells, 2.22 g/l of 6-hydroxynicotinic acid was produced from 2 g/l of nicotinic acid after incubation of 3 hrs under optimum conditions, which correpsonds to 98.2% of theoretical 6-hydroxynicotinic acid yield.

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A Method of Rating Curve Adjustment (수위유량곡선보정방법에 대하여)

  • 박정근
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.18 no.2
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    • pp.4116-4120
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    • 1976
  • With the use of many rivers increased nearly to the capacity, the need for information concerning daily quantities of water and the total annual or seasonal runoff has became increased. A systematic record of the flow of a river is commonly made in terms of the mean daily discharge Since. a single observation of stage is converted into discharge by means of rating curve, it is essential that the stage discharge relations shall be accurately established. All rating curves have the looping effect due chiefly to channel storage and variation in surface slope. Loop rating curves are most characteristic on streams with somewhat flatter gradients and more constricted channels. The great majority of gauge readings are taken by unskilled observers once a day without any indication of whether the stage is rising or falling. Therefore, normal rating curves shall show one discharge for one gauge height, regardless of falling or rising stage. The above reasons call for the correction of the discharge measurements taken on either side of flood waves to the theoretical steady-state condition. The correction of the discharge measurement is to consider channel storage and variation in surface slope. (1) Channel storage As the surface elevation of a river rises, water is temporarily stored in the river channel. There fore, the actual discharge at the control section can be attained by substracting the rate of change of storage from the measured discharge. (2) Variation in surface slope From the Manning equation, the steady state discharge Q in a channel of given roughness and cross-section, is given as {{{{Q PROPTO SQRT { 1} }}}} When the slope is not equal, the actual discharge will be {{{{ { Q}_{r CDOT f } PROPTO SQRT { 1 +- TRIANGLE I} CDOT TRIANGLE I }}}} may be expressed in the form of {{{{ TRIANGLE I= { dh/dt} over {c } }}}} and the celerity is approximately equal to 1.3 times the mean watrr velocity. Therefore, The steady-state discharge can be estimated from the following equation. {{{{Q= { { Q}_{r CDOT f } } over { SQRT { (1 +- { A CDOT dh/dt} over {1.3 { Q}_{r CDOT f }I } )} } }}}} If a sufficient number of observations are available, an alternative procedure can be applied. A rating curve may be drawn as a median line through the uncorrected values. The values of {{{{ { 1} over {cI } }}}} can be yielded from the measured quantities of Qr$.$f and dh/dt by use of Eq. (7) and (8). From the 1/cI v. stage relationship, new vlues of 1/cI are obtained and inserted in Eq. (7) and (8) to yield the steady-state discharge Q. The new values of Q are then plotted against stage as the corrected steadystate curve.

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Effects of Substrate to Inoculum Ratio on Biochemical Methane Potential in Thermal Hydrolysate of Poultry Slaughterhouse Sludge (기질과 접종액의 비율이 도계 가공장 슬러지 열가수분해액의 메탄생산퍼텐셜에 미치는 영향)

  • Oh, Seung-Yong;Yoon, Young-Man
    • Korean Journal of Environmental Agriculture
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    • v.35 no.2
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    • pp.121-127
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    • 2016
  • BACKGROUND: Anaerobic digestion is the most feasible technology because not only the energy embedded in organic matters can be recovered, but also they are stabilized while being degraded. This study carried out to improve methane yield of slaughterhouse wastewater treatment sludge cake by the thermal pre-treatment prior to anaerobic digestion.METHODS AND RESULTS: Slaughterhouse wastewater treatment sludge cake was pre-treated by the closed hydrothermal reactor at reaction temperature of 190℃. BMPs (Biochemical methane potential) of the thermal hydrolysate was tested in the different S(Substrate)/I(Inoculum) ratio conditions. COD(Chemical oxygen demand) and SCOD(Soluble chemical oxygen demand) contents of thermal hydrolysate were 10.99% and 10.55%, respectively, then, the 96.00% of COD was remained as a soluble form. The theoretical methane potential of thermal hydrolysate was 0.51 Nm3 kg-1-VSadded. And BMPs were decreased from 0.56 to 0.22 Nm3 kg-1-VSadded when S/I ratio were increased from 0.1 to 2.0 in the VS content basis. Those were decreased from 0.32 to 0.13 Nm3 kg-1-CODadded when S/I ratio were increased from 0.1 to 2.0 based on COD content. The anaerobic degradability of VS basis have showed 196.9%, 102.2%, 80.7%, 67.4%, and 39.4% in S/I ratios of 0.1, 0.3, 0.5, 1.0, and 2.0, respectively. Also the COD of 119.6%, 76.3%, 70.1%, 69.0%, and 43.1% were degraded anaerobically in S/I ratios of 0.1, 0.3, 0.5, 1.0, and 2.0, respectively.CONCLUSION: BMPs obtained in the S/I ratios of 0.1 and 0.3 was overestimated by the residual organic matters remaining at the inoculum. And inhibitory effect was observed in the highest S/I ratio of 2.0. The optimum S/I ratios giving reasonable BMPs might be in the range of 0.5 and 1.0 in S/I ratio. Therefore VS biodegradability of thermal hydrolysate was in 67.4-80.7% and COD biodegradability showed 69.0-70.1%.