• Title/Summary/Keyword: the property of pi

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Preparation and Properties Enhancement of Epoxy Resin Employing Poly(amic acid) (PAA) (Poly(amic acid) (PAA)를 함유한 에폭시 수지의 제조 및 물성 향상)

  • 이용택;배성호;박병천
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.254-262
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    • 2001
  • Epoxy resin based upon the N,N'-diglycidylaniline which is widely used in optic, electronic and composite material. We modified this epoxy resin with poly(amic acid) (PAA) that is a precursor of polyimide. To improve the mechanical property we controlled PAA content and imidization ratio. PI-modified epoxy blends were prepared for the formation of IPN structure. The possible reaction in the epoxy resin/PAA blends were investigated by FT-IR and inherent viscosity techniques. Thermal properties are measured by TGA, DSC, and TMA. Mechanical properties are measured by UTM and impact test machine. Morphology is investigated by SEM. Thermal stability improved with increasing the content of PAA in blends. As the content of PAA increases in blend, the glass transition temperature and thermal expansion coefficient decreases. Increasing impact strengths in J/m in the range of 920∼2412 were observed in blends. The PAA segment may act as a toughening agent in the epoxy networks, thus contributing the impact strength improvement of the blends.

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An analysis of satisfaction index on computer education of university using kernel machine (커널머신을 이용한 대학의 컴퓨터교육 만족도 분석)

  • Pi, Su-Young;Park, Hye-Jung;Ryu, Kyung-Hyun
    • Journal of the Korean Data and Information Science Society
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    • v.22 no.5
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    • pp.921-929
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    • 2011
  • In Information age, the academic liberal art Computer education course set up goals for promoting computer literacy and for developing the ability to cope actively with in Information Society and for improving productivity and competition among nations. In this paper, we analyze on discovering of decisive property and satisfaction index to have a influence on computer education on university students. As a preprocessing method, the proposed method select optimum property using correlation feature selection of machine learning tool based on Java and then we use multiclass least square support vector machine based on statistical learning theory. After applying that compare with multiclass support vector machine and multiclass least square support vector machine, we can see the fact that the proposed method have a excellent result like multiclass support vector machine in analysis of the academic liberal art computer education satisfaction index data.

Design and Implementation of an Efficient Bulk Loading Algorithm for CIR-Tree (CIR-Tree를 위한 효율적인 대량적재 알고리즘의 설계 및 구현)

  • Pi, Jun-Il;Song, Seok-Il;Yu, Jae-Su
    • Journal of KIISE:Databases
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    • v.29 no.3
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    • pp.193-206
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    • 2002
  • In this paper, we design and implement an efficient bulk-loading algorithm for CIR-Tree. Bulk-loading techniques increase node utilization, improve query performance and reduce index construction time. The CIR-tree has variable size of internal node entries since it only maintains minimal dimensions to decriminate child nodes. This property increases fan-out of internal nodes and improves search performance. Even though several bulk-loading algorithms for multi/high-dimensional index structures have been proposed, we cannot apple them to CIR-tree because of the variable size of internal node entries. In this paper, we propose an efficient bulk- loading algorithm for CIR-tree that improves the existing bulk-loading algorithm and accomodates the property of CIR-tree. We also implement it on a storage system MiDAS-III and show superiority of our algorithm through various experiments.

LCD Driver IC Assembly Technologies & Status

  • Shen, Geng-shin
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.09a
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    • pp.21-30
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    • 2002
  • According the difference of flex substrate, (reel tape), there are three kind assembly types of LCD driver IC is COG, TCP and COF, respectively. The TCP is the maturest in these types for stability of raw material supply and other specification. And TCP is the major assembly type of LCD driver IC and the huge demand from Taiwan's large TFT LCD panel house since this spring. But due to its package structure and the raw material applied in this package, there is some limitation in fine pitch application of this package type, (TCP). So, COF will be very potential in compact and portable application comparison with TCP in the future. There are three kinds assembly methods in COF, one is ACF by using the anisotropic conductive film to connect the copper lead of tape and gold bump of IC, another is eutectic bonding by using the thermo-pressure to joint the copper lead of tape and gold bump of IC, and last is NCP by using non-conductive paste to adhere the copper lead of tape and gold bump of IC. To have a global realization, this paper will briefly review the status of Taiwan's large TFT panel house, the internal driver IC design house, and the back-end assembly house in the beginning. The different material property of raw material, PI tape is also compared in the paper. The more detail of three kinds of COF assembly method will be described and compared in this paper.

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Fabrication and Electrical Properties of IMI-O Polymer LB Films (IMI-O 고분자 LB막의 제작 및 전기적 특성)

  • Jeong, Sang-Beom;Yu, Seung-Yeop;Park, Jae-Cheol;Gwon, Yeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.2
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    • pp.87-91
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    • 2000
  • Metal ion complex of poly(N-(2,4-imidazoly)ethyl)maleimide-alt-l-octadecene (IMO-O) polymer used to confirm the possibility of molecular device made by Langmuir-Blodgett(LB) method. Electrical properties of the metal ion complex LB film were investigated using Metal/Insulator/Metal(MIM) structure. In the surface pressure-area($\pi$-A) isotherm of IMI-O polymer, the surface pressure at collapse point has a difference due to the interaction between polymer and metal ions. And the complex between polymer and metal ions could be verified through the investigation by Raman spectroscopy. In the current-voltage(I-V) property, the conductivity change of IMO-O polymer complexes due to the kinds of metal of metal ions couldn't be observed. However, the limiting area of molecules was changed by the concentration of the metal ions and the conductivity was increased with the occupied molecular area.

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Property and Surface Morphology of Copper Foil on the Current Density (구리 박막의 표면형상과 물성에 대한 전류밀도 영향)

  • Woo, Tae-Gyu;Park, Il-Song;Jung, Kwang-Hee;Seol, Kyeong-Won
    • Korean Journal of Materials Research
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    • v.20 no.10
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    • pp.555-558
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    • 2010
  • This study examined the effect of current density on the surface morphology and physical properties of copper plated on a polyimide (PI) film. The morphology, crystal structure, and electric characteristics of the electrodeposited copper foil were examined by scanning electron microscopy, X-ray diffraction, and a four-point probe, respectively. The surface roughness, crystal growth orientation and resistivity was controlled using current density. Large particles were observed on the surface of the copper layer electroplated onto a current density of 25 mA/$cm^2$. However, a uniform surface and lower resistivity were obtained with a current density of 10 mA/$cm^2$. One of the important properties of FCCL is the flexibility of the copper foil. High flexibility of FCCL was obtained at a low current density rather than a high current density. Moreover, a reasonable current density is 20 mA/$cm^2$ considering the productivity and mechanical properties of copper foil.

A Study on the Monolayer Film Electronics (단분자막 전자소자에 대한 연구)

  • Lee, Yong-Soo;Shin, Dong-Myung;Kim, Tae-Wan;Choi, Jong-Sun;Kang, Dou-Yol;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.249-254
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    • 1999
  • The N-docosyl N'-methyl viologen-$(TCNQ)_2$, (DMVT) was synthesized. We investigated the ${\pi}-A$ isotherm of DMVT to find the optimal deposition condition. Temperature-dependent current-voltage characteristics of the DMVT LB films shows that there is an increase in conductivity at 330K or so. The in-plane electrical conductivity at room temperature is in the range of $10^{-7}{\sim}10^{-6}S/cm$. From the plot of logarithmic conductivity as a function of reciprocal temperature, two types of activation energies, 0.04eV and 0.73eV, were obtained depending on the temperature range. The Ohmic behaviour was observed below 0.6V and the Schottky effect was confirmed at $2.5{\sim}6V$, when the I-V characteristics was measured with Al/LB film/Al structure. I-V measurement for Al/LB film/ITO structure showed the asymmetrical I-V relationship, which resulted from the rectification property.

Investigation the frequency change in number of layers and fabrication morphology of Arachidic Acid LB Films (Arachidic Acid LB박막의 누적층수에 따른 주파수 변화와 모폴로지 특성)

  • Yang, Chang-Heon;Choi, Won-Suk;Lee, Nam-Suk;Chang, Jeong-Soo;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1371-1372
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    • 2007
  • In this study, in order to confirm the application possibility to the molecular electronic device, morphlogical property of the Arachidic acid was investigated. We have investigated morphology by BAM image and AFM. ${\pi}$-A curves investigated surface pressure of this LB film from liquid to solid state ranged between 40 to 45 mN/m. BAM images investigated the different states of Arachidic Acid LB film. When the surface pressure reaches at 40 mN/m, the monolayer was deposited onto the hydrophilic glass substrates by Y-type deposition. We also investigated the frequency characteristics of LB modified glass by QCM. We investigated morphology of arachidic acid by AFM. As a result, we obtained the frequency characteristic and morphology of LB films from controlling the deposited layers.

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Electrical Properties of 4th generational Dendrimer Containing Azo-group (아조 기능기를 가진 제4세대 덴드리머의 전기적 특성)

  • Yang, Ki-Sung;Ock, Jin-Young;Jung, Sang-Bum;Kim, Chung-Kyun;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.904-907
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    • 2003
  • We synthesized dendrimers containing light switchable units, azobenzene group. To apply to the molecular level devices or data storage system using Langmuir-Blodgett(LB) film, we firstly investigated the monolayer behavior using the surface pressure-area(${\pi}-A$) isotherms at air-water interface. And then the surface pressure shift of monolayer by light irradiation was also measured to the dendrimer with azobezene group. As a result, the monolayer of dendrimer with azobenzene group showed the reversible photo-switching behavior by the isomerization of azobenzene group in their periphery. This results suggest that the dendrimers with azobenzene group can be applied to high efficient nano-device of molecular level. And we measured the electrical properties by MIM and STM. The dendrimer with azobenzene group compared trans form and cis form at electrical properties.

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The Syntheses and Application of NIR Dyes Based On Light Absorbing Properties

  • Park, Soo-Youl;Shin, Seung-Rim;Shin, Joung-Il;An, Kyoung-Lyong;Lee, Sang-Oh;Jun, Kun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2010.03a
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    • pp.49-50
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    • 2010
  • The near-infrared absorbing donor-acceptor chromophores have been investigated by varying the electron donating and accepting molecular moiety. A series of near-infrared absorbing chromophores were offered narrow and intense absorption band in a various organic solvents. The dyes synthesised were, however, strongly bathochromic shift which extended well into the near-infrared region. The functional uses of dyes are vast in number, and it is convenient to classify them in some way. In all cases, it is the $\Pi$-chromophore that plays a major role in the functional application. "Light absorption" is of course the most commonly used property of a dye chromophore, and it can be employed directly, e.g. in light filters and optical data recording, or it can be used to drive further functional processes, e.g. fluorescence, photochromism, photosensitization.

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