• Title/Summary/Keyword: the other air pollutants

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Exposure and Toxicity Assessment of Ultrafine Particles from Nearby Traffic in Urban Air in Seoul, Korea

  • Yang, Ji-Yeon;Kim, Jin-Yong;Jang, Ji-Young;Lee, Gun-Woo;Kim, Soo-Hwan;Shin, Dong-Chun;Lim, Young-Wook
    • Environmental Analysis Health and Toxicology
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    • v.28
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    • pp.7.1-7.9
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    • 2013
  • Objectives We investigated the particle mass size distribution and chemical properties of air pollution particulate matter (PM) in the urban area and its capacity to induce cytotoxicity in human bronchial epithelial (BEAS-2B) cells. Methods To characterize the mass size distributions and chemical concentrations associated with urban PM, PM samples were collected by a 10-stage Micro-Orifice Uniform Deposit Impactor close to nearby traffic in an urban area from December 2007 to December 2009. PM samples for in vitro cytotoxicity testing were collected by a mini-volume air sampler with $PM_{10}$ and $PM_{2.5}$ inlets. Results The PM size distributions were bi-modal, peaking at 0.18 to 0.32 and 1.8 to $3.2{\mu}m$. The mass concentrations of the metals in fine particles (0.1 to $1.8{\mu}m$) accounted for 45.6 to 80.4% of the mass concentrations of metals in $PM_{10}$. The mass proportions of fine particles of the pollutants related to traffic emission, lead (80.4%), cadmium (69.0%), and chromium (63.8%) were higher than those of other metals. Iron was the dominant transition metal in the particles, accounting for 64.3% of the $PM_{10}$ mass in all the samples. We observed PM concentration-dependent cytotoxic effects on BEAS-2B cells. Conclusions We found that exposure to $PM_{2.5}$ and $PM_{10}$ from a nearby traffic area induced significant increases in protein expression of inflammatory cytokines (IL-6 and IL-8). The cell death rate and release of cytokines in response to the $PM_{2.5}$ treatment were higher than those with $PM_{10}$. The combined results support the hypothesis that ultrafine particles from vehicular sources can induce inflammatory responses related to environmental respiratory injury.

Investigation into Air Pollution in Car Shipping Workshop in Pyeongtaek Port (자동차 선적작업장의 공기오염 실태조사)

  • Kim, Ji-Ho;Won, Jong-Uk;Kim, Chi-Nyon;Roh, Jaehoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.1
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    • pp.44-53
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    • 2006
  • This study purposed to investigate air pollution in car shipping yards and, for this purpose, we selected an outdoor open-air yard and an indoor ramp into the ship and measured the concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10, PM2.5 and heavy metals in the air. The results of this study are as follows. No significant difference was observed in temperature and humidity between the outdoor and indoor workshop, and the average air flow was 0.52 m/s in the indoor workshop, which is higher than 0.19 m/s in the outdoor workshop(p<0.01). The average concentrations of sulfur dioxide, nitrogen dioxide, carbon monoxide, PM10 and PM2.5 according to workplace were 0.03 ppm(${\pm}0.01$), 0.03 ppm(${\pm}0.01$), 0.46 ppm(${\pm}0.22$), $39.44{\mu}g/m^3$(${\pm}2.45$) and $5.45{\mu}g/m^3$(${\pm}1.15$) respectively in the outdoor workshop, and 0.15 ppm(${\pm}0.05$), 0.22 ppm(${\pm}0.06$), 8.85 ppm(${\pm}3.35$), $236.39{\mu}g/m^3$(${\pm}58.21$) and $152.43{\mu}g/m^3$(${\pm}35.42$) respectively in the indoor workshop. Thus, the concentrations of gaseous substances in the indoor workshop were 4.9-19.2 times higher than those in the outdoor workshop, and the concentrations of fine dusts were 5.9-27.9 times higher(p<0.01). In addition, according to the result of investigating pollutant concentrations according to displacement and the number of car loaded when shipping gasoline cars into the ship, no significant relation between the number of cars loaded and pollutants was observed in shipping passenger cars, but the concentrations of nitrogen dioxide and carbon monoxide got somewhat higher with the increase of the number of cars loaded(p<0.05). In addition, the concentrations of nitrogen dioxide, carbon monoxide, PM10 and PM2.5 in the air were significantly higher when shipping recreational vehicles, the displacement of which is larger than passenger cars, than when shipping passenger cars(p<0.01). On the other hand, the average heavy metal concentrations of the air in indoor workshop were: lead $-0.05{\mu}g/m^3$(${\pm}0.10$); chromium $-0.90{\mu}g/m^3$(${\pm}0.18$); zinc $-0.38{\mu}g/m^3$(${\pm}0.24$); copper $-0.18{\mu}g/m^3$(${\pm}0.22$); and manganese and cadmium not detected. In addition, the complaining rates of 'asthma,' a major symptom of chronic respiratory diseases, were 18.5% and 22.5% respectively in indoor workers and outdoor workers. Thus the rate was somewhat higher in indoor workers but the difference was not statistically significant. The complaining rates of 'chronic cough' and 'chronic phlegm' were very low and little different between indoor and outdoor workers. The results of this study show that the reason for the higher air pollution in indoor than in outdoor workshop is incomplete combustion of fuel due to sudden start and over-speed when cars are driven inside the ship. In order to prevent high air pollution, efficient management measures should be taken including the observance of the optimal speed, the improvement of old ships and the installation of efficient ventilation system.

Long-term Trend Analysis of NOx and SOx over in East Asia Using OMI Satellite Data and National Emission Inventories (2005-2015) (OMI 위성 자료와 국가 배출량 자료를 활용한 동아시아의 NOx, SOx 변화 장기 분석(2005-2015))

  • Seo, Jeonghyeon;Yoon, Jongmin;Choo, Gyo-Hwang;Kim, Deok-rae;Lee, Dong-Won
    • Korean Journal of Remote Sensing
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    • v.36 no.2_1
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    • pp.121-137
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    • 2020
  • Data from the Ozone Monitoring Instrument (OMI) satellite and national emission inventories were used in this study to analyze air quality in East Asia and estimate the impact of domestic and foreign emissions on South Korea's air quality, based on which future emissions were predicted. The concentration trends of nitrogen dioxide (NO2) and sulfur dioxide (SO2) in East Asia from 2005 to 2015 showed that both substances were highest in North East China (NEC), followed by South East China (SEC) and Seoul Metropolitan Area (SMA). The average SO2 concentration was 1.63 times higher in NEC than in SMA. Analysis on the ratios of NO2/SO2 and NOx/SOx provides an indirect picture of the effect of transboundary air pollutants on atmospheric composition in Korea. The concentration ratio of NO2/SO2 in all study areas peaked in 2013 and SMA's emission ratio of NOx/SOx increased in 2015 by over 22% from 2013. Despite the reduction in domestic emissions, the concentration-to-emission ratios (NO2/NOx, SO2/SOx) rose gradually, which implies that other factors besides domestic emissions (e.g., foreign sources, lifetime, etc.) influence air quality in SMA. We estimated future emissions of NOx and SOx in SMA to be 296.2 and 39.0 ktons in 2025 and 284.4 and 33.8 ktons in 2035, respectively. Application of the inter-comparison techniques of this study to the data from the Geostationary Environment Monitoring Instrument (GEMS) is expected to provide concrete information which can be used to improve national emission inventories and figure out factors and sources that affect domestic air quality.

Emission Characteristics of Volatile Organic Compounds by Humidifier with Using Hinoki Cypress Extracts (편백잎추출수의 실내 가습시 휘발성유기화합물 방출 특성)

  • Lee, Min;Park, Sang-Bum;Lee, Sang-Min;Lee, Hee-Young;Kil, Duck-Han
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.747-757
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    • 2014
  • Since the air contamination by air pollutants from indoor construction materials and daily supplies has been increased in recent decades, the public interest of using environmentally friendly products and improving indoor air quality also attracted much attention. As known as effects of phytoncide, it has been used in construction materials and daily supplies with various method. In this study, hinoki cypress (Chamaecyparis obtusa) was used because of its high contents of phytoncide. The leaves of hinoki cypress (C. obtusa), which generated by pruning, were extracted by steam distillation, and then used as humidification water source. Volatile organic compound (VOC) from C. obtusa were characterized by GC-MS (Gas chromatograph-Mass spectrophotometry) in order to evaluate effects and risks of using C. obtusa extracts. Total 86 types and 116 types of VOC were detected from distilled water (DI water) and C. obtusa extracts, respectively. Aromatic compounds (DI water: 13 types, 53%; C. obtusa extracts: 13 types, 38%) and terpenoids (DI water: 16 types, 23%; C. obtusa extracts: 23 types, 33%) were detected more diverse types and higher amount than other compound categories. No additional aromatic compounds were found from C. obtusa extracts, so C. obtusa extracts did not affect on aromatic compounds emission. However, in terpenoids, total amount of emission from C. obtusa extracts increased to 33% from 23% (DI water) and 7 more types of compounds were found from C. obtusa extracts. Especially, from C. obtusa extracts, terpinen-4-ol was emitted 71 times higher than DI water. During the humidification with C. obtusa extracts, emitted terpenoid compounds were well known for higher anti-bacterial, anti-insect, and anti-septic functions, but also these had anti-hypertensive and anti-cancer activities. Therefore, terpenoids from C. obtusa extracts can help to improve public health by using humidifier.

Study on the assessment methodology for the PM10 generated from tire-dust considering the axle load of the truck according to the loading method (화물차 적재 방식에 따른 축 하중을 고려한 타이어 먼지 중 PM10 발생량 평가기법 연구)

  • Lee, Eunjeong;Lee, Heekwan
    • Journal of Urban Science
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    • v.11 no.2
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    • pp.45-54
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    • 2022
  • Recently, regulations on automobile exhaust gas emission are being strengthened. Accordingly, automobile exhaust gas emissions are expected to decrease and continue to decrease. On the other hand, many countries do not yet consider the emission of non-exhaust air pollutants from automobiles as important. Automobile non-exhaust substances are classified into three categories: tire dust emissions, brake wear emissions, and road scattering dust. In particular, in the case of tire dust, research results exist that pollutant emissions increase as the weight of a vehicle increases. Since the weight of trucks varies according to the load and the load along the axles is also different, it can be expected that the emission of PM10 from the tire dust will be different depending on the loading method. Therefore, this study was conducted on the amount of PM10 generated in tire dust considering the axle load of the truck according to the loading method. However, it was confirmed that the total amount of PM10 was less than that all loads are loaded in the front or rear when the load was evenly distributed in the front and rear of the cargo compartment. In particular, if the load is distributed evenly in the front and back of the cargo compartment and the load in the front part is divided into 2 to 6 and loaded, as the number of divided loading increases the amount of PM10 generated decreases. And when the load is divided into 6 pieces, the total amount of PM10 generated is 0.3952g, the minimum value. If the load is divided into 6 or more and loaded evenly, the total PM10 generated continuously increases and converges to about 0.3964g.

Variation Characteristics of TSP Ionic Compositions by Meteorological Phenomena in Jeju Island (기상현상에 따른 제주지역 TSP의 이온조성 변화 특성)

  • Ko, Hee-Jung;Kim, Won-Hyung;Lee, Seung-Hoon;Bu, Jun-Oh;Kang, Chang-Hee;Hu, Chul-Goo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.723-733
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    • 2011
  • The ionic compositions were analyzed from the TSP samples collected at Gosan site in Jeju Island between 2000 and 2008, in order to examine the characteristics of atmospheric aerosols in accordance with the meteorological conditions. For the Asian Dust influence on the ionic compositions, the concentration ratios of $NH_4{^+}$, nss-${SO_4}^{2-}$, $NO_3{^-}$, and $K^+$ were about 1.2~2.3 during Asian Dust over Non-Asian Dust periods, noticeably that of nss-$Ca^{2+}$ was 6.8. Meanwhile the concentrations of nss-${SO_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ have increased as 1.8~4.4 times during the haze event periods, and 1.0~1.6 times during the fog and mist events. The ion balance has resulted that the anionic concentrations are relatively lower than the cationic concentrations, and the discrepancy appears more decidedly as a strong Asian Dust effect. The ammonium ion balance has shown that it exists as a mixture of $NH_4HSO_4$ and $(NH_4)_2SO_4$. The concentration ratios of nss-${SO_4}^{2-}/NO_3{^-}$ for Asian Dust, haze, fog-mist, and non-event periods were respectively 1.8, 5.9, 4.6, and 2.9, which were higher values compared to those in urban areas of China as well as other domestic regions. Especially, the high ratios of sulfur oxides could be presumed by the fact that the longrange transport of air pollutants from Asia continent might affect the atmospheric aerosols of Jeju Island.

Environmental geochemistry of persistent organic pollutants in the Pearl River Delta

  • Peng Ping'an;Fu Jiamo;Sheng Guoying;Xiao Xianming;zhang Gan;Wang Xinming;Mai Bixian;Ran Rong;Cheng Fanzhong
    • Proceedings of the KSEEG Conference
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    • 2002.04a
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    • pp.8-10
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    • 2002
  • POPs in sediments and soil in the PRD are comparable to or much higher than those reported in other regions. Some sites may be classified as POPs- polluted with high ecological risks. Large-scale land transform in the process of regional urbanization may facilitate the transfer of POPs in the soil to the sedimentary system by enhancing the soil run-off. Urban atmospheric PCBs in PRD are found to be less than some of the North American or European urbans, but PAHs are significantly higher. The center of the PRD has been the major source area of PAHs and organochlorine pesticides in the PRD. The northern part of the PRD serves as a regional sink for the air particulates and affiliated POPs.

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Utilization of Element-doping Titania-impregnated Granular Activated Carbon in a Plug-flow System for Removal of BTEX

  • Jo, Wan-Kuen;Shin, Seung-Ho;Hwang, Eun-Song;Yang, Sung-Bong
    • Asian Journal of Atmospheric Environment
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    • v.4 no.3
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    • pp.177-188
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    • 2010
  • The use of an activated carbon (AC) system alone has the limitation that the pollutants are not eliminated but only transferred to another phase with the consumed AC becoming hazardous waste itself. Therefore, the present study investigated the feasibility of using a combined system of granular AC (GAC) with S-doped visible-light-induced $TiO_2$ (GAC/S-doped $TiO_2$) to clean monocyclic aromatic hydrocarbons (MAHs) with concentrations at $\leq$ 3 mg $m^{-3}$, using a continuous air-flow reactor. This study conducted three different experiments: an adsorption test of pure GAC and GAC/S-doped $TiO_2$; a long-term adsorptional photocatalytic (AP) activity test of GAC/S-doped $TiO_2$; and an AP activity test of GAC/S-doped $TiO_2$ under different conditions. For the AP activity test, three parameters were evaluated: various weights of GAC/S-doped $TiO_2$ (0.9, 4.4, and 8.9 g); various flow rates (FRs) (0.5, 1 and 2 L $min^{-1}$); and various input concentrations (ICs) of the target MAHs (0.1, 1, 2 and 3 mg $m^{-3}$). The adsorption efficiencies were similar for the pure GAC and GAC/S-doped $TiO_2$ reactors, suggesting that S-doped $TiO_2$ particles on GAC surfaces do not significantly interfere with the adsorption capacity of GAC. Benzene exhibited a clear AP activity, whereas no other target MAHs did. In most cases, the AP efficiencies for the target MAHs did not significantly vary with an increase in weight, thereby suggesting that, under the weight range tested in this study, the weights or FRs are not important parameters for AP efficiency. However, ICs did influence the AP efficiencies.

Behavior of Formaldehyde Concentration by Temperature and Humidity of Indoor and Outdoor in Underground Shopping Center and Subway(II) (지하상가 실내외 및 지하철의 온도와 습도에 따른 Formaldehyde 거동(II))

  • 권우택
    • Journal of environmental and Sanitary engineering
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    • v.9 no.1
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    • pp.67-75
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    • 1994
  • Formaldehyde has been in widespread industrial use since World War II . Numerous sources of formaldehyde are present in the indoor environment. Additionally, the current trend toward tighter, more energy efficient buildings with lower ventilation rates has led to increase concentrations of this and other pollutants generated indoors. In this paper, the field survey was carried out once a month from January to MarctL 1994 to measure indoor and outdoor formaldehyde concentration in several underground locations in Seoul. The results could be summarized as follows : 1. At Yang- jae underground shopping center, the mean formaldehyde concentration was 77.8ppb for indoor and 68.4ppb for outdoor. At Ban- po underground shopping center, it was 175.8ppb for indoor and 127.3ppb for outdoor. At Jam- shil underground shop ping center, it was 135.2ppd for indoor and 34.6ppb for outdoor. Indoor the No.2 sub way line, it was 105.6ppb. The formaldehyde concentration using Berge equation was as follows : At Yang- jae underground shopping center, the mean formaldehyde concentration was 85.99ppb for indoor and 72.75ppb for outdoor At Ban- po underground shopping center, it was 254. 17ppb for indoor and 138.14ppb for outdoor. At Jam- shil underground shopping center, it was 249.13ppb for indoor and 36.87ppb for outdoor. Indoor the No.2 subway line, it was 131.73ppb. 3, The result of correlation analysis indicated that the relationship between temperature and formaldehyde concentration is very high( $\gamma $= 0.831 ∼ 0.974). 4. Also, the relationship between humidity and formaldehyde concentration is variant ($\gamma $ = 0.246 ∼0.999). 5. The mean formaldehyde concentration indoor and outdoor Ban- po underground shop ping center and indoor Jam- shil underground shopping center and indoor the No.2 sub way line exceed the American Society of Heating, Refrigeration, Air- conditioning Engineers( ASHRAE) stflndard of 100ppb(120 $\mu $g/m$^{3}$).

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Interpretation of the Chemical Transformation of Individual Asian Dust Particles Collected on the Western Coast of Korean Peninsula

  • Ma, Chang-Jin;Kim, Jong-Ho;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.6 no.1
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    • pp.14-22
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    • 2012
  • This paper is focused on the comprehensive and detailed interpretation for the chemical transformation of individual Asian dust (hereafter called "AD") particles during long-range transport from source regions to receptor area. A multi-stage particle sampler was operated at a ground-based site in Taean, Korea directly exposed to the outflow of air masses from China during AD period in April 2003. Both quantitative and qualitative analyses for size-classified individual particles were carried out by a microbeam X-ray fluorescence (XRF) method and a microbeam Particle Induced X-ray Emission (micro-PIXE), respectively. Among major characteristic elements, the elemental masses of soil derived components, sulfur, and chloride varied as a function of particle size showing the monomodal maximum with a steeply increasing at 3.3-4.7 ${\mu}m$ particle size. Although the details on chemical composition of AD particle collected on a straight line from source area to our ground-based site are needed, a large amount of Cl coexisted in and/or on AD particles suggests that AD particles collected in the present study might be actively engaged in chemical transformation by sea-salt and other Cl containing pollutants emitted from the China's domestic sources. Through the statistical analyses it was possible to classify individual AD particles into six distinct groups. The internally mixed AD particles with Cl, which has various sources (e.g., sea-salt, coal combustion origin HCl, gaseous HCl derived from the adsorption of acids to sea-salt, and Cl containing man-made particles) were thoroughly fractionated by the elemental spectra drivened by the double detector system of micro-PIXE.