• Title/Summary/Keyword: ternary composite

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Synthesis and Characteristics of New Quaternary Superhard Ti-Mo-Si-N Coatings (새로운 고경도 Ti-Mo-Si-N 코팅막의 합성 및 기계적 특성)

  • Jeon, Jin-Woo;Hong, Seung-Gyun;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.39 no.6
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    • pp.245-249
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    • 2006
  • In this study, ternary Ti-Mo-N and new quaternary Ti-Mo-Si-N coatings were synthesized on steel substrates(AISI D2) and Si wafers by a hybrid coating system of arc ion plating (AIP) using Ti target and d.c. magnetron sputtering technique using Mo and Si targets in $N_2/Ar$ gaseous mixture. Ternary Ti-Mo-N coatings were substitutional solid-solution of (Ti, Mo)N and showed maximum hardness of approximately 30 GPa at the Mo content of ${\sim}10$. %. The Ti-Mo-Si-N coating with the Si content of 8.8 at. % was a composite consisting of fine (Ti, Mo)N crystallites and amorphous $Si_3N_4$ phase. The hardness of the Ti-Mo-Si(8.8 at. %)-N coatings exhibited largely increased hardness value of ${\sim}48$ GPa due to the microstructural evolution to the fine composite microstructure and the refinement of (Ti, Mo)N crystallites. The average friction coefficient of the Ti-Mo-Si-N coatings largely decreased with increase of Si content. The microstructures of Ti-Mo-Si-N coatings were investigated with instrumental analyses of XRD, XPS, and HRTEM in this work.

The mechanical properties of Reactive Powder Concrete using Ternary Pozzolanic Materials exposed to high Temperature (3성분계 포졸란재를 이용한 반응성 분체 콘크리트(RPC)의 고온특성)

  • Janchivdorj, Khulgadai;So, Hyoung-Seok;Yi, Je-Bang;So, Seung-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.68-71
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    • 2013
  • Reactive Powder Concrete (RPC) is an ultra high strength and high ductility cement-based composite material and has shown some promise as a new generation concrete in construction field. It is characterized by a silica fume-cement mixture with very low water-binder (w/b) ratio and very dense microstructure, which is formed using various powders such as cement, silica fume and very fine quartz sand (0.15~0.4mm) instead of ordinary coarse aggregate. However, the unit weight of cement in RPC is as high as 900~1,000 kg/㎥ due to the use of very fine sand instead of coarse aggregate, and a large volume of relatively expensive silica fume as a high reactivity pozzolan is also used, which is not produced in Korea and thus must be imported. Since the density of RPC has a heavy weight at 2.5~3.0 g/㎤. In this study, the modified RPC was made by the combination of ternary pozzolanic materials such as blast furnace slag and fly ash, silica fume in order to economically and practically feasible for Korea's situation. The fire resistance and structural behavior of the modified RPC exposed to high temperature were investigated.

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Fluorescence Spectroscopic and Atomic Force Microscopic Studies on the Microstructure of Polyimide/Silica-Titania Ternary Hybrid Composites

  • Park, Hae-Dong;Ahn, Ki-Youl;Mohammad A. Wahab;Jo, Nam-Ju;Kim, Il;Kim, Gyuhyun;Lee, Won-Ki;Ha, Chang-Sik
    • Macromolecular Research
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    • v.11 no.3
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    • pp.172-177
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    • 2003
  • Biphenyltetracarboximide-phenylene diamine polyimide/silica-titania ternary hybrid composites were Prepared by thermal imidization and sol-gel reaction. Fluorescence spectroscopic, scanning electron microscopy, and atomic force microscopy studies revealed that the addition of small amount of titania showed profound effects on the microstructure and photophysical behaviors of polyimide/silica hybrid composites, when the content of silica-titania mixture was small or when the ratio of silica to titania in the mixture was high.

Molecular Composite of Cellulose Triacetate and Polyester (I) - Solution Property- (셀루로오즈 트리아세테이트와 폴리에스테르의 분자복합체(I) -용액 성질-)

  • Hong, Young-Keun
    • Textile Coloration and Finishing
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    • v.3 no.4
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    • pp.17-21
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    • 1991
  • A rigid polymer, cellulose triacetate (CTA) dissolved in a combination of trifluoroacetic acid (TFA) and methylene chloride (MC) solution are liguid crystalline above a certain concentration. A flexible polymer, polyethylene terephthalate (PET) also dissolves in TFA/MC, but does not form liguid crystal phase. Ternary solutions, CTA/PET/TFA-MC which CTA and PET were mixed in a same solvent TFA/MC (6/4 : v/v) showed phase separation and mesophase formation.

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Composite Coating of Nickel-Boron Nitride-Phosphours and Nickel-Boron Nitride-Boron Ternary System on Aluminum (알루미늄에 니켈-질화붕소-인과 니켈-질화붕소-붕소의 3원계 복합도금)

  • Kuak Woo-Sup;Yoon, Byung-Ha;Kim, Dai-Ryong
    • Journal of the Korean institute of surface engineering
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    • v.19 no.3
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    • pp.83-91
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    • 1986
  • Codeposited of boron nitride(BN) particle dispersed into electroless nickel-phosphours (Ni-P) and nickel-boron(Ni-B) platings were studied for the purpose of developing the wear resistance and lubricity. BN can be codeposited from electroless nickel plating bath with $NaH_2PO_2$ and $NaBH_4$ as the reducing agents. Most dispersolids were distributed uniformly in the Ni-P and Ni-B matrix. Abrasion loss decreased with increasing amount of codeposits and reached a constant value 2.4 percent by volume percent of BN particle. The wear resistance and the friction coefficient of the heat treated BN composite coatings were improved about three times than that of as-coatings. The BN composite coatings were more wear resistance than hard chromium. Ni-B-BN composite coatings showed lower wear resistance and friction coefficient than Ni-P-BN. The BN content of the deposite was found to be 2.4 v/o for these optium conditions.

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The Dynamic Properties of the Artificial Stone According to the Mixed Ratio Change of the Inorganic Composite and Waste Porcelain (폐자기와 3성분계 무기결합재의 혼합비율 변화에 따른 인조석재의 역학적 특성)

  • Yoo, Yong Jin;Bae, Sang Woo;Lee, Sang Soo;Song, Ha Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.95-96
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    • 2012
  • This study makes with the environment-friendly artificial stone which doesn't use the cement and natural aggregate and increases the blast furnace slag that is the eco-friendly material that is the industrial byproduct, fly ash, and availability of the red mud and applies the coares aggregate substitute material as the cleistothecium. The experimental plan according to it indicated the compressive strength and flexural strength which is the most excellent in the mixied ratio 40% of the result degree of closeness magnetism of experimenting with the optimal mix obtained through the preceding stude.

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Fabrication of $TiB_2$-W Composite by SHS Method (SHS 법에 의한 $TiB_2$-W 복합재료 제조에 대한 연구)

  • 이형복;강석원;이재원;박원석
    • Journal of the Korean Ceramic Society
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    • v.37 no.9
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    • pp.915-920
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    • 2000
  • 합성과 동시에 소결이 이루어지는 HPCS법을 이용하여 TiB$_2$-W 복합체를 텅스텐의 함량 변화에 다라 제조하여 이 복합체의 미세구조 및 기계적 물성에 대하여 연구하였다. 이 연구 결과, 텅스텐의 함량증가에 따라 삼성분 붕화 화합물인 TiWB$_2$의 상이 증가하였으며, 이 상의 증가에 따라 기계적 물성이 향상되었다. 60 MPa의 압력과 130$0^{\circ}C$, 3000 A에서 소결한 TiB$_2$-30vol% W 복합체에서 상대밀도, 강도, 경도 값은 각각 97.2%, 411.5 MPa, 22.36 GPa로 가장 우수한 물성을 얻을 수 있었다.

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New Efficient Scalar Multiplication Algorithms Based on Montgomery Ladder Method for Elliptic Curve Cryptosystems (타원곡선암호시스템에서 Montgomery ladder 방법에 기반한 새로운 스칼라 곱셈 알고리즘)

  • Cho, Sung-Min;Seo, Seog-Chung;Kim, Tae-Hyun;Park, Yung-Ho;Hong, Seok-Hie
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.19 no.4
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    • pp.3-19
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    • 2009
  • This paper proposes efficient scalar multiplication algorithms based on Montgomery ladder method. The proposed algorithm represents the scalar as ternary or quaternary and applies new composite formulas utilizing only x coordinate on affine coordinate system in order to improve performance. Furthermore, side-channel atomicity mechanism is applied on the proposed composite formulas to prevent simple power analysis. The proposed methods saves at least 26% of running time with the reduced number of storage compared with existing algorithms such as window-based methods and comb-based methods.

An Experimental Study for Improving the Early Strength of Ternary Blended Cement Mortar (삼성분계 혼합시멘트 모르타르의 조기강도 향상을 위한 실험적 연구)

  • Bae, Jun-Young;Jang, Young-Il
    • Composites Research
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    • v.25 no.4
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    • pp.110-116
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    • 2012
  • Recently, the development and field applications of Ternary Blended Cement(TBC), where blast furnace slag and fly ash are recycled in Ordinary Portland Cement(OPC) in order to obtain improvements in the durability and heat of hydration reduction performance in large scale civil structures, have been increasing. Also, there are continuing efforts by construction companies to reduce the construction time with the aim of reducing construction costs. Therefore, there is a need to improve the performance of TBC, which has a relatively slow early strength development. In order to improve the early strength of TBC mortar, the compressive strength, SO3 content, and SEM analysis was determined in this study on mortar with the fineness and content of blast furnace slag and anhydrite regulated. As a result, to secure the early strength of TBC mortar, using blast furnace slag with a fineness of approximately $4,200cm^2/g$, adding 3.5% anhydrite with a fineness of approximately $10,000cm^2/g$, and managing the $SO_3$ content to roughly 3.72% was found to provide the most outstanding early strength properties.

Mechanical properties of SFRHSC with metakaolin and ground pumice: Experimental and predictive study

  • Saridemir, Mustafa;Severcan, Metin Hakan;Celikten, Serhat
    • Steel and Composite Structures
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    • v.23 no.5
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    • pp.543-555
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    • 2017
  • The mechanical properties of steel fiber reinforced high strength concrete (SFRHSC) made with binary and ternary blends of metakaolin (MK) and ground pumice (GP) are investigated in this study. The investigated properties are ultrasonic pulse velocity ($U_{pv}$), compressive strength ($f_c$), flexural strength ($f_f$) and splitting tensile strength ($f_{st}$) of SFRHSC. A total of 16 steel fiber reinforced concrete mixtures were produced by a total binder content of $500kg/m^3$ for determining the effects of MK and GP on the mechanical properties. The design $f_c$ was acquired from 70 to 100 MPa by using a low water-binder ratio of 0.2. The test results exhibit that high strength concrete can be obtained by replacing the cement with MK and GP. Besides, correlations between these results are executed for comprehending the relationship between mechanical properties of SFRHSC and the strong correlations are observed between these properties. Moreover, two models in the gene expression programming (GEP) for predicting the $f_c$ of SFRHSC made with binary and ternary blends of MK and GP have been developed. The results obtained from these models are compared with the experimental results. These comparisons proved that the results of equations obtained from these models seem to agree with the experimental results.