• Title/Summary/Keyword: tensile index

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Physical Characterization and Contact Lens Application of Polymer Produced with Propylene Glycol Additive (프로필렌 글리콜을 첨가제로 사용한 고분자재료의 물성 및 콘택트렌즈 응용)

  • Kim, Tae-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.105-109
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    • 2010
  • HEMA (2-hydroxyethyl methacrylate), EGDMA (ethylene glycol dimethacrylate) and propylene glycol was copolymerized in the presence of AIBN (azobisisobutyronitrile) initiator in a mould. The physical properties of the contact lens were measured. The water content of 37.06~38.71%, refractive index of 1.492~1.432, visible transmittance of 89.4~91.5%, tensile strength of 0.1416~0.2302 kgf, and contact angle of $38.60{\sim}53.53^{\circ}$ were obtained. Therefore, the contact lens material produced using propylene glycol as an additive satisfied the basic physical properties required for contact lenses application. It is interesting to note that an increase in wettability and tensile strength while having no significant changes in water content.

Mechanical Properties of Concrete Pavement by Low Fraction of Macro Fiber (매크로 섬유의 저혼입에 따른 콘크리트 포장의 역학적 특성)

  • Choi, Sung-Yong;Park, Young-Hwan;Jung, Woo-Tai;Park, Jong-Sup
    • International Journal of Highway Engineering
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    • v.14 no.6
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    • pp.1-11
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    • 2012
  • PURPOSES : The purpose of the study was to examine dynamic features of concrete after mixing a little macro fiber with small aspect ratio and long length utilized for bridge, tunnel and shotcrete for tensile performance and crack control in domestic/overseas countries with cement concrete pavement mix. METHODS : Coarse aggregates with small aspect ratio and macro fibers with maximum length of approximately 32 mm are introduced in small quantities in the mix proportions of concrete pavement so as to prevent loss of the workability. Then, this study intends to evaluate the applicability of macro fibers in the mix proportions of concrete pavement by examining the basic construction performance, as well as the change of toughness, the equivalent bending strength and the flexural toughness index caused by compression, bending, tension and the flexural stress-displacement curve. RESULTS : As the results, in each kind of macro fiber, polyvinyl alcohol fiber and steel fiber displayed a good performance. CONCLUSIONS : In 0.2 and 0.3% of fiber contents, it is appeared that polyvinyl alcohol fiber has a large effect on improvement of tensile performance and steel fiber on improvement of deforming performance of bending stress.

Analysis of Physical and Antibacterial Properties of Functional Silicone Hydrogel Ophthalmic Lenses Containing Graphene Groups

  • Su-Mi Shin;Hye-In Park;A-Young Sung
    • Korean Journal of Materials Research
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    • v.33 no.1
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    • pp.1-7
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    • 2023
  • The physical and antibacterial properties of ophthalmic lenses fabricated by copolymerization with hydrogel monomers using two types of graphene were measured, and their usability as contact lens materials was analyzed. For polymerization, silicone monomers, including SID-OH, 3-(methacryloxy)propyl tris(trimethylsiloxy)silane, and decamethylcyclopentasiloxane, were used, and N,N-dimethylacetamide, ethylene glycol dimethacrylate as a crosslinking agent, and azobisisobutyronitrile as an initiator were added. Also, graphene oxide nanoparticle (GON) and graphene nanoplate (GNP) were used as an additive, and the physical properties of the lenses fabricated after copolymerization were evaluated. The fabricated lenses satisfied the basic physical properties of general hydrogel contact lenses and showed the characteristics of lenses with high water content, and the disadvantage of very weak durability, due to low tensile strength. However, it was confirmed that the tensile strength and antibacterial properties were greatly improved by adding GON and GNP. With GON, the oxygen permeability and refractive index of the fabricated lenses were slightly improved. Therefore, it was determined that the graphene materials used in this study can be used in various ways as a contact lens material.

Strength Modeling of Mechanical Strength of Polyolefin Fiber Reinforced Cementitious Composites

  • Sakthievel, P.B.;Ravichandran, A.;Alagumurthi, N.
    • Journal of Construction Engineering and Project Management
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    • v.4 no.2
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    • pp.41-46
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    • 2014
  • RCC consumes large quantities of natural resources like gravel stone and steel, and there is a need to investigate on an innovative material that utilizes limited quantities of natural resources but should have good mechanical strength. This study deals with the experimental investigation of strength evaluation of cementitious composites reinforced with polyolefin fibers from 0% to 2.5% (with interval of 0.5%), namely Polyolefin Fiber Reinforced Cementitious Composites (PL-FRCC) and developing statistical regression models for compressive strength, splitting-tensile strength, flexural strength and impact strength of PL-FRCC. Paired t-tests (for each PL fiber percentage 0 to 2.5%) bring out that there is significant difference in compressive and splitting-tensile strength when curing periods (3, 7, 28 days) are varied. Also, a strong relationship exists between the compressive and flexural strength of PL-FRCC. The proposed mathematical models developed in this study will be helpful to ascertain the mechanical strength of FRCC, especially, when the fiber reinforcing index is varied.

A Study on the Applicability of Shrinkage Reduction Effect of Light-weight Aggregate Concrete (경량골재 콘크리트의 수축 저감효과에 관한 적용성 연구)

  • Lim, Sang-Jun;Bang, Chang-Joon;Park, Jong-Hyok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.175-176
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    • 2011
  • Applying previous studies performed in the moisture transportation characteristics and shrinkage of lightweight concrete application of shrinkage reduction is to discuss. Applicability of shrinkage reduction effect of lightweight concrete applies for the analysis of PSC girder bridge beam placed on the construction site. Stress of the concrete bridge deck, rebar quantity is calculated by effective elastic modulus method and crack risk is assessed by moisture transport and differential shrinkage analysis. After approximately 10 days maximum tensile stress occurs 6MPa, similar to the case of normal concrete, a maximum tensile stress occurs 3MPa in lightweight concrete and comparing to normal concrete stress was reduced to approximately 50%. Normal and lightweight concrete crack index, respectively, is reduced 1.6 to 1.2, 1.2 to 0.9 in surface and boundary region. Therefore, reduction in shrinkage of concrete were able to confirm reduction of crack risk.

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New Functional Conductive Polymer Composites Containing Nickel Coated Carbon Black Reinforced Phenolic Resin

  • Farid El-Tantawy;Nadia Abdel Aal;Yong Kiel Sung
    • Macromolecular Research
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    • v.13 no.3
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    • pp.194-205
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    • 2005
  • The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

Stabilization of pitch-based carbon fibers accompanying electron beam irradiation and their mechanical properties

  • Park, Mi-Seon;Ko, Yoonyoung;Jung, Min-Jung;Lee, Young-Seak
    • Carbon letters
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    • v.16 no.2
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    • pp.121-126
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    • 2015
  • Carbon fibers are prepared by stabilizing pitch fibers accompanying electron beam (E-beam) irradiation. The carbon fibers pretreated by E-beam irradiation achieve a higher stabilization index than the carbon fibers that are only heat-stabilized. In addition, the carbon fibers subjected to E-beam irradiation in the stabilization step exhibit a comparable tensile strength to that of general purpose carbon fibers. The carbon fibers pretreated with an absorbed dose of 3000 kGy have a tensile strength of 0.54 GPa for a similar fiber diameter. Elemental, Fourier-transform infrared spectroscopy, and thermogravimetric analyses indicate that E-beam irradiation is an efficient oxidation and dehydrogenation treatment for pitch fibers by showing that the intensity of the aliphatic C-H stretching and aromatic $CH_2$ bending (out-of-plane) bands significantly decrease and carbonyl and carboxylic groups form.

The Study on the Wedding Dress Design by Using the Korean Paper - The Focus on the Ornamental Details- (한지를 이용한 웨딩드레스 디자인 연구 - 장식적 디테일을 중심으로 -)

  • 이수정;채선미
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.4
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    • pp.75-80
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    • 2003
  • The purpose of this study was to design wedding dress by using Korean paper(Hanji). The Korean paper showed the good(excellent) properties of durability, softness, and tensile strength was 3.7Kg, tear index was 6 mN$.$$m_2$/g and folding numbers was 466. The appreance of Hanji was widely varied by blending(mixing) with other materials and various effects, pleating, crumpling, twisting and so on were achieved. The dress silhouette and form transformation of Hanji was very easy. Detailed points those are frill, pleats, gather, bow, paper casting, pin tuck for wedding dress were able to express easily. Hanji wedding dress has the natural texture because of natural properties of Hanji and that is echo friendly products.

Los Angeles Abrasion Test for Estimating Engineering Index on the Sedimentary Rocks of Kyeongsang Basin (퇴적암의 공학지수를 추정하기 위한 L. A. 마모율 시험)

  • Min, Tuk-Ki;Moon, Jong-Kyu;Lee, Sang-Il
    • Journal of the Korean Geotechnical Society
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    • v.23 no.11
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    • pp.15-26
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    • 2007
  • Los Angeles abrasion loss test has usally been applied to the quarry for the purpose of aggregate hardness estimation. 324 blocks from 25 sites of Kyeongsang basin samples of sedimentary rock were examined and tested in laboratary. This paper found that L. A. abrasion loss test is a good method to estimate engineering index such as uniaxial compressive strength, elastic modulus, indirect tensile strength, point load strength index, Schmidt hammer rebound value of sedimentary rocks with high correlation factor. Engineers will prefer L. A. abrasion loss test to the other one for design and construction as this method is quick and easy.

Effect of Isocyanate Group on the Physical Properties of Hydrogel Contact Lenses Containing Silane (실란을 포함한 친수성 콘택트렌즈의 물리적 특성에 대한 Isocyanate Group의 영향)

  • Sung, A-Young;Cho, Seon-Ahr;Kim, Tae-Hun
    • Journal of the Korean Chemical Society
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    • v.56 no.5
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    • pp.597-602
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    • 2012
  • The copolymerization of triacetoxyvinylsilane, EGDMA (ethylene glycol dimethacrylate as a cross-linker), HEMA (2-hydroxyethyl methacrylate), MMA (methyl methacrylate), MA (methacrylic acid) was performed in the presence of AIBN (2,2'-azobisisobutyronitrile) as an initiator. Measurement of the physical properties of the resulting copolymers showed that water content, refractive index, visible ray transmittance, and tensile strength were in the range of 35.63~32.44%, 1.4382~1.4480, 89.0~92.5% and 0.346~0.674 kgf, respectively. The values of tensile strength of copolymers-containing hexamethylene diisocyanate were higher than those of the copolymers containing triacetoxyvinylsilane. From the results we came to the conclusion that the produced copolymers are suitable for the application of ophthalmic contact lens with high tensile strength, wettability and duraility.