• 대한화학회지
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• 제53권6호
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• pp.755-760
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• 2009

Styrene은 중합체와 공중합체로 널리 사용되어져 왔으며, 고 굴절률을 가지고 있기 때문에 콘택트렌즈 재료로 유용하게 사용된다. 본 연구는 styrene을 교차결합제인 EGDMA (ethylene glycol dimethacrylate)와 HEMA (2-hydroxyethyl methacrylate) 그리고 개시제인 AIBN (azobisisobutyronitrile)을 사용하여 공중합 하였다. 공중합한 안 의료용 재료의 물리적 특성을 측정한 결과 굴절률 1.4412-1.4628, 함수율 20-35%, 가시광선 투과율 82.6-87.0%, 인장강도 0.143-0.344 Kgf를 나타내었다. Styrene의 비율이 증가할수록 굴절률과 인장강도는 증가하였으며, 함수율은 감소하였다. 본 실험결과로 볼 때 생성된 공중합체는 기능성을 가진 고성능 콘택트렌즈 재료로 사용될 수 있을 것으로 판단된다.

• Geomechanics and Engineering
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• 제33권3호
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• pp.279-289
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• 2023

Brittleness index (BI) is an important property of rocks because it is a good index to predict rockburst. Due to its importance, several empirical and soft computing (SC) models have been proposed in the literature based on the punch penetration test (PPT) results. These models are very important as there is no clear-cut experimental means for measuring BI asides the PPT which is very costly and time consuming to perform. This study used a novel Multivariate Adaptive regression spline (MARS), M5P, and white-box ANN to predict the BI of rocks using the available data in the literature for an improved BI prediction. The rock density, uniaxial compressive strength (σ_c) and tensile strength (σ_t) were used as the input parameters into the models while the BI was the targeted output. The models were implemented in the MATLAB software. The results of the proposed models were compared with those from existing multilinear regression, linear and nonlinear particle swarm optimization (PSO) and genetic algorithm (GA) based models using similar datasets. The coefficient of determination (R²), adjusted R² (Adj R²), root-mean squared error (RMSE) and mean absolute percentage error (MAPE) were the indices used for the comparison. The outcomes of the comparison revealed that the proposed ANN and MARS models performed better than the other models with R² and Adj R² values above 0.9 and least error values while the M5P gave similar performance to those of the existing models. Weight partitioning method was also used to examine the percentage contribution of model predictors to the predicted BI and tensile strength was found to have the highest influence on the predicted BI.

• 대한화학회지
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• 제54권6호
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• pp.829-834
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• 2010

• 대한화학회지
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• 제54권6호
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• pp.835-840
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• 2010

• 한국구조물진단유지관리공학회 논문집
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• 제21권1호
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• pp.91-99
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• 2017

본 논문은 폴리머 모르타르로 보수된 철근콘크리트 보의 휨거동을 실험적 해석적으로 분석한 결과를 제시한다. 실험적 연구에서는 보수위치, 모르타르 재령을 실험변수로 고려하여 제작된 13개의 보에 대한 3점 휨실험이 실시되었다. 인장측 및 압축측을 보수한 실험체들의 파괴는 모르타르와 콘크리트의 계면에서 발생하지 않았으며, 폴리머 모르타르의 인장변형률이 극한변형률을 초과하는 순간 발생하였다. 압축측을 보강한 실험체들은 기준실험체의 최대하중과 유사하였다. 그들의 연성지수는 기준실험체보다 훨씬 컸다. 인장측을 보수한 실험체는 매우 취성적으로 파괴되었으며, 연성지수가 크게 감소하였다. 폴리머 모르타르로 보수된 철근콘크리트의 보의 휨거동을 예측하기 위해 Opensees을 사용한 재료비선형 해석을 진행하였다. 해석 모델을 단순화하기 위해 2차원 골조요소를 적용하였으며, 재료 비선형성을 고려하기 위해 파이버 모델을 적용하였다. 해석결과는 비선형 구조해석은 압축측 보수 실험체의 휨거동을 적절하게 예측하나, 인장측 휨거동는 다소 과대 평가하는 것으로 나타났다.

• 펄프종이기술
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• 제45권1호
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• pp.6-12
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• 2013

TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

• 통합자연과학논문집
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• 제11권2호
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• pp.113-120
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• 2018

This study was planned to prepare the high strength hydrogel ophthalmic lens containing isocyanate group and nanoparticles. HDI with carbon nanoparticles were used as additives for the basic combination of HEMA, MA and MMA, and the materials were copolymerized with EGDMA as the cross-linking agent and AIBN as the initiator. The mixture was heated at $100^{\circ}C$ for an hour to produce the high performance hydrogel ophthalmic lens by cast mold method. Measurement of the physical characteristics of the produced material showed that the refractive index was in the range of 1.4027~1.4600, water content 25.21~44.01%, contact angle $54.18{\sim}72.94^{\circ}$, visible light transmittance 53.03~92.09%, and tensile strength 0.1024~0.2359 kgf and breaking strength was 0.0872~0.2825 kgf. The results showed an increase of refractive index while the decrease in water content. And also, the breaking strength was highest when the addition ratio of HDI was 5%(wt). As a result of the absorbance measurement, no significant difference was observed in all the samples, so it can be judged that the stabilization of nanoparticles in the polymer was maintained.

• 펄프종이기술
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• 제31권1호
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• pp.46-51
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• 1999

The most important effect of refining is believed as the internal fibrillation. The internal fibrillation is the separation of the fiber wall into several lamellae. The internal fibrillation results in fiber swelling as water penetrates the fiber wall. The increase in paper strength as a result of refining was due to delamination which made the fiber more flexible. Pulp fibers are refined to 20, 40, and 70$^{\circ}$SR freeness at Valley beater. Changes of Physical paper properties are analyzed depending on fiber wall thickness and fiber's collapse index at 2.5 and 5.6kg$_f$ refining load. At same $^[\circ}$SR freeness with 2.5kg$_f$ refining load, fiber wall thickness is increased further than at high 5.6kg$_f$ refining load. With higher fiber wall thickness by lower intensity refining load, higher internal fibrillation, flexibility, collapsability of fibers are achieved. Those effects improve WRV, tensile strength, and burst strength. Tear strength shows opposite trend to tensile and burst strength as usual.

• 자연과학논문집
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• 제8권1호
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• pp.137-143
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• 1995

산성땀액에 면100% 내의(상의)를 처리하고 반복세탁.건조를 한후 내의의 물성변화를 연구, 검토하였다. 수축은 초기의 수축이 크게 나타났으며, 15회 반복세탁에 의해서도 강신도의 영향은 거의 없었으며 백색면 내의의 백색도(Hw)는 감소한 반면 색차($\Delta$E)와 황변도(YI)가 크게 증가하며 일광에 큰 영향을 받고 있음을 알았다. 또한 유색면 내의의 경우 세탁에 의해 색차가 크게 증가함을 보여 세탁초기의 탈색현상이 심각한 것으로 나타났다.

• Geomechanics and Engineering
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• 제29권6호
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• pp.599-614
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• 2022

In this study, the reliability analysis of internal and external stabilities of Reinforced Soil Walls (RSWs) under static and seismic loads are investigated so that it can help the geotechnical engineers to perform the design more realistically. The effect of various variables such as angle of internal soil friction, soil specific gravity, tensile strength of the reinforcements, base friction, surcharge load and finally horizontal earthquake acceleration are examined assuming the variables uncertainties. Also, the correlation coefficient impact between variables, sensitivity analysis, mean change, coefficient of variation and type of probability distribution function were evaluated. In this research, external stability (sliding, overturning and bearing capacity) and internal stability (tensile rupture and pull out) in both static and seismic conditions were investigated. Results of this study indicated sliding as the predominant failure mode in the external stability and reinforcing rupture in the internal stability. First-Order Reliability Method (FORM) are applied to estimate the reliability index (or failure probability) and results are validated using the Monte Carlo Simulation (MCS) method. The results showed among all variables, the internal friction angle and horizontal earthquake acceleration have dominant impact on the both reinforced soil wall internal and external stabilities limit states. Also, the type of probability distribution function affects the reliability index significantly and coefficient of variation of internal friction angle has the greatest influence in the static and seismic limits states compared to the other variables.