• Title/Summary/Keyword: tensile index

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Effect of Hot Pressing/Melt Mixing on the Properties of Thermoplastic Polyurethane

  • Lee, Young-Hee;Kang, Bo-Kyung;Kim, Han-Do;Yoo, Hye-Jin;Kim, Jung-Soo;Huh, Jae-Ho;Jung, Young-Jin;Lee, Dong-Jin
    • Macromolecular Research
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    • v.17 no.8
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    • pp.616-622
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    • 2009
  • In-depth understanding of the influence of hot pressing and melt processing on the properties of thermoplastic polyurethane (TPU) is critical for effective mechanical recycling of TPU scraps. Therefore, this study focused on the effects of hot pressing and melt mixing on molecular weight (MW), polydispersity index (PDI), melt index (MI), characteristic IR peaks, hardness, thermal degradation and mechanical properties of TPU. The original TPU pellet (o-TPU) showed two broad peaks at lower and higher MW regions. However, four TPU film samples, TPU-0 prepared only by hot pressing of o-TPU pellet and TPU-1, TPU-2 and TPU-3 obtained by hot pressing of melt mixed TPUs (where the numbers indicate the run number of melt mixing), exhibited only a single peak at higher MW region. The TPU-0 film sample had the highest $M_n$ and the lowest PDI and hardness. The TPU-1 film sample had the highest $M_w$ and tensile modulus. As the run number of melt mixing increased, the peak-intensity of hydrogen bonded C=O stretching increased, however, the free C=O peak intensity, tensile strength/elongation at break and average MW decreased. All the samples showed two stage degradations. The degradation temperatures of TPU-0 sample (359 $^{\circ}C$ and 394 $^{\circ}C$)were higher than those of o-TPU (342 $^{\circ}C$ and 391 $^{\circ}C$). While all the melt mixed samples degraded at almost the same temperature (365 $^{\circ}C$ and 381 $^{\circ}C$). The first round of hot pressing and melt mixing was found to be the critical condition which led to the significant changes of $M_n$/$M_w$/PDI, MI, mechanical property and thermal degradation of TPU.

Effects of Thermal and Mechanical Fatigue Stress on Bond Strength in Bracket Base Configurations (열적, 기계적 피로응력이 교정용 브라켓의 결합강도에 미치는 영향)

  • Kim, Jong-Ghee;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.30 no.5 s.82
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    • pp.625-642
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    • 2000
  • The purpose of this study is to evaluate the effects of mechanical and thermal fatigue stress on the shear, tensile and shear-tensile combined bond strengths(SBS, TBS, CBS) in various orthodontic brackets bonded to human premolars with chemically cured adhesive(Ortho-one, Bisco, USA). Five types of commercially available metal brackets with various bracket base configurations of Photoetched base(Tomy, Japan), Non-Etched Foil Mesh base(Dentaurum, Germany), Micro-Etched Foil Mesh base(Ortho Organizers, USA), Chessboard base(Daesung, Korea), and Integral base(3M Unitek, USA) were used. Samples were divided into 3 groups, the first group was acted with shear-tensile combined loads($45^{\circ}$) of 200g for 4 weeks(mechanical fatigue stress), the second group was subjected to the 5,000 thermocycles of 15 second dwell time each in $5^{\circ}C\;and\;55^{\circ}C$ baths(thermal fatigue stress), and the third group was the control. Bond strengths were measured at the crosshead speed of 0.5mm/min. The cross-section of bracket base/adhesive interface and the fracture surface were examined with the stereoscope and the scanning electron microscope. The resin remnant on bracket base surface was assessed by ART(Adhesive Remnant Index). The obtained results were summarized as follows, 1. In static bond strength, Photoetched base bracket showed the maximum bond strength and Integral base bracket showed the minimum bond strength(p<0.05). In all brackets, shear bond strength(SBS) was in the greatest value and shear-tensile combined strength(CBS) was in the least value(p<0.05). 2. After mechanical fatigue test, Photoetched base bracket showed the maximum bond strength and Integral base bracket showed the minimum bond strength(p<0.05). In Photoetched base bracket and Micro-Etched Foil Mesh base bracket, shear bond strength(SBS), tensile bond strength(TBS) and shear-tensile combined strength(CBS) were decreased after mechanical fatigue test(p

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Study on Hair Characteristics Analysis and Performance Evaluation of Traditional Brushes (전통 붓의 섬유 특성 분석 및 성능 평가 연구)

  • Park, Sang Hyeon;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.34 no.3
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    • pp.195-209
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    • 2018
  • In this study, the characteristics of various raw hairs used for traditional Korean brushes were examined; further, the characteristics and deterioration patterns of Korean, Chinese, and Japanese brushes were compared, with a quantitative evaluation to assess the brush performance. The tensile strength was generally found to be higher with a greater fiber thickness. Among the hairs examined, the back and flank hair of goat was more damaged than that in other parts, and the tensile strength was low. Higher elasticity of the brush made with hair of high cysteine content was measured. Owing to deterioration by use of the brushes, artificial drying brushes had a higher yellowness index and lower tensile strength than natural drying brushes. Further, it was confirmed that brushes with good absorbency exhibited good consistency, but not good elasticity. Thus, the performance of the brush can be influenced by the kind of material used and the brush usage pattern. In addition, it is possible to identify the material science characteristics of brushes which have been produced only by experience; therefore, the results of this study could provide basic data for manufacturing brushes employed in conservation treatment, in the future.

Effects of Extracting Conditions on the Properties of Pish Meal Protein Isolates and the Permeability of Protein Film for Ester Compounds (추출조건이 어분단백질 물성과 필름의 ester 화합물 투과율에 미치는 영향)

  • YOU Byeong-Jin;SHIM Jae-Man
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.4
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    • pp.320-326
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    • 2001
  • To obtain the basic data for preparing edible or biodegradable film, fish meal protein isolates (FMPI) were prepared through alkaline extraction. And FMPI's properties and the ester compounds permeability of FMPI film were measured. FMPI were extracted under various extracting time with 0.2 N NaOH solution at $60^{\circ}C$, Recovery ratios of FMPI extracted from fish meal were increased with extracting time increasing. Surface hydrophobicity of FMPI extracted for 1 hr showed highest value. Emulsifying activity index (EAI) was increased with the increasement of extracting time but its emulsifying stability index (ESI) showed an inverse results. Viscosity of FMPI solution showed the highest value at pH 2 but showed the lowest value at pH 4, The higher concentration of sorbitol as plasticizer showed the higher ethyl acetate permeability of FMPI film, Ethyl acetate permeability of FMPI films according to kind of plasticizers showed different degree and increased in order as follow: polyethylene glycol, glycerol and sorbitol. Ester compounds having the lower molecular weight showed the higher permeability. Increment of temperature increased the ethyl acetate permeability of FMPI film. FMPI haying higher surface hydrophobicity made FMPI film be higher tensile strength. On elongation of FMPI films, kinds of plasticizer were more effective than surface hydrophobicity of FMPI.

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Estimation of Cerchar abrasivity index based on rock strength and petrological characteristics using linear regression and machine learning (선형회귀분석과 머신러닝을 이용한 암석의 강도 및 암석학적 특징 기반 세르샤 마모지수 추정)

  • Ju-Pyo Hong;Yun Seong Kang;Tae Young Ko
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.26 no.1
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    • pp.39-58
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    • 2024
  • Tunnel Boring Machines (TBM) use multiple disc cutters to excavate tunnels through rock. These cutters wear out due to continuous contact and friction with the rock, leading to decreased cutting efficiency and reduced excavation performance. The rock's abrasivity significantly affects cutter wear, with highly abrasive rocks causing more wear and reducing the cutter's lifespan. The Cerchar Abrasivity Index (CAI) is a key indicator for assessing rock abrasivity, essential for predicting disc cutter life and performance. This study aims to develop a new method for effectively estimating CAI using rock strength, petrological characteristics, linear regression, and machine learning. A database including CAI, uniaxial compressive strength, Brazilian tensile strength, and equivalent quartz content was created, with additional derived variables. Variables for multiple linear regression were selected considering statistical significance and multicollinearity, while machine learning model inputs were chosen based on variable importance. Among the machine learning prediction models, the Gradient Boosting model showed the highest predictive performance. Finally, the predictive performance of the multiple linear regression analysis and the Gradient Boosting model derived in this study were compared with the CAI prediction models of previous studies to validate the results of this research.

A case study on the optimal shafting alignment concerning bearing stiffness for 10,100 TEU container carrier (베어링 강성을 고려한 10,100 TEU 컨테이너 운반선의 최적 추진축계 배치에 관한 사례 연구)

  • Lee, Jae-Ung
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.3
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    • pp.185-190
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    • 2016
  • Damages of the main engine aftmost bearing and the after stern tube bearing tend to increase due to misalignment. And as the shafting system becomes stiffer due to the large engine power, whereas the hull structure becomes more flexible due to optimization by using high tensile thin steel plates. And this is the reason that more sophisticated shaft alignments are required. In this study, the optimum shafting alignment calculation was carried out, considering the thermal expansion effect, exploiting the sensitivity index, which indicates the reasonable position of forward intermediate shaft bearing for shaft alignment. and as the main subject in this study, the elastic deformation on intermediate shaft and main engine bearings occurred by vertical load of shaft mass were examined thoroughly and analyzed allowable load of bearings, reaction influence numbers of all bearings. As the result, a reliable optimum shafting alignment was derived theoretically. To verify these results, they were referred to the engine maker's technical information of main engine installation and being used shafting alignment programs of both Korean Register of Shipping and Det Norske Veritas, their reliability were reviewed.

Physical Properties of Polypropylene Blended Yarns with Yarn Counts and Blended Ratio (Polypropylene 복합방적사의 섬도와 혼용율에 따른 물성)

  • Kim, Jeong-Hwa;Lee, Jung-soon
    • Fashion & Textile Research Journal
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    • v.20 no.5
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    • pp.600-607
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    • 2018
  • Polypropylene fibers, while having many advantages such as light weight, sweat fast drying, water-repellent, drainage, thermal insulation, anti-static property has a drawback in dyeing. In recent years, the development of dyeable polypropylene fibers has expanded its value in the textile market. The purpose of this study is to fabricate composite spun yarns using polypropylene, acrylic, rayon and wool and to analyze tensile properties, uniformity characteristics, bending properties, hairiness, and surface shape according to the degree of fineness and blended ratio. The specimens consisted of 100% polypropylene spun yarn pp30, pp40 and ppa(pp/acrylic), ppr(pp/rayon), ppw(pp/wool), 5 altogether sed in this study. The results of the study are as follows. The breaking strength of polypropylene spun yarn blended with rayon and acrylic was higher than that of 100% polypropylene spun yarn. The polypropylene spun yarn is higher the fineness been shown to decrease the breaking strength and elongation. The bending properties of polypropylene spun yarns were in the order of ppa>ppr>pp40>pp30>ppw. The unevenness of ppw, ppr, and ppa was higher than pp40 and pp30. With the exception of ppw with crimp properties, pp30 and pp40 were found to have a hairiness index greater than ppr, ppa. In the microscopic photographs of polypropylene spun yarn, pp30, which had the highest hairiness index, was found to have a thick yarn and a large number of hairs, and ppw had hairs of 3 mm or more protruding elongated outwardly.

Effect of PCC Pretreatment with Pulp Powder on the Paper Properties (목재펄프 분말을 이용한 PCC 전처리가 종이 성질에 미치는 영향)

  • Kwak, Gun Ho;Cho, Byoung-Uk;Lee, Yong-Kyu;Won, Jong Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.1
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    • pp.39-45
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    • 2014
  • Various approaches have been tried to reduce the emission of carbon dioxide in paper industry. One of important approaches is to use PCC manufactured from emission gas as a filler. However, it was recognized that PCC is inferior to other fillers in the paper strength properties of view. Therefore, pretreatment of PCC with pulp powder was tried to mitigate the strength reduction of paper. Pretreatment of PCC with pulp powder improved the bulk(7.4~12.9%) and air permeability(24.8~42.98%), but there is no significant change in opacity. Tensile index, burst index and stiffness were decreased by the use of pretreated PCC with pulp powder. Anionic and cationic PAM were used as a additive for PCC pretreatment in order to improve strength properties. There was no significant change in bulk in all kinds of PAM used in this study. Most strength properties were improved by the pretreatment of PCC with the anionic and cationic PAM and pulp powder, although the opacity and stiffness were more or less decreased.

Estimation of The Basic Properties of Two-Lift Concrete Pavement to Apply Korea Condition (이층 포설 콘크리트 포장의 국내 적용을 위한 강섬유 보강 콘크리트 기초 물성평가)

  • Won, Hong-Sang;Ryu, Sung-Woo;Hong, Jong-Yong;Cho, Yoon-Ho
    • International Journal of Highway Engineering
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    • v.12 no.1
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    • pp.47-54
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    • 2010
  • This study had a focus on investigating technical validity of Two-Lift Concrete Pavements which had never been constructed in Korea in order to olve the problem of existing concrete pavements. This study found out the application of Steel Fiber Reinforced Concrete (SFRC) which was one of ew techniques. Also, optimal steel fiber contents and pavement thickness were determined. This study also measured compressive strengths, lexural strengths, toughness indexes, tensile strengths and fatigue strengths to estimate the performance of SFRC of according to results of aboratory experiments, slumps and air contents of concrete specimens the standards satisfied and compressive strengths to open traffic. At bending ests, Toughness Index of SFRC increased but flexural strength didn’'t increase as compared with non-steel fiber concretes. And, energy absorption of SFRC was very good and SFRC showed improvement in freezing and thawing resistances. To complete this research, we will evaluate the pplication methods and performance of SFRC at field section.

Effect of Xylanase Pre-and Post-Treatment on oxygen Bleaching of Oak Kraft Pulp

  • Kim, Dong-Ho;Paik, Ki-Hyon
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11a
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    • pp.194-204
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    • 1999
  • The use of genetically cloned xylanase acquired from Bacillus strearthermophillus improves bleachability for oak kraft pulps. Combination of xylanase(X). oxygen(O), ozone(Z). peroxide(P), alkaline extraction(Eo. Eop), and chlorination(C/D, D) have been tested in a variety of bleaching sequences. The effectiveness of xylanase pre-treatment(XO) and post-treatment(OX) in oxygen bleaching is mainly compared. With xylanase treatment the brightness increase by 1.5-2.1% ISO in OZEP, OZEoP, OZEopP and OPZP sequences. There is only numerically difference of brightness gains between OX and XO sequences. With xylanase treatment chemical requirements for bleaching decrease by 42.6-48.6% in OC/DEoD sequence and 47.9-54.7% as active chlorine in OC/DEopD sequence at the same brightness. the reduction of bleaching chemicals is higher in XO sequence than those in OX sequence. Following xylanase treatment the viscosity increases from 11.7-12.0 mPa·s to 12.4-13.5 mPa·s and the brightness stability is considerably improved however the difference of effectiveness between XO and OX sequence is not present. Compared to tensile index vs tear index, the physical properties are similar for TCF bleaching sequences with and without xylanase treatments. However in OC/DEoD and OC/DEopD sequences the physical properties decrease with xylanase treatment. There is no difference in the physical properties between XO and OX sequences. COD, BOD and color of bleaching effluents increase slightly with xylanase treatment, however the discharge of COD end-load into environmental impact decrease.

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