• 공업화학
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• 제16권1호
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• pp.93-100
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• 2005

두 종류의 4관능 폴리에스터 폴리올에 대해 trimellitic anhydride와 glycidyl metacrylate를 반응하여 두 종류의 8관능 광경화형 폴리에스터 폴리올 변성 하이퍼브랜치 메타아크릴레이트를 합성하고 광경화된 필름의 물성을 조사하였다. Thermogravimetric analyzer (TGA)로 측정한 UV 경화필름의 열안정성은 HBMA-2 (hyperbranched methacrylate-2)가 HBMA-1 (hyperbranched methacrylate-1)보다 우수하였다. 또한 HBMA-2가 HBMA-1보다 경도, 내마모성, 인장강도가 우수하였으며, 내후성 테스트에서도 HBMA-2의 yellow index 값이 높은 결과를 보여주었다.

• Elastomers and Composites
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• 제37권3호
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• pp.177-182
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• 2002

범용으로 사용할 수 있는 low smoke type의 난연 polyolefin(halogen free)계 컴파운드의 최적 배합을 구현하기 위해 LDPE, EVA, EEA를 수지로 하고 상용화제로 MAH-graft-PE를 이용하였으며, 난연제로 수산화마그네슘, 수산화알루미늄과 적린을 사용하여 변량 시험을 하였다. 물성은 상온 인장강도, 신장율과 노화후 인장신장 잔율을 기본으로 smoke density 산소 지수 시험을 하였고, 난연성은 UL-94로 확인하였으며, 수산화마그네슘과 수산화알루미늄의 대표 배합을 SEM 촬영하여 분산구조를 확인하였다. HCI 함량 시험을 하여 halogen content를 확인하였다. 또한 halogen free로 난연성(UL-94, V-0)과 저연성을 만족하는 2종의 배합을 도출해 냄으로서 여러 가지 용도로서의 전용이 가능할 것으로 보인다.

• 펄프종이기술
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• 제34권3호
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• pp.46-52
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• 2002

To produce the raw material used for printing and writing paper or high quality tissue, MOWs that were consisted of white ledger, colored ledger and old newspaper were bleached with EoP and EoPY(FAS) method, the EoP bleaching process gave the improvement in brightness and a high color removal efficiency. Especially, MOW B(initial brightness: 59.1％ ISO) that contained much old newspaper showed the higher bleaching efficiency than those of MOW A(initial brightness: 68.3%). After EoPY(FAS) bleaching, MOW's brightness was increased from 68.3% ISO to 84.3∼84.0% ISO, and from 59.1% ISO to 78.7∼79.2% ISO, respectively. Also the tensile and burst index of bleached pulps decreased by 10∼30%. The tear index slightly decreased or halted at the same range as unbleached pulps.

• Fibers and Polymers
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• 제3권3호
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• pp.97-102
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• 2002

A series of waterbome poly(urethane-urea) anionomers were prepared from isophorone diisocyanate (IPDI), polycaprolactone diol (PCL), dimethylol propionic acid (DMPA), ethylene diamine (EDA), and triethylamine (TEA), NaOH, or Cu($(COOCH_3)_2$) as neutralizing agent. This study was performed to decide the effect of neutralizing agent type on the particle size viscosity, hydrogen bonding index, adhesive strength, antistaticity, antibacterial and mechanical properties. The particle size of the dispersions decreased in the following order: TEA based samples (T-sample), NaOH based samples (N-sample), and Cu($(COOCH_3)_2$) based sample (C-sample). The viscosity of the dispersions increased in the order of C-sample, N-sample, and T-sample. Metal salt based film samples Of and C-sample) had much higher antistaticity than TEA based sample. By infrared spectroscopy, it was found that the hydrogen bonding index (or fraction) of samples decreased in the order of T-sam-pie, N-sample, and C-sample. The adhesive strength and tensile modulus/strength decreased in the order of T-sample, N-sam-pie, and C-sample. The C-sample had strong antibacterial halo, however, T- and N-samples did not

• 한국지진공학회논문집
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• 제15권1호
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• pp.19-28
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• 2011

이 연구에서는 손상된 철근콘크리트 구조물의 구조성능평가를 위한 비선형 유한요소해석 기법을 제시하였다. 사용된 프로그램은 철근콘크리트 구조물의 해석을 위한 RCAHEST이다. 재료적 비선형성에 대해서는 균열콘크리트에 대한 인장, 압축, 전단모델과 콘크리트 속에 있는 철근모델을 조합하여 고려하였다. 그리고 철근콘크리트 구조물의 비탄성거동의 예측에 근거한 손상지수를 제시하였다. 이 연구에서는 손상된 철근콘크리트 구조물의 구조성능을 파악하기 위해 제안한 해석기법을 신뢰성 있는 연구자의 실험결과와 비교하여 그 타당성을 검증하였다.

• 한국재료학회지
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• 제29권7호
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• pp.399-407
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• 2019

This research is carried out to analyze the effects of Styrene and PVP on the properties of silicone hydrogel lenses. Styrene group and PVP(Polyvinylpyrrolidone) are used as additives for a basic combination containing silicone monomer, TSMA(trimethylsilyl methacrylate) and DMA(n,n-dimethylacrylamide) added to the mix at ratios of 1~10 %. Silicone hydrogel lens is produced by cast-mold method. The polymerized lens sample is hydrated in a 0.9 % saline solution for 24 hours before its optical and physical characteristics are measured. Measurement of the physical characteristics of the produced material shows that the refractive index is 1.3682~1.4321, water content 77.11~45.73 %, visible light transmittance 95.14~88.20 %, and tensile strength 0.0652~0.3113 kgf. The results show a decrease of refractive index as the ratio of additives and water content decreases. The result of the stabilization test of polymerization show an increase of extractables along with increase of the ratio of additives, but the difference is not significant for all samples, so it can be judged that the stabilization of the polymer is maintained. Therefore, the additions of styrene and PVP should be taken into consideration for their effects on the physical properties of silicone hydrogel lens.

• Structural Engineering and Mechanics
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• 제77권2호
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• pp.231-243
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• 2021

In this paper, a dynamic response mapping model of the wheel-rail system is established by using the support vector regression (SVR) method, and the hierarchical safety thresholds of the subgrade void are proposed based on the reliability theory. Firstly, the vehicle-track coupling dynamic model considering the subgrade void is constructed. Secondly, the subgrade void area, the subgrade compaction index K30 and the fastener stiffness are selected as random variables, and the mapping model between these three random parameters and the dynamic response of the wheel-rail system is built by using the orthogonal test and the SVR. The sensitivity analysis is carried out by the range analysis method. Finally, the hierarchical safety thresholds for the subgrade void are proposed. The results show that the subgrade void has the most significant influence on the carbody vertical acceleration, the rail vertical displacement, the vertical displacement and the slab tensile stress. From the range analysis, the subgrade void area has the largest effect on the dynamic response of the wheel-rail system, followed by the fastener stiffness and the subgrade compaction index K30. The recommended safety thresholds for the subgrade void of level I, II and III are 4.01㎡, 6.81㎡ and 9.79㎡, respectively.

• Advances in concrete construction
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• 제10권6호
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• pp.489-498
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• 2020

This paper investigates mechanical properties of roller compacted concrete (RCC) involving reclaimed asphalt pavement (RAP). In this way, a set of 276 cylindrical RCC specimens were prepared with different RAP sizes (i.e., fine, coarse & total) at various ratios (i.e., 10%, 20%, and 40%). Results reveal that incorporation of RAP decreases unconfined compressive strength (UCS), modulus of elasticity (E), and indirect tensile (IDT) strength of RCC. For each RAP size, a regression model was used to maximize RAP content while satisfying the UCS lower limit (27.6 Mpa) mentioned by ACI as a minimum requirement for RCC used in pavement construction. Moreover, UCS of RAP incorporated mixes, dissimilar to that of control mixes, was found to be sensitive and insensitive to the testing temperature and curing time after 7 days, respectively. The results also demonstrate that the higher amounts of RAP, the more flexibility in RCC is. This issue was also proved by the results of modulus of elasticity test. In addition, the toughness index (TI) shows that increase in RAP content leads to up to 43% increase in energy absorbance capacity of RCC.

• Computers and Concrete
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• 제30권3호
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• pp.165-173
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• 2022

The effect of basalt and polypropylene fibers on the flexural behavior of reinforced concrete (RC) beams is investigated in this paper. The compressive and tensile behaviors of the basalt concrete and polypropylene concrete cylinders are also investigated. Eight beams and 28 cylinders were made with different percentages of basalt and polypropylene fibers. The dosages of fiber were selected as 0.6%, 1.3%, and 2.5% of the total cement weight. Each type of fiber was mixed solely with the concrete mix. Basalt and polypropylene fibers are modern and cheap materials that can be used to improve the structural behavior of RC members. This research is designed to find the optimum percentage of basalt and polypropylene fibers for enhancing the flexural behavior of RC beams. Test results showed that the addition of basalt and polypropylene fibers in any dosage (0.6%, 1.3%, and 2.5%) can increase the flexural strength and displacement ductility index of the beams where the maximum enhancement was measured with 1.3% fibers. The maximum increments in the flexural strength and the displacement ductility index were 30.39% and 260% for the basalt fiber case, while the maximum improvement for the polypropylene fibers case was 55.5% and 230% compared to the control specimen. Finite element (FE) models were then developed in ABAQUS to predict the numerical behaviour of the tested beams. The FE models were able to predict the experimental behaviour with reasonable accuracy. This research confirms the efficiency of basalt and polypropylene fibers in enhancing the flexural behavior of RC beams, and it also suggests the optimum dosage of fibers.

• 한국재료학회지
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• 제33권11호
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• pp.482-490
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• 2023

The purpose of this study was to analyze microstructural changes and evaluate the mechanical properties of TWIP steel subjected to variations in heat treatment, in order to identify optimal process conditions for enhancing the performance of TWIP steel. For this purpose, a homogenization heat treatment was conducted at 1,200 ℃ for 2 h, followed by hot rolling at temperature exceeding 1,100 ℃ and cold rolling. Annealing heat treatment is achieved using a muffle furnace in the range of 600 ℃ to 1,000 ℃. The microstructure characterization was performed with an optical microscope and X-ray diffraction. Mechanical properties are evaluated using micro Vickers hardness, tensile test, and ECO index (UTS × Elongation). The specimens annealed at 900 ℃ and 1,000 ℃ experienced a significant decrease in hardness and strength due to decarburization. Consequently, the decarburization phenomenon is closely related to the heat treatment process and mechanical properties of TWIP steel, and the effect of the microstructure change during annealing heat treatment.