• Title/Summary/Keyword: temperature-shift

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Optical and Dielectric Properties of Reduced SrTiO3 Single Crystals

  • Kang, Bong-Hoon
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.278-281
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    • 2011
  • The optical band gap energy for $SrTiO_3$ by reduction at high temperature was 3.15 eV. The reflectivity of reduced $SrTiO_3$ single crystals showed little variation, however, the reflectivity by the reduction condition had no effect. For the phonon mode at about 790 $cm^{-1}$, a blue-shift took place upon $N_2$ reduction and the decreased. However, a red-shift took place upon a $H_2-N_2$ reduction and the increased at the same phonon mode. With decreasing temperature the dielectric constant decreased rapidly. The thermal activation energies were 0.92-1.02 eV.

Field Effect Transistor of Vertically Stacked, Self-assembled InAs Quantum Dots with Nonvolatile Memory

  • Li, Shuwei;Koike, Kazuto;Yano, Mitsuaki
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.2 no.3
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    • pp.170-172
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    • 2002
  • The epilayer of vertically stacked, self-assembled InAs Quantum Dots (QDs)was grown by MBE with solid sources in non-cracking K-cells, and the sample was fabricated to a FET structure using a conventional technology. The device characteristic and performance were studied. At 77K and room temperature, the threshold voltage shift values are 0.75V and 0.35 V, which are caused by the trapping and detrapping of electrons in the quantum dots. Discharging and charging curves form the part of a hysteresis loop to exhibit memory function. The electrical injection of confined electrons in QDs products the threshold voltage shift and memory function with the persistent electron trapping, which shows the potential use for a room temperature application.

Studies on the Natural Dyes(10) -Dyeing properties of safflower yellow for silk fibers- (天然染料에 관한 硏究(10) -홍화 황색소의 견섬유에 대한 염색성-)

  • Cho, Kyung Rae
    • Textile Coloration and Finishing
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    • v.9 no.5
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    • pp.10-18
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    • 1997
  • In order to study the properties of safflower yellow colors, thermodynamic parameters and dyeing properties on the silk in several dyeing conditions were investigated. The uv-visible spectra of safflower yellow colors in several solvents show hypsochromic shift with the polarity of solvent but bathochromic shift with increasing acidity of solution. The apparent diffusion coefficients and standard affinities of dyeing increased with the increase of dyeing temperature. The standard heat of dyeing(${\Delta}H^0$), entropy change(${\Delta}S^0$) and activation energy($E_{act}$) were calculated to be - 1.144kcal/mol, -7.498(5$0^{\circ}C$)~-3.804(9$0^{\circ}C$)cal/molㆍdeg and 0.123kcal/mol, respectively. The concentration of safflower yellow colors in the silk fiber increased with dyeing temperature, time, concentration of colors and acidity of initial dyebath. Silk fabrics were dyed bright yellow by pre-mordanting with tin chloride. Lightfastness of silk fabrics pre-mordanted by tin chloride was not excellent.

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An Analytical Investigation of a Hydraulic Clutch System of Powershift Transmission (파워시프트 변속기 유압클러치시스템의 해석적 연구)

  • Lee, J.C.
    • Transactions of The Korea Fluid Power Systems Society
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    • v.6 no.1
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    • pp.25-31
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    • 2009
  • This study presents an analytical model of hydraulic clutch system of a power shift transmission to analyze pressure modulation characteristics. A typical hydraulic clutch system was modeled by using AMESim in which the parameters of major components were measured for simulation. Test apparatus was established using the components of power shift and power shuttle clutches with instrumental equipment. The results of simulation and experiment were so close that the proposed analytical model in this study was validated. However the cylinder model analogized clutch dynamics need to be improved in future study. The effects of parameters of orifice diameter, accumulator stroke and oil temperature on pressure modulation were analyzed respectively. The results of parameter sensitivity analysis show that modulation time and set pressure can be easily adjusted by changing parameter values. It is also found that the hydraulic clutch system used in this study is so susceptible to oil temperature that cooling equipment is necessary.

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Distributions of Hyperfine Parameters in Amorphous $Fe_{83}B_9Nb_7Cu_1$ Alloys (비정질 $Fe_{83}B_9Nb_7Cu_1$의 M$\)

  • 윤성현;김성백;김철성
    • Journal of the Korean Magnetics Society
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    • v.9 no.6
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    • pp.271-277
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    • 1999
  • Amorphous $Fe_{83}B_9Nb_7Cu_1$ alloy has been studied by M$\"{o}$ssbauer spectroscopy. Revised Vincze method was used and distributions of hyperfine field, isomer shift, and quadrupole line broadening of the sample at various temperatures have been evaluated and Curie temperature and $H_{hf}\;(0)$ were calculated to be 393 K and 231 kOe, respectively. Temperature variation of reduced average hyperfine field shows a flattered curvein comparison with the Brillouin curve for S=1. This behavior can be explained on the basis of Handrich molecular field model, in which the parameter Δ, which is a measure of fluctuation in exchange interactions, is assumed to have the temperature dependence ${Delta}=0.75-0.64{\tau}+0.47{\tau}^2$ where $\tau$ is $T/T_C$. At low temperature, the average hyperfine field can be fitted to $H_{hf}\;(T)=H_{hf}\;(0)\;[1-0.44\;(T/T_C)^{3/2}-0.28(T/T_C)^{5/2}-… ]$, which indicates the presence long wave length spin wave excitations. At temperature near TC, reduced average hyperfine field varies as $1.00\;[1-T/T_C]^{0.39}$. It is also found that half-width of the hyperfine field distribution was 102 kOe (3.29 mm/s) at 13 K and decreased monotonically as temperature increased. Above the Curie temperature, an average quadrupole splitting value of 0.43 mm/s was found. Average line broadening due to quadrupole splitting distribution was 0.31 mm/s at 13 K and decreases monotonically to 0.23 mm/s at 320 K, whereas that due to the isomer shift distribution is 0.1 mm/s at 13 K and 0.072 mm/s at 320 K, which is much smaller than that of both hyperfine field and quadrupole splitting. The temperature dependence of the isomer shift can be fitted within the harmonic approximation to a Deybe model with a Debye temperature ${Theta}_D=424{\pm}5K$.TEX>.

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Different Types of Active Region EUV Bright Points by Hinode/EIS

  • Lee, Kyoung-Sun;Moon, Yong-Jae;Kim, Su-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.28.2-28.2
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    • 2010
  • We have investigated seven Extreme-Ultraviolet (EUV) bright points in the active region (AR 10926) on 2006 December 2 by the EUV imaging spectrometer (EIS) onboard Hinode spacecraft. We determined their Doppler velocities and non-thermal velocities from 15 EUV spectral lines (log T=4.7-7.2) by fitting each line profile to a Gaussian function. We present the Doppler velocity map as a function of temperature which corresponds to a different height. As a result, these active region bright points show two different types of characteristics. Type 1 bright point shows a systematic increase of Doppler velocity from -68 km/s (blue shift) at log T=4.7 to 27 km/s (red shift) at log T=6.7, while type 2 bright points have Doppler velocities in the range of -20 km/s and 20 km/s. Using MDI magnetograms, we found that only type 1 bright point was associated with the canceling magnetic feature at the rate of $2.4{\times}10^{18}$ Mx/hour. When assuming that these bright points are caused by magnetic reconnection and the Doppler shift indicates reconnection out flow, the pattern of the Doppler shift implies that type 1 bright point should be related to low atmosphere magnetic reconnection. We also determined electron densities from line ratio as well as temperatures from emission measure loci using CHIANTI atomic database. The electron densities of all bright points are comparable to typical values of active regions (log Ne=9.9-10.4). For the temperature analysis, the emission loci plots indicate that these bright points should not be isothermal though background is isothermal. The DEM analysis also show that while the background has a single peak distribution (isothermal), the EUV bright points, double peak distributions.

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An Optimization of Synthesis Method for High-temperature Water-gas Shift Reaction over Cu-CeO2-MgO Catalyst (고온수성가스전이반응 적용을 위한 Cu-CeO2-MgO 촉매의 제조방법 최적화)

  • I-Jeong Jeon;Chang-Hyeon Kim;Jae-Oh Shim
    • Clean Technology
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    • v.29 no.4
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    • pp.321-326
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    • 2023
  • Recently, there has been a growing interest in clean hydrogen energy that does not emit carbon dioxide during combustion due to the increasing focus on carbon neutral. Research related to hydrogen production continues, and in this study, we applied waste-derived synthesis gas to the water-gas shift reaction to simultaneously treat waste and produce high-purity hydrogen. To enhance catalytic activity in the high-temperature water-gas shift (HT-WGS) reaction, magnesium was used as a support material alongside cerium. Cu-CeO2-MgO catalysts were synthesized, with copper acting as the active component for the HT-WGS reaction. A study on the catalytic activity based on the preparation method was conducted, and the Cu-CeO2-MgO catalyst prepared by impregnation method exhibited the highest activity in the HT-WGS reaction. The observed superior performance of the Cu-CeO2-MgO catalyst prepared through the impregnation method can be attributed to its significantly higher oxygen storage capacity and amount of active Cu species.