• Title/Summary/Keyword: temperature cycles

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Crystalline structures and electrical properties of $Pb[(Zr,Sn)Ti]NbO_3$ Thin Films deposited using RF Magnetron Sputtering Method (RF 마그네트론 스퍼터링 방법으로 제작된 $Pb[(Zr,Sn)Ti]NbO_3$ 박막의 결정구조와 전기적 특성)

  • Choi, Woo-Chang;Choi, Yong-Jung;Choi, Hyek-Hwan;Lee, Myoung-Kyo;Kwon, Tae-Ha
    • Journal of Sensor Science and Technology
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    • v.9 no.3
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    • pp.242-247
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    • 2000
  • $Pb_{0.99}[(Zr_{0.6}Sn_{0.4})_{0.9}Ti_{0.1}]_{0.98}Nb_{0.02}O_3(PNZST)$ thin films were deposited by RF magnetron sputtering on $(La_{0.5}Sr_{0.5})CoO_3(LSCO)/Pt/Ti/SiO_2/Si$ substrate using a PNZST target with excess PbO of 10 mole%. The thin films deposited at substrate temperature of $500^{\circ}C$, and at RF power of 80W were crystallized to a perovskite phase after rapid thermal annealing(RTA). The thin films annealed at $650^{\circ}C$ for 10 seconds in air exhibited the good structures and electrical properties. The fabricated PNZST capacitor had a remanent polarization value of about $20\;{\mu}C/cm^2$ and coercive field of about 50 kV/cm. The reduction of the polarization after $2.2{\times}10^9$ switching cycles was less than 10%.

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Effect of Vibrio alginolyticus on the Algicidal Activity of Shewanella sp. SR-14 (Vibrio alginolyticus가 Shewanella sp. SR-14의 미세조류 증식저해 활성에 미치는 영향)

  • KIM Ji Hoe;PARK Hee Yeon;LEE Tae Seek;KIM Shin-Hee;PARK Jeong Heum;CHANG Dong Suck
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.5
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    • pp.430-434
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    • 2001
  • The algicidal activity of Shewanella (formerly Alteromonas) sp. SR-14 against diatom, Chaetoceros calcitrans was reported in our previous papers. In this study, the effect of Vibrio alginolyticus on the algicidal activity of Shewanelia sp, SR-14 was examined under the optimum algicidal conditions, i.e., temperature ($21\pm1^{\circ}C$), light intensity (4,000 lux), and light: dark cycle (12 hour: 12 hour). Shewanella sp. SR-14 grew well in the presence or the absence of V. alginolyticus in Conwy medium. Algal growth was only inhibited by Shewanella sp. SR-14. V. alginolyticus did not show the algicidal activity, Growth of C. calcitrans increased synergistically with growth of V. alginolyticus. When the initial inoculum of V. alginolyticus was only 1 log cycle higher than that of Shewanella sp. SR-14, the effect of V. alginolyticus on the algicidal activity of Shewanella sp. SR-14 was insignificant during incubation of mixed culture, i.e., two bacterial species and the alga. However, when V. alginolyticus dominated Shewanella sp. SR-14 by 3 log cycles of bacterial counts, it was found that the strain SR-14 could not inhibited growth of C. calcitrans up to 5 days of incubation.

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Evaluation of Crack Resistance of Cold Joint as Usage of Sealing Tape (실링 테이프 적용에 따른 시공조인트 균열 저항성 평가)

  • Lee, JaeJun;Lee, Seonhaeng;Kim, Du-Byung;Lee, Jinwook
    • International Journal of Highway Engineering
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    • v.20 no.3
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    • pp.1-9
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    • 2018
  • PURPOSES : In order to evaluate a crack resistance at cold joint, sealing tape was adopted to apply at cold joint instead of typical tack coat material(RSC-4). The sealing tape was made by hot sealing material. The crack resistance as function of environmental and traffic loading was measured with visual observation. METHODS : In this study, the crack resistance was evaluated as function of environmental and traffic loading. The freeze-thaw method was adopted for environmental loading of asphalt pavement. condition. The damage of cold joint under freeze-thaw action is initiated by ice expansion load and accelerated by the interfacial damage between new and old asphalt pavement. The traffic loading was applied with wheel tracking machine on the cold joint area of the asphalt pavement for 3 hours at $25^{\circ}C$. The evaluation of crack resistance was measured with visual observation. The freeze-thaw results shows that the sealing tape was significantly increased the crack resistance based on. RESULTS : To estimate the crack resistance at cold joint area due to the environmental loading, the Freeze-thaw test was conducted by exposing the product to freezing temperature(approximately $-18^{\circ}C$) for 24 hours, and then allowing it to thaw at $60^{\circ}C$ for 24 hours. The tack coat material(RSC-4) was debonded after 21 cycles of the Freeze-thaw test. The first crack was observed after 14 freeze-thaw cycle with RSC-4 material. But, the sealing tape was not debonded after 24 cycle test. Also, the sealing tape shows the better performance of the crack resistance under the traffic loading with wheel track test. The crack was generated the under traffic loading with RSC-4(tack coating), however, the crack was not shown with sealing tape. It indicates that the sealing tape has a strong resistance of tensile stress due to traffic loading. CONCLUSIONS :Based on limited laboratory test result, a performance of crack resistance using the sealing tape is better than that of general tack coat material(RSC-4). It means that the sealing tape is possible to extend a pavement service life because the crack, one of the main pavement distresses, will be delayed.

Preparation of Metal Hydrides Using Chemical Synthesis and Hydriding Kinetics (화학적 합성법에 의한 금속수소화물의 제조 및 수소화 속도론적 연구)

  • Lee, Yun Sung;Oh, Jae Wan;Moon, Sung Sik;Nahm, Kee Suk
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.255-260
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    • 1998
  • Metal hydrides, $LaNi_5$ and $LaNi_{4.5}Al_{0.5}$, were prepared using chemical synthetic method, and their physical properties were examined using various analytic techniques such as TGA, XRD, SEM and EDX. The activation of the chemically prepared $LaNi_5$ and $LaNi_{4.5}Al_{0.5}$ was achieved by two hydriding/dehydriding cycles only. The miasurements of P-C-T curves revealed that 6 and 5.5 hydrogen atoms were stored in LaNi5and $LaNi_{4.5}Al_{0.5}$, respectively. The hydriding reaction rated for $LaNi_{4.5}Al_{0.5}$ were measured by the method of initial rates. It was found that the shrinking unreacted core model could be applied for the analysis of hydriding kinetics of $LaNi_5$. The rate controlling step of this reaction was the dissociative chemisorption of hydrogen molecules on the surface of $LaNi_5$. The activation energy was $9.506kcal/mol-H_2$. The rates measured in the temperature range from 273 to 343K and in pressure difference ($P_o-P_{eq}$) range form 0.25 to 0.66atm could be expressed as the following equation ; $\frac{dX}{dt}=4.636(P_o-P_{eq})$ exp($\frac{-9506}{RT}$).

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The Effect of Reaction Temperature for Synthesis of LiMn2O4 by Calcination Process and the Electrochemical Characteristics (소성법에 의한 LiMn2O4의 제조시 반응 온도의 영향과 전기화학적 특성)

  • Lee, Chul-Tae;Lee, Jin-Sik;Kim, Hyun-Joong
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.220-225
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    • 1998
  • The spinel structured $LiMn_2O_4$ was prepared from $Li_2CO_3$ and $MnO_2$ by calcination at various temperatures in the range of $750{\sim}900^{\circ}C$. It was found that the most suitable cubic structure of $LiMn_2O_4$ was obtained by heating at $850^{\circ}C$ for 12 hrs. However, in the calcination at $900^{\circ}C$, $Mn^{4+}$ of 0.06M was changed to $Mn^{+3}$ by the oxygen loss, so that it has been shown that the formula has changed to $LiMn_2O_{3.97}$. This phenomena were in agreement with the Jahn-Teller distortion by the increment of $Mn^{+3}$ ion on the octahedral sites of the spinel structured $LiMn_2O_4$. The results showed that after 15 charge/discharge cycles in the voltage range from 3.5V to 4.3V versus Li/$Li^+$ with a current density of $0.25mA/cm^2$, the spinel structured $LiMn_2O_4$ that was prepared at $900^{\circ}C$ showed a lower discharge capacity, 82~50 mAh/g, while the $LiMn_2O_4$, prepared at $850^{\circ}C$, showed the discharge capacity of 102~64 mAh/g.

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A Study on Hybrid DeNOx Process Using Selective Catalytic Reduction and Adsorption (선택적촉매환원과 흡착을 이용한 복합 탈질공정 연구)

  • Moon, Seung-Hyun;Jeon, Dong-Hwan;Park, Sung-Youl
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.12
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    • pp.1329-1336
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    • 2007
  • This study was carried out to develop an efficient process abating high NO concentration. A hybrid process of selective catalytic reduction(SCR) and activated carbon fiber(ACF) adsorption was newly designed and tested. Used ACF in NO adsorption was regenerated by simultaneously applying heat and vacuum. The result of ACF regeneration was for superior in the desorption condition at $140^{\circ}C$ and vacuum 600 mmHg. A commercial catalyst was used at the conditions of reaction temperature at $300^{\circ}C$, $NH_3/NO$ mole ratio = 1.0 for SCR process. NO evolved from ACF regeneration reactor could be removed by SCR reactor up to 98%. But high concentration of NO was exhausted from SCR reactor for one minute when the flue gas of NO 300 ppm and deserted NO from ACF regeneration were simultaneously treated by the same SCR reactor. Therefore, it is necessary to use additional small sized SCR reactor or to increase $NH_3$ concentration for a short time along with NO concentration rather than to mix flue gas with the gas evolving from ACF regeneration at fixed $NH_3$ inlet concentration. The hybrid process of SCR and ACF showed high NO removal efficiency over 80% at any time courses. Through the repeated cycles, stable DeNOx efficiency was maintained, indicating that the hybrid process would be a good countermeasure to the spotaneously high NO concentration instead of increasing the SCR capacity.

Studies on the induction of pregnancy and the number of fetuses during pregnancy in rats

  • Choi, Seung-Hee;Cho, Yong-Seong;Kim, Min-Ji;Lee, Chae-Hyeok;Seong, Hwan-Hoo;Baek, Soon-Hwa;Lee, Jang-Hee
    • Journal of Animal Reproduction and Biotechnology
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    • v.35 no.3
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    • pp.232-238
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    • 2020
  • This study used adult wistar-based rats to observe the sexual cycle as a morphological characteristic of vaginal epithelial cells by vaginal smearing, and investigated the fetal number through mating with male rats of the same strain. The target animal was a 12 to 13-week-old Wistar-based mature unlighted rat (weight 220 g to 240 g), room temperature 23 ± 2℃, 14 hours artificial lighting (05:00 to 19:00 hours), 10 hours Adapted individuals were used for rearing for at least 2 weeks under the conditions of the darkroom (19:00 to 05:00). The feed was managed for free feeding of pellet feed for animals and water. The vaginal smearing method was used for the experiments by observing the sexual cycle every morning and confirming that the normal sexual cycle of 4 or 5 days was repeated at least 2 cycles or more. As a result, the proestrus was found to have few red blood cells, the cells and nuclei were rather large and round, and many nucleated cells were identified. In the case of the estrus, the cells were large and the nuclei were not stained, and most of the keratinocytes were found. In addition, in the metestrus and diestrus, there were many white blood cells, and it was confirmed that nucleated epithelial cells and keratinocytes were significantly reduced. The pregnancy period was 21 ± 1.8 days, and the number of live births per delivery was 11.9 on average. The number of fetuses on the 8th and 10th days of pregnancy were 15.2 ± 0.4 and 15.4 ± 0.3, respectively. On the contrary, the number of fetuses on the 12th day of pregnancy was 12.9 ± 0.6, which was significantly (p < 0.05) decreased compared to the 10th day of pregnancy, and the number of fetuses was similar until delivery. As a result of investigating the change of body weight according to the birth weight and growth stage after delivery, the birth weight of female and male was 9.2 ± 2.0 g and 9.8 ± 2.5 g, respectively. After that, until the 16th day, the female and the male showed similarly moderate weight gain, and then showed a rapid weight gain until the 21st day of lactation. With reference to the results of this study, it is expected to be used as basic data for determining the mating time of rodents and controlling pregnancy and fetal number.

Satellite-Measured Vegetation Phenology and Atmospheric Aerosol Time Series in the Korean Peninsula (위성기반의 한반도 식물계절학적 패턴과 대기 에어로졸의 시계열 특성 분석)

  • Park, Sunyurp
    • Journal of the Korean Geographical Society
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    • v.48 no.4
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    • pp.497-508
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    • 2013
  • The objective of this study is to determine the spatiotemporal influences of climatic factors and atmospheric aerosol on phenological cycles of the Korea Peninsular on a regional scale. High temporal-resolution satellite data can overcome limitations of ground-based phenological studies with reasonable spatial resolution. Study results showed that phenological characteristics were similar among evergreen forest, deciduous forest, and grassland, while the inter-annual vegetation index amplitude of mixed forest was differentiated from the other forest types. Forest types with high VI amplitude reached their maximum VI values earlier, but this relationship was not observed within the same forest type. The phase of VI, or the peak time of greenness, was significantly influenced by air temperature. Aerosol optical thickness (AOT) time-series showed strong seasonal and inter-annual variations. Generally, aerosol concentrations were peaked during late spring and early summer. However, inter-annual AOT variations did not have significant relationships with those of VIs. Weak relationships between AOT amplitude and EVI amplitude only indicates that there would be potential impacts of aerosols on vegetation growth in the long run.

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Theoretical Study on Fuel Savings of Marine Diesel Engine by Exhaust-Gas Heat-Recovery System of Combined Cycle (복합 사이클의 배기가스 열회수 시스템에 의한 선박용 디젤엔진의 연료 절약에 관한 이론적 연구)

  • Choi, Byung Chul;Kim, Young Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.2
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    • pp.171-179
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    • 2013
  • The thermodynamic characteristics of a combined cycle applied with a topping cycle such as a trilateral cycle at relatively high temperatures and a bottoming cycle such as an organic Rankine cycle at relatively low temperatures have been theoretically investigated. This is an electric generation system used to recover the waste heat of the exhaust gas from a diesel engine used for the propulsion of a large ship. As a result, when the boundary temperature between the topping and the bottoming cycles increased, the system efficiencies of energy and exergy were simultaneously maximized because the total exergy destruction rate (${\sum}\dot{E}_d$) and exergy loss ($\dot{E}_{out2}$) decreased, respectively. In the case of a marine diesel engine, the waste heat recovery electric generation system can be utilized for additional propulsion power, and the propulsion efficiency was found to be improved by an average of 9.17 % according to the engine load variation, as compared to the case with only the base engine. In this case, the specific fuel consumption and specific $CO_2$ emission of the diesel engine were reduced by an average of 8.4% and 8.37%, respectively.

Structural and Electrochemical Properties of Li2Mn0.5Fe0.5SiO4/C Cathode Nanocomposite

  • Chung, Young-Min;Yu, Seung-Ho;Song, Min-Seob;Kim, Sung-Soo;Cho, Won-Il
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4205-4209
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    • 2011
  • The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ silicate was prepared by blending of $Li_2MnSiO_4$ and $Li_2FeSiO_4$ precursors with same molar ratio. The one of the silicates of $Li_2FeSiO_4$ is known as high capacitive up to ~330 mAh/g due to 2 mole electron exchange, and the other of $Li_2FeSiO_4$ has identical structure with $Li_2MnSiO_4$ and shows stable cycle with less capacity of ~170 mAh/g. The major drawback of silicate family is low electronic conductivity (3 orders of magnitude lower than $LiFePO_4$). To overcome this disadvantage, carbon composite of the silicate compound was prepared by sucrose mixing with silicate precursors and heat-treated in reducing atmosphere. The crystal structure and physical morphology of $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ was investigated by X-ray diffraction, scanning electron microscopy, and high resolution transmission electron microscopy. The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$/C nanocomposite has a maximum discharge capacity of 200 mAh/g, and 63% of its discharge capacity is retained after the tenth cycles. We have realized that more than 1 mole of electrons are exchanged in $Li_2Mn_{0.5}Fe_{0.5}SiO_4$. We have observed that $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ is unstable structure upon first delithiation with structural collapse. High temperature cell performance result shows high capacity of discharge capacity (244 mAh/g) but it had poor capacity retention (50%) due to the accelerated structural degradation and related reaction.