• Title/Summary/Keyword: temperature cycles

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Study of optimum growth condition of phase change Ge-Sb-Te thin films as an optical recording medium using in situ ellipsometry (In situ 타원법을 사용한 광기록매체용 Ge-Sb-Te 박막의 최적성장조건 연구)

  • Kim, Sang-Youl;Li, Xue-Zhe
    • Korean Journal of Optics and Photonics
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    • v.14 no.1
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    • pp.23-32
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    • 2003
  • The spectroe-ellipsometric constant $\Delta$, Ψ and the ellipsometric growth curves at the wavelength of 632.8 nm are collected. These are critically examined to find out the optimum growth condition of phase change $Ge_2Sb_2Te_5(GST)$ thin films as an optical recording medium. GST films are prepared using DC magnetron sputtering technique, under the selected experimental conditions of Ar gas pressure (5 mTorr, 7 mTorr and 10 mTorr), DC power of sputtering gun (15 W, 30 W and 45 W), and substrate temperature (from room temperature to 18$0^{\circ}C$). Based on the three film model, the density distribution of deposited GST films are obtained versus Ar gas pressure and DC power by analyzing spectro-ellipsometric data. The calculated evolution curves at the wavelength of 632.8 nm, are fit into the in situ observed ones to get information about the evolution of density distribution during film growth. The density distribution showed different evolution curves depending on deposition conditions. The GST films fabricated at DC power of 30 W or 45 W, and at Ar gas pressure of 7 mTorr turned out to be the most homogeneous one out of those prepared at room temperature, even though the maximum density difference between the dense region and the dilute region of the GST film was still significant (~50%). Finally, in order to find the optimum growth condition of homogeneous GST thin films, the substrate temperature is varied while Ar gas pressure is fixed at 7 mTorr and DC power at 30 W and 45 W respectively. A monotonic decrease of void fraction except for a slight increase at 18$0^{\circ}C$ is observed as the substrate temperature increases. Decrease of void fraction indicates an increase of film density and hence an improvement of film homogeneity. The optimum condition of the most homogeneous GST film growth turned out to be 7 mTorr of Ar gas pressure, 15$0^{\circ}C$ of substrate temperature. and 45 W of DC power. The microscopic images obtained using scanning electron microscope, of the samples prepared at the optimum growth condition, confirmed this conclusion. It is believed that the fabrication of homogeneous GST films will be quite beneficial to provide a reliable optical recording medium compatible with repeated write/erase cycles.

Experimental Study on Thermochemical Water Splitting Hydrogen Production Using $MnO_2/Mn_2O_3$/NaOH System Added with $ZrO_2$ ($ZrO_2$ 첨가 $MnO_2/Mn_2O_3$/NaOH 계를 이용한 열화학적 물분해 수소제조 실험 연구)

  • Cha, Kwang-Seo;Ryu, Jae-Chun;Lee, Dong-Hee;Kim, Young-Ho;Park, Chu-Sik;Kim, Jong-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.4
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    • pp.353-361
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    • 2006
  • As one of the thermochemical water splitting hydrogen production cycles, which could be operated at the lower temperature below 1200 K, we investigated the feasibility of the cyclic operation of Ispra Mark 2 cycle with the addition of $ZrO_2$. The cycle is theoretically composed of three reaction steps; (1) 1st step($2MnO_2{\rightarrow}Mn_2O_3+0.5O_2$), (2) 2nd step($Mn_2O_3+4NaOH{\rightarrow}2Na_2O{\cdot}MnO_2+H_2+H_2O$) and (3) 3rd step($2Na_2O{\cdot}MnO_2H_2O{\rightarrow}4NaOH+2MnO_2$). From the TPR tests, the temperature ranges for $O_2$ production in 1st step and $H_2$ production in 2nd step were $550{\sim}750^{\circ}C$ and $650{\sim}750^{\circ}C$, respectively. In $MnO_2/Mn_2O_3/NaOH$ system, the formation of molten products due to the reaction between manganese oxides and NaOH were greatly decreased with the addition of $ZrO_2$. In addition, the results of a cyclic test were discussed with the viewpoint of $H_2$ production amounts and the feasibility of the process improvement.

Experimental Study on Optimization of Absorber Configuration in Compression/Absorption Heat Pump with NH3/H2O Mixture (NH3/H2O 혼합냉매를 사용한 압축/흡수식 히트펌프 시스템의 흡수기 최적화에 관한 실험적 연구)

  • Kim, Ji-Young;Kim, Min-Sung;Baik, Young-Jin;Park, Seong-Ryong;Chang, Ki-Chang;Ra, Ho-Sang;Kim, Yong-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.3
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    • pp.229-235
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    • 2011
  • This research aims todevelopa compression/absorption hybrid heat pump system using an $NH_3/H_2O$ as working fluid.The heatpump cycle is based on a combination of compression and absorption cycles. The cycle consists of two-stage compressors, absorbers, a desorber, a desuperheater, solution heat exchangers, a solution pump, a rectifier, and a liquid/vapor separator. The compression/absorption hybrid heat pump was designed to produce hot water above $90^{\circ}C$ using high-temperature glide during a two-phase heat transfer. Distinct characteristics of the nonlinear temperature profile should be considered to maximize the performance of the absorber. In this study, the performance of the absorber was investigated depending on the capacity, shape, and arrangementof the plate heat exchangers with regard tothe concentration and distribution at the inlet of the absorber.

Optimization of Resistance Spot Weld Condition for Single Lap Joint of Hot Stamped 22MnB5 by Taking Heating Temperature and Heating Time into Consideration (핫스템핑 공정에서 가열온도 및 유지시간을 고려한 22MnB5의 단일겹치기 저항 점용접 조건 최적화)

  • Choi, Hong-Seok;Kim, Byung-Min;Park, Geun-Hwan;Lim, Woo-Seung;Lee, Sun-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.10
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    • pp.1367-1375
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    • 2010
  • In this study, optimization of the process parameters of the resistance spot welding of a sheet of aluminum-coated boron alloyed steel, 22MnB5, used in hot stamping has been performed by a Taguchi method to increase the strength of the weld joint. The process parameters selected were current, electrode force, and weld time. The heating temperature and heating time of 22MnB5 are considered to be noise factors. It was known that the variation in the thickness of the intermetallic compound layer between the aluminum-coated layer and the substrate, which influences on the formation of nugget, was generated due to the difference of diffusion reaction according to heating conditions. From the results of spot weld experiment, the optimum weld condition was determined to be when the current, electrode force, and weld time were 8kA, 4kN, and 18 cycles, respectively. The result of a test performed to verify the optimized weld condition showed that the tensile strength of the weld joint was over 32kN, which is considerably higher than the required strength, i.e., 23kN.

A Simulation Study to Investigate Climatic Controls on Net Primary Production (NPP) of a Rugged Forested Landscape in the Mid-Western Korean Peninsula (기복이 심한 한반도 중서부 산림경관에서 기후가 순일차생산(NPP)에 미치는 영향에 대한 모사연구)

  • Eum Sungwon;Kang Sinkyu;Lee Dowon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.1
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    • pp.66-77
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    • 2005
  • We have investigated microclimatic controls on the spatiotemporal variations of net primary production (NPP) of a rugged forested watershed using the process-based biogeochemical model (BIOME-BGC). To validate the model simulation of water and carbon cycles at the plot scale, we have conducted field survey over deciduous broadleaf forest (DBF) and evergreen needleleaf forest (ENF) since 2000. The modeled values of soil temperature, soil moisture and soil respiration showed high correlation with those from the field measurements. The modeled seasonal changes of NPP showed high correlation with air temperature but no significant correlation with water related parameters. The precipitation frequency turned out to be the best climatic factor to explain the annual variation of NPP. Furthermore, NPP of ENF was more sensitive to precipitation frequency than that of DBF. With changes in vegetation cover and topography, the spatial distribution of NPP was of great heterogeneity, which was negatively correlated with the magnitude of NPP. Despite the annual precipitation of 1,400mm, NPP at the study site was constrained by the amount of water available for the vegetation. Such a modeling result should be verified by the field measurements.

Effects of Operating Variables on Sorption Capacity of CO2 Absorbents for SEWGS Process (SEWGS 공정용 CO2 흡수제들의 흡수능력에 미치는 조업변수들의 영향)

  • Ryu, Ho-Jung;Kim, Hyo-Sung;Lee, Seung-Yong;Lee, Dong-Ho;Kim, Jae-Chang
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.994-1001
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    • 2012
  • The Effects of operating variables on reactivity of two $CO_2$ absorbents (PKM1-SU and P4-600) for SEWGS process were investigated in a pressurized fluidized bed reactor. For both $CO_2$ absorbents, $CO_2$ sorption capacity decreased as the number of absorption-regeneration cycles increased. PKM1-SU absorbent represented higher $CO_2$ sorption capacity than that of P4-600 absorbent. However, P4-600 absorbent represented better performance than PKM1-SU absorbent from the view points of regeneration temperature and regeneration rate. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the steam concentration increased. However, $CO_2$ sorption capacity increased initially as the steam concentration increased from 5% to 10%, but maintained thereafter for P4-600 absorbent. For both $CO_2$ absorbents, $CO_2$ sorption capacity increased as the final regeneration temperature increased. For PKM1-SU absorbent, $CO_2$ sorption capacity increased as the pressure increased and the increment tendency was drastic at higher pressure than 15 bar.

Interannual variabilities of the East Asia precipitation associated with tropical and subtropical sea surface temperature (열대 및 아열대 SST에 관련된 동아시아 강우량의 경년 변동성)

  • Ha, Kyung-Ja
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.28-28
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    • 1995
  • The aim of the present study is to investigate the interannual variabilities of the East Asia monsoon rainfall associated with the global sea surface temperature anomaly(SSTA). For this study, the summer rainfall(from June to August) over the twenty-eight period of 1961-1988 were analyzed with being divided by nine-subregions over East Asia including Korea, China and Japan. From the analysis of the principal modes explaining the interannual variation, the interannual variabilities of summer rainfalls in South Japan and Korea are larger than those of the other subregions of the East Asia. There is a strong negative correlation between the summer rainfalls of south China and Korea. In this study, the relationship between the summer monsoon of each subregion and SSTs of the tropical NINO regions, of western Pacific warm pool, and of the subtropical ocean were investigated. The longitudinal sections of the lagged cross correlations of the summer rainfal1 anomaly in (a) Korea and (b) south China, and the monthly SSTA in the equatorial(averaged from 65 to 6N) Pacific were analyzed. The negative maximum correlation pattems of Korea''s stammer rainfal1 and SSTs over the eastern Pacific is transfered to positive maximum conrlation over central Pacific region with a biennial periodicity. In South China, the significant positive correlations are found at -12 month lag over the eastern Pacific and maximum negative correlation at 16 month lag over the central Pacific with the quasi-biennial oscillation. But the correlation coefficient reverses completely to that in Korea. In order to investigate the most prevailing interannual variability of rainfall related to the favored SSTA region, the lagged cross correlations between East Asia rainfall and SSTs over the moO regions(NINO 1+2(0-105, 90W-80W), NINO 3(5N-5S, 150W-90W), NINO 4(5N-5S, 160E-l50W) and the western Pacific worm pool (5N-5S, 120E-l60E) were analyzed. Among the lagged cross-correlation cycles in NINO regions, the maximum correlations for the negative lagged months prevail in NINO 1+2 and NINO 3, and the cross correlations for the positive lagged months NINO 4. It is noteworthy that correlation between the western Pacific warm pool SSTA and the monsoon rainfall in Korea and South China have the maximum value at negative 4 month lag. The evolution of the correlation between the East Asia monsoon rainfall and SSTA is linked to the equatorial convective cluster and related to northward propagating situation, and raising the possibility that the East Asia monsoon precipitation may be more fundamentally related to the interaction of intraseasonal oscillations and the sub-regional characteristics including the surface boundary conditions and the behavior of climatological air mass.

Interannual variabilities of the East Asia precipitation associated with tropical and subtropical sea surface temperature (열대 및 아열대 SST에 관련된 동아시아 강우량의 경년 변동성)

  • 하경자
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.413-426
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    • 1995
  • The aim of the present study is to investigate the interannual variabilities of the East Asia monsoon rainfall associated with the global sea surface temperature anomaly(SSTA). For this study, the summer rainfall(from June to August) over the twenty-eight period of 1961-1988 were analyzed with being divided by nine-subregions over East Asia including Korea, China and Japan. From the analysis of the principal modes explaining the interannual variation, the interannual variabilities of summer rainfalls in South Japan and Korea are larger than those of the other subregions of the East Asia. There is a strong negative correlation between the summer rainfalls of south China and Korea. In this study, the relationship between the summer monsoon of each subregion and SSTs of the tropical NINO regions, of western Pacific warm pool, and of the subtropical ocean were investigated. The longitudinal sections of the lagged cross correlations of the summer rainfal1 anomaly in (a) Korea and (b) south China, and the monthly SSTA in the equatorial(averaged from 65 to 6N) Pacific were analyzed. The negative maximum correlation pattems of Korea's stammer rainfal1 and SSTs over the eastern Pacific is transfered to positive maximum conrlation over central Pacific region with a biennial periodicity. In South China, the significant positive correlations are found at -12 month lag over the eastern Pacific and maximum negative correlation at 16 month lag over the central Pacific with the quasi-biennial oscillation. But the correlation coefficient reverses completely to that in Korea. In order to investigate the most prevailing interannual variability of rainfall related to the favored SSTA region, the lagged cross correlations between East Asia rainfall and SSTs over the moO regions(NINO 1+2(0-105, 90W-80W), NINO 3(5N-5S, 150W-90W), NINO 4(5N-5S, 160E-l50W) and the western Pacific worm pool (5N-5S, 120E-l60E) were analyzed. Among the lagged cross-correlation cycles in NINO regions, the maximum correlations for the negative lagged months prevail in NINO 1+2 and NINO 3, and the cross correlations for the positive lagged months NINO 4. It is noteworthy that correlation between the western Pacific warm pool SSTA and the monsoon rainfall in Korea and South China have the maximum value at negative 4 month lag. The evolution of the correlation between the East Asia monsoon rainfall and SSTA is linked to the equatorial convective cluster and related to northward propagating situation, and raising the possibility that the East Asia monsoon precipitation may be more fundamentally related to the interaction of intraseasonal oscillations and the sub-regional characteristics including the surface boundary conditions and the behavior of climatological air mass.

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Atmosphere and Green Pepper Quality Influenced by Active Air Flushing in Fresh Produce Container Controlled in Real-time $O_2$ Concentration (실시간 $O_2$ 농도 제어 풋고추 용기에서 능동기체치환 시스템이 기체조성과 품질보존에 미치는 효과)

  • Jo, Yun Hee;An, Duck Soon;Lee, Dong Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.20 no.2
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    • pp.29-33
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    • 2014
  • Active air flushing mini-pumps were installed in a rigid polypropylene container ($32cm{\time}23cm{\time}18cm$) containing 900 g of fresh green peppers for effectively controlling its $O_2$ concentration on real time basis to preserve the product quality. The performance of the constructed system was compared to that of the modified atmosphere (MA) container system with gas diffusion tube controlled in close/open cycles responding to real time $O_2$ concentration at 10 and $20^{\circ}C$. In the control logic, the $O_2$ concentration was programmed to be located exactly at 13% or stay in the range of 13-15%. The active air flushing system could control the $O_2$ concentration in the desired level or range at both temperatures, while the passive diffusion system could work only under the low temperature condition of $10^{\circ}C$. At higher temperature of $20^{\circ}C$, the passive diffusion system could not manage the produce respiration increased more highly than the gas transfer through the diffusion tube, resulting in too low $O_2$ concentration and too high $CO_2$ concentration which would be injurious to the green pepper. When tested at $20^{\circ}C$, the MA container system could preserve the green pepper better than the perforated air package in terms of weight loss, ascorbic acid and chlorophyll contents and firmness.

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A Study on The Characteristics of Solar Cell by Thermal Shock test (열충격 시험을 통한 태양전지 특성에 관한 연구)

  • Kang, Min-Soo;Jeon, Yu-Jae;Shin, Young-Eui
    • Journal of Energy Engineering
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    • v.21 no.3
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    • pp.249-253
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    • 2012
  • In this study, The report analysed the characteristics of power drop in solar cell through thermal shock test. The solar cells were tested 500 cycles in $-40^{\circ}C$ lowest temperature and $120^{\circ}C$ highest temperature by thermal shock test on ironbound conditions, that excerpted standard of PV Module(KS C IEC-61215). The result of the efficiency analysis through measure of I-V, efficiency of Cell decreased from 13.9% to 11.0% and decreasing rate was 20.9% after test. The result of the surface analysis through EL, solar cell has damage of gridfinger and ribbon joint. Cell cracks were founded in damage of cells through cross section of solar cells. Also, Fill factors were decreased from 72.3% to 62.0% after thermal shock test and decreasing rate is 11.8%. therefore, Yearly power drop is aggravated with facts that cell crack, damage of surface and power loss of cell by change of I-V characteristic curve with decreasing of parallel resistance.