• Title/Summary/Keyword: temperature cycles

Search Result 884, Processing Time 0.028 seconds

Triallyl Borate as an Effective Separator/Cathode Interphase Modifier for Lithium-ion Batteries

  • Ha Neul Kim;Hye Rim Lee;Taeeun Yim
    • Journal of Electrochemical Science and Technology
    • /
    • v.14 no.3
    • /
    • pp.272-282
    • /
    • 2023
  • Ni-rich layered oxides cathode has recently gained attention as an advanced cathode material due to their applicable energy density. However, as the Ni component in the layered site is increased, the high reactivity of Ni4+ results in parasitic reaction associated with decomposing electrolyte, which leads to a rapid decreasing the lifespan of the cell. The electrolyte additive triallyl borate (TAB) improves interfacial stability, leading to a stable cathode-electrolyte interphase (CEI) layer on the LNCM83 cathode. A multi-functionalized TAB additive can produce a uniformly distributed CEI layer via electrochemical oxidation, which implies an increase in long-term cycling performance. After 100 cycles at elevated temperature, the cell tested by 0.75 TAB retained 88.3% of its retention ratio, whereas the cell performed by TAB-free electrolyte retained 64.1% of its retention. Once the TAB additive formed CEI layers on the LNCM83 cathode, it inhibited the decomposition of carbonate-based solvents species in addition to the dissolution of transition metal components from the cathode. The addition of TAB to LNCM83 cathode material is believed to be a promising way to increase the electrochemical performance.

Quench/recovery test results of the YBCO coated conductors(CCs) having various stabilizer thicknesses (YBCO coated conductors(CCs)의 안정화재 두께 변화에 따른 quench/recovery 특성 분석에 관한 연구)

  • Kwon, N.Y.;Kim, H.S.;Kim, K.L.;Kim, K.J.;Yim, S.W.;Kim, H.R.;Hyun, O.B.;Lee, H.G.
    • Progress in Superconductivity and Cryogenics
    • /
    • v.11 no.3
    • /
    • pp.10-14
    • /
    • 2009
  • Since a stabilizer of YBCO coated conductor (CC) plays a very important role of bypassing over-current and transferring heat generated in the moment of fault, it is one of big issues to determine the material of the stabilizer and its dimension for the high performance of the HTS power application system. Especially, in the case of a superconducting fault current limiter (SFCL), which requires it to react immediately to the occurrence of fault, characteristics of stabilizer are decisive in limiting fault current and recovering superconducting properties during and after quenching. In this paper, the quench / recovery characteristics of YBCO CCs with various thickness of stabilizer were analyzed. The quench/recovery test carried out at 20 $V_{rms}$, 5 cycles (60 Hz) and results showed that as the thickness of the stabilizer decreased, both the final approach temperature and the recovery time decreased.

Synthesis of Pd/Cu-Fe polymetallic nanoparticles for in situ reductive degradation of p-nitrophenol

  • Wenbin, Zhang;Lanyu, Liu;Jin, Zhao;Fei, Gao;Jian, Wang;Liping, Fang
    • Membrane and Water Treatment
    • /
    • v.13 no.2
    • /
    • pp.97-104
    • /
    • 2022
  • With a small particle size, specific surface area and chemical nature, Pd/Cu-Fe nanocomposites can efficiently remove the organic compounds. In order to understand the applicability for in situ remediation of contaminated groundwater, the degradation of p-nitrophenol by Pd/Cu-Fe nanoparticles was investigated. The degradation results demonstrated that these nanoparticles could effectively degrade p-nitrophenol and near 90% of degradation efficiency was achieved by Pd/Cu-Fe nanocomposites for 120 min treatment. The efficiency of degradation increased significantly when the Pd content increased from 0.05 wt.% and 0.10 wt.% to 0.20 wt.%. Meanwhile, the removal percentage of p-nitrophenol increased from 75.4% and 81.7% to 89.2% within 120 min. Studies on the kinetics of p-nitrophenol that reacts with Pd/Cu-Fe nanocomposites implied that their behaviors followed the pseudo-first-order kinetics. Furthermore, the batch experiment data suggested that some factors, including Pd/Cu-Fe availability, temperature, pH, different ions (SO42-, PO43-, NO3-) and humic acid content in water, also have significant impacts on p-nitrophenol degradation efficiency. The recyclability of the material was evaluated. The results showed that the Pd/Cu-Fe nanoparticles have good recycle performance, and after three cycles, the removal rate of p-nitrophenol is still more than 83%.

Enhancement of the energy efficiency of hydrogen SOFC system by integrated cold energy utilization and waste heat recovery method

  • Nguyen Quoc Huy;Duong Phan Anh;Ryu Bo Rim;Lee Jin Uk;Kang Ho Keun
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
    • /
    • 2022.11a
    • /
    • pp.160-161
    • /
    • 2022
  • Hydrogen is bridge fuel with high energy content and environmentally friendly to satisfy the stringent IMO regulation relating to greenhouse gas (GHG) emissions. There is growing interest in hydrogen in numerous nations and regions illustrated by an extensive range of research and development in technology. Regarding maritime applications, researchers have recognized the utilization of hydrogen as a fuel for fuel cells, a device that converts the chemical energy of the fuel to electrical energy. Solid oxide fuel cell (SOFC), with high working temperature, is easy to combine with the waste heat recovery cycles/devices to increase output power and thermodynamic performances as well. Furthermore, the cold energy from liquid hydrogen supplied to SOFC can also be used to generate more power. In this study, we proposed a SOFC integrated system with the idea of combining the waste heat recovery from the SOFC exhaust stream and cold energy utilization from LH2. The designation is aimed to target small-scale vessel which uses electric propulsion for short distances voyage.

  • PDF

Fatigue Behavior of 23Cr26Ni Heat Resistant Steel (23Cr26Ni 내열강의 피로 특성)

  • Lee, H.W.;Kwun, S.I.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.24 no.2
    • /
    • pp.92-98
    • /
    • 2011
  • The influence of the cooling condition after solution treatment on the high temperature fatigue resistance of 23Cr-26Ni heat resistant steel was investigated. Two different cooling conditions were applied to the steel after solution treatment at $1200^{\circ}C$ for 3 hours. One specimen was water quenched immediately after the solution treatment. The other one was furnace cooled at a rate of $0.5^{\circ}C/min$ down to $750^{\circ}C$ after the solution treatment. Then, both specimens were aged at $750^{\circ}C$ for 5 hours. Under two different heat treatment conditions, the low cycle fatigue (LCF) test was performed at $600^{\circ}C$ and room temperature (RT). Only cyclic hardening continued from the beginning until fracture at all strain amplitudes during LCF at $600^{\circ}C$. This phenomenon was attributed to the increase in the dislocation density due to cyclic deformation, which resulted in the interaction between the newly created dislocations and precipitates. Cyclic hardening followed by saturation and cyclic softening was observed at RT. Cyclic softening was attributed to the dislocation annihilation rate exceeding the dislocation generation rate. Other probable factor for cyclic softening was some cavities formed around grain boundaries after 20 cycles. WQ and FC have a similar LCF behavior at RT and $600^{\circ}C$ as shown in the cyclic stress response curves.

Evaluation of Moisture Susceptibility of Porous Hot Mixed Asphalt Mixtures with Hydrated Lime using Non-destructive Impact Test (비파괴 충격파 시험을 통한 소석회 첨가 투수성 가열 아스팔트 혼합물의 수분민감성 평가)

  • Kim, Dowan;Mun, Sungho
    • International Journal of Highway Engineering
    • /
    • v.17 no.4
    • /
    • pp.77-87
    • /
    • 2015
  • PURPOSES: It is theoretically well known all over the world, that porous hot mixed asphalt (HMA) with hydrated Lime improves moisture and rutting resistance, and reduces pothole occurrence frequency, as well as the life cycle cost (LCC). METHODS : Addictive in the two different formations of the liquid anti-stripping Agent and powder Hydrated-Lime was applied in this investigation in order to obtain relatively clear results according to their types and conditions. Firstly, the moisture conditions were set, and applied to the porous HMA mixtures with hydrated lime (anti-stripping agent). Next, it was followed by a non-destructive test with the application of three freeze-thaw cycles, which were individually carried out thrice to compare the results of the dynamic moduli. Lastly, the hydrated lime effect related to moisture sensibility to porous HMA has been verified through the analysis of the modulus results regarding the change rate of dynamic modulus per n-cycle. RESULTS: It is clear from this investigation, that the dynamic modulus is inversely proportional to the change in temperature, as the graph representing the rigidity of the thermorheologically simple (TRS) material showed gradual decline of the dynamic modulus with the increase in temperature. CONCLUSIONS: The porous HMA mixture with the anti-stripping agent (hydrated Lime) has been found to be more moisture resistant to freezing and thawing than the normal porous HMA mixture. It is clear that the hydrated lime helps the HMA mixture to improve its fatigue resistance.

Evaluation of Material Properties in Austenite Stainless Steel Sheet with Scanning Acoustic Microscopy (초음파현미경을 이용한 오스테나이트 스테인레스강의 재료특성 평가)

  • Park, Tae-Sung;Kasuga, Yukio;Park, Ik-Keun;Kim, Kyoung-Suk;Miyasaka, Chiaki
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.21 no.2
    • /
    • pp.267-275
    • /
    • 2012
  • Austenite stainless steel 304 has properties of high resistance to corrosion and temperature changes. Therefore, this material is widely used in various of industries. However, when the material is subjected to heating and cooling cycles the forming accuracy, for example, the right angle associated with a sharp bend such as corner is lost. This phenomenon is caused by the reversion of the deformation-induced martensite into austenite when the temperature in increased. This result in misfit of a structure or an assembly, and an increase in residual stress. Hence, it is important to understand this process. In this study, to evaluate the mechanical behavior of the deformation-induced martensite and reversed austenite, a scanning acoustic spectroscope including the capability of obtaining both phase and amplitude of the ultrasonic wave (i.e., the complex V(z) curve method) was used. Then, the velocities of the SAW propagating within the specimens made in different conditions were measured. The experimental differences of the SAW velocities obtained in this experiment were ranging from 2,750 m/s to 2,850 m/s, and the theoretical difference was 3.6% under the assumption that the SAW velocity was 2,800 m/s. The error became smaller as the martensite content was increased. Therefore, the SAW velocity may be a probe to estimate the marternsite content.

MEASUREMENT OF OPERATIONAL ACTIVITY FOR NONROAD DIESEL CONSTRUCTION EQUIPMENT

  • HUAI T.;SHAH S. D.;DURBIN T. D.;NORBECK J. M.
    • International Journal of Automotive Technology
    • /
    • v.6 no.4
    • /
    • pp.333-340
    • /
    • 2005
  • In order to better quantify the contribution from nonroad sources to emission inventories, it is important to understand not only the emissions rates of these engines but also activity patterns that can be used to accurately portray their in-use operation. To date, however, very little information is available on the actual activity patterns of nonroad equipment. In this study, a total of 18 pieces of nonroad equipment were instrumented with collected data including intake manifold air pressure (MAP), exhaust temperature and, on a subset of vehicles, engine rpm and throttle position. The equipment included backhoes, compactors, dozers, motor graders, loaders and scrappers used in applications such as landfilling, street maintenance and general roadwork. The activity patterns varied considerably depending on the type of equipment and the application. Daily equipment operating time ranged from less than 30 minutes to more than 8 hours, with landfill equipment having the highest daily use. The number of engine starts per day ranged from 3-11 lover the fleet with an average of 5 starts per day. The average percent idle time for the fleet was approximately $25\%$ with a range from 11 to $65\%$ for individual pieces of equipment. Duty cycles based on exhaust temperature/throttle position profiles were also developed for two graders and one dozer.

Differential Diagnosis of Porcine Viral Diarrhea by Multiplex RT-PCR (Multiplex RT-PCR에 의한 돼지 바이러스 설사증의 감별 진단)

  • Hwang, Bo-Won;Kim, Toh-Kyung;Kim, Eun-Gyeong;Kim, Yong-Hwan;Yeo, Sang-Geon
    • Journal of Veterinary Clinics
    • /
    • v.23 no.3
    • /
    • pp.300-307
    • /
    • 2006
  • In the present study, methods of the reverse transcription-polymerase chain reaction(RT-PCR) were evaluated for the rapid detection and differentiation of transmissible gastroenteritis virus(TGEV), porcine epidemic diarrhea virus(PEDV) and rotavirus in piglets suffering from diarrhea. For the purposes, the PCR conditions were first confirmed for the amplification of VP7 gene of rotavirus and N gene of TGEV and PEDV using each specific primers and their annealing temperature. Multiplex RT-PCR methods were further determined to distinguish these viral infections and the results are as follows. For the specific amplification of these viral genes, the reliable PCR condition was determined as 30 cycles of reaction consisting each 1 min of denature at $94^{\circ}C$, annealing at $42^{\circ}C$ and polymerization at $72^{\circ}C$ with 1.0 mM $MgCl_2$. It was able to differentiate these viral infections in the intestines and feces of piglets suffering from diarrhea by duplex PCR for TGEV and PEDV and single PCR for rotavirus with a primer-annealing temperature of $42^{\circ}C$. When the multiplex RT-PCR were undertaken for the field samples, 17 cases of PEDV and 5 cases of rotavirus infections were differential diagnosed in a total of 92 samples of intestines and feces of the piglets with diarrhea.

Photocatalytic Property of Nano-Structured TiO$_2$ Thermal Sprayed Coating - Part II: TiO$_2$ -WO$_3$ Coating - (나노구조 TiO$_2$용사코팅의 미세조직 제어 공정기술 개발과 광촉매 특성평가 - Part II: TiO$_2$- WO$_3$ 코팅 -)

  • 이창훈;최한신;이창희;김형준;신동우
    • Journal of Welding and Joining
    • /
    • v.21 no.4
    • /
    • pp.46-55
    • /
    • 2003
  • TiO$_2$-WO$_3$(8.2wt%) coatings were prepared by the APS (Atmospheric Plasma Spraying) process to clarify the relationship between the process parameters(H$_2$ gas flow rate of plasma 2nd gas and spraying distance) of the APS coating and photo-decomposition efficiency kinetics of the MB(methylene blue) aqueous solution decomposition and to understand the effect of addition of WO$_3$ on photocatalytic properties of TiO$_2$ sprayed coating. Further, the temperature and velocity of flying particles were measured by DPV-2000 to investigate the relationship between microstructure of coatings and process parameters. Properties of coatins were investigated by XRD, SEM, XPS, RAMAN, UV/VIS spectrometer. In case of the TiO$_2$-WO$_3$(8.2wt%) coating, it had a lower anatase fraction than that of pure-TiO$_2$ coatings because of flying in the higher temperature plasma plume by the heavy weight of TiO$_2$, WO$_3$. And, when WO$_3$ added powders were spayed, the doping effects of W ions substituted into the Ti ion sites was not occured during melting and solidification cycles of spraying. It was found that the addition of WO$_3$ was ineffective effective on increasing photo-decomposition efficiency of TiO$_2$ sprayed coating.