• Bulletin of the Korean Chemical Society
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• 제16권10호
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• pp.929-933
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• 1995

The electronic band structure and electrical properties of KMo4O6 containing chains of condensed molybdenum octahedra are analyzed by means of the extended Hu&ckel tight-binding method. KMo4O6 has partially filled bands of 1D as well as 3D character. They also exhibit the anisotropic band dispersions with bandwidths much larger along the c* axis than along the directions perpendicular to it. Thus, conduction electrons are essentially delocalized along the c* direction (i.e., the chain of condensed molybdenum octahedra) in the solid. The 1D band of two partially filled d-block bands leads to Fermi surface nesting with the wave vector q=0.3c*. The CDW instability due to this nesting is expected to cause the phase transition associated with the resistivity anomaly at low temperature. The characteristics of metallic behavior in the crystallographic ab plane are explained on the basis of the unnested 2D Fermi surfaces.

• 대한원격탐사학회지
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• 제38권4호
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• pp.387-394
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• 2022

Coastal upwelling is a significantly imperative process for understanding the interactions between physical and ecological processes and has been investigated incessantly. In this study, we explored the upwelling index, specifically upwelling age (UA). UA enabled us to observe the initiating, sustaining, and decaying upwelling processes. Although the sensitivity of many other geophysical parameters to estimate UA has been investigated, the wind direction has not been evaluated. Thus, we assessed the appropriate wind direction for the UA and obtained efficient upwelling signals from the four coastal stations. Furthermore, we applied the UA and compared it with the satellite sea level anomaly, sea surface temperature, and chlorophyll-a changes to validate how UA depicts their spatial extents. Thus, UA can predict the timing of coastal upwelling events using predicted geophysical parameters.

• Journal of Information Technology Applications and Management
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• 제29권5호
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• pp.27-37
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• 2022

This study intends to link agricultural machine history data with related organizations or collect them through IoT sensors, receive input from agricultural machine users and managers, and analyze them through AI algorithms. Through this, the goal is to track and manage the history data throughout all stages of production, purchase, operation, and disposal of agricultural machinery. First, LSTM (Long Short-Term Memory) is used to estimate oil consumption and recommend maintenance from historical data of agricultural machines such as tractors and combines, and C-LSTM (Convolution Long Short-Term Memory) is used to diagnose and determine failures. Memory) to build a deep learning algorithm. Second, in order to collect historical data of agricultural machinery, IoT sensors including GPS module, gyro sensor, acceleration sensor, and temperature and humidity sensor are attached to agricultural machinery to automatically collect data. Third, event-type data such as agricultural machine production, purchase, and disposal are automatically collected from related organizations to design an interface that can integrate the entire life cycle history data and collect data through this.

• Journal of Chest Surgery
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• 제9권1호
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• pp.1-9
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• 1976

The present. study reports four cases of congenital heart diseases, who received open heart surgery by the Sarn's Heart-Lung-Machine in the department of Thoracic Surgery, Hanyang University Hospital during the period between July 1975 and May 1976. The Heart-Lung-Machine consisted of the Sarn's five head roller pump motor system (model 5000), heat exchanger, bubble trap, the Rygg-Kyvsgaard oxygenator, and monitors. The priming of pump oxygenator was carried out by the hemodilution method using Hartman's solution and whole blood. Of the four cases of the heart diseases, three whose body weight were below 30kg, received the partial hemodilution priming and the remaining one whose body weight was 52kg received the total hemodilution priming with Hartman's solution alone. The rate of hemodilution was in the average of 60.5ml/kg. Extracorporeal circulation was performed at the perfusion flow rate of the average 94.0ml/kg/min, and at the moderate hypothermia between 35'5"C and 30'5"C of the rectal temperature. In the total cardiopulmonary bypass, arterial blood pressure was anged between 30 mmHg and 85 mmHg, generally maintaining over 60 mmHg and venous pressure was measured between 4 and $23cmH_2O$, generally maintaining below $10cmH_2O$. The first case: The patient, a nine year old girl having the symptoms and physical signs typical to cardiac anomaly was definitely diagnosed as isolated pulmonary stenosis through the cardiac catheterization. There was, however, no cyanosis, no pathological finding by X-ray and E.C.G. tracings. The valvulotomy was performed through the arteriotomy of pulmouary artery under the total cardiopulmonary bypass. Postoperative course of the patient was uneventful, and murmur and the clinical symptoms disappeared. The second case: A 12 year old boy with congenital heart anomaly was positively identified as having ventricular septal defect through the cardiac catheterization. As in the case with the first case, the patient exhibited the symptoms and physical signs typical to cardiac anomaly, but no pathological abnormality by X-ray and E.C.G. tracings. The septal defect was localized on atrioventricular canal and was 2 by 10 mm in size. The septal defect was closed by direct simple sutures under the cardiopulmonary bypass. Postoperative hemodynamic study revealed that the pressure of the right ventricle and pulmonary artery were decreased satisfactory. Postoperative course of the patient was uneventful, and murmur and the clinical symptoms disappeared. The third case: The patient, a 19 year old girl had been experienced the clinical symptoms typical to cardiac anomaly for 16 years. The pink tetralogy of Fallot was definitey diagnosed through the cardiac catheterization. The patient was placed on an ablolute bed rest prior to the operation because of severe exertional dyspnea, fatigability, and frequent syncopal attacks. However, she exhibited very slight cyanosis. Positive findings were noted on E.C.G. tracings and blood picture, but no evidence of pathological abnormality on X-ray was observed. All of the four surgical approaches such as Teflon patch closure (3 by 4cm in size) of ventricular septal defect, myocardial resection of right ventricular outflow tract, valvulotomy of pulmonary valvular stenosis, and pericardial patch closing of ventriculotomy wound were performed in 95 minutes under the cardiopulmonary bypass. Postoperative hemodynamic study revealed that the pressure of the right ventricle was decreased and pulmonary artery was increased satisfactorily. Postoperative course of the patient was uneventful, and murmur and the clinical symptoms disappeared. The fourth case: The patient, a 7 1/4 year old girl had the symptoms of cardiac anomaly for only three years prior to the operation. She was positively identified as having acyanotic tetralogy of Fallot by open heart surgery. The patient showed positive findings by X-ray and E.C.G. tracings, but exhibited no cyanosis and normal blood picture. All of the three surgical approaches, such a myocardial resection of hypertrophic sight ventricular outflow tract, direct suture closing of ventricular septal defect and pericardial patch closing of ventriculotomy wound were carried out in 110 minutes under the cardiopulmonary bypass. Postoperative hemodynamic study revealed that the pressure of the right ventricle was decreased and pulmonary artery was increased satisfactorily. Postoperative course of the patient was uneventful, and the symptoms disappeared.

• 한국지구과학회지
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• 제38권7호
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• pp.469-480
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• 2017

Controversy has surrounded the potential impacts of phytoplankton on the tropical climate, since climate models produce diverse behaviors in terms of the equatorial mean state and El $Ni{\tilde{n}}o$-Southern Oscillation (ENSO) amplitude. We explored biophysical impacts on the tropical ocean temperature using an ocean general circulation model coupled to a biogeochemistry model in which chlorophyll can modify solar attenuation and in turn feed back to ocean physics. Compared with a control model run excluding biophysical processes, our model with biogeochemistry showed that subsurface chlorophyll concentrations led to an increase in sea surface temperature (particularly in the western Pacific) via horizontal accumulation of heat contents. In the central Pacific, however, a mild cold anomaly appeared, accompanying the strengthened westward currents. The magnitude and skewness of ENSO were also modulated by biophysical feedbacks resulting from the chlorophyll affecting El $Ni{\tilde{n}}o$ and La $Ni{\tilde{n}}a$ in an asymmetric way. That is, El $Ni{\tilde{n}}o$ conditions were intensified by the higher contribution of the second baroclinic mode to sea surface temperature anomalies, whereas La $Ni{\tilde{n}}a$ conditions were slightly weakened by the absorption of shortwave radiation by phytoplankton. In our model experiments, the intensification of El $Ni{\tilde{n}}o$ was more dominant than the dampening of La $Ni{\tilde{n}}a$, resulting in the amplification of ENSO and higher skewness.

• 한국지구과학회지
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• 제21권2호
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• pp.137-158
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• 2000

측과 모델에서 각각 유도된 하부 성층권의 온도를 비교 ${\cdot}$ 분석하기 위하여 전구에 대한 1980-98년 기간의 위성관측 MSU 채널4 (하부 성층권) 밝기온도와 두 개의 대기대순환 모델(NCEP, 1980-97년; GEOS, 1981-94년) 재분석 자료를 상관 및 경험직교함수 분석을 통하여 조사하였다. 월평균 기후값의 아노말리에서 MSU 온도는 남반구 겨울에 고위도 지역에서 현저하게 감소하였으나 (20-22K), 남반구 봄인 10월에는 오스트레일리아의 이남 지역에서 하부 성층권 온도 및 오존 전량이 주목 할만하게 동시에 상승하였다. 열대지방에서는 온도 연주기가 중 ${\cdot}$ 고위도에 비하여 뚜렷하지 않았다. 전구 대부분의 지역에서관측과 모델 사이에 상관은 높았으나 (r${\ge}$0.95), 아열대 제트기류가 통과하는 20N-3ON 지역, 북미 대륙 그리고 안데스산맥 남단지역에서 낮았다(r${\sim}$O.75). MSU 및 모델 재분석들의 월평균값에 대한 모드 1은 연주기와 함께 화산 폭발시에 하부 성층권의 온도 상승을 나타냈다. 한반도 지역에 대한 분석은 하부 성층권 온도가 대류권과 대조적으로 여름에 하강하고 겨울에 상승하는 형태를 보였다. 열대 태평양에 대한 MSY 및 재분석들의 아노말리 모드 1은 화산폭발에 의한 하부 성층권 온도 상승을 나타냈다. 모드 2는 MSH와 GEOS에서 준2년 주기진동 (QBO), 그러나 NCEP에서 엘니뇨 특징을 보였다. 엘니뇨 특징은 MSU와 GEOS의 경우에 모드 3에서 나타났다. 관측과 모델 모두에서 하부 성층권 온도에 대한 기여율이 대체로 화산폭발, QBO, 엘니뇨 순으로 높았다. 열대 대서양의 결과도 무시할 만한 엘니뇨 기여를 제외하고 열대 태평양과 비슷하였다 본 연구는 하부 성층권 온도에 대한 위성관측과 모델 재분석 자료와의 비교를 통하여 상호 정확성을 진단할 수 있음을 보여준다.

• 전기화학회지
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• 제24권3호
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• pp.52-64
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• 2021

Li_1+xFe_xTi_2-x(PO₄)_3-y(BO₃)_y (x = 0.2, 0.5)계 유리에서 Fe doping과 BO₃ 치환이 유리 또는 결정화유리(glass-ceramics) 전해질의 구조적, 열적 및 전기적 특성에 미치는 영향을 조사하였다. 또한, Li_1.5Fe_0.5Ti_1.5(BO₃)₃ 유리분말을 소결하고, 소결 온도에 따른 결정상과 이온전도도 영향도 검토하였다. Li_1+xFe_xTi_2-x(PO₄)_3-y(BO₃)_y 유리에서 Fe²⁺ 및 Fe³⁺ 이온은 network modifier로서 FeO₆ 팔면체를 형성하거나 network former로서 유리망목구조에 들어가 FeO₄ 유사 사면체를 형성하면서 유리의 구조를 변화시키는 것으로 확인되었다. 한편, BO₃는 BO₃ 또는 BO₄ 그룹을 형성하였는데, BO₃ 치환량이 작은 경우 boron은 (PB)O₄ 망목구조를 형성하지만, BO₃ 치환량이 증가하면 붕소이상현상(boric oxide anomaly)이 생겨나면서 BO₄는 BO₃로 변화하고 이로 인하여 비가교산소(non-bridging oxygen)가 증가하였다. BO₃ 치환은 유리전이온도와 결정화 온도를 낮추는 효과가 있으며, Fe 첨가량이 증가하면 Fe³⁺의 일부는 Fe²⁺로 환원되며, 유리전이온도와 연화온도를 낮아지게 하고 결정화온도를 높아지게 하는 것으로 확인되었다. Li_1+xFe_xTi_2-x(PO₄)_3-y(BO₃)_y (x = 0.2, 0.5) 유리에서 BO₃ 함량이 증가함에 따라 이온전도도는 증가하였으며, x = 0.2 및 0.5에서 각각 8.85×10^-4 및 1.38×10^-4S/cm의 이온전도도값을 나타내었다. 본 연구에서 얻어진 높은 이온전도도는 Fe³⁺의 산화상태 변화와 붕소이상현상에 의한 BO₃ 생성 및 이로 인한 비가교산소의 생성에 기인한 것으로 생각된다. Li_1.5Fe_0.5Ti_1.5(BO₃)₃ 유리를 800℃에서 소결한 결과 이온전도도가 급격히 저하되었는데 이는 결정화유리 분말이 고온에서 유리화되었기 때문으로 생각된다. 따라서 유리분말을 800℃에서 소결한 후, 다시 460℃에서 조핵하고, 600℃에서 결정성장을 시킨 결과, 이온전도도가 열처리전과 동등 수준으로 회복되는 것을 확인하였다.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume II
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• pp.1011-1014
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• 2006

Coarse resolution (9 - 50 km pixels) Sea Surface Temperature satellite data are frequently considered adequate for open ocean research. However, coastal regions, including coral reef, estuarine and mesoscale upwelling regions require high-resolution (1-km pixel) SST data. The AVHRR SST data often suffer from navigation errors of several kilometres and still require manual navigation adjustments. The second serious problem is faulty and ineffective cloud-detection algorithms used operationally; many of these are based on radiance thresholds and moving window tests. With these methods, increasing sensitivity leads to masking of valid pixels. These errors lead to significant cold pixel biases and hamper image compositing, anomaly detection, and time-series analysis. Here, after manual navigation of over 40,000 AVHRR images, we implemented a new cloud filter that differs from other published methods. The filter first compares a pixel value with a climatological value built from the historical database, and then tests it against a time-based median value derived for that pixel from all satellite passes collected within ${\pm}3$ days. If the difference is larger than a predefined threshold, the pixel is flagged as cloud. We tested the method and compared to in situ SST from several shallow water buoys in the Florida Keys. Cloud statistics from all satellite sensors (AVHRR, MODIS) shows that a climatology filter with a $4^{\circ}C$ threshold and a median filter threshold of $2^{\circ}C$ are effective and accurate to filter clouds without masking good data. RMS difference between concurrent in situ and satellite SST data for the shallow waters (< 10 m bottom depth) is < $1^{\circ}C$, with only a small bias. The filter has been applied to the entire series of high-resolution SST data since1993 (including MODIS SST data since 2003), and a climatology is constructed to serve as the baseline to detect anomaly events.

• 한국수산과학회지
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• 제21권6호
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• pp.331-340
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• 1988

대마난류 수형의 계절 변화를 19개년 $(1965\~1983)$의 해양관측 자료를 사용하여 (thermosteric anomaly)로서 검토했다. $33.8\%_{\circ}$의 염분값을 지표로 살펴본 바에 의하면, 대한해협을 통해 유입된 하계 표층 저염수는 여름부터 가을동안에 표층의 수형변화에 영향을 주고 있다. 표면에서 $\delta_T$의 값은 수온에 의한 영향을 많이 받지만, 하계에는 일시적으로 염분에 영향을 받는다. 그 값은 최저 수온이 나타나는 겨울에 가장 작고, 봄에 수온의 상승에 따라 차츰 증가하며, 최고 수온 및 최저 염분이 나타나는 여름에 가장 크고, 가을에 수온의 하강에 따라 차츰 감소한다. 그리고 저염수의 유입 때문에 고오도 서방역은 8월에 779 cl/t, 한국 연안역은 9월에 622 cl/t으로 쿠로시오역의 8월의 값 622cl/t 보다 더 크다. 깊이 100m에서 $\delta_T$ 변화는 표면만큼 탁월하지 않으며, 년중 수온 변화에 의존하고, 대마난류역의 북쪽 정점으로 갈수록 감소한다.

• 한국환경과학회지
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• 제4권5호
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• pp.28-28
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• 1995

The aim of the present study is to investigate the interannual variabilities of the East Asia monsoon rainfall associated with the global sea surface temperature anomaly(SSTA). For this study, the summer rainfall(from June to August) over the twenty-eight period of 1961-1988 were analyzed with being divided by nine-subregions over East Asia including Korea, China and Japan. From the analysis of the principal modes explaining the interannual variation, the interannual variabilities of summer rainfalls in South Japan and Korea are larger than those of the other subregions of the East Asia. There is a strong negative correlation between the summer rainfalls of south China and Korea. In this study, the relationship between the summer monsoon of each subregion and SSTs of the tropical NINO regions, of western Pacific warm pool, and of the subtropical ocean were investigated. The longitudinal sections of the lagged cross correlations of the summer rainfal1 anomaly in (a) Korea and (b) south China, and the monthly SSTA in the equatorial(averaged from 65 to 6N) Pacific were analyzed. The negative maximum correlation pattems of Korea''s stammer rainfal1 and SSTs over the eastern Pacific is transfered to positive maximum conrlation over central Pacific region with a biennial periodicity. In South China, the significant positive correlations are found at -12 month lag over the eastern Pacific and maximum negative correlation at 16 month lag over the central Pacific with the quasi-biennial oscillation. But the correlation coefficient reverses completely to that in Korea. In order to investigate the most prevailing interannual variability of rainfall related to the favored SSTA region, the lagged cross correlations between East Asia rainfall and SSTs over the moO regions(NINO 1+2(0-105, 90W-80W), NINO 3(5N-5S, 150W-90W), NINO 4(5N-5S, 160E-l50W) and the western Pacific worm pool (5N-5S, 120E-l60E) were analyzed. Among the lagged cross-correlation cycles in NINO regions, the maximum correlations for the negative lagged months prevail in NINO 1+2 and NINO 3, and the cross correlations for the positive lagged months NINO 4. It is noteworthy that correlation between the western Pacific warm pool SSTA and the monsoon rainfall in Korea and South China have the maximum value at negative 4 month lag. The evolution of the correlation between the East Asia monsoon rainfall and SSTA is linked to the equatorial convective cluster and related to northward propagating situation, and raising the possibility that the East Asia monsoon precipitation may be more fundamentally related to the interaction of intraseasonal oscillations and the sub-regional characteristics including the surface boundary conditions and the behavior of climatological air mass.