• Title/Summary/Keyword: tar

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Ablative Mechanism of SiC Coated Carbon/carbon Composites with Ratio of Oxygen to Fuel at Combusion Test (연소시험에서 산소와 연료 비에 따른 탄화규소로 코팅된 탄소/ 탄소 복합재의 삭마 메커니즘)

  • Zhang, Eun-Hee;Kim, Zeong-Baek;Joo, Hyeok-Jong
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.227-233
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    • 2007
  • Carbon/carbon (C/C) composites as unique materials possess exceptional thermal resistance with light weight, high stiffness, and strength even at high temperature. However, one serious obstacle for application of the C/C composites is their poor oxidation resistance in high temperature oxidizing environments. SiC coating has been employed to protect the composites from oxidation. This study explored combustion characteristics of 4-directional (4D) carbon/carbon composites using liquid fuel rocket engine to investigate ablative motion of the materials. C/C composites were made of coal tar pitch as a matrix precursor, and heat-treated at $2300^{\circ}C$. Throughout repeated densification process, the density of the material reached $1.903g/cm^3$. After machining 4D C/C composites, the nozzle surface was coated by a SiC layer by pack-cementation method to improve oxidation resistance. Erosion characteristics of SiC-coated C/C composites were measured as function of the ratio of oxygen to fuel. The morphological change of the composites after combustion test was investigated using SEM and erosion mechanism also was discussed.

Development Status of BTL (Biomass to Liquid) Technology (BTL(Biomass to Liquid) 기술 현황)

  • Chae, Ho-Jeong;Jeong, Kwang-Eun;Kim, Chul-Ung;Jeong, Soon-Yong
    • Journal of Energy Engineering
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    • v.16 no.2
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    • pp.83-92
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    • 2007
  • In view of stringent environment regulations to control the emission of green house gases and also depleting fossil fuel reserves, it is high quality desirable to develop alternative technologies to produce high quality fuels. To this end Biomass to Liquid (BTL) technology has received much attention in recent years. BTL process generally consists of gasification of biomass to produce bio-syngas, cleaning and control of $H_{2}/CO$ mole ratio of bio-syngas and Fischer-Tropsch synthesis & upgrading systems. Choren, Germany has first developed the commercial BTL process using unique gasification system i.e., Carbo-V. A new technology to remove tars and BTX has been developed by ECN in Netherlands employing a gasification system combined with OLGA technology. Several other countries including USA and Japan are showing great interest in BTL technology. Thus in view of our national energy security and also the environmental regulations, it is essential to develop alternative technologies like BTL in order to meet the increasing demand of energy though our insufficient biomass resources. In this paper we present an overview and development status of BTL-diesel technology.

Distribution of Evergreen Broad-leaved Plants and Climatic Factors (한반도 상록활엽수의 지리적 분포와 기후요소)

  • 구경아;공우석;김종규
    • Journal of the Korean Geographical Society
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    • v.36 no.3
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    • pp.247-257
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    • 2001
  • The relationships between the distribution of 132 species, 61 genera evergreen broad-leaved trees and shrubs(EBTS) and climatic factors have discussed. The distributional patterns of EBTS were categorized into seven groups on the basis of the number of distributing sites, distributional attitudes and latitudes. Out of seven group. the cold-tolerant EBTS were common at groups I and II, along tilth Empetrum nigrum var. japonicum. Diapensia lapponics subsp. obovata of group III. However, the warmth-tolerant EBTS were rich at groups III. IV V, and VI The lower distributional limits of cold-tolerant EBTS in the groups I and UU decreased as one moves toward south. The upper distributional limit of warmth-tolerant EBTS in the groups III, IV and V decreased with increasing latitude. However. no clear distributional tendency is noticed in the groups VI and VII. The range of warmth-tolerant EBTS appear to show close relationship with the January mean temperature -4 $\^{C}$ and January mean minimum temperature -9$\^{C}$ than others. On the other hand, that of the cold-tolerant EBTS seem to respond well to the August mean temperature 19$\^{C}$ and August mean maximum temperature 26$\^{C}$ than others.

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Volatile Substances and Physicochemical Characteristics of Pyroligneous Liquor (목초액의 휘발성 성분과 이화학적 특성)

  • Kim Jong-Soo;Park Seung-Woo;Choi Jung-Hwan;Lee Eun-Young;Lee Sang-Han;Chung Shin-Kyo
    • Food Science and Preservation
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    • v.12 no.6
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    • pp.656-661
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    • 2005
  • To develop food additives from pyroligneous liquor, we first examined the physicochemical characteristics of volatile substances. The pH, gravity, acidity, solution tar, and scorched remains in the pyroligneous liquor were 2.50, 1.020, $0.8\%$ $2.31\%$ and $0.008\%$ respectively. The main compounds of pyroligneous liquor were 2,6-dimethoxyphenol (syringol), 2-hydroxy-2-cyclopenten-l-one, 1,2-benzenediol (catechol), phenol, 2 (5H)-furanone, 2-methoxyphenol (guaiacol), 5-hydroxymethyl-2 furancarboxaldehyde were found in organic phase, whereas catechol, 1,4 : 3,6-dianhydro-${\alpha}d$-glucopyranose, cyclopropyl carbinol, 5-hydroxymethyl-2 furancarboxaldehyde in aqueous phase.

Physical and Chemical Properties of Charcoal Added Paper for Cigarette Filter (활성탄 첨가에 따른 담배용 필터지의 이화학적 특성)

  • Lee, Mun-Yong;Jeon, Yang;Kim, Yeong-Ho;Lee, Jong-Il
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04a
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    • pp.77-77
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    • 1999
  • 담배용 필터에 사용되고 있는 재료는 아세테이트, 종이, 폴리프로펼렌, 부직포등이 주로 이용되고 있으 며 담배연기의 흡착능을 향상시키기 위한 방법으로 활성탄 제오라이트와 같은 흡착제를 담배필터에 첨가하여 사용하고 있다. 본 실험에서는 펼터에 가장 보편적으로 많이 사용하고 있는 활성탄을 종이 제조과정에 첨가하여 나타나는 물리적 특성을 관찰하였고 제조된 종이를 담배필터에 적용하기 위하여 현행 습식 크림핑(crimping)방법과는 달리 건식 크림핑(crimping)방법을 이용한 적합한 조건을 검토하 였으며 이에 따른 담배필터에서의 연기흡착능을 분석한 결과는 다음과 같다. 1. 시트의 물리적 특성과 담배 연기성분 홉착능을 예측하기 위하여 펄프의 불성과 uv 홉착능을 분 석한 결과 Sw-BKP가 Hw-BKP에 비하여 강도적 성질이 우수하였고 또한 메틸렌불루(methylene b blue) 흡착능도 높은 경 향을 나타내 었다. 2. 활성탄 함량의 증가에 따라 섬유간의 결합력이 약화됨에 따라서 시트의 인장강도 및 파열강도가 감 소하는 경향이 가장 크게 나타났으며 평량이 펼프 배합비보다 높은 인자로 작용하였다. 또한 인자 간의 교호작용에서는 평량과 활성탄 함량에 따라서 크게 나타났으며 평량, Sw-BKP의 함량이 증가할 수록 인장강도는 증가하였다. 3. Stiffness는 활성탄 함량 펄프 배합비 평량의 순에따라 중요한 인자로 작용하였고 활성탄 함량 이 많을수록 stiffness는 감소하였으며 평 량 Sw-BKP의 함량이 높을수록 증가하였다 인자간의 교 호작용은 평량과 활성탄 함량이 다른 요인에 비하여 높은 경향을 보였다. 4. 인열강도는 활성탄 함량이 증가함에 따라 가장 크게 감소하였고 시트의 평량이 펄프 배합비보다 높은 인자로 작용하였으며 평 량 Sw-BKP의 함량이 높을수록 증가하였다 인자간의 교호작용에서는 펄프 배합비와 활성탄 함량에 따라 크게 나타났다. 5. 종이 필터지에서 시트의 평량이 bulk에 가장 큰 인자로 작용하였는데 이는 같은 두께에서 평량올 변화시킨 요인으로 판단되며 시트의 평량이 높을수록 감소하였고 활성탄 함량, Sw-BKP의 배합비 가 높을수록 증가하였다. 또한, 인자간의 교호작용은 평 량과 활성 탄 함량에 따라 크게 작용하였다. 6 6. Crimp index는 관능검사 결과로서 활성탄 함량이 증가함에 따라 현저하게 저하되었으며 평량 및 S Sw-BKP의 배합비가 높을수록 양호한 결과를 나타내었다. 인자간의 교호작용에서는 평량과 펄프 배합비에 따라 가장 높은 경향을 나타내었다. 7 활성탄을 첨가하여 제조한 종이필터의 담배 연기성분 흡착능은 acetate tow에 charcoal을 첨가한 필터에 비하여 tar흡착능이 6% 이상 향상되었고, 특히 증기상 물질(vapour phase)중 aldehyde류에 대한 제거율(removal efficiency)이 높게 나타났다. 8. 건식 크림핑 방법에 의한 담배필터 제조시 펼프의 홉착능, 시트의 강도적 특성, 크림핑 조건 및 담 배 연기성분 흡착능 등을 고려하여 적정조건을 선정하였으며, 펄프 배합비(Sw-BKP따w-BKP)는 6 65/35, 시트의 평량은 40g/$m^2$ 활성탄 함량은 10% 이었다.

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Establishment of an Analytical Method for Azorubine, an Undesignated Food Colorant in Korea

  • Kim, Min-ji;Park, Ju-hee;Suh, Hee-Jae;Lee, Chan
    • Journal of Food Hygiene and Safety
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    • v.31 no.5
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    • pp.311-318
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    • 2016
  • Azorubine is a synthetic tar color containing azo-bond in the molecular structure. This food colorant has been allowed to be used for beverages, cheese and dried fruits in the European Union and for some food in Australia. Even though it is applicable as a food color in many countries, this compound has not been permitted in Korea so far as a food additive. Thus, this study was performed to establish an analysis method for azorubine in Korea by comparison of three HPLC analysis methods for azorubine and other azo-compounds which are officially used in the European Food Safety Authority (EFSA, EU), the Food Standard Agency (FSA, England) and the National Institute of Food and Drug Safety Evaluation (NIFDS, Korea). The analysis method of the FSA for azorubine showed the best linearity ($r^2=0.999$), limit of detection (LOD, $0.07{\mu}g/mL$), limit of quantification (LOQ, $0.20{\mu}g/mL$), precision (0~0.5%) and accuracy (98.6~100.7%) among tested HPLC methods using a C-18 column and diode array detector (DAD) with ammonium acetate solution and acetonitrile as an eluent solution. Finally selected method of FSA was further verified by inter-day and intra-day experiments with linearity, LOD, LOQ, precision and accuracy. Recovery test showed the recover ratios of 97~103%, 95~101%, and 93~102% in beverages, breads/snacks and other foods, respectively. Inter-laboratory test represented the absolute value of z-score of less than 2 which means satisfactory levels in this test. Selected method of FSA showed reliable analytical results in application test using food samples collected in commercial markets in Europe.

Transplant Quality and the Yield of 'Momotaro-Yoku' Tomato as Affected by Seedling Age and Container Size Used for Raising Seedling in Summer (모모타로-요쿠 토마토 하계 육묘시 용기 크기와 묘령이 정식 후 생육 및 수량에 미치는 영향)

  • 최영하;조정래;이한철;박동금;권준국;이재한
    • Journal of Bio-Environment Control
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    • v.11 no.1
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    • pp.12-17
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    • 2002
  • Tn establish the criteria for appropriate seedling production method in the summer, the effect of container size and seedling age on the growth and yield were evaluated with tomato. The seedling quality was higher when seedlings were grown polyethylene in 9cm pots than in 72 cell plugs. Seedling quality increased with increase in seedling age in polyethylene pots, whereas seedling age did not affect seedling quality in plug trays. Fruits matured earlier on plants started from pot-grown transplants for a long duration than with plug tray-grown transplants for a shorter duration. Not only total yield in 4 months, but the early yield in the first 2 months, was higher with pot-nursed transplants than with plug tray-nursed transplants. With pot-grown transplants, The early yield in initial 2 months was the lowest in 25 day-old transplants, whereas there was no significant differences between 35- and 45-day-old transplants. Seedling age did not affect the cumulative yield for 3 months after the first harvest. With plug tray-grown transplants, the cumulative yield tar initial 3 months was the highest in plants grown for 35 days in the nursery, followed by 25 day and 45 day. However, there were no significant differences among seedling ages in the total yield.

Ethanol Fermentation of Fusant between Heterologous Transformant of Saccharomyces cerevisiae and Candida tropicalis in Pilot Scale (Pilot Scale에서의 Fusant의 Ethanol 발효)

  • Seu, Jung-Hwn;Kim, Young-Ho;Lee, Soon-Mo;Bang, Byung-Ho
    • Microbiology and Biotechnology Letters
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    • v.17 no.1
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    • pp.14-18
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    • 1989
  • As the final experiment to assess the possibility of industrial application of FSC14-75, ethanol productivity from liquefied sweet potato starch was examined in a pilot scale of 300 liters. FSC14-75 produced 6.6%(v/v) of ethanol from 13.3% of liquefied sweet potato starch in 8 days, and the residual sugar was 3.15%. The corresponding efficiency was 70% of the theoretical maximum. Since we could isolate unicellular cell and flocculent cell from the fermentation broth, we designated them FSC14-75(S) and FSC14-75(F), respectively. We investigated ethanol productivity of FSC14-75(F) compared with that of FSC14-75(S) from liquefied potato starch in a mini·tar tormentor scale of 2.5 liters. FSC14-75(F) was found more favorable than the counterpart in terms of ethanol productivity, and produced 8.1%(v/v) of ethanol from 15% of liquefied potato starch with an efficiency of 75%. In a pilot scale fermentation with 15% of liquefied sweet potato starch, ethanol productivity of FSC14-75(F) reached maximum level of 7.7%(v/v) after 8 days, and the residual sugar was 1.9%. However, the ethanol productivity was not enhanced by a supplementary addition of Thermamyl to the fermentation broth after sterilization.

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Distribution status survey of livestock Products Sold via Online Websites (온라인 축산물 유통 실태 조사)

  • Kim, Ji Yeon;Seo, Eun Ju;Koh, Ba Ra Da;Seo, Doo Ri;Jung, Bo Ram;Seo, Mi Hee;Lim, Jin Teak;Kim, Eun Sun;Kim, Yong Hwan
    • Korean Journal of Veterinary Service
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    • v.39 no.1
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    • pp.13-20
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    • 2016
  • This study is aimed to find out distribution status of online-market livestock products by purchasing and examining 120 cases of livestock products (seasoned meat: 17, 33 cases of packaged meat, 23 cases of ground meat, 19 cases of ham, 11 cases of sausage, 4 cases of bacon, 1 case of meat processing, 8 cases of Meat extract processed, and 4 cased of Dry storage of meat) at 17 On-line markets from April to August. 2015. We checked the weight of them first, and carried out ingredients test for each of processed meats. And we performed gene screening test on the products which were labelled 'Hanwoo' to investigate that the products were made of Korean native cattle. we also carried out test of identifying domestic animal species on ham, sausage and ground processed products. After weighing all products, we could know that all of them were delivered more than labelled weight or in allowable error. The result values of test which measured level of preservatives, Nitrite, Volatile Basic Nitrite (VBN), and tar Color by the type of processed meat products were in permissible range or not detected. Also, 17 beefs inspected Korean native cattle gene test were confirmed that they were made by real korean native cattle. But 2 cases of Ham, sausage, and ground processed products had difference between label and goods. In this study, we could make a decision that livestock products, distributed in On-line markets, were safe and expect to make higher degrees of hygiene for livestock products seller. Futhermore, we hoped result of this study could be used by basic data for progressive national policy decisions.

Effects of Temperatures on Development and Distribution of Mulberry scale, Pseudaulacaspis pentagona, within Tree (온도조건이 뽕나무깍지벌레의 발육 및 수내분포에 미치는 영향)

  • 박종대;김규진
    • Korean journal of applied entomology
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    • v.29 no.4
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    • pp.238-243
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    • 1990
  • These studies were conduced to investigate the effects of temperatures on development of each stage and distribution within tree and overwintering of mulberry scale, Pseudaulacaspis pentagona Tar. & Tozz. Growth ratio of each stage with different temperatures was not significant within range of optimum temperatures of growth. Developmental threshold and effective temperatures of each stage were $12.3^{\circ}C$ and 46.9 degree day in eggs, $10.8^{\circ}C$, and 183.8 degree day in first nymph, $9.8^{\circ}C$ and 188.2 degree day in second nymph, $10.3^{\circ}C$ and 383.0 degree day in gross nymphal stage, respectively. Longevity of female adults were 39.6 days in $18^{\circ}C$, 28.4 days in $22^{\circ}C$, 18.1 days in$26^{\circ}C$, and 15.7 days in$30^{\circ}C$. Average number of eggs in ovary and laid by individual female were 83.3 and 75.7, respectively. Optimum temperatures of growth were $22^{\circ}C$-$26^{\circ}C$ but all the eggs were not hatched at $35^{\circ}C$. Distribution of each stage within tree in summer was great at lower part of branch and overwintering adults was dominantly located in NE-SE followed by SE-SW, SW-NW and NW-NE. Percent mortality due to cold weather was 36.2.

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