• Advances in nano research
• /
• v.13 no.2
• /
• pp.187-197
• /
• 2022

The synthesis of organic and hybrid organic-inorganic perovskites directly from solution improves the cost- and energy-efficiency of processing. To date, numerous research efforts have been devoted to investigating the influence of the various solvent parameters for the synthesis of lead halide perovskites, focused on the effects of different single solvents on the efficiency of the resulting perovskites. In this work, we investigated the effect of solvent blends for the first time on the structure and phase of perovskites produced via the Lewis base vapor diffusion method to develop a new synthetic approach for water-stable CsPbBr₃ particles with nanometer-sized dimensions. Solvent blends prepared with DMF and water-miscible solvents with different Gutmann's donor numbers (D_N) affect the Pb ions differently, resulting in a variety of lead bromide species with various colors. The use of a DMF/isopropanol solvent mixture was found to induce the formation of the Ruddlesden-Popper perovskite based on lead bromide. This perovskite undergoes a blue color shift in the solvated state owing to the separation of nanoplatelets. In contrast, the replacement of isopropanol with DMSO, which has a high DN, induces the formation of spherical CsPbBr₃ perovskite nanoparticles that exhibit green emission. Finally, the integration of acetone in the solvent system leads to the formation of lead bromide complexes with a yellow-orange color and the perovskite CsPbBr₃.

• Korean Chemical Engineering Research
• /
• v.43 no.6
• /
• pp.704-714
• /
• 2005

Phase separations of Poly(4-vinylphenol)(PVPh)/Ethyl Acetate and PVPh/Butyl Acetate solutions were measured using the thermal optical analysis (TOA) method. The experimental phase separation data were correlated with liquid-liquid equilibria relations based on PC-SAFT equation of state. The phase separations of these system showed the behaviors of LCST (lower critical solution temperature)-type. The measured cloud temperatures were lowered with increasing in molecular weights of polymer(PVPh), and cloud temperatures of PVPh/Ethyl Acetate solutions shifted to lower temperature regions, compared to the PVPh/Butyl Acetate solutions. Extents of cross-association between solvent molecule and polymer in the PVPh/Ethyl Acetate solutions were measured using the FT-IR spectrum analysis method, and cross-association parameters of PC-SAFT model were estimated from experimental extents of cross-association. By using the estimated cross-association parameters between PVPh and solvent molecule, binodal and spinodal curves of liquid-liquid equilibria in PVPh/Ethyl Acetate and PVPh/Butyl Acetate solutions were calculated from PC-SAFT equation of state. The calculated binodal curves of these system were shown to be well agreeable with the experimental cloud temperature curves.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.12 no.1
• /
• pp.23-28
• /
• 2009

There is several ways of recycling methods for waste FRP boats. The main one is mechanical recycling that is one of the simple and technically proven methods. It recently has been reported that FRP can be recycled by separating into laminated glass fiber layers instead of crushing into powder. Even though the mechanical recycling is a good way for the eligibility of laminated glass fiber reinforced material, the system should have another option which can collect resin of FRP. Because the resin is still very useful renewable energy source, that cannot be discarded, But FRP is made up of laminated glass fiber(roving cloth layer) which is fire retardant substances and very hard to break into each layer. Due to the high cost of fossil energy the waste plastics should be regenerated to the source of renewable energy. Laminated glass fiber which is recyclable in a very limited way, is currently a serious barrier to waste FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly FRP waste regenerating system. The recycled glass fiber which is obtained by the separation of the roving layer from FRP waste has been found to be useful for concrete(FRC) products or concrete(FRC) structures as fiber reinforced material. And it can be successively applied to renewable energy applications using the waste resins of FRP residue without laminated glass fiber.

• Current Optics and Photonics
• /
• v.1 no.2
• /
• pp.107-112
• /
• 2017

An adaptive optics system can be simulated or analyzed to predict its closed-loop performance. However, this type of prediction based on various assumptions can occasionally produce outcomes which are far from actual experience. Thus, every adaptive optics system is desired to be tested in a closed loop on an optical test bench before its application to a telescope. In the close-loop test bench, we need an atmospheric simulator that simulates atmospheric disturbances, mostly in phase, in terms of spatial and temporal behavior. We report the development of an atmospheric turbulence simulator consisting of two point sources, a commercially available deformable mirror with a $12{\times}12$ actuator array, and two random phase plates. The simulator generates an atmospherically distorted single or binary star with varying stellar magnitudes and angular separations. We conduct a simulation of a binary star by optically combining two point sources mounted on independent precision stages. The light intensity of each source (an LED with a pin hole) is adjustable to the corresponding stellar magnitude, while its angular separation is precisely adjusted by moving the corresponding stage. First, the atmospheric phase disturbance at a single instance, i.e., a phase screen, is generated via a computer simulation based on the thin-layer Kolmogorov atmospheric model and its temporal evolution is predicted based on the frozen flow hypothesis. The deformable mirror is then continuously best-fitted to the time-sequenced phase screens based on the least square method. Similarly, we also implement another simulation by rotating two random phase plates which were manufactured to have atmospheric-disturbance-like residual aberrations. This later method is limited in its ability to simulate atmospheric disturbances, but it is easy and inexpensive to implement. With these two methods, individually or in unison, we can simulate typical atmospheric disturbances observed at the Bohyun Observatory in South Korea, which corresponds to an area from 7 to 15 cm with regard to the Fried parameter at a telescope pupil plane of 500 nm.

• (The)Study of the Eastern Classic
• /
• no.33
• /
• pp.31-56
• /
• 2008

Jang Hyeon-gwang(張顯光, 1554-1637), whose pseudonym or courtesy name is 'Yeoheon(旅軒)', had made a thorough study on the intrinsic nature of Neo-Confucianism in a more sincere fashion, when comparing him with other Neo-Confucianists in Joseon period. Also he was a renowned scholar who expanded its philosophical system in-depth. Yeoheon thereby had strengthened his philosophical system accordant with the Great Learning(大學) and Doctrine of the Mean(中庸), which are the fundamental systems of Neo-Confucianistic education. Based on such considerations, Yeoheon's thought on education can be illuminated from three different perspectives. First, Yeoheon deepened his a theory of good governance by a virtuous ruler(聖人君主論, pronounced, 'Seongingunjuron') as the standard of education. Essentially, his theory pursues Refraining from desire, and preserving the laws of nature(存天理?人欲, pronounced, 'Joncheolliarinnyok'), and put emphasis on ethical awakening, and the governance through a virtue of moral excellence. Second, Yeoheon stressed the learning theories related to 'sincerity' or true heart(誠) and 'piety' or 'respect'(敬)) as the form of education(誠敬, pronounced, 'Seonggyeong'). Also he expounded that people needs "to establish a ground of Respect and Sincerity in their mind." He recognized the differences between the two virtues, meanwhile, however, he understood it as in an identical context. Third, Yeoheon advocated harmony between separation and integration(分合, pronounced, 'Bunhap') as a method for education. Through his unique 'Discourse on Longitude and Latitude', dubbed, 'Li-Gi Gyeongwiseol (理氣經緯說) in which the principle(Li, 理) is equal to the intrinsic energy or material force(Gi, 氣), he maintained his view on the Doctrine of the Mean, in that he was not inclined to either sides according to the logic of Change(易, pronounced 'Yeok'). When reviewing Yeoheon's contemplation in education in the meaning of modern education, he laid the standards for education on the establishment of morality, and he also provides us with an idea which induces us to look through the form and method for education from the perspective of Doctrine of the Mean. In short, Yeoheon's view on education embodies wisdom of traditional Neo-Confucianistic Education having consistency, and it provides for an implication of the review of the importance of the balance in relation to methodological bias toward confusion in the standards for modern education, and unsystematic contents therein.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.11 no.1
• /
• pp.50-54
• /
• 2008

There are several basic classes of recycling methods for FRP boats. The main one is 'Mechanical recycling' which involves shredding and grinding of the scrap FRP in a new product. That is one of the simpler and more technically proven methods. It recently has been reported that FRP can be recycled by separating into layers instead of crushing into powder. Many researchers should be more interested in these mechanical recycling for the eligibility. Nevertheless, because resins is very useful renewable energy, most of waste FRP regenerating methods depend on incineration (reclamation) or thermal recycling (pyrolysis). FRP is made up of laminated glass- fiber (roving cloth layer) which is also very unlikely to break into each layer. If there is an extracting method which is efficient and environment friendly removing glass fiber from waste FRP, it should also solve the another urgent problem. Laminated glass-fiber which is very limited renewable, is a serious barrier to wast FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly waste FRP regenerating system. And it should be applied to renewable energy applications with the waste resins of FRP. Also recycling glass fiber obtained by the separation of the roving layer from waste FRP will be consider to be useful for concrete products or structures.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.3
• /
• pp.49-55
• /
• 2017

Most motor cases adopt deep drawing products, which are excellent in waterproof functions, concentricity, right angle, and quality. In addition, the blower motor and seat motor, which are installed in the car interior and do not require waterproof function, adopts a multi-forming manufacturing method. The deep drawing process requires an expensive transfer press that can digest approximately 12 processes, such as drawing, trimming and piercing. On the other hand, products can be produced with low investment because the multi-forming method is composed of one multi-forming machine or one multi-forming machine and one press. The multi-forming machine is a high-priced facility that is mostly imported and a bending / shearing process multi-foaming machine, which was developed by domestic small and medium-sized enterprises, is not enough to reduce the production cost. An integral multi - forming machine is used as a limited working method for thin material and small products. A large product and thick material has a high shear load. A large product and thick material has a high shear load and uses a single crank press. After blanking, the worker manually feeds the material to a multi-forming machine. When the bending operation is performed in the multi-forming machine, it is transferred to the press again to calibrate the dimensions. This variance in work processes has resulted in lower cost competitiveness due to the lower productivity, quality issues, and excessive operator input. The aim of this study was to establish a stable and cost - effective production system through bending / shearing process separation and facility automation.

• Journal of the Korean Geotechnical Society
• /
• v.32 no.4
• /
• pp.5-14
• /
• 2016

Numerical simulation of dynamic soil-pile-structure interaction embedded in a dry sand was carried out. 3D model of the dynamic centrifuge model tests was formulated in a time domain to consider nonlinear behavior of soil using the finite difference method program, FLAC3D. As a modeling methodology, Mohr-Coulomb criteria was adopted as soil constitutive model. Soil nonlinearity was considered by adopting the hysteretic damping model, and an interface model which can simulate separation and slip between soil and pile was adopted. Simplified continuum modeling (Kim et al., 2012) was used as boundary condition to reduce analysis time. Calibration process for numerical modeling results and test results was performed through the parametric study. Verification process was then performed by comparing numerical modeling results with another test results. Based on the calibration and validation procedure, it is identified that proposed modeling method can properly simulate dynamic behavior of soil-pile system in dry condition.

• Journal of Venture Innovation
• /
• v.5 no.2
• /
• pp.85-99
• /
• 2022

Dryers becoming commercially available for experimental and industrial use are classified to general drying oven, hot-air dryer, vacuum dryer, freezing dryer, etc. and kinds of them are various from the function, size and volume, etc. But the moisture measurement is not applied although it is important factor for the quality control and the performance improvement of products, and then now is very passive because the weight is weighed arbitrarily after dry-end. Generally the method for measuring moisture is divided by a direct measurement method and a indirect measurement method, and the former such as the change of weight or volume on the front and rear of separation of moisture, etc. is mainly used. Relatively a indirect measurement is very limited to apply due to utilize measurement apparatuses using temperature conductivity and micro-wave etc. In this research, we easily designed the moisture measurement system using the open-source based Arduino, and monitored moisture fluctuations and weight profiles in the real-time without the effect of external environment. Concretely the temperature-humidity and load cell sensors were packaged into a drying oven and the various change values were measured, and their sensors capable to operate 60℃ and 80℃ were selected to suitable for the moisture sensitive materials and the food dry. And also the performance safety using the organic samples of banana, pear, sawdust could be secured because the changes of evaporation rate as the dry time and temperature, and the measurement values of load cell appeared stable response characteristics through repeated experiments. Hereafter we judge that the reliability can be improved increasingly through the expansion of temperature-humidity range and the comparative analysis with CFD(Computational Fluid Dynamics) program.

• Journal of the Society of Disaster Information
• /
• v.16 no.2
• /
• pp.237-247
• /
• 2020

Purpose: This study aims to draw the problems and improvements of NFSC 103 sprinkler head discharge obstruction prevention standard to increase the fire extinguishing performance of sprinkler system in order to contribute to the protection of people's lives and property in the event of a fire. Method: NFSC 103 was compared to NFPA 13 which is the latest 2019 version in U.S in terms of sprinkler head discharge obstruction prevention. Results: This study found that NFSC 103 doesn't define even the basic concept of sprinkler discharge obstruction. And NFSC 103 doesn't have detailed standard for side wall sprinkler head discharge obstruction prevention as well as the "height" criteria of the "three times" separation rule. Conclusion: NFSC 103 needs a lot of supplements and improvements such as the addition of definition for water discharge obstructions, the adoption of sidewall sprinkler heads standard for preventing water discharge obstructions and the additional establishment of the "three times rule" considering the "height" of obstacles to promote the advance of fire safety standard equal or above fire fighting advanced country and increase the reliability for the suppression performance of sprinkler system.