• Title/Summary/Keyword: synthetic variety

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Flexural Characteristics of High Performance Fiber Reinforced Cement Composites used in Hybrid Synthetic Fibers (하이브리드 합성섬유를 이용한 고인성 섬유보강 복합체의 휨특성)

  • Han Byung Chan;Jeon Esther;Park Wan-Shin;Lee Young-Seak;Hiroshi Fukuyama;Yun Hyun-Do
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.734-737
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    • 2004
  • The synthetic fibers such as polypropylene(PP) and polyvilyl-alcohol(PVA) fiber are poised as a low cost alternative for reinforcement in structural applications. It has been reported that synthetic fiber in cement composites can control restrained tensile stresses and cracks and increase toughness, resistance to impact, corrosion, fatigue and durability. High performance fiber reinforced cementitious composite(HPFRCCs) shows ultra high ductile behavior in the hardened state, because of the fiber bridging properties. Therefore, a variety of experiments have being performed to access the performance of HPFRCCs recently. The research emphasis is on the flexural behavior of HPFRCCs made in synthetic fibers, and how this affects the composite property, and ultimately its strain-hardening performance. Three-point bending tests on HPFECCs are carried out. As the result of the bending tests, HPFRCCs showed high flexural strength and ductility. HPFRCCs made in PVA or Hybrid fiber were, also, superior to PP of singleness. On the other hand, effect of sand volume fraction on HPFRCCs made in PP was insignificant.

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Synthesis, Spectral Property and Dyeing Assessment of Azo Disperse Dyes Containing Carbonyl and Dicyanovinyl Groups

  • Choi, Yun Seok;Lee, Kun Su;Kim, Hye Jin;Choi, Jong Yun;Kang, Soon Bang;Lee, Eui Jae;Keum, Gyochang
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.863-867
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    • 2013
  • A series of azo disperse dyes having dicyanovinyl groups was synthesized by the Knoevenagel condensation with malononitrile from carbonyl substituted phenylazo disperse dyes which were prepared by conventional diazo coupling reaction of aniline derivatives as diazo components. A variety of coupling components such as anilines, an indole and a pyridone were used. The azo disperse dyes were evaluated for their spectral properties and dyeing assessment on the polyester fabrics. The azo disperse dyes containing dicyanovinyl groups showed bathochromic shifts and darker colors due to increased electron withdrawing strength in their azo components and extended conjugation by dicyanovinyl groups than their parent carbonyl substituted azo dyes. The dyes containing 2-acetylamino-5-methoxy substituent in the coupling component exhibited higher wavelength of maximum absorbance (${\lambda}_{max}$) and significant negative solvatochromism than those of other dyes due to intramolecular hydrogen bonding.

Evaluation of the Genetic Toxicity of Synthetic Chemicals (XVI) - in vitro Mouse Lymphoma Assay with 3 chemicals -

  • Kim, Youn-Jung;Ryu, Jae-Chun
    • Molecular & Cellular Toxicology
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    • v.2 no.4
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    • pp.244-250
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    • 2006
  • The detection of many synthetic chemicals used in industry that may pose a genetic hazard in our environment is of great concern at present. Since these substances are not limited to the original products, and enter the environment, they have become widespread environmental pollutants, thus leading to a variety of chemicals that possibly threaten the public health. In this respect, to regulate and to evaluate the chemical hazard will be important to environment and human health. The genotoxicity of 3 synthetic chemicals was evaluated in L5178Y $tk^{+/-}$ mouse lymphoma cells in vitro. 9H-carbazole (CAS No. 86-74-8) did not induce significant mutation frequencies both in the presence and absence of metabolic activation system. 1, 3-Dichloro-2-propanol (CAS No. 96-23-1) revealed a significant increase of mutation frequencies in the range of $625-373\;{\mu}g/mL$ in the absence of metabolic activation system and $157-79\;{\mu}g/mL$ in the presence of metabolic activation system. And also, fenpropathrin (CAS No. 64257-84-7) appeared the positive results only in the absence of metabolic activation system. Through the results of MLA tk assay with 3 synthetic chemicals in L5178Y cells in vitro, we may provide the important clues on the genotoxic potentials of these 3 chemicals.

Evaluation of the Genetic Toxicity of Synthetic Chemicals (XIV)-in vitro Chromosomal Aberration Assay with 11 Chemicals in Chinese Hamster Lung Cells

  • Kim, Youn-Jung;Ryu, Jae-Chun
    • Molecular & Cellular Toxicology
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    • v.2 no.2
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    • pp.89-96
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    • 2006
  • The detection of many synthetic chemicals used in industry that may pose a genetic hazard in our environment is of great concern at present. Since these substances are not limited to the original products, and enter the environment, they have become widespread environmental pollutants, thus leading to a variety of chemicals that possibly threaten the public health. In this respect, to regulate and to evaluate the chemical hazard will be important to environment and human health. The clastogenicity of 11 synthetic chemicals was evaluated in Chinese hamster lung fibroblast cells in vitro. 1-Chloro-3-bromopropane CAS No. 109-70-6) induced chromosomal aberrations with significance at the concentration of $185.0\;{\mu}g/mL\;and\;1,600\;{\mu}g/mL$ both in the presence and absence of metabolic activation system, respectively. Triphenyl phosphite (CAS No. 101-02-0), which is one of the most cytotoxic chemical among 11 chemicals tested revealed no clastogenicity in the range of $95.0-4.9\;{\mu}g/mL$ both in the presence and absence of metabolic activation system. From the results of chromosomal aberration assay with 11 synthetic chemicals in Chinese hamster lung cells in vitro, 1-chloro-3-bromopropane revealed a positive clastogenic result in this study.

A hybrid neutronics method with novel fission diffusion synthetic acceleration for criticality calculations

  • Jiahao Chen;Jason Hou;Kostadin Ivanov
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1428-1438
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    • 2023
  • A novel Fission Diffusion Synthetic Acceleration (FDSA) method is developed and implemented as a part of a hybrid neutronics method for source convergence acceleration and variance reduction in Monte Carlo (MC) criticality calculations. The acceleration of the MC calculation stems from constructing a synthetic operator and solving a low-order problem using information obtained from previous MC calculations. By applying the P1 approximation, two correction terms, one for the scalar flux and the other for the current, can be solved in the low-order problem and applied to the transport solution. A variety of one-dimensional (1-D) and two-dimensional (2-D) numerical tests are constructed to demonstrate the performance of FDSA in comparison with the standalone MC method and the coupled MC and Coarse Mesh Finite Difference (MC-CMFD) method on both intended purposes. The comparison results show that the acceleration by a factor of 3-10 can be expected for source convergence and the reduction in MC variance is comparable to CMFD in both slab and full core geometries, although the effectiveness of such hybrid methods is limited to systems with small dominance ratios.

Algorithm for Predicting Functionally Equivalent Proteins from BLAST and HMMER Searches

  • Yu, Dong Su;Lee, Dae-Hee;Kim, Seong Keun;Lee, Choong Hoon;Song, Ju Yeon;Kong, Eun Bae;Kim, Jihyun F.
    • Journal of Microbiology and Biotechnology
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    • v.22 no.8
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    • pp.1054-1058
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    • 2012
  • In order to predict biologically significant attributes such as function from protein sequences, searching against large databases for homologous proteins is a common practice. In particular, BLAST and HMMER are widely used in a variety of biological fields. However, sequence-homologous proteins determined by BLAST and proteins having the same domains predicted by HMMER are not always functionally equivalent, even though their sequences are aligning with high similarity. Thus, accurate assignment of functionally equivalent proteins from aligned sequences remains a challenge in bioinformatics. We have developed the FEP-BH algorithm to predict functionally equivalent proteins from protein-protein pairs identified by BLAST and from protein-domain pairs predicted by HMMER. When examined against domain classes of the Pfam-A seed database, FEP-BH showed 71.53% accuracy, whereas BLAST and HMMER were 57.72% and 36.62%, respectively. We expect that the FEP-BH algorithm will be effective in predicting functionally equivalent proteins from BLAST and HMMER outputs and will also suit biologists who want to search out functionally equivalent proteins from among sequence-homologous proteins.

Evaluation of the Genetic Toxicity of Synthetic Chemicals (Ⅷ) - In vivo Bone Marrow Micronucleus Assay of 8 Synthetic Chemicals in Mice - (합성화학물질들의 유전독성평가(Ⅷ) -마우스의 골수세포를 이용한 8종 합성화학물질들의 생체내 소핵시험-)

  • Ryu, Jae-Chun;Kim, Kyung-Ran;Kim, Youn-Jung
    • Environmental Analysis Health and Toxicology
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    • v.18 no.2
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    • pp.137-143
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    • 2003
  • To validate and to estimate the chemical hazard playa very important role to environment and human health. The detection of many synthetic chemicals used in industry that may pose a genetic hazard in our environment is of great concern at present. Since these substances are not limited to the original products, and enter the environment, they have become widespread environmental pollutants, thus leading to a variety of chemicals that possibly threaten the public health. In this resepct, the clastogenicity of 8 synthetic chemicals was evaluated with bone marrow micronucleus assay in mice. The positive control, mitomycin C(2mg/kg,i.p.) revealed significant induction ratio of percentage of micronucleated polychromatic erythrocytes/l,000 polychromatic erythrocytes compared to carboxymethylcellulose control. The chemicals with relatively high LD$\_$50/ value such as phenylisocyanate (CAS No. 103-71-9), m-aminochlorobenzene (CAS No. 108-42-9) and 2-chloro-4-nitroaniline (CAS No. 121-87-9) revealed no significant induction of micronucleated polychromatic erythrocytes in mice. From this results, 8 synthetic chemicals widely used in industry have revealed no significant micronucleus induction of clastogenicity in mice in this experiment.

Synthesis of Pine Tree Ash and Red Pepper Stem Ash (소나무재와 고추나무대재 합성에 관한 연구)

  • Han, Young-Soon;Lee, Yong-Seok;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.393-401
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    • 2006
  • The development of Korean glaze originated from the development of ash glazes. Ash not only has strong solubility but also can shows the glaze a variety of different colors according to what the glaze has in it as the main component. In addition, it gives a feeling of lucidness and softness. For these reasons, there are a lot of needs for ash and many potters want to take advantage of ashes as glaze. But natural ashes have not been widely used as glaze primarily because it is relatively hard to find or manufacture. Considering the difficulty of finding or manufacturing natural ashes, this study aims to formulate synthetic ash which not only is available to the potters in general but also has the sam ε characteristics as the natural ashes. To achieve this aim, this study examines the characteristics of the pine tree ash, the main component of the glaze of celadon porcelains, and the red pepper stem ash, the main component of the brown glaze, both of which have been used by the Korean traditional potters. In this study, the alkaline component of the glaze. A important ingredient when the ashes are synthesized, was supplied by mixing of $Na_2CO_3$, Chungju limestone and rice straw ash. Furthermore, the synthetic ash, when it shows no change of pH in its composition rate of 6:2:2, was found to be usable as the most stable material. In conclusion, the formula which frits some raw $materials-Na_2CO_3$, Chungju limestone and rice straw ash-can duplicate the synthetic ash which is simila to the natural ash.

Occurrence of Synthetic Musk Compounds in Surface and Waste Waters in Korea (국내 하천수 및 하수처리장 유입.방류수의 합성머스크화합물 오염실태 조사)

  • Lee, In-Jung;Lee, Chul-Gu;Heo, Seong-Nam;Lee, Jae-Gwan
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.821-826
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    • 2011
  • Synthetic musk compounds are widely used as fragrances in a variety of personal care products like soaps, sampoos, cosmetics and perfumes. The occurrence of synthetic musk compounds in municipal sewage effluent and other environmental samples could negatively impact the health of the ecosystem and humans, due to persistent and long-term chronic exposure of aquatic organisms. Fifteen synthetic musk compounds (musk ketone, musk xylene, musk ambrette, musk moskene, musk tibetene, HHCB, AHTN, ADBI, AHDI, DPMI, ATII, ethylenebrasssylate, ambretettolide, cyclopentadecanolide, OTNE) were analysed in surface waters and sewage treatment plants (STP) influents/effluents in Korea by GC/MS. Method detection limits were $0.005{\sim}0.398{\mu}g/L$. HHCB and AHTN were most frequently observed in both surface waters and STP influents/effluents.

A Review on the Asbestos Substitutes and Health Hazards (석면 대체물질의 종류 및 건강영향 고찰)

  • Park, Seung-Hyun;Ahn, Jungho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.3
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    • pp.184-195
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    • 2013
  • Objectives: The purpose of this study is to provide information in reference to the health hazards of asbestos substitutes. Methods: This study was conducted by reviewing the literature on the types of asbestos substitutes, product development using alternative materials and the health effects associated with asbestos substitutes. Results: Synthetic or natural fibers such as synthetic vitreous fiber, polyamide, attapulgite, sepiolite and wollastonite are known as asbestos substitutes. According to the patents data of the United States and Europe since the 1970s, many asbestos-free products have been developed in a variety of industries. Health hazards of some asbestos substitutes including synthetic vitreous fibers have been evaluated by many experts, however, additional researches are required to be carried out in the future. Conclusions: Alternatives to asbestos are necessary to develop the asbestos-free products. Health hazards for only several asbestos substitutes have been assessed so far and occupational exposure limit has not been established for many asbestos substitutes yet. Therefore, even though workers are handling asbestos-free products, it is recommended to control the working environment well enough in order to minimize the exposure of workers to dusts or fibers caused during the working process.