• Title/Summary/Keyword: synthetic temperature

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Antimicrobial activity against Propionibacterium acnes bacteria of Smilacis glabrae Rhizoma extracts (토복령 추출물의 여드름 균에 대한 항균활성)

  • Park, Jang-Soon;Kwon, Hye-Jin
    • Journal of the Korea Convergence Society
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    • v.8 no.12
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    • pp.425-430
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    • 2017
  • This study was conducted to measure the antimicrobial activity and antiseptic effect of Smilax china root extracts against Propionibacterium acnes and to develop natural antimicrobial extracts as an alternative for synthetic preservatives, which have recently been controversial. Extracts were obtained from dried Korean Smilax china root at room temperature using two solvents, distilled water and 95% EeOH, separately. According to the results of this study, the antimicrobial effect of Propionibacterium acnes 3314 and Propionibacterium acnes 3320 against Propionibacterium acnes was outstanding. In particular, the clear zone of the extract using distilled water showed the highest activity with 16.61 mm. As for the result of the collection of contaminated skin sample, the clear zone was 24.48 mm. This indicates that Smilax china root extracts show a high activity against skin flora as well as a high antimicrobial activity against Propionibacterium acnes. In conclusion, it is confirmed that Smilax china root extracts can be used as raw materials for cosmetics that have antimicrobial activity and antiseptic effect, and it is expected that Smilax china root extracts will be used as basic materials for the development of future natural preservatives.

Optimum Process Condition by Experimental Design Method for the Synthesis of Methylchlorosilanes(MCS) (실험계획법에 의한 메틸염화실란 합성의 최적공정조건)

  • Cho, Chul Kun;Han, Kee Do
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.394-398
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    • 1998
  • An optimum synthetic condition was studied for the MCS used as a silicone monomer. The contact mixture was made from the four component catalyst system($CuCl/ZnCl_2/Sn/Cd$) and silicon particles. The contact mass was used for a series of experiments with methyl chloride, which were designed and done to explore the optimum condition for MCS synthesis by an experimental design method. The optimum temperature and MeCl flow rate, which were obtained using 50g contact mass at 60rpm and 1 atm, were in the range of $300-305^{\circ}C$ and of 70-80ccm. Also a continuous run was performed to confirm the conditions. The results showed that the average reaction rate and selectivity were 170(g-MCS/hr.kg-Si) and 0.05 respectively at 67% conversion of MeCl and 92% silicon utilization rate. Also the parameters of overall reaction rate equation and a total pressure were estimated on the basis of the results of the continuous run.

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Effect of Etomidoline on the Isolated smooth Muscle of Rabbit (Etomidoline이 각종 평활근에 미치는 영향)

  • Kim, W.J.;Kim, J.H.;Sheen, Y.Y.
    • The Korean Journal of Pharmacology
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    • v.16 no.2 s.27
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    • pp.25-29
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    • 1980
  • Etomidoline ($Nonspa^{\circledR}$), which is chemically related to tertiary amine, is new synthetic antispasmodic agent with analgesic action. Antispasmodic effect of this agent is stronger than hyoscine butylbromide ($Buscopan^{\circledR}$), quaternary amine, and the absorption from intestine is also much higher. This study was undertaken to determine the effect of etomidoline on duodenal motility and other smooth muscles of rabbit. Strips of various isolated smooth muscle, 2 cm long from adult rabbits weighting about 2 kg, were suspended in a muscle chamber containing Tyrode's solution, which was bubbled with oxygen gas, and the temperature of the solution was kept constant at $38^{\circ}C$. After being washed with fresh solution several times the strips of smooth muscle attained constant motility and tonus. Etomidoline and other drugs were added in various concentrations to the chamber. Contractility of the strips was measured by using polygraph (Grass, model 7). The results are as follows: 1) In isolated rabbit atrium etomidoline produces a slight depression of contractility and the rate is also decreased. 2) On the other hand, etomidoline relaxed isolated strips of stomach, duodenal, and detrusor of rabbit. This relaxing effect of etomidoline on isolated duodenal strip of rabbit was not blocked by ${\alpha}$-adrenergic blocking agent, phenoxybenzamine, but by ${\beta}$-adrenergic blocking agent, propranolol. 3) Etomidoline did not exert any effect on isolated aorta, gall bladder, and trigone of rabbit. From the above results, it may be concluded that the relaxing effect of etomidoline on duodenal strip is related ${\beta}$-adrenergic receptor.

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Treatment of Refractory Dye Wastewater Using AOPs (고도산화공정(AOPs)을 이용한 난분해성 염색폐수 처리)

  • Kim, Jong-Oh;Lee, Kwon-Ki;Jung, Jong-Tae;Kim, Young-Noh
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.3
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    • pp.21-29
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    • 2006
  • The treatment performance of ozonation and three types of advanced oxidation processes (AOPs) such as $O_3/H_2O_2$, $O_3/UV$, $O_3/H_2O_2/UV$ was experimentally investigated for the treatment of refractory synthetic dye wastewater. The removal efficiency of $COD_{cr}$, color and biodegradability ($BOD_5/COD_{cr}$) were relatively evaluated in each treatment unit with simulated dye wastewater. Optimal operational conditions of pH, temperature, dosage and circulation flow rate were also investigated. All suggested processes revealed an effectiveness for the removal of color within a short operational time, moreover, $O_3/H_2O_2/UV$ process showed the highest $COD_{cr}$ removal and biodegradability enhancement among proposed oxidation process.

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A Feasibility Study on Shale Gas Plant Water Treatment by Direct Contact Membrane Distillation (셰일가스 플랜트 용수 처리를 위한 직접 접촉 막 증발법 적용 가능성 연구)

  • Koo, Jae-Wuk;Han, Jihee;Lee, Sangho;Hong, Seungkwan
    • The KSFM Journal of Fluid Machinery
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    • v.16 no.1
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    • pp.56-60
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    • 2013
  • Non-conventional oil resources such as shale gas are becoming increasingly important and have drawn the attention of several major oil companies all over the world. Nevertheless, the market-changing growth of shale gas production in recent years has resulted in the emergence of environmental and water management challenges. This is because the water used in the hydraulic fracturing process contains large amount of pollutants including ions, organics, and particles. Accordingly, the treatment of this flowback water from shale gas plant is regarded as one of the key technologies. In this study, we examined the feasibility of membrane distillation as a treatment technology for the water from shale gas plants. Direct contact membrane distillation (DCMD) is a thermally-driven process based on a vaper pressure gradient across a hydrophobic membrane, allowing the treatment of feed waters containing high concentration of ions. Experiments were carried out put in the lab-scale under various conditions such as membrane types, temperature difference, flow rate and so on. Synthetic feed water was prepared and used based on the data from literature. The results indicated that DCMD is suitable for treating not only low-range flowback water but also high-range flowback water. Based on the theoretical calculation, DCMD could have over 80% of recovery. Nevertheless, organic pollutants such as oil and surfactant were identified as serious barriers for the application of MD. Further works will be required to develop the optimum pretreatment for this MD process.

Dyeing Properties of PET/Dyeable PP Double Knit Fabric (PET/가염PP 이종 편성물의 염색 특성)

  • Chang, Young-Min;Lee, Jin-Ah;Park, Jong-Ho;Koh, Joon-Seok;Jung, Young-Jin;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.53-58
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    • 2008
  • New dyeable PP fiber and several products from it has been developed through dispersing polyester copolymer into PP resin by a Korean synthetic fiber manufacturer and its colleagues. The dyeing properties of PET/dyeable PP double knit fabric were examined with three different types of disperse dye in this study. It was found that the disperse dye, exhausted on dyeable PP at early stage of dyeing, migrated to PET at elevated dyeing temperature when two fibers were dyed in the same dye bath. The ratios of dye distribution between two substrates dyed at $120^{\circ}C$ and $130^{\circ}C$ showed no difference. S type disperse dyes showed good build-up properties and acceptable color fastness while high light fastness type exhibited the lowest amounts of exhaustion but excellent color fastness. It might be concluded that the most appropriate dye for PET/dyeable PP double knit fabric was S type, and that some color difference between PET side and dyeable PP side was unvoidable.

Effect of Water on the Kinetics of Nitric Oxides Reduction by Ammonia over V-based Catalyst (바나듐계 촉매상에서 암모니아를 이용한 질소산화물의 환원반응속도에 수분이 미치는 영향에 관한 연구)

  • Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.6
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    • pp.73-82
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    • 2012
  • The main and side reactions of the three selective catalytic reduction (SCR) reactions with ammonia over a vanadium-based catalyst have been investigated using synthetic gas mixtures in the temperature range of $170{\sim}590^{\circ}C$. The three SCR reactions are standard SCR with pure NO, fast SCR with an equimolar mixture of NO and $NO_2$, and $NO_2$ SCR with pure $NO_2$. Vanadium based catalyst has no significant activity in NO oxidation to $NO_2$, while it has high activity for $NO_2$ decomposition at high temperatures. The selective catalytic oxidation of ammonia and the formation of nitrous oxide compete with the SCR reactions at the high temperatures. Water strongly inhibits the selective catalytic oxidation of ammonia and the formation of nitrous oxide, thus increasing the selectivity of the SCR reactions. However, the presence of water inhibits the SCR activity, most pronounced at low temperatures. In this study, the experimental results are analyzed by means of a dynamic one-dimensional isothermal heterogeneous plug-flow reactor (PFR) model according to the Eley-Rideal mechanism.

Identification of Clostridium perfringens AB&J and Its Uptake of Bromophenol Blue

  • Kim, Jeong-Dong;An, Hwa-Yong;Yoon, Jung-Hoon;Park, Yong-Ha;Fusako Kawai;Jung, Chang-Min;Kang, Kook_-Hee
    • Journal of Microbiology and Biotechnology
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    • v.12 no.4
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    • pp.544-552
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    • 2002
  • Several microorganisms from rat and human feces and lumen fluid of cows were screened for their ability to decolorize the synthetic dyes. Consequently, a novel dye-degrading strain AB&J was isolated. Taxonomic identification including 165 rDNA sequencing and phylogenetic analysis indicated that the isolate had 99.9% homology in its 165 rDNA base sequence with Clostridium perfringens. After 27 h Incubation with the strain, brilliant blue R, bromophenol blue, crystal violet, malachite green, methyl green, and methyl orange were decolorized by about 69.3%, 97.7%, 96.3%, 97.9%, 75.1%, and 97.2%, respectively. The triphenlmethane dye, bromophenol blue, was decolorized extensively by growing Clostridium perfringens AB&J cells in liquid cultures under anaerobic condition, although their growth was strongly inhibited in the initial stage of incubation. This group of dyes is toxic, depending on the concentration used. The dye was significantly decolorized at a relatively lower concentration of below 50 $\mu g \;ml^{-1}$, however, the growth of the cells was mostly suppressed at a dye concentration of 100 $\mu g \;ml^{-1}$. The decolorization activity in cell-free extracts was much higher in cytoplasm than in periplasm and cytoplasmic membrane. Therefore, the enzyme related uptake of bromophenol blue seemed to be localized in cytoplasm. The optimal pH and temperature of bromophenol blue uptake fur decolorization activities were 7.0 and 4$0^{\circ}C$, respectively.

High Pressure X-ray Diffraction Study of LiFePO4/C-olivine-like Phase (LiFePO4/C-유사 감람석 결정구조에 대한 고압 X-선회절연구)

  • Hwang, Gil-Chan;Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.1
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    • pp.35-44
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    • 2013
  • Synthetic carbon-coated olivine-like structured lithium iron phosphate ($Li^+Fe^{2+}(PO_4)^{3-}/C$) powder composites were compressed up to 35.0 GPa in the symmetrical diamond anvil cell at room temperature. Bulk modulus of $LiFePO_4/C$ was determined to be $130.1{\pm}10.3$ GPa. New peak appears at the d-spacing of 3.386 ${\AA}$ above 18 GPa, and another new one at 2.854 ${\AA}$ around 35 GPa. The crystallographic symmetry of the sample (i.e. orthorhombic) is apparently retained up to 35 GPa as no clear evidence for the phase transition into spinel structure has been observed. The pressure-induced volume change in the M1 site ($Li^+O_6$) is more significant than those in M2($Fe^{2+}O_6$) and $PO_4$ tetrahedral sites.

A study on suitability selection of artificial reef by GIS (GIS을 활용한 인공어초의 적지 선정에 관한 연구)

  • Kim, Bum-Kyu;Hwang, Do-Hyun;Yoon, Hong-Joo;Seo, Won-Chan
    • The Journal of the Korea institute of electronic communication sciences
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    • v.10 no.5
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    • pp.629-636
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    • 2015
  • This study carried out in order to investigate the most basic elements of suitability selection methods for composition of artificial reef. Acquired data by in-situ measurements and satellite remote sensing analysed in applying GIS. To identify the characteristic of marine environment around the West Sea, the South Sea and the East Sea of Korea, physical conditions-seabed sediment and depth, biological conditions-chlorophyll-${\alpha}$, chemical conditions-Sea Surface Temperature(SST) and DO were used. Suitable sites for artificial reef are selected Taean Peninsula, Geoje, Wando, Pohang, Seocheon, etc. From now on, it will be helpful to effectively utilize artificial reef as well as construct synthetic database. It is also expected to use basic data for artificial reef facilities management.