• Title/Summary/Keyword: swelling degree

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Electron Beam-Induced Modification of Poly(dimethyl siloxane) (전자빔을 이용한 Poly(dimethyl siloxane)의 개질)

  • Kang, Dong-Woo;Kuk, In-Seol;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak;Nho, Young-Chang;Mun, Sung-Yong;Lee, Young-Moo
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.157-160
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    • 2011
  • In this paper, poly (dimethyl siloxane) (PDMS) was modified using electron beam irradiation and its property was investigated. PDMS sheets prepared using a conventional thermal curing method were irradiated by electron beams at absorbed doses between 20 and 200 kGy and their properties were characterized using swelling degree and contact angle measurements, universal testing machine (UTM), thermogravimetric analyzer (TGA), and X -ray photoelectron spectrometer (XPS). The results of the swelling degree measurements, UTM, and TGA revealed that the swelling degree of the irradiated PDMS sheets was reduced down to 24% in comparison to the control sheet, and their compression strength and thermal decomposition temperature increased up to maximum 2.5 MFa and $10^{\circ}C$, respectively, due to the increase in crosslinking density by irradiation. In addition, on the basis of the results of contact angle measurements and XPS, the wettability of the PDMS sheets was enhanced up to 24% owing to the generation of hydrophilic functional groups on the PDMS surface by oxidation during electron beam irradiation.

Mechanical Properties of Cellulose/Chitosan and Sericin/Chitosan Blend Films

  • Kiyohisa Takahashi;Kenji Nagata;Yoon, Heung-Soo
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.9-10
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    • 2003
  • Cellulose/chitosan and sericin/chitosan blend films with various mixing ratios were prepared and tensile properties, solubilities to the aqueous solution of acetic acid and the degree of swelling by the distilled water were measured. The interaction between the components of blend film and the blending effect were investigated.

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Physicochemical Properties and Hydration of Rice on Various Polishing Degrees (도정도에 따른 쌀의 수화와 이화학적 특성)

  • Kim, Kyung-Ae;Jeon, Eun-Ryae
    • Korean Journal of Food Science and Technology
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    • v.28 no.5
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    • pp.959-964
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    • 1996
  • The physicochemical and gelatinization properties of rice flours, which were prepared by polishing nonwaxy brown rice (Dongjin byeo), depending on polishing degrees were investigated. The contents of protein, ash, lipid and fiber decreased significantly as the degrees of polishing increased and water uptake of rice grains decreased during hydration. When the surface of the soaked rice grains was examined by the SEM, extensive crack formation was observed. The water binding capacities, swelling power and solubility of rice flour increased as the polishing degree increased. By the amylogram, the initial gelatinization temperatures of rice flour decreased as the polishing degree increased and the peak viscosities, the breakdown and consistency of rice flour increased as the polishing degree increased.

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Effect of Cations on the Sorption and the Tensile Properties of CMC Fibers (CMC섬유내의 양이온이 섬유의 흡습성과 인장 성질에 미치는 영향)

  • 이미식
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.1
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    • pp.113-120
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    • 1994
  • The Purpose of this study was to improve the moisture related properties of viscose rayon fibers. Viscose rayon filament yarns were partially etherified to make CMC fibers. CMC fibers were converted to the sodium, calcium, and ferric salt forms by an ion exchange method. The property changes of ion exchanged CMC fibers were examined. Cation contents of fibers were varied depending on the degree of substitution of CMC fibers. The strength of Na, Ca, Fe-CMC was higher than H-CMC owing to the plasticization by moisture sorption and the crosslinking by cations. The moisture regain was increased by carboxymethylation and that of Fe-CMC showed the highest value. The degree of swelling determined by the water retention value was observed to be Na-CMC > Ca-CMC > H-CMC > Fe-CMC. The solution retention value was decreased in the order . Ca-CMC > Na-CMC > H-CMC > Fe-CMC.

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Preparation of photo-crosslinkable silk sericin hydrogel

  • Kim, Jung Eun;Kim, Eui Hwa;Lee, Ki Hoon
    • International Journal of Industrial Entomology and Biomaterials
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    • v.36 no.1
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    • pp.10-14
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    • 2018
  • A photo-crosslinkable sericin hydrogel has been prepared by introducing methacrylate groups on sericin. Lysine was the amino acid for methacrylation and the degree of methacrylation was increased with the amount of methacrylic anhydride added. When the concentration of methacrylic anhydride was 20% of sericin, 0.635 mmol/g of methacrylate group could be introduced. The storage modulus of sericin hydrogel was increased proportionally with the degree of methacrylation. However, the swelling ratio of sericin hydrogel decreased with the increase of methacrylation.

Enzymatic Hydrolysis of Cellulose (섬유소(纖維素)의 당화(糖化))

  • Lee, Kye-Joon
    • Korean Journal of Pharmacognosy
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    • v.7 no.2
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    • pp.85-93
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    • 1976
  • Since cellulose is the only organic material that is annually replenishable in very large quantities, we must explore ways to utilize it as a source of energy, food and chemicals. For the utilization of this resource, it is first enzymatic hydrolyzed to glucose, then the glucose can be used as a food, converted single cell protein by microorganism, fermented to clean burning fuel and other chemicals. Cellulolytic enzyme, cellulase, consists of two or three major components, $C_1-cellulase$, $C_x-cellulase$ and ${\beta}-glucosidase$. $C_x-cellulase$ are fairly common but $C_1-cellulase$ are quite rare. Trichoderma viride is the best source of active cellulose, especially $C_1-enzyme$. Saccharification rate of cellulose in greatly influenced by the degree of crystallinity and extent of lignification. But by the pretreatment the substrate with cellulose swelling agent, delignifying reagent and physical treatment, the degree of saccharification is enhanced. Thus, glucose syrups of 2 to 10% concentration are realized from milled newspaper. The enzymatic hydrolysis of such energy rich material, such as cellulose, to glucose is technically feasible and practically achievable on a very large scale.

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Preparation and Characterization of PVAL/PVP/Hexylene Glycol/Chitosan Hydrogels by $\gamma$-Ray ($\gamma$-선을 이용한 PVAL/PVP/헥실렌 글리콜/키토산 수화젤의 제조 및 특성)

  • 최은경;김형일;노영창
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.349-357
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    • 2003
  • Hydrogels for wound dressing from a mixture of poly(vinyl alcohol) (PVAL), poly(N-vinyl pyrrolidone) (PVP), hexylene glycol (HG) and chitosan were made. The hydrogels were obtained by physical crosslinking of freezing and thawing, chemical crosslinking of irradiation, and irradiation after freezing and thawing of mixture solutions. The solid concentration of PVAL/PVP/HG/chitosan was 15 wt%. The concentration of chitosan was 0.3 wt%, and the ratio of PVAL/PVP was 6:4. The concentration of HG was in the range of 1∼5 wt%. The number of repeated freezing and thawing was in the range of 1∼3 times, and gamma irradiation doses were 25, 35 and 50 kGy. The physical properties such as gelation, water absorption and gel strength of hydrogels were examined. Gel content and gel strength decreased as HG concentration increased, whereas degree of swelling increased. Gel content and gel strength increased as irradiation dose and the number of freezing and thawing increased, whereas degree of swelling decreased. The hydrogels were evaluated for the healing effect for animals and for the antibacterial effect.

Preparation and Physical Properties of Blend Films of Natural Rubber and Chloroprene Rubber Latex (NR/CR 라텍스 블렌드 필름의 제조 및 물리적 특성)

  • Kim, Kong Soo;Park, Jun Ha;Eum, Ju Song
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.691-697
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    • 1996
  • The NR films were prepared with mixing of natural rubber latex(NRL) with various additives, and NR/CR films were prepared by blend ratio of chloroprene rubber latex(CRL). The swelling degree and the mechanical properties of these films were measured according to the procure time. As a result, optimum condition were showed the swelling degree : 80~85%, precure time : 48~60hrs., and tensile strength was reduced but elongation was increased as increasing the blend ratio of CRL. On the mechanical properties of films prepared by different dipping process in these optimum condition, the tensile strength and tear strength of NR/CR films by one dipping process are better than NR-d-CR films by two dipping process. The surface of these films were observed with scanning electron microscopy(SEM). It was found that phase separation was occured as increasing the blend ratio of CRL.

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Effect of Acupuncture and High Frequency Therapy Applied to the Region Branching to the External Carotid Artery on Reduction of Facial Edema in Patients with Sequelae of Peripheral Facial Palsy: A Case Report (말초성 안면마비 후유증 환자에서 침 치료와 바깥목동맥으로의 분지 영역에 시행한 고주파 병행 치료의 안면부종 감소 효과: 증례보고)

  • An, Sunjoo;Choi, Seonghwan;Kang, Shinwoo;Park, Seohyun;Keum, Dongho
    • Journal of Korean Medicine Rehabilitation
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    • v.30 no.4
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    • pp.233-241
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    • 2020
  • This study was performed to evaluate the effect of high frequency therapy applied to the region branching to the external carotid artery for peripheral facial paralysis sequelae. A patient suffering with facial edema due to facial paralysis sequelae had been treated with acupuncture, high frequency therapy on the branch area to the external carotid artery for 7 weeks. The evaluation of clinical outcome was done by degree of swelling by measuring the distance of the face and skin temperature of face through digital infrared thermographic imaging. After treatment, the patient's degree of swelling and the temperature difference between the affected side and normal side was decreased. In addition, the temperature was changed in the entire facial area as well as the treatment point of high frequency therapy. This result shows that acupuncture combined with high frequency therapy at the region branching to the external carotid artery could be an effective way to improve facial blood flow, although further clinical studies will be needed.

Preparation of High Molecular Weight Atactic Poly(vinyl alcohol) Hydrogel by Electron Beam Irradiation Technique (전자빔 조사를 이용한 고분자량 혼성배열 폴리(비닐 알코올) 수화젤의 제조)

  • Kim, Kyung-Sik;Lee, Young-Jae;Lyoo, Won-Seok;Noh, Seok-Kyun
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.587-592
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    • 2008
  • High molecular weight poly(vinyl alcohol) (PVA) hydrogel to be expected as a candidate material for the wound-dressing was successfully prepared by electron beam (EB) irradiation. To produce PVA hydrogels with various gel fractions, degrees of swelling in water, gel strengths, and elongations, two different number-average degrees of polymerization [($P_n$)s] of PVA were adapted such as 1700 and 4000, and the PVA solution concentration and irradiation dose of EB were controlled to range of 5 $\sim$ 20% and 30 $\sim$ 100 kGy, respectively. The gel fraction and strength of PV A hydrogel were increased with increasing molecular weight of PVA, solution concentration, and irradiation dose of EB. On the contrary, the degree of swelling and elongation of PVA hydrogel were decreased. The thermal property and crystallinity related to degree of crosslinking of PVA hydrogel were examined by the analyses of differential scanning calorimetry and X-ray diffraction.