• Title/Summary/Keyword: surfactant coating

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Effect of surfactant addition on curtain coating color properties and curtain stability (계면활성제 첨가가 커튼 코팅용 도공액의 물성과 커튼 안정성에 미치는 영향)

  • Oh, Kyu-Deok;Kim, Chae-Hoon;Youn, Hye-Jung;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.5
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    • pp.49-54
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    • 2011
  • Curtain coating has been considered as the best coating technology because it is a coating technology that forms contour coating layer with better coverage. To increase the curtain stability surfactants are being used. In this study, the effect of a surfactant on the stability of curtain coating colors was examined by evaluating dynamic surface tension with a bubble surface tensiometer. Di-2-ethylhexyl sodium sulfosuccinate was used as a surfactant since it showed low dynamic surface tension at low surface age. And we evaluated the influence of surfactant on coating color properties including surface tension, viscosity and curtain stability. The surface tension of coating color was decreased when surfactant addition was increased up to 0.5 pph, but it was leveled off at 0.3 pph of surfactant addition. With the increase of surfactant addition rate, viscosity of coating color were increased. Micelles formed by surfactant contributed to the increase of the viscosity. Curtain stability was improved with the addition of surfactant until it reached up to 0.5 pph. Excessive addition of surfactant (> 0.5 pph) didn't improve curtain stability. This was attributed to Marangoni effect(self-healing) and decreasing of curtain thickness.

A Surfactant-based Method for Carbon Coating of LiNi0.8Co0.15Al0.05O2 Cathode in Li Ion Batteries

  • Chung, Young-Min;Ryu, Seong-Hyeon;Ju, Jeong-Hun;Bak, Yu-Rim;Hwang, Moon-Jin;Kim, Ki-Won;Cho, Kwon-Koo;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2304-2308
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    • 2010
  • A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

The Effect of Surfactant on the Electrorheological Properties of Phosphoric Ester Cellulose ER Fluids (인산 에스테르 셀룰로오스 ER 유체의 전기유변학적 특성에 대한 계면활성제의 영향)

  • 안병길;최웅수;권오관
    • Tribology and Lubricants
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    • v.15 no.3
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    • pp.240-247
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    • 1999
  • The electrorheological (ER) behavior of suspensions in silicone oil of phosphoric ester cellulose particles (average particle size : 18$\pm$1${\mu}{\textrm}{m}$) coated with octadecylamine ( $C_{18}$ $H_{37}$ N $H_2$) as surfactant was investigated at room temperature. For development of anhydrous ER suspension using at real application, it should be researched how can reduce deposition of ER particles in ER suspension. Anhydrous ER suspensions mixing with phosphoric ester cellulose particles coated with octadecylamine were measured. As increasing the coating concentration of octadecylamine, not only analysis of electrical properties such as dielectric constant, current density and electrical conductivity but also rheological properties of ER suspensions were studied. From the experimental results, coating concentration of surfactant had large influence to ER properties of anhydrous ER suspension. Current density, conductivity and electrorheological effect ($\tau$/$\tau$$_{0}$) of ER suspension were linearly reduced with increasing the coating concentration of octadecylamine. But ER suspensions dispersed the phosphoric ester cellulose particles coated with octadecylamine showed reducing deposition of ER particles and could be redispersed easily.

Surface modification of silica aerogel by surfactant adsorption and heat treatment methods (계면활성제 흡착 및 열처리를 이용한 실리카 에어로겔의 표면 개질)

  • Kim, Nam-Yi;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.282-289
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    • 2010
  • In preparation of silica aerogel-based hybrid coating materials, the combination of hydrophobic aerogel with organic polar binder material is shown to be very limited due to dissimilar surface property between two materials. Accordingly, the surface modification of the aerogel would be required to obtain compatibilized hybrid coating sols with homogeneous dispersion. In this study, the surface of silica aerogel particles was modified by using both surfactant adsorption and heat treatment methods. Four types of surfactants with different molecular weights and HLB values were used to examine the effect of chain length and hydrophilicity. The surface property of the modified aerogel was evaluated in terms of visible observation for aerogel dispersion in water, water contact angle measurement, and FT-IR analysis. In surface modification using surfactants, the effects of surfactant type and content, and mixing time as process parameter on the degree of hydrophilicity for the modified aerogel. In addition, the temperature condition in modification process via heat treatment was revealed to be significant factor to prepare aerogel with highly hydrophilic property.

Method to Increase the Surface Area of Titania Films and Its Effects on the Performance of Dye-Sensitized Solar Cells

  • Ko, Young-Seon;Kim, Min-Hye;Kwon, Young-Uk
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.463-466
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    • 2008
  • We report a method to increase the surface area of the titania films used as the anodes of dye-sensitized solar cells (DSSCs) by applying additional titania-coating. The modification was achieved by spin-coating a coating solution that contained a surfactant with a titania source onto the titania electrodes, followed by calcination. Previous similar attempts without a surfactant all reported decreased surface areas. We fabricated DSSCs by using the modified titania films as the anode and measured their performances. The increased surface area increased the amount of adsorbed dyes, which resulted in increased current densities. At the same time, the titania-coating increased both the open-circuit voltage and the current density by reducing the charge-recombination rates of the injected electrons, similar to the results of literatures. Therefore, our method shows an additional mechanism to increase the current density of DSSCs in addition to the other mechanisms of surface modifications with titania-coatings.

Simple Algorithm of Structure Features Extration for Stereo Image Matching (스테레오 영상 정합을 위한 새로운 구조 정보 추출 알고리즘)

  • 최환언
    • Journal of the Korean Graphic Arts Communication Society
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    • v.9 no.1
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    • pp.1-11
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    • 1991
  • In this reseach, double-layered photoconductor consist of the carrier generation layer(CGL) of $\varepsilon$ type copper phthalocyanine thin film by an aqueous coating method and the carrier transport layer(CGL) of polyvinyl carbazol(PVK) by spin coating. We inverstigated effect of the surfactant solution and cathod electrolysis to the crystal type of $\varepsilon$-CuPc in CGL with TEM, SEM and X- ray diffraction spectroscopy and studied the mechanism of an aqueous coating for the preparation of CGL. The effect of the washing of CGL about the electrophotographic characteristics of the $\varepsilon$-CuPc/PVK doublelayered photoconductors is studied also.

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A Study of the High Sensitive Nonsilver Halide Imaging Material( II ) - Study of the aqueous coating mechanism and washing effect of the CGL in the $\varepsilon$-CuPc/PVK double-layered organic photoconductor - (고감도 비은염 화상재료 개발연구 ( II ) - Copper Phthalocyanine/PVK 전자사진감광체의 CGL의 수성 coating mechanism과 세정효과에 관한 연구 -)

  • 이상남
    • Journal of the Korean Graphic Arts Communication Society
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    • v.9 no.1
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    • pp.27-44
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    • 1991
  • In this research, double-layered photoconductor consist of the carrier generation layer(CGL) of ${\varepsilon}$ type copper phthalocyanine thin film by an aqueous coating method and the carrier transport layer(CGL) of polyvinyl carbazol(PVK) by spin coating. We inverstigated effect of the surfactant solution and cathod electrolysis to the crystal type of ${\varepsilon}$-CuPc in CGL with TEM, SEM and X-ray diffraction spectroscopy and studied the mechanism of an aqueous coating for the preparation of CGL. The effect of the washing of CGL about the electrophotographic characteristics of the ${\varepsilon}$-CUPC/PVK double-layered photoconductors is studied also.

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Nanoparticles Modified With Cationic Thiol Surfactant as Efficient Inhibitors for the Corrosion of Carbon Steel

  • Azzam, Eid M.S.;Sami, Radwa M.;Alenezi, Khalaf M.;El Moll, Hani;Haque, A.
    • Journal of Electrochemical Science and Technology
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    • v.12 no.3
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    • pp.308-316
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    • 2021
  • In this work, we report synthesis, characterization and corrosion inhibition properties of cationic thiol surfactant-capped silver (SC-Ag-NPs) and gold (SC-Au-NPs) nanoparticles. SC-Ag-NPs and SC-Au-NPs were characterized using regular techniques include TEM. Corrosion study was carried out using carbon steel (CS) in 3.5% NaCl aqueous solution and characterized using multiple electrochemical techniques. Our results suggest that the paint containing SC-Ag-NPs and SC-Au-NPs endow efficient corrosion protection to the CS. Especially, SC-Au-NPs based paint form a stronger barrier between the metal and the corrosive ions, leading to better inhibition properties.

Mechanical properties of coating of NATM resin on Stainless Steel (스테인레스 스틸에 대한 NATM 수지의 코팅에 대한 기계적 특성)

  • Kim, Ki-Jun;Lee, Joo-Youb;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.238-243
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    • 2014
  • The mechanical properties of NATM resin were measured by SEM, FT-IR spectra, tensile properties, mole % of [NCO/OH], and particle size analyzer on stainless steel. Growing concerns in the environment-friendly NATM resin, we have synthesized the solvent-free NATM resin to be coating on metals such as stainless. The properties of the synthesized NATM resin to be contained polyols, MDI, silicone surfactant, fillers and crosslink agents(diethyltoluene diamine, anhydrosorbitol), that they have highly stronger in intensity and longer durability than general NATM resin to be contained polyols, IPDI, silicone surfactant, fillers in general packing materials and coatings. The rigid segments of polyurethane in mechanical properties of coatings were due to cross linkage and the increase mole % of [NCO/OH]. In conclusion, the NATM microstructure with cross linkage can be good material for coating of anticorrosion of metal substrates such as stainless steel.

Influence Factor on Magnetization Property of Carbonyl Iron-based Magnetorheological Fluids

  • Wang, Daoming;Zi, Bin;Qian, Sen;Qian, Jun;Zeng, Yishan
    • Journal of Magnetics
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    • v.21 no.4
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    • pp.622-628
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    • 2016
  • Magnetization property is a critical factor for magnetorheological fluids (MRFs) to achieve the liquid-solid transition. The main focus of this study is on exploring the influence factors on magnetization properties of MRFs. In this paper, a theoretical analysis is performed to discuss the magnetization characteristics of MRFs firstly. Then, a method for the preparation of carbonyl iron-based MRFs is illustrated and five MRFs samples with various material parameters are prepared. It is succeeded by a series of experiments on testing the hysteresis loop and the magnetization curve of each sample and the influence factors are compared and analyzed. Experimental results indicate that there is basically no hysteresis phenomenon on MRFs which exhibits superparamagnetic behavior at room temperature. A surfactant coating on magnetic particles can slightly improve the MRFs magnetization. Additionally, the magnetic susceptibility and the saturation magnetization both increase with the particle concentration, whereas the influence of particle diameter is relatively very small. Moreover, as the temperature increases, the magnetization decreases and the declining rate accelerates gradually.