• Title/Summary/Keyword: surface-modification technology

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Effect of surface modification of carbon felts on capacitive deionization for desalination

  • Lee, Jong-Ho;Ahn, Hong-Joo;Cho, Donghwan;Youn, Jeong-Il;Kim, Young-Jig;Oh, Han-Jun
    • Carbon letters
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    • v.16 no.2
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    • pp.93-100
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    • 2015
  • Surface modified carbon felts were utilized as an electrode for the removal of inorganic ions from seawater. The surfaces of the carbon felts were chemically modified by alkaline and acidic solutions, respectively. The potassium hydroxide (KOH) modified carbon felt exhibited high Brunauer-Emmett-Teller (BET) surface areas and large pore volume, and oxygen-containing functional groups were increased during KOH chemical modification. However, the BET surface area significantly decreased by nitric acid ($HNO_3$) chemical modification due to severe chemical dissolution of the pore structure. The capability of electrosorption by an electrical double-layer and the efficiency of capacitive deionization (CDI) thus showed the greatest enhancement by chemical KOH modification due to the appropriate increase of carboxyl and hydroxyl functional groups and the enlargement of the specific surface area.

Nickel Doping on Cobalt Oxide Thin Film Using by Sputtering Process-a Route for Surface Modification for p-type Metal Oxide Gas Sensors

  • Kang, Jun-gu;Park, Joon-Shik;An, Byeong-Seon;Yang, Cheol-Woong;Lee, Hoo-Jeong
    • Journal of the Korean Physical Society
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    • v.73 no.12
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    • pp.1867-1872
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    • 2018
  • This study proposes a route for surface modification for p-type cobalt oxide-based gas sensors. We deposit a thin layer of Ni on the Co oxide film by sputtering process and annealed at $350^{\circ}C$ for 15 min in air, which changes a typical sputtered film surface into one interlaced with a high density of hemispherical nanoparticles. Our in-depth materials characterization using transmission electron microscopy discloses that the microstructure evolution is the result of an extensive inter-diffusion of Co and Ni, and that the nanoparticles are nickel oxide dissolving some Co. Sensor performance measurement unfolds that the surface modification results in a significant sensitivity enhancement, nearly 200% increase for toluene (at $250^{\circ}C$) and CO (at $200^{\circ}C$) gases in comparison with the undoped samples.

MICROSTRUCTURE AND MECHANICAL STRENGTH OF SURFACE ODS TREATED ZIRCALOY-4 SHEET USING LASER BEAM SCANNING

  • Kim, Hyun-Gil;Kim, Il-Hyun;Jung, Yang-Il;Park, Dong-Jun;Park, Jeong-Yong;Koo, Yang-Hyun
    • Nuclear Engineering and Technology
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    • v.46 no.4
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    • pp.521-528
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    • 2014
  • The surface modification of engineering materials by laser beam scanning (LBS) allows the improvement of properties in terms of reduced wear, increased corrosion resistance, and better strength. In this study, the laser beam scan method was applied to produce an oxide dispersion strengthened (ODS) structure on a zirconium metal surface. A recrystallized Zircaloy-4 alloy sheet with a thickness of 2 mm, and $Y_2O_3$ particles of $10{\mu}m$ were selected for ODS treatment using LBS. Through the LBS method, the $Y_2O_3$ particles were dispersed in the Zircaloy-4 sheet surface at a thickness of 0.4 mm, which was about 20% when compared to the initial sheet thickness. The mean size of the dispersive particles was 20 nm, and the yield strength of the ODS treated plate at $500^{\circ}C$ was increased more than 65 % when compared to the initial state. This strength increase was caused by dispersive $Y_2O_3$ particles in the matrix and the martensite transformation of Zircaloy-4 matrix by the LBS.

Surface Modification Effect and Mechanical Property of para-aramid Fiber by Low-temperature Plasma Treatment (저온 플라즈마 처리를 이용한 파라 아라미드 섬유의 표면 개질 효과 및 역학적 특성(2))

  • Park, Sung-Min;Son, Hyun-Sik;Sim, Ji-Hyun;Kim, Joo-Young;Kim, Taekyeong;Bae, Jin-Seok
    • Textile Coloration and Finishing
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    • v.27 no.1
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    • pp.18-26
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    • 2015
  • para-aramid fibers were treated by atmosphere air plasma to improve the interfacial adhesion. The wettability of plasma-treated aramid fiber was observed by means of dynamic contact angle surface free energy measurement. Surface roughness were investigated with the help of scanning electron microscopy and atomic force microscopy. The tensile test of aramid fiber roving was carried out to determine the effect of plasma surface treatments on the mechanical properties of the fibers. A pull-out force test was carried out to observe the interfacial adhesion effect with matrix material. It was found that surface modification and a chemical component ratio of the aramid fibers improved wettability and adhesion characterization. After oxygen plasma, it was indicated that modified the surface roughness of aramid fiber increased mechanical interlocking between the fiber surface and vinylester resin. Consequently the oxygen plasma treatment is able to improve fiber-matrix adhesion through excited functional group and etching effect on fiber surface.

Manufacturing of Organic Light Emitting Display by Polymer Inkjet Printing

  • Kim, Myong-Ki;Shin, Kwon-Yong;Lee, Sang-Ho;Hwang, Jun-Young;Kang, Heui-Seok;Kang, Kyung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1476-1478
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    • 2009
  • The characteristics of polymer inkjet printing were investigated systematically in this paper. PEDOT/PSS as a hole injection layer and MEH-PPV as a light emitting layer were used for inkjet printing experiment. Inkjet head controlling technology and surface modification technology were also applied for polymer inkjet printing. With the developed polymer inkjet printing technology, OLED(Organic Light Emitting Display) was successfully fabricated and demonstrated.

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Comparative Analysis of Two Selective Bleaching Methods on Alpaca Fibers

  • Liu, Xin;Hurren, Christopher J.;Wang, Xungai
    • Fibers and Polymers
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    • v.4 no.3
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    • pp.124-128
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    • 2003
  • Dark brown Alpaca fiber was reduced in shade via selective bleaching with peroxide. Two selective oxidative bleaching methods were tested on alpaca top to assess their effectiveness for color removal and fiber quality properties. Color change, bundle strength, weight loss, fiber diameter, surface modification, dye-ability and dye wash fastness were assessed for both methods and compared with the original brown top. Bleach method 1 (BL-I) showed little surface modification, 5.8% weight loss and 2.4% strength loss. D1925 yellowness index was reduced to 74.3 from 83.1 and provided a good base for the dyeing of medium to deep shades. Bleach method 2 (BL-II) displayed considerable surface modification, 7.8% weight loss and 18% strength loss. BL-II also resulted in a mean diameter reduction of 1.9 micron during bleaching. Yellowness was reduced to 64.5 from 83.1 and provided a very good base for the dyeing of medium to deep shades. BL-I showed better exhaustion of the premetallised dye Lanaset Violet B than BL-II. Wash fastness for BL-II was 1 grey scale unit poorer than BL-I. BL-II showed far better color clarity at pale depths however the wash fastness of the finished product was not good enough to maintain the depth or clarity of the color. BL-I showed poorer clarity of color but exhibited better wash fastness results.

The Formation of Hybridized Porous Structure of Al Alloy by Alkali Surface Modification (알칼리 표면개질을 통한 다공성 알루미늄 합금의 하이브리드 기공구조 형성)

  • Seo, Young-Ik;Kim, Young-Moon;Lee, Young-Jung;Kim, Dae-Gun;Lee, Kyu-Hwan;Kim, Young-Do
    • Journal of Powder Materials
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    • v.16 no.1
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    • pp.22-27
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    • 2009
  • To improve the filtration efficiency of porous materials used in filters, an extensive specific surface area is required to serve as a site for adsorption of impurities. In this paper, a method for creating a hybridized porous alloy using a powder metallurgical technique to build macropores in an Al-4 wt.% Cu alloy and subsequent surface modification for a microporous surface with a considerably increased specific surface area is suggested. The macropore structure was controlled by granulation, compacting pressure, and sintering; the micropore structure was obtained by a surface modification using a dilute NaOH solution. The specific surface area of surface-modified specimen increased about 10 times compare to as-sintered specimen that comprised of the macropore structure. Also, the surface-modified specimens showed a remarkable increase in micropores larger than 10 nm. Such a hybridized porous structure has potential for application in water and air purification filters, as well as membrane pre-treatment and catalysis.

Surface Modification Technology and Research Trends of Separators for Lithium-Ion Batteries (리튬이온 전지용 분리막의 표면 개질 기술 및 연구 동향)

  • Ha, Seongmin;Kim, Daesup;Kwak, Cheol Hwan;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.343-351
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    • 2022
  • Lithium-ion batteries (LIBs) are considered promising energy storage devices with good performance such as high energy density, slow self-discharge rate, high rate charge capacity, and long battery life. However, the application of these LIBs in the high-energy density electric vehicle and large device industries poses a major safety problem. In order to solve this problem, developing a material having high thermal stability and intrinsic safety is the ultimate solution for improving the stability and electrochemical performance of LIBs. This review introduced a surface modification technology of a separator to overcome the stability problem of a commercial separator, and summarized and summarized the research trends using the modified separator for a lithium-ion battery. Based on this, the future prospects for the separator development by surface modification were discussed.

Preparation of PET Nanocomposites: Dispersion of Nanoparticles and Thermal Properties

  • Her, Ki-Young;Kim, Dae-Heum;Lim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.4
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    • pp.71-73
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    • 2008
  • The development of polymer/inorganic nanocomposites has attracted a great deal of interest due to the improved hybrid properties derived from the two different components. Various nanoscale fillers have been used to enhance polymer mechanical and thermal properties, such as toughness, stiffness, and heat resistance. The effects of the filler on the final properties of the nanocomposites are highly dependent on the filler shape, particle size, aggregate size, surface characteristics, polymer/inorganic interactions, and degree of dispersion. In this paper, we describe the influence of different $CaCO_3$ dispersion methods on the thermal properties of polyethylene terephthalate (PET)/$CaCO_3$ composites: i.e., the adsorption of $CaCO_3$ on the modified PET surface, and the hydrophobic modification of the hydrophilic $CaCO_3$ surface. We prepared PET/$CaCO_3$ nanocomposites using a twin-screw extruder, and investigated their thermal properties and morphology.