• Title/Summary/Keyword: surface-modification

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Hydrophilic surface formation of polumer treated by ion assisted reaction and its applications (이온빔보조 반응법을 이용한 고분자 표면의 친수성처리와 그 응용)

  • Cho, J.;Choi, S. C.;Yun, K.H.;Koh, S. K.
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.262-268
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    • 1999
  • Polycarbonate (PC) and Polymethylmethacrylate (PMMA) surface was modified by ion assisted reaction (IAR) technique to obtain the hydrophilic functional groups and improve the wettability. In conditions of ion assisted reaction, ion beam energy was changed from 500 to 1500eV, and ion dose and oxygen gas blown rate were fixed $1\times10^{16}$ ions/$\textrm{cm}^2$ and 4ml/min, respectively. Wetting angle of water on PC and PMMA surface modified by $Ar^+$ ion without blowing oxygen at 4ml/mon showed $5^{\circ}$ and $10^{\circ}$. Changes of wetting angle with oxygen gas and $Ar^+$ ion irradiation were explained by considering formation of hydrophilic group due to a reaction between irradiated polymer chain by energetic ion irradiation and blown oxygen gas. X-ray photoelectron spectroscopy analysis shows that hydrophilic groups such as -C-O, -(C=O)- and -(C=O)-O- are formed on the surface of polymer by chemical interaction. The polymer surface modification using ion assisted reaction only changed the surface physical properties and sept the bulk properties. In comparison with other modification methods, the surface modification by IAR treatment was chemically stable and enhanced the adhesion between metal and polymer surface. The applications of various kinds of polymer surface modification methods, metal and polymer surface. The applications of various kinds of polymer surface modification could be appled to the new materials about hydrophilic surface properties by IAR treatment. The adhesion between metal film and polymer measured by Scotch tape test whether the hydrophilic surfaces could improve the adhesion strength or not.

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Effect of the Amplitude in Ultrasonic Nano-crystalline Surface Modification on the Corrosion Properties of Alloy 600

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.18 no.5
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    • pp.196-205
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    • 2019
  • Surface modification techniques are known to improve SCC by adding large compressive residual stresses to metal surfaces. This surface modification technology is attracting attention because it is an economical and practical technology compared to the maintenance method of existing nuclear power plants. Surface modification techniques include laser, water jet and ultrasonic peening, pinning and ultrasonic Nano-crystal surface modification (UNSM). The focus of this study was on the effect of ultrasonic amplitude in UNSM treatment on the corrosion properties of Alloy 600. A microstructure analysis was conducted using an optical microscope (OM), scanning electron microscope (SEM) and electron backscattering diffraction (EBSD). A cyclic polarization test and AC-impedance measurement were both used to analyze the corrosion properties. UNSM treatment influences the corrosion resistance of Alloy 600 depending on its amplitude. Below the critical amplitude value, the pitting corrosion properties are improved by grain refinement and compressive residual stress, but above the critical amplitude value, crevices are formed by the formation of overlapped waves. These crevices act as corrosion initiators, reducing pitting corrosion resistance.

Recent Advances in Carbon-Nanotube-Based Epoxy Composites

  • Jin, Fan-Long;Park, Soo-Jin
    • Carbon letters
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    • v.14 no.1
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    • pp.1-13
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    • 2013
  • Carbon nanotubes (CNTs) are increasingly attracting scientific and industrial interest because of their outstanding characteristics, such as a high Young's modulus and tensile strength, low density, and excellent electrical and thermal properties. The incorporation of CNTs into polymer matrices greatly improves the electrical, thermal, and mechanical properties of the materials. Surface modification of CNTs can improve their processibility and dispersion within the composites. This paper aims to review the surface modification of CNTs, processing technologies, and mechanical and electrical properties of CNT-based epoxy composites.

Surface modification by tribochemical treatment in-situ

  • Du, Da-Chang;Kim, Seock-Sam;Suh, Chang-Min
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.178-190
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    • 2001
  • Tribological conditions and additive chemistry between frictional Interfaces were discussed in the present paper. The principles of the tribochemical surface modification were drawn on the basis of data of literatures and experiments. Results of gear tests proved experimentally that the principles would have potential applications in industry.

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Bio-Inspired Surface Modification of 3-Dimensional Polycaprolactone Scaffold for Enhanced Cellular Behaviors

  • Jo, Seon-Ae;Gang, Seong-Min;Park, Su-A;Lee, Hae-Shin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.202-202
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    • 2011
  • The research of 3-dimensional (3-D) scaffold for tissue engineering has been widely investigated as the importance of the 3-D scaffold increased. 3-D scaffold is needed to support for cells to proliferate and maintain their biological functions. Furthermore, its architecture defines the shape of the new bone and cartilage growth. Polycaprolactone (PCL) has been one of the most promising materials for fabricating 3-D scaffold owing to its excellent mechanical property and biocompatibility. However, there are practical problems for using it, in vitro and in vivo; extracellular matrix components and nutrients cannot penetrate into the inner space of scaffold, due to its hydrophobic property, and thus cell seeding and attachment onto the inner surface remain as a challenge. Thus, the surface modification strategy of 3-D PCL scaffold is prerequisite for successful tissue engineering. Herein, we utilized a mussel-inspired approach for surface modification of 3-D PCL scaffold. Modification of 3-D PCL scaffolds was carried out by simple immersion of scaffolds into the dopamine solution and stimulated body fluid, and as a result, hydroxyapatite-immobilized 3-D PCL scaffolds were obtained. After surface modification, the wettability of 3-D PCL scaffold was considerably changed, and infiltration of the pre-osteoblastic cells into the 3-D scaffold followed by the attachment onto the surface was successfully achieved.

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A Study on the Tribological Characteristics of Surface Modification (The 1st) (표면개질의 트라이볼로지 특성에 관한 연구(제1보))

  • Oh, Seong-Mo;Chae, Wang-Seok;Lee, Bong-Goo;Kim, Dong-Hyun;,
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.5 s.98
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    • pp.145-150
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    • 1999
  • We have studied on the tribological characteristics of surface modification by Arc Ion Implantation(AIP) coating method. Coating materials were deposited by the Titanium carbide(TiC) and Titanium nitride(TiN). An experimental process was established to determine the tribological characteristics of friction and wear behaviour with the variation of applied load, temperature and the time by the Falex friction and wear test machine. The results, It can be improved that when the surface modification of hard coatings(TiC, TiN) was deposited steel, the tribological characteristics become better. It is argued that improved because of excellence of the anti-wear, the extreme pressure properties and the heat stability.

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Effect of Surface Modification of Waste Glass for Fine Aggregate on the Mechanical Properties and Alkali Silica Reaction of Mortar (잔골재용 폐유리의 표면개질이 모르타르의 역학적 특성 및 알칼리 실리카 반응에 미치는 영향)

  • Son, Min-Jae;Kim, Gyu-Yong;Lee, Sang-Kyu;Sasui, Sasui;Eu, Ha-Min;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.23-24
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    • 2020
  • In this study, effect of surface modification of waste glass for fine aggregates on the mechanical properties and alkali silica reaction of mortar was analyzed. As a result, it was confirmed that the incorporation of waste glass fine aggregate decreases the mechanical properties of the mortar and increase the alkali silica reaction expansion. On the other hand, the surface modification of the waste glass fine aggregate is effective in improving this problem. However, unlike green and brown waste glass, it is judged that an additional experiment to determine the cause is necessary for white waste glass where alkali silica reactive expansion occurs extremely.

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Surface Modification of Screen-Mesh Wicks to Improve Capillary Performance for Heat Pipes (히트파이프 모세관 성능 개선을 위한 스크린-메쉬 윅의 표면 개질)

  • Jeong, Jiyun;Lim, Hyewon;Kim, Hyewon;Lee, Sangmin;Kim, Hyungmo
    • Tribology and Lubricants
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    • v.38 no.5
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    • pp.185-190
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    • 2022
  • Among the operating limits of a heat pipe, the capillary limit is significantly affected by the characteristics of the wick, which is determined by the capillary performance. The major parameters for determining capillary performance are the maximum capillary pressure and the spreading characteristics that can be expected through the wick. A well-designed wick structure improves capillary performance and helps improve the stability of the heat pipe by enhancing the capillary limit. The capillary performance can be improved by forming a porous microstructure on the surface of the wick structure through surface modification techniques. In this study, a microstructure is formed on the surface of the wick by using a surface modification method (i.e., an electrochemical etching process). In the experiment, specimens are prepared using stainless-steel screen mesh wicks with various fabrication conditions. In addition, the spreading and capillary rise performances are observed with low-surface-tension fluid to quantify the capillary performance. In the experiments, the capillary performance, such as spreading characteristics, maximum capillary pressure, and capillary rise rate, improves in the specimens with microstructures formed through surface modification compared with the specimens without microstructures on the surface. The improved capillary performance can have a positive effect on the capillary limit of the heat pipe. It is believed that the surface microstructures can enhance the operational stability of heat pipes.

Preparation and Characterization of ACF Using Lyocell Adopting Surface Modification Process (리오셀 표면개질공정을 도입한 ACF 제조 및 특성)

  • Jo, Young Hyuk;Jin, Young Min;Lee, Soon Hong
    • Journal of the Korean Society of Safety
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    • v.31 no.1
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    • pp.66-73
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    • 2016
  • Lyocell fibers were used as a precursor in order to improve yield and strength of cellulose-based precursor while manufacturing activated carbon fiber(ACF). Lyocell fibers as a precursor for the preparation of ACF were surface-modified by reaction with 3-aminopropyltriethoxysilane(APTES) and pre-treated with KOH and H3PO4. Using aforementioned precursor, ACFs were prepared by a series of stabilization, carbonization and activation process at high temperatures. On each process, FT-IR, TGA, UTM and SEM were used to observe fibers' physical properties including structure and porous surfaces. FT-IR results proved that surface modification was achieved during stabilization, carbonization and activation process. TGA results during carbonization process found that surface modified fibers with APTES 0.02 mol(A2) showed higher thermostability, and extended pre-treatment increased yield. Especially, yield was found to have an increase of 10~20 wt% with surface modification during activation process. UTM results showed that tensile strength has the same order of concentration of APTES after surface modification, however, was found to show lower tensile strength than lyocell fibers after stabilization process. SEM results revealed that more homogeneous porosity control could be proceed after modifying the surface for the effective removal of hazardous substances.