• Title/Summary/Keyword: surface wetting

Search Result 371, Processing Time 0.024 seconds

Effect of Al and Mg Contents on Wettability and Reactivity of Molten Zn-Al-Mg Alloys on Steel Sheets Covered with MnO and SiO2 Layers

  • Huh, Joo-Youl;Hwang, Min-Je;Shim, Seung-Woo;Kim, Tae-Chul;Kim, Jong-Sang
    • Metals and materials international
    • /
    • v.24 no.6
    • /
    • pp.1241-1248
    • /
    • 2018
  • The reactive wetting behaviors of molten Zn-Al-Mg alloys on MnO- and amorphous (a-) $SiO_2$-covered steel sheets were investigated by the sessile drop method, as a function of the Al and Mg contents in the alloys. The sessile drop tests were carried out at $460^{\circ}C$ and the variation in the contact angles (${\theta}_c$) of alloys containing 0.2-2.5 wt% Al and 0-3.0 wt% Mg was monitored for 20 s. For all the alloys, the MnO-covered steel substrate exhibited reactive wetting whereas the $a-SiO_2$-covered steel exhibited nonreactive, nonwetting (${\theta}_c>90^{\circ}$) behavior. The MnO layer was rapidly removed by Al and Mg contained in the alloys. The wetting of the MnO-covered steel sheet significantly improved upon increasing the Mg content but decreased upon increasing the Al content, indicating that the surface tension of the alloy droplet is the main factor controlling its wettability. Although the reactions of Al and Mg in molten alloys with the $a-SiO_2$ layer were found to be sluggish, the wettability of Zn-Al-Mg alloys on the $a-SiO_2$ layer improved upon increasing the Al and Mg contents. These results suggest that the wetting of advanced high-strength steel sheets, the surface oxide layer of which consists of a mixture of MnO and $SiO_2$, with Zn-Al-Mg alloys could be most effectively improved by increasing the Mg content of the alloys.

Effects of Surface Roughness and Interface Wettability in a Nanochannel (나노 채널에서의 표면 거칠기와 경계 습윤의 효과)

  • Choo, Yun-Sik;Seo, In-Soo;Lee, Sang-Hwan
    • The KSFM Journal of Fluid Machinery
    • /
    • v.13 no.2
    • /
    • pp.5-11
    • /
    • 2010
  • The nanofluidics is characterized by a large surface-to-volume ratio, so that the surface properties strongly affect the flow resistance. We present here the results showing that the effect of wetting properties and the surface roughness may considerably reduce the friction of fluid past the boundaries. For a simple fluid flowing over hydrophilic and hydrophobic surfaces, the influences of surface roughness are investigated by the nonequilibrium molecular dynamics (NEMD) simulations. The fluid slip at near a solid surface highly depends on the wall-fluid interaction. For hydrophobic surfaces, apparent fluid slips are observed on smooth and rough surfaces. The solid wall is modeled as a rough atomic sinusoidal wall. The effects on the boundary condition of the roughness characteristics are given by the period and amplitude of the sinusoidal wall. It was found that the slip velocity for wetting conditions at interface decreases with increasing effects of surface roughness. The results show the surface rougheness and wettability determines the slip or no-slip boundary conditions. The surface roughness geometry shows significant effects on the boundary conditions at the interface.

Influence of Rainfall-induced Wetting on Unsaturated Weathered Slopes (강우시 국내 불포화 풍화토 사면에서의 습윤영향 분석)

  • Jeong Sang-Seom;Kim Jae-Hong;Park Seong-Wan
    • Journal of the Korean Geotechnical Society
    • /
    • v.20 no.7
    • /
    • pp.159-169
    • /
    • 2004
  • Surface failures of slopes in weathered soil are caused by infiltration due to prolonged rainfall. These failures are mainly triggered by the deepening of the wetting band accompanied by a decrease in suction induced by the infiltrating water. This paper reports trends of rainfall-induced wetting band depth in two types of weathered soils that are commonly found in Korea. Both theoretical and numerical analyses are presented based on the soil-water characteristic curve (SWCC) obtained using filter paper as well as tensiometer tests. It is found that the magnitude of wetting front suction plays a key role in the stability of slopes in weathered soils. Theoretical analysis based on modified Green and Ampt model tends to underestimate the wetting band depth for typical Korean weathered soils. It was also deduced that for Korean weathered soils, the factor of safety drops rapidly once the wetting band depth of 1.2 m is reached.

Stability Analysis on Unsaturated Gneiss Weathered Soil Slopes Considering Wetting Path Soil-Water Characteristic Curve (습윤경로 함수특성곡선을 고려한 불포화 편마풍화토 사면의 안정해석)

  • Park, Seong-Wan;Shin, Gil Ho
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.29 no.5C
    • /
    • pp.191-198
    • /
    • 2009
  • It has been reported in Korea that surface slope failures in weathered soil are mainly caused by downward infiltration due to rainfall. These failures are triggered by the deepening of the wetting band in soils accompanied by a decrease in matric suction induced by the water infiltration. So, a need exists that these trends of wetting path in gneiss weathered soils, which is commonly found in Korea, are assessed by phenomenological approach. In this paper, numerical analyses of unsaturated soil slope under rainfall conditions are presented based on the wetting path soil-water characteristic curve in the laboratory. As the field SWCC matches well with the wetting path of the laboratory SWCC from the literatures, it seems reasonable to adopt the laboratory wetting SWCC as an upper boundary condition in the assessment of unsaturated slope instability.

Effects of Fiber Surface Modification on the Flow Characteristics and Wettability in the Resin Transfer Molding Process (섬유의 표면개질이 수지이동 성형공정에서의 유동특성 및 젖음성에 미치는 영향)

  • 김세현;이건웅;이종훈;김성우;이기준
    • The Korean Journal of Rheology
    • /
    • v.11 no.1
    • /
    • pp.34-43
    • /
    • 1999
  • Flow-induced voids during resin impregnation and poor fiber wetting have known to be highly detrimental to the performance of composite parts manufactured by resin transfer molding(RTM) process. In this study, in order to overcome these serious problems encountered in RTM, the effects of surface modification by using silane coupling agent as a surface modifier on the flow characteristics, the wetting between resin and fiber, and void content were investigated. For the experiments of microscopic flow visualization and curing in a beam mold, glass fiber mats having plain weaving structure and epoxy resin were used. Modifying the fiber surface was found to result in a significant decrease of dynamic contact angle between resin and fiber and increase of wicking rate. Therefore, it was confirmed that the surface modification employed in this study could improve the wettability of reinforcing fibers as well as micro flow behavior. In addition, It was revealed that high temperature and low penetration rate of the resin are more favorable processing conditions to reduce the dynamic contact angle. However, surface modified fiber mat was found to have lower permeability than the unmodified one, which may be explained in terms of the decrease of contact time between resin and fiber owing to improvement of wetting. It was also exhibited that surface modification had a significant influence on void formation in RTM process, resulting in a decrease of overall void content due to the improvement of wetting in cured composite parts.

  • PDF

A Study on the Thermal Oxidation and Wettability of Lead-free Solders of Sn-Ag-Cu and Sn-Ag-Cu-In

  • Lee, Hyunbok;Cho, Sang Wan
    • Applied Science and Convergence Technology
    • /
    • v.23 no.6
    • /
    • pp.345-350
    • /
    • 2014
  • The surface oxidation mechanism of lead-free solder alloys has been investigated with multiple reflow using X-ray photoelectron spectroscopy. It was found that the solder surface of Sn-Ag-Cu-In solder alloy is surrounded by a thin $InO_x$ layer after reflow process; this coating protects the metallic surface from thermal oxidation. Based on this result, we have performed a wetting balance test at various temperatures. The Sn-Ag-Cu-In solder alloy shows characteristics of both thermal oxidation and wetting balance better than those of Sn-Ag-Cu solder alloy. Therefore, Sn-Ag-Cu-In solder alloy is a good candidate to solve the two problems of easy oxidation and low wettability, which are the most critical problems of Pb-free solders.

Fabrication of Ultra-smooth 10 nm Silver Films without Wetting Layer

  • Devaraj, Vasanthan;Lee, Jongmin;Baek, Jongseo;Lee, Donghan
    • Applied Science and Convergence Technology
    • /
    • v.25 no.2
    • /
    • pp.32-35
    • /
    • 2016
  • Using conventional deposition techniques, we demonstrate a method to fabricate ultra-smooth 10 nm silver films without using a wetting layer or co-depositing another material. The argon working pressure plays a crucial role in achieving an excellent surface flatness for silver films deposited by DC magnetron sputtering on an InP substrate. The formation of ultra-smooth silver thin films is very sensitive to the argon pressure. At the optimum deposition condition, a uniform silver film with an rms surface roughness of 0.81 nm has been achieved.

Wetting Properties of Biopolyester Films Prepared by Thermo-Compression Method

  • Rhim, Jong-Whan;Hong, Seok-In
    • Food Science and Biotechnology
    • /
    • v.16 no.2
    • /
    • pp.234-237
    • /
    • 2007
  • Water resistance of three biopolyester films, such as poly-L-lactate (PLA), poly-hydroxybutyrate-co-valerate (PHBV), and Ecoflex, and low density polyethylene (LDPE) film was investigated by measuring contact angle of various probe liquids on the films. The properties measured were initial contact angle of water, dynamic change of the water contact angle with time, and the critical surface energy of the films. Water contact angle of the biopolyester films ($57.62-68.76^{\circ}$) was lower than that of LDPE film ($85.19^{\circ}$) indicating biopolyester films are less hydrophobic. The result of dynamic change of water contact angle also showed that the biopolyester films are less water resistant than LDPE film, but much more water resistant than cellulose-based packaging materials. Apparent critical surface energy for the biopolyester films (35.15-38.55 mN/m) was higher than that of LDPE film (28.59 mN/m) indicating LDPE film is more hydrophobic.

Development of Highly Efficient Oil-Water Separation Materials Utilizing the Self-Bonding and Microstructuring Characteristics of Aluminum Nitride Nanopowders (질화알루미늄 나노분말의 자가 접착과 미세구조화 특성을 활용한 고효율 유수분리 소재 개발)

  • Heon-Ju Choi;Handong Cho
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.27 no.3
    • /
    • pp.601-607
    • /
    • 2024
  • The discharge of oily wastewater into water bodies and soil poses a serious hazard to the environment and public health. Various conventional techniques have been employed to treat oil-water mixtures and emulsions; Unfortunately, these approaches are frequently expensive, time-consuming, and unsatisfactory outcomes. Porous materials and adsorbents are commonly used for purification, but their use is limited by low separation efficiencies and the risk of secondary contamination. Recent advancements in nanotechnology have driven the development of innovative materials and technologies for oil-contaminated wastewater treatment. Nanomaterials can offer enhanced oil-water separation properties due to their high surface area and tunable surface chemistry. The fabrication of nanofiber membranes with precise pore sizes and surface properties can further improve separation efficiency. Notably, novel technologies have emerged utilizing nanomaterials with special surface wetting properties, such as superhydrophobicity, to selectively separate oil from oil-water mixtures or emulsions. These special wetting surfaces are promising for high-efficiency oil separation in emulsions and allow the use of materials with relatively large pores, enhancing throughput and separation efficiency. In this study, we introduce a facile and scalable method for fabrication of superhydrophobic-superoleophilic felt fabrics for oil/water mixture and emulsion separation. AlN nanopowders are hydrolyzed to create the desired microstructures, which firmly adhere to the fabric surface without the need for a binder resin, enabling specialized wetting properties. This approach is applicable regardless of the material's size and shape, enabling efficient separation of oil and water from oil-water mixtures and emulsions. The oil-water separation materials proposed in this study exhibit low cost, high scalability, and efficiency, demonstrating their potential for broad industrial applications.