• Journal of Korean Society of Environmental Engineers
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• v.29 no.9
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• pp.1027-1034
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• 2007

This research was focused on the selective separation of $CO_2$ or $CH_4$ from mixture of these gases, by controlling the size of pore or pore gate. Pitch based activated carbon fibers(ACF) were used as adsorbents. The size of pore gate was controlled by the molecule having similar size to that of pore opening. After the adsorption of adsorbate on pore surface, planar molecules such as benzene and naphthalene covered the pore gate. The slow release of adsorbate from the pores covered by planar molecules makes apertures between planar molecules covering pore gate and this structure can be fixed by rapid pyrolysis. The control of pore gate using benzene as covering molecules could not accomplished due to the simultaneous volatilization of benzene and adsorbate$(CO_2)$ caused by similar temperatures of benzene volatilization and adsorbate desorption. Therefore we replaced benzene with naphthalene looking for the stability at a $CO_2$ desorption temperature. The naphthalene molecule was adsorbed on the ACF up to 15% of ACF weight and showed no desorption until $100^{\circ}C$, indicating that the molecule could be used as a good cover molecule. Naphthalene could cover almost all the pore gate, reducing BET surface area from 753 $m^2/g$ to 0.7 $m^2/g$. A mixed gas$(CO_2:CH_4=50:50)$ was adsorbed on the naphthalene treated OG-7A ACF. The amount of $CO_2$ adsorption increased with total pressure, whileas thai of $CH_4$ was not so much influenced on the pressure, indicating that $CO_2$ made more compounds on the ACF surface along with total pressure increase. The most $CO_2$ and the least $CH_4$ were adsorbed in the condition of 0.4 atm, resulting in the highly pure $CH_4$ left in ACF.

• The Journal of Korean Academy of Prosthodontics
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• v.46 no.5
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• pp.490-499
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• 2008

Statement of problem: Bioactive materials must have the ability to spontaneously form a bone like apatite layer on their surface and induce direct biochemical bonding to bone. A simple chemical treatment via alkali and heat has been revealed to induce bioactivity in titanium. Purpose: The purpose of this study was to evaluate the surface characteristics and stability of alkali and heat treated implants. Material and methods: Specimens were divided into three groups; group 1 was the control group with machined surface implants, groups 2 and 3 were treated with alkali solutions and heat treated in the atmosphere and vacuum conditions respectively. The surface characteristics were observed with FESEM, XPS, TF-XRD and AFM. Stability was evaluated with the resonance frequency analysis, periotest and removal torque values. One-way ANOVA and Duncan test were used for statistical analysis. Results: 1. Groups treated with alkali and heat showed similar characteristics. Groups 2 and 3 showed high compositions of Na ions on the surface with sub-micron sized pores compared to group 1. Group 2 showed mixed compositions of anatase and rutile with superior contents of rutile. 2. Resonance frequency analysis : The ISQ of group 2 showed significantly higher values than that of groups 1 and 3 at 12 weeks. The ISQ of groups 1 and 2 showed significant increase after 4 weeks, and the ISQ of group 3 increased significantly after 2 and 4 weeks respectively (P < .05). 3. Periotest: The PTV of groups 1 and 2 showed significant decrease after 4 weeks, and the PTV of group 3 showed significant decrease after 2 and 4 weeks respectively (P < .05). 4. Removal torque analysis: The removal torque value of group 2 was significantly higher than those of groups 1 and 3 at 2, 4 and 8 weeks. The removal torque values of groups 1 and 3 showed increase at 4 and 12 weeks, but the removal torque value of group 2 showed increase after 4 weeks (P < .05). Conclusion: An oxide layer with appropriate crystal structure and amorphous sodium titanate layer can be obtained on titanium implants through alkali and heat treatment in the atmosphere, and even alkali and heat treatment in vacuum conditions, provided a bioactive surface containing sodium. These surface layers can be considered to be effective for enhancement of osseointegration and reduction of healing period for implant treatment.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.9
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• pp.735-742
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• 2009

The bone of spinal animals has a hydroxylapatite ($Ca_{10}(PO_4)_6(OH)_2$, HAp) structure which is well known as an excellent inorganic ion exchanger for various heavy metal ions in solutions. In this study, the reusability of cow-bone, pig-bone and fish-bone as a potential material for the removal of heavy metals in solutions was evaluated from the removal of Cu(II) ion in batch tests. The surface properties of three bones, calcined at different temperatures, were measured with SEM, XRD, FT-IR analyses. From the SEM analysis, a clear development of heterogeneity as well as pores having small diameter was observed as the calcination temperature increased. The results of X-ray diffraction analysis showed well developed crystallinity on the surface of calcined bones obtained at higher temperatures, suggesting a transform of amorphous type to crystalline type. Fourier transform infrared (FT-IR) analysis showed disappearance of water molecule on the surface of HAp and organic functional groups of the HAp with increasing the calcination temperatures. Cu(II) removal in the control test was below 15%. By the way, additional 40% increase of Cu(II) removal was observed in the presence of calcined bones. For three bones, Cu(II) removal was decreased as the calcined temperature increased. Cu(II) removal was increased as the solution pH increased due to a favorable condition for the cation exchange as well as precipitation.

• Journal of Navigation and Port Research
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• v.28 no.6
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• pp.565-572
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• 2004

Residual current plays more important role than the tidal current for long-term material transport in coastal areas. The main component of residual current is tide-induced residual current. Otherwise, wind driven current and buoyancy-driven current are important components which change the residual current. To clarify the characteristic of coastal current, application of a three -dimensional model is necessary. This study focuses on clarifying the stratified systems of coastal water affected by freshwater runoff from a river and analyzes the structure of current at Ulsan bay by applying a three-dimensional buoyancy-driven current model. According to the result of “Ulsan bay” study, it shows that the surface layer in semi-enclosed estuaries, which affected by freshwater runoff. has flows going out, and the bottom layer has flows coming in. Besides when the wind blows toward inside of the bay, the surface layer has flows coming in and the bottom layer has flows going out as compensation flows for the surface circulation. The results of simulation could be applicable to examine vertical upwelling, which might be caused by construction of artificial fishing reef to build aqua farm, submerged breakwater to control coastal sediment, and the formulation of oceanic ridge, or a basic study on application to the usage of deep water.

• Journal of the korean academy of Pediatric Dentistry
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• v.40 no.3
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• pp.168-176
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• 2013

The aim of this study was to evaluate the acid neutralizing capacity and to observe surface changes of giomer in comparison with composite resin, when it comes in contact with an acidic solution. A packable giomer(Beautifil II) and a flowable giomer(Beautifil Flow F02) were used as experimental groups, while a packable composite resin($Filtek^{TM}$ Z-250) was used as control group. pH values were measured after mixing the specimens of the disc and powder types with a pH 2.0 hydrochloric acid solution, respectively. Also, in the case of powder type giomers used in the earlier experiment, their pH values were measured again after mixing them with a fresh acid solution. Moreover, surface structure changes of disc type specimens were observed by using a scanning electron microscopy(SEM). In the disc type test, the pH values of packable giomer were significantly increased after 24 hours(p < 0.05). In contrast, in the powder type test, the pH values of packable and flowable giomers were dramatically increased within 30 minutes. The pH value of packable giomer, in particular, was higer than that of flowable giomer(p < 0.05). In the repeated neutralizing test, the degree of pH variation was lower than that of the previous neutralizing test(p < 0.05). Erosive changes on the surface of packable giomer were observed to be more than those on composite resin and flowable giomer as well. In conclusion, giomer has a acid neutralizing capacity, when it comes in contact with an acidic solution. Especially, packable giomer with high filler content has a greater acid neutralizing capacity than flowable giomer.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 1999.04a
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• pp.5-5
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• 1999

The Principal deficiency of the existing notion about the sintering-mixtures consists in the fact that almost no attention is focused on the Phenomenon of alloy formation during sintering, its connection with dimensional changes of powder bodies, and no correct ideas on the driving force for the sintering process in the stage of establishing chemical equilibrium in a system are available as well. Another disadvantage of the classical sintering theory is an erroneous conception on the dissolution mechanism of solid in liquid. The two-particle model widely used in the literature to describe the sintering phenomenon in solid state disregards the nature of the neighbouring surrounding particles, the presence of pores between them, and the rise of so called arch effect. In this presentation, new basic scientific principles of the driving forces for the sintering process of a two-component powder body, of a diffusion mechanism of the interaction between solid and liquid phases, of stresses and deformation arising in the diffusion zone have been developed. The major driving force for sintering the mixture from components capable of forming solid solutions and intermetallic compounds is attributed to the alloy formation rather than the reduction of the free surface area until the chemical equilibrium is achieved in a system. The lecture considers a multiparticle model of the mixed powder-body and the nature of its volume changes during solid-state and liquid-phase sintering. It explains the discovered S-and V-type concentration dependencies of the change in the compact volume during solid-state sintering. It is supposed in the literature that the dissolution of solid in liquid is realised due to the removal of atoms from the surface of the solid phase into the melt and then their diffusicn transfer from the solid-liquid interface into the bulk of liquid. It has been shown in our experimental studies that the mechanism of the interaction between two components, one of them being liquid, consist in diffusion of the solvent atoms from the liquid into the solid phase until the concentration of solid solutions or an intermetallic compound in the surface layer enables them to pass into the liquid by means of melting. The lecture discusses peculimities of liquid phase formation in systems with intermediate compounds and the role of the liquid phase in bringing about the exothermic effect. At the frist stage of liquid phase sintering the diffusion of atoms from the melt into the solid causes the powder body to grow. At the second stage the diminution of particles in size as a result of their dissolution in the liquid draws their centres closer to each other and makes the compact to shrink Analytical equations were derived to describe quantitatively the porosity and volume changes of compacts as a result of alloy formation during liquid phase sinteIing. Selection criteria for an additive, its concentration and the temperature regime of sintering to control the density the structure of sintered alloys are given.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.727-731
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• 2008

Mesoporous Pt-Au alloy films were successfully fabricated on ITO-coated glass by electrodeposition method using tri-blockcopolymer (P123) as a templating agent. The electrolyte consisted of 10 mM hydrogen hexachloroplatinate ($H_2PtCl_6$), 10 mM hydrogen tetrachloroaurate ($HAuCl_4$), and proper amount of P123. For comparison, control samples were electrodeposited without $HAuCl_4$ and P123. Film composition was determined by EDS(Energy Dispersive X-ray Spectroscopy), and the mesoporous structure was confirmed by TEM(Transmission Electron Microscopy). SEM(Scanning Electron Microscopy) was utilized to examine surface morphology, and it was observed that the addition of P123 affected the particle growth, resulting in the significant change of surface morphology. Methanol oxidation and CO oxidation were carried out to investigate electrocatalytic activities of synthesized samples. It was observed that the catalytic activity was strongly dependent on the film compositions. Compared with nonporous electrode prepared without P123 templating, mesoporous films prepared with P123 templating showed much higher catalytic activities and stability for both methanol oxidation and CO oxidation. These enhanced electrocatalytic activities were due to the high surface area and facilitated charge transfer of mesoporous films.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.6
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• pp.148-156
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• 2022

Although most domestic concrete structures are simultaneously exposed to freeze-thaw and chloride environments, concrete durability in the field is evaluated by each single action, and the evaluation of chloride-caused damage of concrete requires additional indoor experimental analysis of chloride contents by coring samples from structures in the field. However, in Korea, policies to strengthen facility maintenance, such as 「Special Act on the Safety Control and Maintenance of Establishments」 and 「Framework Act on Sustainable Infrastructure Management」, have been established and implemented since 2018 and facilities subject to safety inspection management by the government and local governments increases, the effective simplification technology for the inspection and diagnosis of concrete structure is needed. Therefore, this study attempted to evaluate the possibility of determining the acceleration chloride penetration of freeze-thaw damaged concrete by using the surface rebound value. For this purpose, concrete specimens already having freeze-thaw damage by exposure to the freeze-thaw acceleration environment were immersed in chloride water. After that, the acceleration relationship of chloride penetration according to freeze-thaw damage was analyzed using the amount of chloride contents in concrete.

• Journal of Veterinary Clinics
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• v.19 no.2
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• pp.228-235
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• 2002

Mastitis is the most costly disease results in lost milk production, decreased milk quality, milk discard, early culling of cows, drug costs and labor costs in dairy cow. Until now, a antibiotic administration at the end of lactation, dry cow therapy has been known the most effective and widely used mastitis control method. However, dry cow therapy do not control a new infection in the late dry and prepartum period because dry cow products have only persistent activity in the early dry period. Therefore, this study was conducted to evaluate clinical effect of sustained released biodegradable cephalexin microsphere using PLGA in bovine mastitis control during dry period. PLGA has been approved as controlled drug release system because of non-toxic, non-tissue reactive and bioerodible characteristics. This study revealed that cephalexin microsphere had a spherical shape with characteristic porous structure on the surface. Also, in vitro drug release studies are clearly observed that the release rate of cephalexin from PLGA microsphere decrease during the first 21 days after initial burst and then increase again between 3 and 4 weeks showing pulsatile releasing pattern. On the other hand, as tried in field the new infection rate, cure rate and mean SCC after parturition in cephalexin microsphere infused group were significantly differenced as compared to the control group. Accordingly, a sustained release of cephalexin from a biodegradable microsphere could make dry cow therapy more efficiently by preventing a new infection and decreasing the number of existing infection of mammary gland during dry period.

• Atmosphere
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• v.23 no.2
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• pp.187-204
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• 2013

This study analyzed the synoptic distribution and vertical structure about four cases of precipitation occurrences using NCEP/NCAR reanalysis data and upper level data of winter intensive observation to be performed by National Institute of Meteorological Research at Bukgangneung, Incheon, Boseong during 63days from 4 JAN to 6 MAR in 2012, and Observing System Experiment (OSE) using 3DVAR-WRF system was conducted to examine the precipitation predictability of upper level data at western and southern coastal regions. The synoptic characteristics of selected precipitation occurrences were investigated as causes for 1) rainfall events with effect of moisture convergence owing to low pressure passing through south sea on 19 JAN, 2) snowfall events due to moisture inflowing from yellow sea with propagation of Siberian high pressure after low pressure passage over middle northern region on 31 JAN, 3) rainfall event with effect of weak pressure trough in west low and east high pressure system on 25 FEB, 4) rainfall event due to moisture inflow according to low pressures over Bohai bay and south eastern sea on 5 MAR. However, it is identified that vertical structure of atmosphere had different characteristics with heavy rainfall system in summer. Firstly, depth of convection was narrow due to absence of moisture convergence and strong ascending air current in middle layer. Secondly, warm air advection by veering wind with height only existed in low layer. Thirdly, unstable layer was limited in the narrow depth due to low surface temperature although it formed, and also values of instability indices were not high. Fourthly, total water vapor amounts containing into atmosphere was small due to low temperature distribution so that precipitable water vapor could be little amounts. As result of OSE conducting with upper level data of Incheon and Boseong station, 12 hours accumulated precipitation distributions of control experiment and experiments with additional upper level data were similar with ones of observation data at 610 stations. Although Equitable Threat Scores (ETS) were different according to cases and thresholds, it was verified positive influence of upper level data for precipitation predictability as resulting with high improvement rates of 33.3% in experiment with upper level data of Incheon (INC_EXP), 85.7% in experiment with upper level data of Boseong (BOS_EXP), and 142.9% in experiment with upper level data of both Incheon and Boseong (INC_BOS_EXP) about accumulated precipitation more than 5 mm / 12 hours on 31 January 2012.