• Title/Summary/Keyword: surface structure control

검색결과 839건 처리시간 0.027초

수분에 의한 페로브스카이트 박막의 분해 및 δ-phase 결정 형성을 억제하기 위한 표면 처리 기술 (Surface Treatment to Inhibit Water-induced Decomposition and δ-phase Formation of Perovskite Thin Films)

  • 손경난;;정인영;안세진;장효식
    • Current Photovoltaic Research
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    • 제9권2호
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    • pp.23-30
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    • 2021
  • Perovskite solar cells (PSCs) are currently attracting attention as a promising source of photovoltaic power generation for their rapid increase in efficiency within a short research period. However, the 2-step deposition method, which has been considered as a proper film fabrication route in commercialization point of view of PSC, requires a complicated control of environment to achieve high efficiency because each step of the process are affected by humidity in different manner. It is clearly a large hurdle for this technic to be transferred to industrialization. In this study, we developed a simple surface treatment by which high quality perovskite films can be fabricated through 2-step deposition method in a relatively wide humidity range without complicated humidity control at each step.

표면 처리 방법에 따른 타이타늄의 미세 표면 거칠기, 표면 젖음성, fibronectin 흡착량에 미치는 영향 (EFFECTS OF VARIOUS SURFACE TREATMENTS FOR TITANIUM ON SURFACE MICRO ROUGHNESS, STATIC WETTABILITY, FIBRONECTIN ADSORPTION)

  • 신화섭;김영수;신상완
    • 대한치과보철학회지
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    • 제44권4호
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    • pp.443-454
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    • 2006
  • Purpose: This study aims to get the fundamental data which is necessary to the development direction of implant surface treatment hereafter, based on the understanding the surface structure and properties of titanium which is suitable for the absorption of initial tissue fluid by researching effects of additional surface treatments fir sandblasted with large git and acid-etched(SLA) titanium on surface micro-roughness, static wettability, fibronectin adsorption Materials and Method: In the Control groups, the commercial pure titanium disks which is 10mm in diameter and 2mm in thickness were treated with HCI after sandblasting with 50$\mu$m $Al_2O_3$. The experiment groups were made an experiment each by being treated with 1) 22.5% nitric acid according to SLA+ASTM F86 protocol, 2) SLA+30% peroxide, 3) SLA+NaOH, 4) SLA+ Oxalic acid, and 5) SLA+600$^{\circ}C$ heating. In each group, the value of Ra and RMS which are the gauges of surface roughness was measured, surface wettability was measured by analyzing with Sessile drop method, and fibronectin adsorption was measured with immunological assay. The significance of each group was verified by (SPSS, ver.10.0 SPSS Inc.) Kruskal-Wallis Test. (α=0.05) And the correlation significance between Surface micro-roughness and surface wettability. surface roughness and fibronectin adsorption, and surface wettability and fibronectin adsorption was tested by Spearman's correlation analysis. Result: All measure groups showed the significant differences in surface micro-roughness, surface wettability, and fibronectin adsorption. (p<0.05) There was no significance in correlation among the surface micro-roughness, surface wettability, and fibronectin adsorption. (p>0.05) Conclusion: Surface micro-roughness and surface wettability rarely affected the absorption of initial tissue fluid on the surface of titanium.

로봇 매니플레이터를 위한 정확한 사전 결정 출력 성능을 갖는 새로운 적분 가변구조 레귤레이션 제어기 (A New Integral Variable Structure Regulation Controller for Robot Manipulators with Accurately Predetermined Output Performance)

  • 이정훈
    • 전기전자학회논문지
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    • 제8권1호
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    • pp.96-107
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    • 2004
  • 본 연구에서는 고도의 비선형 로봇 매니플레이터를 위한 새로운 적분 가변 구조 제어기를 설계하였다. 특수 적분 슬라이딩 면과 외란 관찰기를 이용한 사전 성능을 갖는 개선된 레귤레이션 제어이다. 어떠한 리칭 구간도 없이 주어진 초기조건부터 원점까지 슬라이딩 궤적을 정확히 사전 결정하기 위하여 특수한 초기 조건을 갖는 적분 변수를 갖는 슬라이딩 면이 채택되었다. 그리고 외란 관찰기를 사용한 연속 입력은 큰 계산 부하 없이 사전 추적오차 범위내의 사전에 결정된 슬라이딩 궤적을 추적하게 한다. 사전에 결정된 슬라이딩 궤적을 사전에 결정된 추적 오차의 성능은 슬라이딩 면의 값과 슬라이f딩 출력의 오차와 관계와 페루프 안정성과 함께 두 개의 정리를 통하여 명확히 검진되었다. 제안된 레귤레이션 제어기의 설계는 성능 설계와 강인성 설계로 각 독립 링크 상에 분리된다. 제안된 알고리즘의 유용성은 매개변수 불확실성과 페이로드 변동하의 이 축 로봇의 레귤레이션 제어에 대한 시뮬레이션 연구를 통하여 무 리칭 구간, 무 오버슈트, 사전 추적 오차를 갖는 사전 결정 출력, 용이한 출력 가변성, 설계 단계의 분리 등의 관점에서 입증되었다.

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Synthetic Strategy and Optical Property Characterization of Complex Nanorods: Plasmon Wave Guide and Solar Cell

  • Park, Sung-Ho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.111-111
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    • 2012
  • In this talk, we represent a novel approach to investigating intra-nanorod surface plasmon coupling with control over block compositions. The multi-component rod-like nanostructures, which consist of optically active components (Au and Ag) and optically less active component (for example, Ni) in UV-vis-NIR spectral window, showed interesting optical response depending on each block length and the total length of the structure. By controlling the composition and relative lengths of the blocks that comprise these structures, we can tailor the overall optical properties. Depending on the relative fraction of Au and Ag blocks, the intensity of the transverse modes varied without noticeable peak shifts. However, the strong intraparticle surface plasmon coupling resulted in the collective appearance of longitudinal LSP modes, including higher-order modes. The experimental observations were confirmed by theoretical calculation, using a discrete dipole approximation method. In addition, we will briefly discuss how single nanorod solar cells can be synthesized by using by using electrochemical deposition and AAO hard templates.

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An Isothermal Temperature Source with a Large Surface Area using the Metal-Etched Microwick-Inserted Vapor Chamber Heat Spreader

  • Go, Jeong-Sang;Kim, Kyung-Chun
    • Journal of Mechanical Science and Technology
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    • 제18권4호
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    • pp.681-688
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    • 2004
  • For use of the thermal cycle of the biochemical fluid sample, the isothermal temperature source with a large surface area was designed, fabricated and its thermal characterization was experimentally evaluated. The comprehensive overview of the technology trend on the temperature control devices was detailed. The large surface area isothermal temperature source was realized by using the vapor chamber heat spreader. The cost-effectiveness and simple manufacturing process were achieved by using the metal-etched wick structure. The temperature distribution was quantitatively investigated by using IR temperature imaging system at equivalent temperatures to the PCR thermal cycle. The standard deviation was measured to be within 0.7$^{\circ}C$ for each temperature cycle. This concludes that the presented isothermal temperature source enables no temperature gradient inside bio-sample fluid. Furthermore it can be applied to the cooling of the electronic devices due to its slimness and low thermal spreading resistance.

미세액적의 표면에너지 제어를 통한 박막 제조 공정에 대한 연구 (A NUMERICAL STUDY ON A THIN FILM MANUFACTURING PROCESS USING THE CONTROL OF SURFACE ENERGY OF A MICRODROPLET)

  • 서영호;손기헌
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.221-226
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    • 2008
  • Numerical simulation is performed for microdroplet deposition on a pre-patterned micro-structure. The level-set method for tracking the liquid-gas interface is extended to treat the immersed (or irregular-shaped) solid surface. The no-slip condition at the fluid-solid interface as well as the matching conditions at the liquid-gas interface is accurately imposed by incorporating the ghost fluid approach based on a sharp-interface representation. The method is further extended to treat the contact angle condition at an immersed solid surface. The present computation of a patterning process using microdroplet ejection demonstrates that the multiphase characteristics between the liquid-gas-solid phases can be used to improve the patterning accuracy.

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미세액적의 표면에너지 제어를 통한 박막 제조 공정에 대한 연구 (A NUMERICAL STUDY ON A THIN FILM MANUFACTURING PROCESS USING THE CONTROL OF SURFACE ENERGY OF A MICRODROPLET)

  • 서영호;손기헌
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년 추계학술대회논문집
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    • pp.221-226
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    • 2008
  • Numerical simulation is performed for microdroplet deposition on a pre-patterned micro-structure. The level-set method for tracking the liquid-gas interface is extended to treat the immersed (or irregular-shaped) solid surface. The no-slip condition at the fluid-solid interface as well as the matching conditions at the liquid-gas interface is accurately imposed by incorporating the ghost fluid approach based on a sharp-interface representation. The method is further extended to treat the contact angle condition at an immersed solid surface. The present computation of a patterning process using microdroplet ejection demonstrates that the multiphase characteristics between the liquid-gas-solid phases can be used to improve the patterning accuracy.

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사면의 지표변위계측을 위한 사진측량기법의 적용 (Application of Photogrammetry Method to Measurement of Ground-Surface Displacement on the Slope)

  • 한중근;배상호;오다영
    • 한국환경복원기술학회지
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    • 제4권3호
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    • pp.10-18
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    • 2001
  • The existing measurement system to ground-surface displacement survey of the slope has been including the hazard for the measure in site and the difficulty for install, maintenance and control of expensive instruments, which are impossible of whole survey on the slope surface. To overcome of those defects, Softcopy Photogrammertry method is used, which can measure displacement of ground-surface on the slope and structure deformation vectors. Recently, the survey methods applying the advantages of Photogrammetry and Digital Photogrammetry Survey are widely used. In this study, therefore, the development and application of the new instrument mechanism on the the site example are studied. Through the application of Softcopy Photogrammetry, the 3-D data of ground surface on the dangerous slope could be effectively obtained at the long distance, which are obtained through the reform process of contour line. Those are different to the results of the Close-Range Photogrammetry analysis. In ground instrumentation parts, the new practical system shall be the technical base to improve of the instrument machine as well as can be widely applied in civil engineering and others branch.

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Control of Surface Chemistry and Electrochemical Performance of Carbon-coated Silicon Anode Using Silane-based Self-Assembly for Rechargeable Lithium Batteries

  • Choi, Hyun;Nguyen, Cao Cuong;Song, Seung-Wan
    • Bulletin of the Korean Chemical Society
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    • 제31권9호
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    • pp.2519-2526
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    • 2010
  • Silane-based self-assembly was employed for the surface modification of carbon-coated Si electrodes and their surface chemistry and electrochemical performance in battery electrolyte depending on the molecular structure of silanes was studied. IR spectroscopic analyses revealed that siloxane formed from silane-based self-assembly possessed Si-O-Si network on the electrode surface and high surface coverage siloxane induced the formation of a stable solid-electrolyte interphase (SEI) layer that was mainly composed of organic compounds with alkyl and carboxylate metal salt functionalities, and PF-containing inorganic species. Scanning electron microscopy imaging showed that particle cracking were effectively reduced on the carbon-coated Si when having high coverage siloxane and thickened SEI layer, delivering > 1480 mAh/g over 200 cycles with enhanced capacity retention 74% of the maximum discharge capacity, in contrast to a rapid capacity fade with low coverage siloxane.

비 분해성고분자와 블렌드를 이용한 생분해성 폴리유산의 효소분해속도 조절 (Control of Enzymatic Degradability of Biodegradable Polylactide by Blending with Non-degradable Polymers)

  • 장성호;박상보;이원기
    • 한국환경과학회지
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    • 제19권9호
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    • pp.1161-1167
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    • 2010
  • The effects of addition of non degradable polymers, polystyrene (PS) and poly(methyl methacrylate) (PMMA) on the rate of enzymatic degradation of biodegradable poly(l-lactide) (PLLA) have been studied in term of surface structure. Since a component in multicomponent polymeric system has shown surface enrichment, PS and PMMA which have lower surface energy than PLLA were selected as a minor blend component (5 wt%). Enzymatic degradation was carried out at $37^{\circ}C$ and pH 8.5 in the aqueous solution of Proteinase K. Two blend systems, partially miscible (PS/PLLA) and immiscible (PMMA/PLLA), showed the surface enrichment of 4 and 2 times of PS and PMMA, respectively. From the weight loss profile data, the slow degradation rate of both blend films was observed. This indicates that PS or PMMA domains which exist at surface act as a retardant of enzymatic attack.