• Title/Summary/Keyword: surface states

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Electronic States Calculation of Fe4N by DV-Xα cluster calculation (DV-Xα 클러스터 계산법에 의한 Fe4N의 전자상태계산)

  • Song, Dong-Won;Lee, In-Seop;Bae, Dong-Su
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.44-47
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    • 2002
  • DV(Discrete Variation)-X${\alpha}$ cluster calculation was employed to calculate the electronic states of ${\gamma}'- Fe_4N$ which was one of iron nitride phases synthesized from plasma ion nitriding to improve surface hardness and wear resistance. The result of calculated electron density of states for Fe was similar to the result of band calculation. The cluster used for calculation of electronic states of ${\gamma}'-Fe_4N$ was based on $Fe_{14}N$ cluster which comprises 15 atoms. Finally the electronic states of ${\gamma}'- Fe_4N$ such as net-charge, band order, energy level, electron wave-function, and contour map for electron density were derived by the calculation.

Effects of Surface Charges on Hydrophobicity and Surface Potential Decay with Various Surface States of Silicone Rubber for Outdoor Insulator (옥외용 실리콘 절연재료의 발수성에 미치는 표면전하의 영향과 표면 상태에 따른 표면전위 감쇠)

  • 연복희;박충렬;허창수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.678-686
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    • 2002
  • This paper presents the effects of accumulation of surface charges on hydrophobic level and the changes of surface potential decay with various artificial environment treatments on high temperature vulcanized (HTV) silicone rubber used for outdoor insulating material. For this study, the charging apparatus by corona discharge, in which grid electrode was installed between the main corona and ground electrode, was used. From this study, it was found that the accumulation of surface charges above a critical surface potential on silicone insulating materials could lead to the temporary loss of surface hydrophobicity. In addition, corona stress and water absorption stress increase the decay rate of surface charges of HTV silicone rubber, while ultraviolet (UV) stress causes longer decay time. We could conclude that the effects of surface charges on hydrophobicity level and the changes of surface state by various artificial treatments were found through a trend of surface potential decay.

Nominal States Relationship and Its Sliding Mode Control Application

  • Kim, Min-Chan;Ko, Chang-Min;Park, Seung-Kyu;Kwak, Gun-Pyong;Yoon, Tae-Sung;Ahn, Ho-Kyun
    • Journal of information and communication convergence engineering
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    • v.7 no.3
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    • pp.356-360
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    • 2009
  • A novel method to derive a Nominal States Relationship (NSR) of a control system is proposed. The obtained relationship is used to design a sliding surface which can have the characteristic of a nominal system. With this sliding surface, a Sliding Mode Control (SMC) system which has the characteristics of the nominal system controlled by pole placement is designed for an uncertain system.

The Characteristics of Residual Films on Silicon Surface $CHF_3/C_2F_6$ Reactive Ion Etching ($CHF_3/C_2F_6$ 플라즈마에 의한 실리콘 표면 잔류막의 특성)

  • 권광호;박형호;이수민;강성준;권오준;김보우;성영권
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.145-152
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    • 1992
  • Si surfaces exposed to CHF3/C2F6 gas plasmas ih reactive ion etching (RIE) have been characterized by X-ray photoelectron spectroscopy (XPS). CHF3/C2F6 gas plasma exposure of Si surface leads to the deposition of residual film containing carbon and fluorine. The narrow scan spectra of C 1s show various bonding states of carbon as C-Si, C-F/H, C-CFx(x $\leq$ 3), C-F, C-F2, and C-F3. The chemical bonding states of fluorine are described with F-Si, F-C and F-O. And the oxygen and silicon are also detected. The effects of parameters for reactive ion etching as CHF3/C2F6 gas ratio, RF power, and pressure are investigated.

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High Reliable GaAs HBT with InGaP Ledge Emitter Structure (외부 베이스표면을 에미터 ledge로 포장한 InGaP/GaAs HBT의 신뢰도 향상)

  • 박재홍;박재운
    • Journal of the Korea Society of Computer and Information
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    • v.5 no.4
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    • pp.102-105
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    • 2000
  • The self-aligned AICaAs/GaAs HBTs with the mesa-etched emitter showed severe degradation in current gain under stress. The cause was identified to be due to instability of the surface states on extrinsic base. In this paper the surface states were diminished by the hetero-passivation of the InGaP ledge emitter and the reliability was drastically improved. The activation energy of current gain degradation was extracted to be 1.97eV and MTTF to be 4.8$\times$108 at 14$0^{\circ}C$ which has satisfied MIL standards.

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An Experimental Study on the Influence of Moisture State of Aggregates on the Properties of the Recycled Aggregate Concrete (재생골재 콘크리트의 특성에 대한 골재 함수상태의 영향에 관한 실험적 연구)

  • Yang Keun-Hyeok;Lee Jae-Sam;Kang Kyung-In;Jung Sang-Jin;Chung Heon-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.137-140
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    • 2005
  • The objective of this experimental study is to grasp an influence of moisture state of aggregate on the characteristics of the recycled aggregate concrete. The moisture states of the aggregates were controlled at prewetted, oven-dried and saturated surface-dried states prior to use. To maintain the designed mix proportioning unchanged, the amounts of water and aggregates used in mixing were adjusted according to the actual moisture contents of the aggregates. Test results showed that the saturated surface-dried state aggregate concretes exhibited the highest compressive strength.

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Aiming at "All Soils All States All Round Geo-Analysis Integration"

  • Asaoka, Akira;Noda, Toshihiro
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.3-26
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    • 2009
  • Superloading yield surface concept is newly introduced together with subloading yield surface conception in order to describe full gradation continuously of the mechanical behavior of soils from typical sand through intermediate soil to typical clay (All Soils). Finite deformation theory has been applied to the soil skeleton-pore water coupled continuum mechanics, which enables us to discuss things in a perpetual stream from stable state to unstable state like from deformation to failure and vice versa like from liquefaction to post liquefaction consolidation of sand (All States). Incremental form of the equation of motion has been employed in the continuum mechanics in order to incorporate a rate type constitutive equation, which is "All Round" enough to predict ground behavior under both static and dynamic conditions. The present paper is the shortened version of the lecture note delivered in 2008 Theoretical and Applied Mechanics Conference, Science Council Japan, but with newly developed application examples.

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A Study on In-Porcess Sensor for Recognizing Cutting Conditions (복합가능형 절삭상태인식용 In-Process Sensor에 관한 연구)

  • Chung, Eui-Sik;Kim, Yeong-Dae;NamGung, Suk
    • Journal of the Korean Society for Precision Engineering
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    • v.7 no.2
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    • pp.47-57
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    • 1990
  • In-process recognition of the cutting states is one of the very important technologies to increase the reliability of mordern machining process. In this study, practical methods which use the dynamic component of the cutting force are proposed to recognize cutting states (i.e. chip formation, tool wear, surface roughness) in turning process. The signal processing method developed in this study is efficient to measure the maximum amplitude of the dynamic component of cutting force which is closely related to the chip breaking (cut-off frequency : 80-500 Hz) and the approximately natural frequency of cutting tool (5, 000-8, 000 Hz). It can be clarified that the monitoring of the maximum apmlitude in the dynamic component of the cutting force enables the state of chip formation which chips can be easily hancled and the inferiority state of the machined surface to be recognized. The microcomputer in-process tool wear monitor- ing system introduced in this paper can detect the determination of the time to change cutting tool.

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A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction I. TPR Studies of $Mo/\gamma -Al_2O_3$ Catalysts

  • 박진남;김준희;이호인
    • Bulletin of the Korean Chemical Society
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    • v.19 no.12
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    • pp.1363-1368
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    • 1998
  • Mo/γ-Al2O3 catalysts were prepared by impregnation method in various conditions to identify the states of surface Mo species. TPR (Temperature-Programmed Reduction) and Raman spectroscopy were applied to analyze the surface Mo species. TPR analysis revealed that MoO3 was reduced to Mo through MoO2, the intermediate state and the increase of Mo loading enhanced the reducibility of Mo oxide till the formation of monolayer coverage. High temperature calcination induced oxygen defects in MoO3 giving their unstable states for easier reduction. Raman spectroscopy analysis showed that the increase of Mo loading induced the polymeric Mo oxide.

Surface Characterization of Silicone Rubber for Outdoor Insulation by Measurement of Surface Voltage Decay

  • Youn, Bok-Hee;Huh, Chang-Su;Cho, Han-Gu
    • KIEE International Transactions on Electrophysics and Applications
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    • v.12C no.4
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    • pp.214-219
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    • 2002
  • The influence of ultraviolet (UV) irradiation and corona on the surface degradation of high temperature vulcanized (HTV) silicone rubber used for outdoor insulation through measuring surface voltage decay after corona charging, surface resistivity, contact angle and X-ray photoelectron spectroscopy (XPS) analysis was studied. The surface resistivity calculated by the surface voltage decay was compared with a value directly obtained from the three electrode method having the guard ring electrode. A good agreement between the two methods for surface resistivity was obtained. UV treated specimens showed the slower decrease of surface voltage decay, while the corona exposed specimens showed a dramatically faster decrease. Although both artificial treatments cause the same oxidative products, which was confirmed with XPS, we could distinguish the difference between the reactions of the two treatments by monitoring the surface voltage decay on corona-charged specimen. In addition, we could derive the specific surface states of the silicone rubber treated by accelerated artificial aging factors and the degradation process.