• Korean Journal of Environmental Agriculture
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• v.36 no.1
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• pp.63-66
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• 2017

BACKGROUND: The phenol concentrations in water samples were determined using gas chromatography after derivatization of the analyte to phenyl acetate followed by extraction using a large volume of solvent. However, this procedure requires an additional purification step and is not analytically efficient. METHODS AND RESULTS: In this study, phenol was first extracted from an acidified water sample using ethyl acetate and then acetylated using acetic anhydride in the presence of a small amount of water and $K_2CO_3$. The derivative was extracted using 1mL of n-butyl acetate. One microliter of the extract was analyzed by GC-MS without further purification. The calibration curve showed good linearity with the $r^2$ value of 0.9968. The method detection limit and the limit of quantitation were estimated to be $0.18{\mu}g/L$ and $0.56{\mu}g/L$, respectively. Repeatability (RSD, n=3) and recovery (n=3) were 9.1%-4.3% and 90.6%-110.5%, respectively. The concentrations of phenol in a few samples of stream water were distributed in the range of $2.51-7.51{\mu}g/L$. CONCLUSION: This method is simpler and faster to implement than those currently utilized and shows high analytical reliability. It can be applied to the quantitative determination of phenol concentrations in surface water and groundwater samples.

• Applied Chemistry for Engineering
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• v.5 no.2
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• pp.345-356
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• 1994

Each of the three cationized compounds synthesized previously, poly(OMA-co-DAMA)[PODC], poly(DMA-co-DAMA)[PDDC] and poly(EMA-co-DAMA)[PEDC] was blended with waxes, emulsifiers and cationized fatty carbamide(ODTCC) synthesized in this study for the preparation of some durable softening water-repellenting agents, PODCW, PDDCW and PEDCW. The results of washability, tearing strength, crease recovery and contact angle of the cotton fabrics treated with PODCW, PDDCW and PEDCW with and without textile finishing resin, showed remarkable improvement of the physical properties. Rating of water repellency of cotton fabric treated with PODCW was 80, but those treated with PDDCW and PEDCW were not high enough to use in industry. Proper curing temperature of the synthesized water-repelleting agents was $140^{\circ}C$; proper using concentration was 3wt%; sodium acetate was the best catalyst for water-repellenting agents among the used, and proper concentration was 0.6wt%. From the results of reaction mechanism of cellulosic fiber with water-repellenting agent and washability of the fibers treated with water-repellenting agents the prepared water-repellenting agent proved to be durable. Surface structures of cotton fabrics treated with water-repellenting agent were investigated by SEM.

• Korean Journal of Food Science and Technology
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• v.43 no.3
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• pp.277-281
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• 2011

A rapid and very sensitive high-performance liquid chromatography/atmospheric-pressure chemical-ionization mass spectrometry method to detect ethylenethiourea (ETU) fungicide residues in fruits was developed. Methylene chloride was used as the surface extraction solvent for the target component. Recovery rates improved when cysteine hydrochloride and sodium carbonate were added to product prior to fortification. The limits of detection and quantification were approximately 0.006 and 0.02 mg/kg, respectively, from mandarin oranges. Recoveries from mandarin oranges, oranges, bananas, and pears, spiked in the range of 0.05-0.5 mg/kg, averaged 80-100%. The proposed method was used to monitor the presence of ETU in commercial fruits purchased from different markets in Seoul, Korea. ETU was found in four orange peels and in three mandarin orange peel samples. The highest ETU residue levels were $73.6{\mu}g/kg$ and $29.8{\mu}g/kg$.

• Journal of the Korean Society of Clothing and Textiles
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• v.29 no.8 s.145
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• pp.1176-1187
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• 2005

The purpose of this study was to evaluate the efficiency of cooling vests developed for farm workers harvesting red pepper in summer. The study was performed using the following two steps: 1) Climatic chamber test, 2) Field test. For the chamber test, a work environment was simulated as $33^{\circ}C$ and $65\%$RH, and the thermo-physiological and subjective responses were measured with and without cooling vests. Twelve young males participated as subjects. For the field test, three farmers participated while harvesting red pepper on the form, in summer. The measurements used were same as in the chamber test. Subjects were tested without any cooling vests, as a control. They were tested wearing vests with 2 frozen gel packs (CV2: Cooling area, $308cm^2$), and vests with 4 frozen gel packs (CV4: Sooting area, $616cm^2$). As a result of the chamber test, rectal temperature($T_{re}$) and mean skin temperature( $T_{sk}$) were lower in both CVs than in Control, and this tendency was statistically significant in CV4 (p<.05). Clothing microclimate temperature ($T_{clo}$) and total sweat rate (TSR) were significantly lower when wearing cooling vests (p<.05) Heart rate (HR) was also lower in wearing cooling vests than in Control, and the speed of recovery to the comfort level was faster when the subjects wore cooling vests. In addition, subjects felt 'less hot, less humid, and less uncomfortable' in both CVs than in Control. Field tests showed a similar tendency with the chamber tests. In particular, wearing the cooling vest was effective in restraining the raise of $T_{clo}$ on the back. It can be concluded that the cooling vest was effective in alleviating heat strain and discomfort in both the chamber test and the field test, despite the cooling area of the cooling vest being just $3.4\%$ of the body surface area ($616cm^2$).

• Ecology and Resilient Infrastructure
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• v.6 no.4
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• pp.267-276
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• 2019

The Gonggeomji Reservoir is a historical irrigation facility built in the 8th century and designated as a wetland protected area by Ministry of Environment, Korea. In order to collect the baseline data necessary for developing a sustainable conservation strategy, we investigated the classification of actual vegetation, the vegetation distribution and the floristic structure of the vegetation in the Gonggeomji Wetland Protection Area. In the whole protection area, a total of 26 plant communities were classified including the wetland, riparian, grassland, forest, farmland, and orchard vegetation. According to the results of detrended correspondence analysis, the structure of wetland vegetation was mainly affected by water depth and human disturbance. In reservoir wetlands, floating vegetation such as Utricularia vulgaris var. japonica, Trapa japonica, and emergent vegetation such as Nelumbo nucifera, Typha spp. completely covered the water surface. Since 2014, the reservoir wetland has been terrestrialized with the expansion of emergent and hygrophytic plants. For the sustainable conservation and restoration of wetland protected areas, it is necessary to naturalize the topography and wetland vegetation, recovery the hydrologic system, and restore ecosystem connectivity from wetlands to forests.

• Korean Chemical Engineering Research
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• v.40 no.6
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• pp.694-702
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• 2002

Activated carbons have been used as adsorbents in various industrial application, such as solvent recovery, gas separation, deodorization, and catalysts. In this study, the effects of residual water on the activated carbon adsorbent surface on the adsorption capacity of $CCl_4$ were investigated. Adsorption behavior in a fixed bed was studied in terms of feed concentration, flow rate, breakthrough curve and adsorption capacity for $CCl_4$. Desorption characteristics of residual water on activated carbon were also studied. The water contents of the activated carbon were varied in the range of 0-20%(w/w) and all experiments were performed at 298.15 K. The adsorption equilibrium data $CCl_4$ on the activated carbon were well expressed by Langmuir isotherm. The adsorption capacity of $CCl_4$ decreased with increasing residual water content. Desorption of residual water in activated carbon decreased expotentially with $CCl_4$ adsorption. The obtained breakthrough curves using LDF(linear driving force) model represented our experimental data.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.142-149
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• 2020

In this study, the electrochemical performance of Graphite/Silicon/Pitch composites as anode material was investigated to improve the low theoretical capacity of artificial graphite. Spherical artificial graphite surface was coated with polyvinylpyrrolidone (PVP) amphiphiles material to synthesize Graphite/Silica material by silica islands growth. The Graphite/Silicon/Pitch composites were prepared by petroleum pitch coating and magnesiothermic reduction. The Graphite/Silicon/Pitch composite electrodes manufactured using poly(vinylidene fluoride) (PVDF), carboxymethyl cellulose (CMC) and polyacrylic acid (PAA) binders. The coin type half cell was assembled using various electrolytes and additives. The Graphite/Silicon/Pitch composites were analysed by X-ray diffraction (XRD), scanning electron microscope (SEM) and a thermogravimetric analyzer (TGA). The electrochemical characteristics of Graphite/Silicon/Pitch composite were investigated by constant current charge/discharge, rate performance, cyclic voltammetry and electrochemical impedance spectroscopy. The Graphite/Silicon/Pitch composites showed high cycle stability at a graphite/silica/pitch ratio (1:4:8 wt%). When the electrode is prepared using PAA binder, the high capacity and stability is obtained. The coin type half cell assembled using EC: DMC: EMC electrolyte showed high initial capacity (719 mAh/g) and excellent cycle stability. The rate performance has an capacity retention (77%) at 2 C/0.1 C and an capacity recovery (88%) at 0.1 C / 0.1 C when the vinylene carbonate (VC) was added.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.1
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• pp.61-65
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• 2012

Once oil has spilled, oil spill responders use a variety of countermeasures to reduce the adverse effects of spilled oil on the environment. Mechanical methods of containment and recovery are preferred as the first response when the use of other methods fail or are ineffective. In these cases, the application of oil dispersants shall be use only as a last resort. While effectiveness of dispersants in removing oil form the sea surface is proven, the use of dispersants is controlled in almost all countries due to the toxicity of their active agents and the dispersed oil on the marine environment. However, according to reports, after dispersant application, no significant toxicity to fish or shrimp was observed in the field-collected samples. Moreover, the results also indicate that dispersant-oil mixtures are generally no more toxic to the aquatic test species than oil alone. During the Deepwater Horizon Incident, dispersants were applied to floating oil and injected into the oil plume at depth. These decisions were carefully considered by state and federal agencies, as well as BP, to prevent as much oil as possible from reaching sensitive shoreline habitats. Net Environmental Benefit Analysis for dispersant use assumed that dispersants appear to prevent long-term contamination resulting absence of oil in the substrate and will benefit marine wildlife by decreasing the risk of significant contamination to feathers or fur. Further study to use dispersants with scientific baseline is needed for our maritime environment which consistently threaten huge oil spill incidents occurrence.

• Clean Technology
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• v.8 no.3
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• pp.119-128
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• 2002

In the present study the membrane filtration characteristics of a commercially available synthetic water-based cutting oil through two kinds of ultrafiltration membranes (HF1-45-CM50 and HF1-43-CM100) with molecular weight cut-offs of 50,000 and 100,000, respectively, have been investigated in detail. Among these membranes, the hydrophilic one (HF1-45-CM50) was found to show a satisfactory result for both the permeate flux and the permeability of oil components, whereas the permeate flux obtained with the hydrophobic membrane (HF1-43-CM100) appears to be significantly low, indicating that synthetic cutting oil was easily wetted on the hydrophobic membrane surface and induced more membrane fouling. The effect of material characteristics of the membrane on the filtration characteristics was found to be much more significant compared with the mean pore size of the membrane. Backflushing by nitrogen gas was applied to reduce the formation of a gel layer and membrane fouling. With the hydrophilic membrane, the backflushing was found to increase the permeate flux, whereas the backflushing resulted in a decrease in flux for the hydrophobic membrane. The flux recovery was observed to be highest when the membranes fouled with waste synthetic cutting oil were immersed into a cleaning solution for more than 72 hours and then backflushed by nitrogen gas.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.19 no.4 s.74
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• pp.407-418
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• 2006

In this paper, an efficient yet accurate stress analysis based on the first-order shear deformation theory (FSDT) is presented. The transverse shear strain energy is modified via the mixed variational theorem, so that the shear correction factors are automatically involved in the formulation. In the mixed variational formulation, the transverse stresses are taken to be functions subject to variations. The transverse shear stresses based on an efficient higher order plate theory (EHOPT, Cho and Parmerter, 1993) are utilized and modified, while the transverse normal stress is assumed to be the third-order polynomial of thickness coordinates, which satisfies both zero transverse shear stresses and prescribed surface fractions in top and bottom surfaces. On the other hand, the displacements are assumed to be those of the FSDT Resulting strain energy expressions are referred to as an EFSDTM3D that stands for an enhanced first-order shear deformation theory based on the mixed formulation for three dimensional elasticity, The developed EFSDTM3D preserves the computational advantage of the classical FSDT while allowing for important local through-the-thickness variations of displacements and stresses through the recovery procedure that is based on the least square minimization of in-plane stresses. Comparisons of displacements and stresses of both laminated and sandwich plates using the present theory are made with the classical FSDT, three-dimensional exact solutions, and available data in the literature.