• 제목/요약/키워드: surface properties

검색결과 13,459건 처리시간 0.04초

Properties of Carbon Black Used as Catalysts for Methane Decomposition

  • Kim, Myung-Soo;Han, Ling;Dai, Shuangye;Park, Hong-Soo;Hahm, Hyun-Sik
    • 한국응용과학기술학회지
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    • 제23권3호
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    • pp.199-206
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    • 2006
  • Direct decomposition of methane over three types of carbon black (N330-p, N330-f, and HI-900L) was carried out in a fluidized bed quartz reactor. Properties of carbon black before and after reaction were measured and found to be related with surface structure and weight gain. For N330-p and N330-f, some carbon deposit on the surface was considered to be the reason for the increase of BET surface area and pore volume with weight gain. Carbon deposits on the surface and the conglutination of some aggregates may explain the slight increase of particle size. Properties of HI-900L changed much more significantly with weight gain. It is supposed that the increase of aggregate size of HI-900L were due to some unknown oily components. The corresponding agglomeration might be the reason for the decrease of BET surface area with weight gain, as compared with the increase of that for the case of N330 black.

캘린더 처리조건이 도공지 품질에 미치는 영향 (Effect of Calendering Variables on the Properties of Coated paper)

  • 이용규;김창근;이광섭
    • 펄프종이기술
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    • 제33권2호
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    • pp.49-57
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    • 2001
  • This study was performed to identify the effect of calendering variables on the properties of coated paper such as sheet gloss, surface roughness, opacity, etc. The effect of calendering variables including the number of nips, pressure, machine speed and moisture content on the properties of coated paper was investigated. The calender was installed with two steel rolls and one cotton-made roll. With this calender, the coated sheets were passed through the calender from 1 to 4 times, applying the linear pressure on calender rolls, 5 through 100kg/cm and operating the machine speed 3 to 12m/min. Also, the moisture content of coated sheet was varied about 5 and 10%. It was found that sheet gloss and surface roughness of coated paper was increased with increasing the number of passing nips, linear roll pressure and the moisture content of coated paper. But it was shown that the opacity and brightness of coated paper were decreased under the above conditions due to the blackening. It was also suggested that the soft nip possibly increased the thermoplasticity of coating layer with the heat of steel roll, resulting in the reinforcement of surface properties positively. The sheet gloss and surface roughness of coated paper could be improved by the longer dwell time over the rolls.

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열처리가 유리섬유 강화 복합재료의 전기적 및 기계적 성질에 미치는 영향 (Effects of Heat Treatment on Electrical and Mechanical Properties of Glass Fiber Reinforced Epoxy)

  • 이백수;이덕출
    • 한국전기전자재료학회논문지
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    • 제11권3호
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    • pp.174-180
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    • 1998
  • In this work, the properties of FRP, which is applied recently in the composite insulating materials, by thermal treatment were investigated. The specimens were epoxy glass laminates fabricated by thermal press method and had the volume content of 46[%] cutted $45^{\circ}C$ in the fiber direction and 1.0[mm] thickness. The experimental results showed that the amount of weight loss, wettability, surface potential, and surface resistivity increased up to 200[$^{\circ}C$] as a function of temperature. Usually, most degradations caused the hydrophilic to decrease the contact angle. But, in this work on thermal-degradated FRP, we can confirm the introduction of hydrophobic properties by cross-linking and the ablation of polar small-molecules rather than chain scission and oxidation. Finally, weight loss and contact angle increased. These phenomena show the existence of hydrophobic surface. With the change to the hydrophobic surface and the electrical potential and resistivity on FRP surface increased. But, the dielectric properties and tensile stength are decreased.

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와이어 브러싱한 알루미늄 판재 표면 및 압연접합 계면의 미세조직 및 기계적 성질 (Microstructure Evolution and Mechanical Properties of Wire-Brushed Surface and Roll-Bonded Interface of Aluminum Sheets)

  • 김수현;김형욱;강주희;어광준
    • 대한금속재료학회지
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    • 제49권5호
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    • pp.380-387
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    • 2011
  • Wire brushing, which is a typical surface preparation method for roll bonding, has recently been highlighted as a potentially effective method for surface nanocrystallization. In the present study, the microstructure evolution and hardness of the wire-brushed surface and roll-bonded interface of a 1050 aluminum sheet were investigated. Wire brushing formed protruded layers with a nanocrystalline structure and extremely high surface hardness. After roll bonding, the protruded layers remained as hard layers at the interface. Due to their hardness and brittleness the interface hard layers, can affect the interface bonding properties and also play an important role determining the mechanical properties of multi-layered clad sheets.

Modeling and Characterization of Steam-Activated Carbons Developed from Cotton Stalks

  • Youssef, A.M.;Hassan, A.F.;Safan, M.
    • Carbon letters
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    • 제14권1호
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    • pp.14-21
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    • 2013
  • Physically and chemically activated carbons (ACs) exhibited high adsorption capacities for organic and inorganic pollutants compared with other adsorbents due to their expanded surface areas and wide pore volume distribution. In this work, seven steam-ACs with different burn-off have been prepared from cotton stalks. The textural properties of these sorbents were determined using nitrogen adsorption at $-196^{\circ}C$. The chemistry of the surface of the present sorbents was characterized by determining the surface functional C-O groups using Fourier transform infrared spectroscopy, surface pH, $pH_{pzc}$, and Boehm's acid-base neutralization method. The textural properties and the morphology of the sorbent surface depend on the percentage of burn-off. The surface acidity and surface basicity are related to the burn-off percentage. A theoretical model was developed to find a mathematical expression that relates the % burn-off to ash content, surface area, and mean pore radius. Also, the chemistry of the carbon surface is related to the % burn-off. A mathematical expression was proposed where % burn-off was taken as an independent factor and the other variable as a dependent factor. This expression allows the choice of the value of % burn-off with required steam-AC properties.

양성고분자에 의한 표면사이징과 이에 의한 도공층의 구조 및 도공지 물성 변화 (Effect of Surface Sizing with Cationic Polymer Additives on the Coating Structure and Coated Paper Properties)

  • 전대구;이학래
    • 펄프종이기술
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    • 제40권1호
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    • pp.1-8
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    • 2008
  • It is essential to use base papers having proper surface characteristics in coating operation for improving coated paper quality and coater runnability. To fulfill these purposes, surface sizing of coating base stock with oxidized starch is commonly practiced. Use of cationic starch for surface sizing improves coated paper quality since cationic starch penetrates less into paper structure. The immediate objective of this study was to examine the influence of surface sizing with starch solutions containing cationic polymers on the rheology of coating colors and the effect on physical properties of coated papers. Changes of rheological characteristics of coating colors placed on the plastic substrate surface sized with cationic and anionic starch were determined. Results of rheological test showed that cationic polymer surface sizing agent increased electrostatic interaction with coating colors and increased storage modulus. This new technology of using cationic polymer as surface sizing additive was considered to be advantageous for base papers at low basis weights since it would improve the coverage and optical properties of coated papers.

급속가열용 플라스틱 사출금형을 위한 고기능성 표면처리 (High functional surface treatments for rapid heating of plastic injection mold)

  • 박현준;조균택;문경일;김태범;김상섭
    • Design & Manufacturing
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    • 제15권3호
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    • pp.7-12
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    • 2021
  • Plastic injection molds used for rapid heating and cooling must minimize surface damage due to friction and maintain excellent thermal and low electrical conductivity. Accordingly, various surface treatments are being applied. The properties of Al2O3 coating and DLC coating were compared to find the optimal surface treatment method. Al2O3 coating was deposited by thermal spray method. DLC films were deposited by sputtering process in room temperature and high temperature PECVD (Plasma enhanced chemical vapor deposition) process in 723 K temperature. For the evaluation of physical properties, the electrical and thermal conductivity including surface hardness, adhesion and wear resistance were analyzed. The electrical resistance of the all coated samples was showed insulation properties of 24 MΩ/sq or more. Especially, the friction coefficient of high temp. DLC coating was the lowest at 0.134.

견직물의 물리적 자극에 따른 태와 역학적 특성 (Physical Stimulus of Silk Woven Fabrics, Subjective Hand and Mechanical Properties)

  • 김춘정;나영주
    • 한국의류학회지
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    • 제24권3호
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    • pp.429-439
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    • 2000
  • This study was aimed to investigate the handle and mechanical properties of silk woven fabrics according to the fabric structure and yarn types 56 male and female students evaluated 16 black specimens with semantic differential scale of 20 hand adjectives. Mechanical parameters such as surface properties, bending properties and compression properties were tested using by KES-FS system. Data were analyzed through factor analysis, pearson correlation coefficient and t-test using PC SAS package. The results were as follows: The hand adjectives were grouped as 4 'surface roughness', 'flexibility', ;sense of thermal', and 'dryness'. 'Surface roughness' was highly sensed at satin fabrics of hard-twist yarn, noil yarn and spun yarn, while it was not at the fabrics of normal satin and twill at all. 'Flexibility' was reverse to 'surface roughness'. Thermal sense was felt highly at satin fabrics of noil-yarn, while low at plain fabrics of normal yarn. 'Dryness' was high at satin fabrics of hard-twist yarn and while it was low at normal satin fabrics. Predicted equations for subjective hand from mechanical properties of fabrics were developed using Stevens's law and stepwise regression and the coefficients of determination were high.

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Influence of Aminized Graphite Nanosheets on the Physical Properties of PMMA-based Nanocomposites

  • Kim, Ki-Seok;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.196-200
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    • 2011
  • In this work, poly(methyl methacrylate) (PMMA) was grafted onto amine treated graphite nanosheets ($NH_2$-GNs) and the surface characteristics and physical properties of the $NH_2$-GNs-g-PMMA films were investigated. The graft reaction of $NH_2$-GNs and PMMA was confirmed from the shift of the $N_{1S}$ peak, including amine oxygen and amide oxygen, by X-ray photoelectron spectroscopy (XPS). The surface characteristics of the $NH_2$-GNs-g-PMMA films were measured as a function of the $NH_2$-GN content using the contact angle method. It was revealed that the specific component of the surface free energy (${\gamma}s$) of the films was slightly increased as the $NH_2$-GN content increased. Also, the thermal and mechanical properties of the $NH_2$-GNs-g-PMMA films were enhanced with the addition of $NH_2$-GNs. This can be attributed to the chemical bonding caused by the graft reaction between the $NH_2$-GNs and the PMMA matrix.

TiN 코팅층 집합조직의 변화에 따른 마찰, 마멸과 내부식 특성 (The Characteristics of Frictional Behavior, Wear and Corrosion Resistance of Textured TiN Coated Layer)

  • 김희동;김인수;성동영;이민구
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2003년도 춘계학술대회논문집
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    • pp.99-104
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    • 2003
  • TiN coated films show a good mechanical properties, high thermal properties and wear, erosion and corrosion resistance and are widely used as a coating materials in tools, ornaments, parts and semiconductors. In spite of these good properties, the fracture of TiN coated films occur during use. The fracture of TiN thin films is related to their microstructure. Especially, the life of TiN coated layer is related to the texture of the TiN films. One researcher suggested that the corrosion and erosion resistance of the TiN thin films is related to a uniform and dense structure of films. In this study, we studied the relationships between textures and friction coefficient, erosion and corrosion in TiN coated films. The flatness of (115) texture surface of TiN thin films is flatter than that of (111) texture surface. The friction coefficient of (115) texture surface of TiN thin films is similar with that of (111) texture surface. The wear resistance of (115) texture surface of TiN thin films is better than that of (111) texture surface. The erosion and corrosion resistance of (115) texture surface of TiN thin films is better than that of (111) torture surface. As well as texture, the wear, erosion and corrosion of TiN thin films has to consider defects such as pinholes, cracks, surface roughness and open columnar structure. The life of TiN coated products is influenced by the properties of wear, erosion, and corrosion resistance of TiN thin films and is related to texture of TiN coated films, density of pinholes and cracks, density of structure, and surface flatness.

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