• 제목/요약/키워드: surface properties

검색결과 13,459건 처리시간 0.037초

DLC 박막이 코팅된 폴리머 애자의 표면 및 물리적 특성 (Surface and Physical Properties of Polymer Insulator Coated with Diamond-Like Carbon Thin Film)

  • 김영곤;박용섭
    • 한국전기전자재료학회논문지
    • /
    • 제34권1호
    • /
    • pp.16-20
    • /
    • 2021
  • In this study, we tried finding new materials to improve the stain resistance properties of polymer insulating materials. Using the filtered vacuum arc source (FVAS) with a graphite target source, DLC thin films were deposited on silicon and polymer insulator substrates depending on their thickness to confirm the surface properties, physical properties, and structural properties of the thin films. Subsequently, the possibility of using a DLC thin film as a protective coating material for polymer insulators was confirmed. DLC thin films manufactured in accordance with the thickness of various thin films exhibited a very smooth and uniform surface. As the thin film thickness increased, the surface roughness value decreased and the contact angle value increased. In addition, the elastic modulus and hardness of the DLC thin film slightly increased, and the maximum values of elastic modulus and hardness were 214.5 GPa and 19.8 GPa, respectively. In addition, the DLC thin film showed a very low leakage current value, thereby exhibiting electrical insulation properties.

폴리우레탄 고분자 LB막의 표면구조 관찰 및 전기적 특성 (Observation of Surface Morphology and Electrical Properties of Polyurethane Polymer LB Films)

  • 서정열;신훈규;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제50권8호
    • /
    • pp.371-375
    • /
    • 2001
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area (${\pi}$-A) isotherms. The surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy(AFM) and UV-vis spectroscopy, respectively. And, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity and the dielectric constant. In the surface morphologies, physicochemical and electrical properties of polyurethane derivatives LB films, the properties is different as to the polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

  • PDF

Surface and Dielectric Properties of Oriental Lacquer Films Modified by UV-Curable Silicone Acrylate

  • Hong, Jin-Who;Kim, Hyun-Kyoung
    • Macromolecular Research
    • /
    • 제14권6호
    • /
    • pp.617-623
    • /
    • 2006
  • In order to achieve an oriental lacquer (OL) film with a thick consistency, UV-curable silicone acrylate (SA) was added to OL by a dual curing process. The addition of 5 wt% UV-curable SA to the OL fomulation enabled the preparation via a single drying step of a $77{\mu}m-thick$ film exhibiting excellent surface properties. FTIR-ATR was used to investigate the effect of UV-curable SA on the behavior of film formation during curing, and the relaxation behavior of the produced films was investigated by dielectric spectroscopy. Dielectric properties were measured in the frequency range $10^{-2}-10^5\;Hz$ at various temperatures between -100 and $200^{\circ}C$. The results demonstrated that OL modified by UV-curable SA has a higher glass transition temperature and stronger secondary relaxation at a lower temperature than the conventional OL system. The OL film modified with UV-curable SA was presumed to be harder at the surface and tougher than conventional OL film.

팁페이파, 필터권지 및 접착제 특성이 제품담배 공기희석율에 미치는 영향 (The Effect of the Characteristics of Tipping Paper, Plug Wrap and Glue on the Cigarette Ventilation)

  • 김정열;김종열;신창호
    • 한국연초학회지
    • /
    • 제24권1호
    • /
    • pp.60-66
    • /
    • 2002
  • The ventilation rate of a ventilated filter cigarette depends on the details of its construction and on the properties of its components such as tobacco column pressure drop, filter pressure drop, tipping paper and plug wrap permeability, and vent position. Also, It was affected by the condition of adhesion of glue between tipping paper and plug wrap. This study was carried out to find the effect of surface properties of tipping paper and plug wrap, and a characteristics of glue on the ventilation rate of cigarettes. Our results indicated that the surface properties of tipping paper and plug wrap affected on the ventilation rate of cigarette. Also, the variation of ventilation rate was affected by the surface properties of tipping paper and the size of glue particles. We also found that the surface properties of tipping paper and plug wrap, and the emersion size of glue were the major factors to concern in the design for materials of cigarettes.

Helium/Oxygen Atmospheric Pressure Plasma Treatment on Poly(ethylene terephthalate) and Poly(trimethylene terephthalate) Knitted Fabrics: Comparison of Low-stress Mechanical/Surface Chemical Properties

  • Hwang Yoon Joong;McCord Marian G.;Kang Bok Choon
    • Fibers and Polymers
    • /
    • 제6권2호
    • /
    • pp.113-120
    • /
    • 2005
  • Helium-oxygen plasma treatments were conducted to modify poly(trimethylene terephthalate) (PIT) and poly(ethylene terephthalate) (PET) warp knitted fabrics under atmospheric pressure. Lubricant and contamination removals by plasma etching effect were examined by weight loss $(\%)$ measurements and scanning electron microscopy (SEM) analysis. Surface oxidation by plasma treatments was revealed by x-ray photoelectron spectroscopy (XPS) analyses, resulting in formation of hydrophilic groups and moisture regain $(\%)$ enhancement. Low-stress mechanical properties (evaluated by Kawabata evaluation system) and bulk properties (air permeability and bust strength) were enhanced by plasma treatment. Increasing interfiber and interyarn frictions might play important roles in enhancing surface property changes by plasma etching effect, and then changing low-stress mechanical properties and bulk properties for both fabrics.

PU 유도체 단분자막의 온도에 따른 전기 물성과 표면 형상 관찰 (Electrical Properties and Surface Morphology for Temperature in PU Derivatives Monolayers)

  • 서정열;김도균;박재철;권영수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
    • /
    • pp.458-460
    • /
    • 2000
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area ($\pi$-A) isotherms. And, the surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy (AFM) and UV-vis spectroscopy, respectively. Also, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity, the dielectric constant and activation energy. In the surface morphologies, physicochemical, electrical properties of polyurethane derivatives LB films, the properties is different as to the Polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

  • PDF

Spreading Kinetics of Poly(diisobutylene maleic acid) at the Air-water Interface

  • Kim, Nam Jeong
    • 한국응용과학기술학회지
    • /
    • 제32권4호
    • /
    • pp.661-668
    • /
    • 2015
  • The surface rheological properties of polymer monolayer show complicated non-linear viscoelastic flow phenomena when they are subjected to spreading flow. These spreading flow properties are controlled by the characteristics of flow units. The kinetics of the formation of an interfacial film obtained after spreading poly(diisobutylene maleic acid) at air-water interface were studied by measuring of the surface pressure with time. The experimental data were analyzed theoretically according to a nonlinear surface viscoelastic model. The values of dynamic modulus, static modulus, surface viscosities and rheological parameters in various area/ monomer were obtained by appling experimental data to the equation of nonlinear surface viscoelastic model.

아크 금속 용사 표면 처리 방법에 따른 Zn-Al 금속 용사 피막의 물리적 특성 평가 (Evaluation of physical properties of Zn-Al metal coating according to arc metal spray surface treatment method)

  • 장종민;김영관;이한승
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2022년도 가을 학술논문 발표대회
    • /
    • pp.89-90
    • /
    • 2022
  • Arc metal spraying is a widely used method for improving the performance of construction structures such as corrosion resistance and electromagnetic wave shielding. However, when arc metal spraying is applied to a concrete structure, adhesion performance may deteriorate. Therefore, the effect of each surface treatment method on the physical properties between the arc metal spray coating and concrete was reviewed by evaluating the deposition efficiency and adhesion performance according to the arc metal spray surface treatment method (surface reinforcing agent, roughening agent, and sealing agent). As a result, it is suggested as an optimal surface treatment condition to induce non-interface failure by using a roughening agent and to improve the properties of concrete and metal coatings by applying a surface reinforcing agent and sealing agent.

  • PDF

고로슬래그 미분말의 치환율 변화에 따른 제치장 콘크리트의 표면광택 특성 (Properties of Surface Grossing of Exposed Concrete with the Contents of Blast Furnace Slag)

  • 전충근;김효구;김정진;김기철;한천구
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2000년도 가을 학술발표회 논문집(II)
    • /
    • pp.911-914
    • /
    • 2000
  • Surface glossing and physical properties of exposed concrete varied with blast furnace slag content are dsicussed in this paper. According to experimental results, as the content of blast furnace slag increases, concrete gains high strength moderately at later stage and surface glossing increase. It shows that glossing decrease with age. Surface glossing shows high as W/B decreases and surface coating is applied. Concrete according to form type shows good results in surface glossing in order for acryl form, fancy form and steel form.

Surface and Mechanical Interfacial Properties of Oxyfluorinated Carbon Fibers-reinforced Composites

  • Park, Soo-Jin;Seo, Min-Kang;Lee, Young-Seak
    • Carbon letters
    • /
    • 제4권2호
    • /
    • pp.69-73
    • /
    • 2003
  • In this work, the effect of a direct oxyfluorination on surface and mechanical interfacial properties of PAN-based carbon fibers is investigated. The changes of surface functional groups and chemical composition of the oxyfluorinated carbon fibers are determined by FT-IR and XPS measurements, respectively. ILSS of the composites is also studied in terms of oxyfluorination conditions. As a result, FT-IR exhibits that the carboxyl/ester groups (C=O) at 1632 $cm^{-1} and hydroxyl group (O-H) at 3450 $cm^{-1} are observed in the oxyfluorinated carbon fibers. Especially, the oxyfluorinated carbon fibers have a higher O-H peak intensity than that of the fluorinated ones. XPS result also shows that the surface functional groups, including C-O, C=O, HO-C=O, and C-$F_x$ after oxyfluorination are formed on the carbon fiber surfaces, which are more efficient and reactive to undergo an interfacial reaction to matrix materials. Moreover, the formation of C-$F_x$ physical bonding of the carbon fibers with fluorine increases the surface polarity of the fibers, resulting in increasing ILSS of the composites. This is probably due to the improvement of interfacial adhesion between fibers and matrix resins.

  • PDF