• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.6
• /
• pp.773-787
• /
• 2003

There are variations in the temperature Held due to urban heat island and anthropogenic heating so that regional scale meteorological field is changed. Therefore we simulate and predict the regional climate change according to surface characteristics through regional meteorological model. This study investigates the regional meteorological field by urbanization that influences in local circulation system using CSU-RAMS and simulates dry deposition velocity (V$_{d}$) using PNU/DEM which includes surface characteristics (such as albedo, surface hydrology and rough-ness length etc.) with calculated meteorological field. During the summer, horizontal distributions of V$_{d}$ were simulated using CSU-RAMS and PNU/DEM at Busan metropolitan area. The estimated values of V$_{d}$ were larger in forest and agricultural areas than water areas since ozone with low water solubility is destroyed slowly at wet surface or water.water.

• Journal of the Korean Electrochemical Society
• /
• v.11 no.3
• /
• pp.135-140
• /
• 2008

An electrochemical generation of ozonized water was investigated by using ${\beta}-PbO_2$ as an anode and tap water as an anolyte. According to the potentiometric ozone detection which utilizes potential differences arisen from a chemical reaction of ozone and iodide, increasing tendency of ozone concentration on electrolysis time could be observed to show the maximum value of 8 ppm at an electrolysis time of 10 min. Ozone could be generated promptly even at an electrolysis time of 10 sec., suggesting great advantages of this electrochemical process in terms of simplicity and readiness that might be applied directly to practical uses including medical and/ or food industries. Influences of electrolysis on the properties and surface conditions of a $PbO_2$ electrode were also discussed from the results of cyclic voltammetry, scanning electron microscope, and X-ray diffractometer.

• The Korean Journal of Ecology
• /
• v.24 no.2
• /
• pp.117-119
• /
• 2001

Solar ultraviolet-B (UV-B) irradiances incident on a horizontal surface at Taegu, Korea during 1996-1998 were calculated with 5 minute averages of measurements taken every 30 seconds by a broadband UV-B sensor. The average, maximum and minimum of daily UV-B dose were 11.31, 22.04 and 3.20kJ m$^{-2}$ day$^{-1}$ , respectively, for the measuring period. Variations in stratospheric ozone concentration measured from space explain 85% of changes in the daily UV-B dose. It was expected that decrease of 50 Du in stratospheric ozone cause increase of 24.1% in daily UV-B dose in this study.

• Journal of Environmental Science International
• /
• v.6 no.4
• /
• pp.335-350
• /
• 1997

Numerical simulations of photochemical air pollution (CBM: Carbon-Bond Mechanisms under a theoretical three-dimensional local wind system are carried to clarify the fundamental characteristics of the effects of local wind on photochemical air pollution. According to the AWS data of Pusan coastal area and KMA, the surface wind of Pusan during summertime showed a very remarkable land and sea breeze circulation. The ozone concentration distribution using local wind model showed that high ozone concentration zone near coastal area moved toward inland In the afternoon. This change implies a sea breeze Increases the ozone concentration, but a land breeze decreases it in Pusan coastal area.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2002.11a
• /
• pp.39-42
• /
• 2002

Ozone is one of the most significant atmospheric constituents controlling the intensity of solar UV-B irradiance (280 to 320nm), and the decrease of the total ozone amount supported by ozonesondes and spectrometers will result in the increase of UV-B irradiance at the earth's surface. For example, 1% decrease in stratospheric ozone is expected to yield a 2-3% increase in UV-B irradiance and in the incidence of skin cancer. (omitted)

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.9
• /
• pp.989-994
• /
• 2005

The treatment efficiency and the degradation characteristics of humic acid were investigated in three processes-GAC adsorption, Ozone alone and Ozone/GAC hybrid process, in which $UV_{254}$, DOC, molecular size distribution and surface change of GAC were evaluated. DOC removal rate in Ozone/GAC hybrid profess(ca. 80%) was higher than the arithmetic sum of Ozone alone(38%) and GAC adsorption(19%). This result approves that the combined Ozone/GAC hybrid process brings synergistic effects on DOC removal from the HA containing water. $UV_{254}$ decrease rate was also at the highest in Ozone/GAC hybrid process from the three processes. It may be interpreted that the granular activated carbon in Ozone/GAC hybrid process acts as not only an adsorbent but also a catalyst for ozonation, and futhermore offers an additional reaction site between adsorbed organic matter and ozone. In the study of molecular sire distribution, there was no significant change of molecular size distribution in the GAC adsorption process during the reaction time of 120 min. In Ozone alone process, the fraction of molecular size over 30 kDa was decreased a little at the beginning and left constant after 10 min. But in Ozone/GAC hybrid process, the molecules size over 30 kDa of HA was significantly decreased from 36.3% to 3.9%. And also the fraction of smaller molecular size below 0.5 kDa was increased from 4.8%(untreated HA) to 12.3%(in Ozone alone) and 40.1%(in Ozone/GAC) respectively at the reaction time of 120 min.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 1999.10a
• /
• pp.81-82
• /
• 1999

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 1998.05a
• /
• pp.140-141
• /
• 1998

• Textile Coloration and Finishing
• /
• v.28 no.2
• /
• pp.63-69
• /
• 2016

Poly(butylene terephthalate)(PBT) surface was modified by UV/ozone irradiation and the effect of UV energy on the surface properties of the irradiated PBT films were characterized by the reflectance, surface roughness, contact angles, ESCA, and ATR analyses of the film surface. The surface reflectance, at the short wavelength of visible spectrum of particularly 400nm, decreased with increasing UV energy. And the irradiation roughened the film surface uniformly in the nano scale. The maximum surface roughness increased from 110nm for the unirradiated sample to 303nm at the UV energy of $10.6J/cm^2$. The surface energy of PBT film increased from $50.5mJ/m^2$ for the unirradiated PBT to $58.8mJ/m^2$ at the irradiation of $21.2J/cm^2$. The improvement in hydrophilicity was caused by the introduction of polar groups containing oxygens such as C-O and C=O bonds resulting in higher $O_{1s}/C_{1s}$. The increased dyeability of the modified film to cationic dyes may be resulted from the photochemically introduced anionic and dipolar dyeing sites on the PBT films surfaces.

• Journal of the Korean earth science society
• /
• v.26 no.3
• /
• pp.283-296
• /
• 2005

The effect of ozone and surface temperature on the ozone band at $9.7{\mu}m$ has been investigated from radiative transfer theory together with observations in order to derive empirical methods for remotely sensing ground-ozone concentration. Simultaneous observations of satellite (MODIS Aqua; ECT 13:30) and ground-ozone at 79 stations have been used over the Seoul Metropolitan Area (SMA; 125.7-127.2 E, 37.2-37.7 N) during four ozone-warning days in the year 2003. Cloud effect on the band in the methods was filtered out based on synoptic observations. Upwelling radiance values at $9.6{\mu}m$ which have been estimated at the given ozone concentration of 327-391 DU depend on surface temperature (Ts) showing $5.52\~5.78Wm^{-2}sr^{-1}\;at\;Ts = 290 K,\;and\;9.00\~9.57Wm^{-2}sr^{-1}$ Ts = 325K. Thus, the partitioned contributions of ozone and temperature to intensity of ozone absorption band are $0.26Wm^{-1}sr^{-1}/64\;DU\;and\;0.31 Wm^{-2}sr^{-1}/35K$, respectively. Here the intensity which has been used to remotely detect ground-ozone concentration from infrared satellite measurement is defined as the difference in brightness temperature between $11{\mu} m\;and\;9.7{\mu}m (i.e.,\; T_{11-9.7})$. The methods in this study have been applied to estimate ground-ozone from MODIS data in cases that there are significant correlations between the band intensity and ground-ozone. The values of estimated ozone significantly correlate (0.49-0.63) with ground observations at a significance level of $1\%$. For the improved methods, further study may be required to use tropospheric ozone rather than ground-ozone, considering the variation stratospheric ozone.