• Title/Summary/Keyword: surface impedance

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The Study on Structural Change and Improvement of Electrochemical Properties by Co-precipitation Condition of Li[Ni0.8Co0.15Al0.05]O2 Electrode (Li[Ni0.8Co0.15Al0.05]O2 전극의 공침 조건을 통한 구조적 변화와 전기적 특성의 향상 고찰)

  • Im, Jung-Bin;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.98-103
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    • 2011
  • [ $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ ]cathode material for lithium secondary battery is obtained using co-precipitation method. To determine the optimal metal solution concentration value, the CSTR coprecipitation was carried out at various concentration values(1-2 mol/L). The surface morphology of coated samples was characterization by SEM(scanning electron microscope) and XRD (X-Ray Diffraction)analyses. Impedance analysis and cyclic voltammogram presented that internal resistance of the cell was dependent upon the concentration of metal solution. such data is very helpful in determining the optimal content of metal solution concentration to enhancing electrochemical property by adjusting powder size distribution and crystal structure.

Vertically Half Disc-Loaded Ultrawideband Monopole Antenna (VHDMA) with Horizontally Top-Loaded Small Disc (수평 원형 디스크가 로딩된 반원 디스크 초광대역 모노폴 안테나)

  • 이재욱;조춘식;김종면
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.15 no.11
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    • pp.1051-1061
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    • 2004
  • In this Paper, a new antenna(VHMDA) characteristics of half-circular/elliptical disc-loaded planar antennas with horizontally top-loaded small disc is studied by simulation and measurements with additional resonant structure. The transfer function characteristics of Gaussian pulse from the designed UWB transmitter antenna has been investigated. The radiation pattern of the proposed antenna in azimuth is nearly omni-directional response, which is usulally required in conventional monopole antenna. In addition to that, the simulation and measured results show that the return loss characteristics of VHDMA covers considerably large bandwidth with small area. From the measured results of the circular and half-circular disc-loaded monopole antennas with small disc mounted on the top, it is found that the half disc-loaded monopole antenna with additional structure can be comparable to the circular disc-loaded monopole antenna in respect o( size and electrical performances. Surface wave and dielectric losses often caused by the printed antenna using high dielectric constant does not occur in metallic planar antenna with good impedance matching and without lossy matching unit. This structure implies that the performance of return loss is directly related with the radiation efficiency.

Model-Based Detection of Pipe Leakage at Joints (모델 기반 파이프 연결부 누수 감지 시스템)

  • Kim, Taejin;Youn, Byeng D.;Woo, Sihyeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.3
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    • pp.347-352
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    • 2015
  • Time domain reflectometry (TDR) is widely used for wire failure detection. It transmits a pulse that is reflected at the boundaries of different characteristic impedances. By analyzing the reflected signal, TDR makes it possible to locate the failure. In this study, TDR was used to detect the water leakage at a pipe joint. A wire attached to the pipe surface was soaked by water when a leak occurred, which affected the characteristic impedance of the wet part, resulting in a change in the reflected signal. To infer the leakage from the TDR signal, we first developed a finite difference time domain-based forward model that provided the output of the TDR signal given the configuration of the transmission line. Then, by solving the inverse problem, the locations of the leaks were found.

Electrochemical Performance of Activated Carbon Electrode Materials with Various Post Treatments for EDLC (활성탄의 후 처리에 의한 EDLC 전극재의 전기화학 성능 개선)

  • Lee, Eunji;Kwon, Soon Hyung;Choi, Pooreum;Jung, Ji Chul;Kim, Myung-Soo
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.285-292
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    • 2014
  • Commercial activated-carbon used as the electrode material of an electric double-layer capacitor (EDLC) was posttreated with various acids and alkalis to increase its capacitance. The carbon samples prepared were then heat-treated in order to control the amount of acidic functional groups formed by the acid treatments. Coin-type EDLC cells with two symmetric carbon electrodes were assembled using the prepared carbon materials and an organic electrolyte. The electrochemical performance of the EDLC was measured by galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the various activated carbons, the carbon electrodes (CSsb800) prepared by the treatments of coconutshell-based carbon activated with NaOH and $H_3BO_5$, and then heat treated at $800^{\circ}C$ under a flow of nitrogen gas, showed relatively good electrochemical performance. Although the specific-surface-area of the carbon-electrode material ($1,096m^2/g$) was less than that of pristine activated-carbon ($1,122m^2/g$), the meso-pore volume increased after the combined chemical and heat treatments. The specific capacitance of the EDLC increased from 59.6 to 74.8 F/g (26%) after those post treatments. The equivalent series resistance of EDLC using CSsb800 as electrode was much lower than that of EDLC using pristine activated carbon. Therefore, CSsb800 exhibited superior electrochemical performance at high scan rates due to its low internal resistance.

Artificial Magnetic Conductor(AMC) Polarizer Backed Circular-Polarized(CP) Antenna (인공 자기 도체 편파 변환기를 이용한 원형 편파 안테나)

  • Chang, Ki-Hun;Ahn, Ji-Hwan;Yoon, Young-Joong
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.5
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    • pp.459-467
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    • 2010
  • A new type of circularly polarized(CP) antenna that is characterized by having both low-profile and greater axial-ratio bandwidth(ARBW) beyond existing antennas is introduced through analysis of artificial magnetic conductor(AMC) polarizer, and experimentally demonstrated. Although it is made use of a linear-polarized dipole antenna with close proximity to ground plane, it is backed by AMC polarizer so as to efficiently radiate with circularly changed polarization whose ARBW is determined by the texture geometry, whereas existing antennas exhibit CP surface-current on radiators, which limit ARBW. The mechanism of the polarization conversion is theoretically analyzed for ARBW, and the experimental properties including the impedance matching, CP radiation pattern, axial-ratio pattern, ARBW, and two-port isolation are discussed.

Influences of Body Fluid on Crossed Thermal Effects (체수분이 교차성 열효과에 미치는 영향)

  • Lee, Sang-Un;Kanazawa, Yoshinori;Kim, Yong-Kwon
    • Journal of Korean Physical Therapy Science
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    • v.9 no.2
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    • pp.151-157
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    • 2002
  • This study examined the changes in body temperature through conductive heat applied to the body and clarified the influences of body fluid on the thermal effects. Body fluid was measured using the Segmental Bioelectrical Impedance Analysis method. The subjects consisted of 13 men and 14 women. TBW was 37.56 (4.35 L for men and 29.93 (3.12 L for women, with the former being significantly (p<0.01) higher. The amount of body fluid in the right and left legs was 6.46 (0.83 L and 6.39 (0.86 L for men and 4.78 (0.49 L and 4.78 (0.49 L for women, respectively, with men's values being significantly (p<0.01) higher than women's on both the right and left sides. The maximal change in the surface temperature was 33.93 (0.61(C at the start of a warm bath to 3407 (0.61(C after 14 min for men. In contrast, the maximal change was 33.38 (0.99(C at the start to 33.73 (0.86(C after 18 min for women. For the other sites, the maximal temperature in Depths 1 and 2 was attained earlier for men than for women. The decrease in body temperature after the end of warming was more remarkable for men. Men had fluid with a higher conductivity than women, indicating influences of body fluid on the changes in body temperature. There were few changes in body composition with a partial bath having a crossed effect, indicating that this is a safe therapeutic method for elderly people.

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Experimental Study on Corrosion and Thermal Conductivity Characteristics of Thermal Spray Coating for Sea Water Heat Exchanger (해수용 열교환기 적용을 위한 열분사 코팅의 부식 및 열전도 특성에 관한 실험적 연구)

  • Cho, Meang-Ik;Huh, Cheol;Kwon, Young-Chul;Kwon, Jeong-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6098-6105
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    • 2013
  • In the present study, the characteristics of corrosion and thermal conductivity of thermal spray coatings for seawater heat exchangers were examined experimentally. The coating types of theZn and Al thermal spray coatings with additional epoxy and silicone sealers were tested. To examine the corrosion characteristics of the thermal spray coating, the cyclic voltamogram curve was measured followed by SEM imaging for surface characterization. The laser flash method was usedto measure the thermal conductivity of the specimen. The conductivity test results showed that thermal conductivity decreased by3 ~ 4% with the silicone sealer and decreased by 70 ~ 75% with the epoxy sealer.

Preparation and capacitance properties of graphene based composite electrodes containing various inorganic metal oxides

  • Kim, Jeonghyun;Byun, Sang Chul;Chung, Sungwook;Kim, Seok
    • Carbon letters
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    • v.25
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    • pp.14-24
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    • 2018
  • Electrochemical properties and performance of composites performed by incorporating metal oxide or metal hydroxide on carbon materials based on graphene and carbon nanotube (CNT) were analyzed. From the surface analysis by field emission scanning electron microscopy and field emission transmission electron microscopy, it was confirmed that graphene, CNT and metal materials are well dispersed in the ternary composites. In addition, structural and elemental analyses of the composite were conducted. The electrochemical characteristics of the ternary composites were analyzed by cyclic voltammetry, galvanostatic charge-discharge tests, and electrochemical impedance spectroscopy in 6 M KOH, or $1M\;Na_2SO_4$ electrolyte solution. The highest specific capacitance was $1622F\;g^{-1}$ obtained for NiCo-containing graphene with NiCo ratio of 2 to 1 (GNiCo 2:1) and the GNS/single-walled carbon $nanotubes/Ni(OH)_2$ (20 wt%) composite had the maximum specific capacitance of $1149F\;g^{-1}$. The specific capacitance and rate-capability of the $CNT/MnO_2/reduced$ graphene oxide (RGO) composites were improved as compared to the $MnO_2/RGO$ composites without CNTs. The $MnO_2/RGO$ composite containing 20 wt% CNT with reference to RGO exhibited the best specific capacitance of $208.9F\;g^{-1}$ at a current density of $0.5A\;g^{-1}$ and 77.2% capacitance retention at a current density of $10A\;g^{-1}$.

Enhancing Effects of NaHSO3 on Corrosion of T91 Steel

  • Wu, Tangqing;Tan, Yao;Wang, Jun;Xu, Song;Liu, Lanlan;Feng, Chao;Yin, Fucheng
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.368-378
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    • 2020
  • In the paper, corrosion behavior of T91 steel in different concentrations of NaHSO3 solution was studied in combination with scanning electron microscope (SEM) and electrochemical measurements. The results showed that the steel exhibited active anodic dissolution characteristics in the solution, and NaHSO3 concentration affected both cathodic and anodic behaviors. The steel surface was covered by intact corrosion products in the solutions, but the compactness and mechanical properties of the corrosion products degraded with the increase of NaHSO3 concentration. In low-concentration NaHSO3 solution the steel tended to undergo uniform corrosion with slight corrosion pits, but its corrosion mode gradually transited to localized corrosion as the NaHSO3 concentration increased. The mechanical property degradation of the corrosion products caused by sulfur compounds and the pH decrease of the solution are the important factors to accelerating its corrosion process.

Improved ILDC Formulation for Very Thin Gap/Crack (아주 가는 균열의 산란 해석을 위한 향상된 ILDC 공식)

  • Lee, Hyunsoo;Koh, Il-Suek
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.9
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    • pp.938-943
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    • 2014
  • The scattered field by a gap/crack on the PEC surface of a large object having low-observable RCS cannot be negligible, but may not be analyzed by the known high-frequency technique. If the electrical width of the crack is very small, the crack can be modeled by an impedance strip, whose scattering formulation can be analytically obtained based on a low-frequency approximation. The scattering solution is formulated for the 2D strip and TE(Transverse Electric) or TM(Transverse Magnetic) wave incidence, from which a 3D ILDC(Incremental Length Diffraction Coefficients) can be extracted. Using the ILDC formulation, the scattering by any arbitrary shaped crack can be estimated. In this paper, an improved ILDC equations are proposed, which combine the known TE and TM solutions. The improved accuracy of the proposed solution is numerically verified.