• Title/Summary/Keyword: surface groups

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Adsorption of Ammonia on the Sulfuric Acid Treated ACF

  • Kim, K.H.;Shin, C.S.
    • Carbon letters
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    • v.2 no.2
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    • pp.109-112
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    • 2001
  • For the adsorption of ammonia, activated carbon fibers (ACFs) were subjected to sulfuric acid treatment in order to modify the surface functional groups. The surface acid and base value of ACFs were measured using titration and FT-IR spectrometry. SEM was used to investigate the surface morphology. Acid treatments by $H_3PO_4$, $H_2SO_4$, and $HNO_3$ were performed to increase the adsorption capacity of $NH_3$. As a result, Cellulose-based ACF has high adsorption capacity for ammonia. The ammonia removal efficiency of ACF was the maximum which was treated by 15 wt% sulfuric acid at $100^{\circ}C$ for 60 min. The average pore diameter little increased from $19{\AA}$ to $20.8{\AA}$ and the specific surface area of ACF considerably decreased and acid values increased by 15 wt% sulfuric acid treatment. Ammonia reacted with sulfonyl radicals. After adsorption of ammonia, white material was grown on the surface of ACF through the adsorption of ammonia and it was determined to ammonium sulfate.

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The Effect of Plasma Treatment on Surface Properties and Adhesion Characteristics of semiconductive Silicone Rubber (반도전성 실리콘 고무의 표면 특성과 접착특성에 미치는 플라즈마 처리의 영향)

  • Hwang, Sun-Mook;Hong, Joo-Il;Hwang, Cheong-Ho;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.254-255
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    • 2005
  • In this work, the effects of plasma treatment on surface properties of semi conductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy(XPS). The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths. As a result, semiconductive silicone rubber surfaces treated with plasma discharge led to and increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. these results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semi conductive silicone rubber.

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Effects of SLA surface treated with NaOH on surface characteristics and response of osteoblast-like cell (염기처리한 SLA 표면이 표면 특성 및 골모유사세포의 반응에 미치는 영향)

  • Park, Jin-Chul;Kim, Joo-Hyeun;Kang, Eun-Sook;Ryu, Jae-Jun;Huh, Jung-Bo
    • The Journal of Korean Academy of Prosthodontics
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    • v.52 no.3
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    • pp.211-221
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    • 2014
  • Purpose: The purpose of this study was to evaluate the surface characteristics and response of osteoblast-like cell at SLA surface treated with NaOH. Materials and methods: Three kinds of specimens were fabricated for the experiment groups. Control group was a machined surface, SLA group was a conventionally SLA treated surface, and SLA/NaOH gorup was SLA surface treated with NaOH. To evaluate the surface characteristics, the surface elemental composition (XPS), surface roughness and surface contact angle were evaluated in each group. And the cytotoxicity, cell adhesion, cell proliferation and ATP activity of osteoblast-like cells (MG-63 cells) were compared in each group for evaluatation of the cell responses. Statistical comparisons between groups were carried out via one-way ANOVA using the SPSS software (SPSS Inc., Chicago, USA), and then performed multiple comparisons. The differences were considered statistically significant at P<.05. Results: SLA surface treated with NaOH (SLA / NaOH group) was changed to hydrophilic surface. All groups did not show the cytotoxicity to the MG-63. In cell adhesion studies, SLA / NaOH group showed the higher degree of adhesion than anothers (P<.05), Up to 7 days of incubation, the proliferation was showed the increasing tendency in all groups but SLA / NaOH group showed the highest cell proliferation between the three groups (P<.05). At 7 days of incubation, there was no difference in ALP activities between the three groups, but at 14 days, SLA / NaOH group showed significant increase in ALP activities (P<.05). Conclusion: In this study, SLA surface treated with NaOH promoted cell adhesion, proliferation and differentiation. It means that SLA/NaOH group is possible to promote osseointegration of implants.

AN EXPERIMENTAL STUDY ON BOND STRENGTH OF GLASSIONOMER CEMENT TO DENTIN SURFACE FOLLOWING ACID TREATMENT (산처리(酸處理)에 따른 상아질(象牙質)에 대한 Glassionomer Cement의 접착강도(接着强度)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Lee, Won-Seob;Min, Byung-Soon;Choi, Ho-Young;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.13 no.1
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    • pp.123-129
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    • 1988
  • The purpose of this study was to evaluate the bond strength of glassionomer cement against cut dentin surface which was treated with various surface cleaning agents. 48 freshly extracted human 3rd molars were ground flat through the enamel into the dentin using 600 grit silicone carbide paper under a flow of water. The were divided into four groups by the following cleaning procedure on cut dentin surface; Group I : No surface treatment after grinding with 600 grit silicone carbide paper as control group Group II : Surface treatment with 50% citric acid for 30 seconds. Group III : Surface treatment with 37% phosphoric acid for 30 seconds. Group IV : Surface treatment with 10% poly acrylic acid for 30 seconds. The specimens in 4 groups were immersed in distilled water at $37^{\circ}C$ for 24 hours before testing after cleanising with water-spray and drying with air. Bond strength was measured with Instron Universal Testing Machine (Autograph S-100, Shimadzu, Kyoto, JAPAN). The results were as follows: 1. The bond strengths of group II, III & IV were not seemed to be shown more significant improvement than a group I. 2. The bond strengths in groups which were treated with 50% citric acid, 37% phosphoric acid and 10% polycrylic acid, were ranked 24.70kg/$cm^2$, 22.02kg/$cm^2$ and 31.13kg/$cm^2$, but its difference was not significant, statistically.

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The Effects of Transverse Abdominis Ratio and Balance Ability during Bridge Exercises on Different Support Surface (지지면 변화에 따른 교각운동이 복횡근 두께와 균형능력에 미치는 영향에 관한 연구)

  • Ann, Jun-il;Kim, Yoon-hwan;Park, Jong-hang;Ann, Mi-rae;Jung, Yeon-woo;Kim, Tae-won
    • The Journal of Korean Academy of Orthopedic Manual Physical Therapy
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    • v.23 no.1
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    • pp.23-30
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    • 2017
  • Purpose: The purpose of this study was to investigate the effect of transverse abdominis ratio and balance ability during bridge exercises on different support surface. Methods: The subjects were 20 students at G University. Ultrasound equipment was used to measure the transverse abdominisratio and the computerized balance measurement equipment was used to measure the balance ability before and after bridge exercises on different support surface. Results: Transverse abdominis ratio change between the groups was a significant difference only in the unstable support surface training group (p<.05). Normal standing eye close balance ability change between the groups was significantly different only in the unstable support surface training group (p<.05). The changes in the transverse abdominis ratio after 7 days of exercise and 14 days after exercise were significantly different between the groups (p<.05). Normal standing eye close balance ability showed a significant difference at 7 days after exercise and 14 days after exercise (p<.05). Conclusions: It is more effective to balance ability and ratio of the transverse abdominis when bridge exercises on an unstable support surface than to perform bridge exercises on a stable support surface. Therefore, we propose an effective program for patients with instability of the lumbar in clinical practice. bridge exercises on different support surface.

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Shear bond strength analysis of PFM metal and zirconia with different surface condition (PFM metal과 zirconia의 표면상태에 따른 전단결합강도 분석)

  • Jung, Jae-Kwan;Kim, Kyung-Ah;Lee, Su-Ok;Kim, Ki-Baek;Kim, Jae-Hong;Kim, Il-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4329-4335
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    • 2014
  • This study examined the effects of the shear bond strength when the surface condition of the metal and zirconia, each being the lower structures, was different when determining the bond strength (metal group) of the metal lower structure with upper ceramics, and the shear bond strength (zirconia group) of zirconia lower structure with the upper ceramics in prosthetic appliances of metal-ceramic crown and zirconia-ceramic crowns. The metal groups were divided into a total of four groups: the group with no condition on the metal surface(NM), the group with sand-blasting(SM), the group with applied opaque ceramics(OM), and the group with applied opaque ceramics and sand-blasting(SOM). The zirconia groups were also separated into four groups: the group with no condition(NZ), the group with sand-blasting(SZ), the group treated with ZirLiner on the zirconia surface(LZ), and the group applied with ZirLiner along and sand-blasting(SLZ). To examine the effects on the shear bond strength according to the surface condition of each of the four metal and zirconia groups, SPSS was used to conduct one-way ANOVA. For metal-ceramic crowns, it would be best to apply opaque ceramics after sand-blasting on the surface of the metal, the lower structure. For zirconia-ceramic crowns, it is recommended to apply the ZirLiner after sand-blasting on the surface of zirconia, the lower structure.

Physical Properties of Mercaptopyruvic-acid Layer Formed on Gold Surfaces

  • Park, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2611-2616
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    • 2011
  • We studied the physical properties of the mercaptopyruvic-acid layer formed on gold surfaces, which has the interactions with the titanium dioxide surface for design of gold- titanium dioxide distribution. Surface force measurements were performed, using the atomic force microscope (AFM), between the surfaces as a function of the salt concentration and pH value. The forces were analyzed with the DLVO (Derjaguin-Landau-Verwey-Overbeek) theory, to evaluate the potential and charge density of the surfaces quantitatively for each salt concentration and each pH value. The difference in the properties reflected the effect of the isoelectric point on the surface forces. The forces were interpreted for the evaluation with the law of mass action and the ionizable groups on the surface. The salt concentration dependence of the surface properties, found from the measurement at pH 8.0, was consistent with the prediction from the law. It was found that the mercaptopyruvic-acid layer had higher values for the surface charge densities and potentials than the titanium dioxide surfaces at pH 8, which may be attributed to the ionized-functional-groups of the mercaptopyruvic-acid layer.

The effect of various polishing systems on surface roughness and phase transformation of monolithic zirconia

  • Caglar, Ipek;Ates, Sabit Melih;Duymus, Zeynep Yesil
    • The Journal of Advanced Prosthodontics
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    • v.10 no.2
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    • pp.132-137
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    • 2018
  • PURPOSE. The purpose of this study was to evaluate and compare three polishing systems on the surface roughness and phase transformation of monolithic zirconia. MATERIALS AND METHODS. 100 disk shaped specimens (10 mm diameter, 3 mm thickness) were fabricated from monolithic zirconia blocks. 20 specimens were left as a control group and remaining specimens were grinded by diamond bur to simulate the occlusal adjustments. Grinded specimens were randomly divided into 4 groups: group G (no polishing), group M (Meisinger, zirconia polishing kit), group E (EVE Diacera, zirconia polishing kit), and group P (EVE Diapol, porcelain polishing kit). Surface roughness was measured with profilometer and surface topography was observed with SEM. XRD analysis was performed to investigate the phase transformation. Statistical analysis was performed with one-way ANOVA and Tukey's post hoc tests at a significance level of P=.05. RESULTS. All polishing groups showed a smoother surface than group G. Among 3 polishing systems, group M and group E exhibited a smoother surface than the group P. However, no significant differences were observed between group M and group E (P>.05). Grinding and polishing did not cause phase transformations in zirconia specimens. CONCLUSION. Zirconia polishing systems created a smoother surface on zirconia than the porcelain polishing system. Phase transformation did not occur during the polishing procedure.

Optical Properties of PVA Polarizing Films Surface-modified by UV Irradiation (자외선 조사에 의해 표면 개질된 PVA 편광필름의 광학특성)

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.18 no.6 s.91
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    • pp.49-56
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    • 2006
  • Surface treatment using UV irradiation was carried out to improve optical properties of polarizing films. The effects of UV energy of the UV-treated PVA films were investigated by measuring reflectance, surface roughness, contact angles, ESCA, and ATR. Reflectance decreased at wavelength of 450 nm or less and surface roughness increased with increasing UV energy. Water contact angle increased in the irradiated PVA films and surface energy decreased with increase in w energy. An analysis showed that the OH groups were broken and some new groups were introduced such as C=C and C=O bonds together with increased $O_{1s}/C_{1s}$, resulting in the observed surface modification effect. Surface modified PVA polarizing films showed improvement in light transmittance of polarizing films at high wavelength region without deteriorating polarization efficiency, which was not affected by UV irradiation sequence during manufacturing processes such as coloring and drawing.

Influence of Grease Consistency on the Wear of Gear Surfaces

  • Li, Chen-Xiao;Park, Haneum;Lee, Chul-Hee
    • Tribology and Lubricants
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    • v.38 no.3
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    • pp.115-119
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    • 2022
  • This paper selected three kinds of grease with the same type but different consistency for the experiment. The purpose of the experiment is tested the effect of different consistency of grease on the wear of the gear surface. Different torque test groups were selected in the test, and the lubrication effect of different greases was tested in the test groups with the same torque. After each set of tests, the wear of the gear surfaces was observed and recorded. The data recorded in the experiment included the area of the wear area on the gear surface, the type of wear and the volume of wear. After the test, the gear surface roughness was measured. By calculating the wear volume, the effects of different concentrations of grease on the gear surface wear were compared. The experimental results show that under different stress conditions, the consistency of the grease has a great influence on the lubricating effect of the gear surface and the gear wear. Under the condition with low speed and high torque, different grease consistency affect the gear surface wear, the high consistency grease can reduce the wear of the gear surface, so that the gear can get better lubrication effect during the work.