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Effects of Addition of Sulfuric Acid on the Etching Behavior of Al foil for Electrolytic Capacitors II. Microstructures of Dielectric Layers and AC Impedance Analysis (전해 콘텐사용 알루미늄박의 애칭특성에 미치는 황산첨가의 영향 II. 유전층의 조직 및 임피던스 분석)

  • Kim, Seong-Gap;Yu, In-Jong;Sin, Dong-Cheol;O, Han-Jun;Ji, Chung-Su
    • Korean Journal of Materials Research
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    • v.10 no.5
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    • pp.375-381
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    • 2000
  • Aluminium foil for electrolytic capacitors was anodized at the voltage of 100V and 140V for 10 minutes in ammonium adipate solution to form aluminum oxide layer on aluminum substrate as an dielectric film. The thickness, the stoichiometry and the crystal structure of the layer were investigated by using RBS and TEM . In addition EIS technique was employed to study the effects of addition of sulfuric acid on the increment of the foil surface area. It was found that the thickness values of the layers anodized at 100V and 140V were about 130 nm and 190 nm respectively and the stoichiometry of the elements of aluminum and oxygen was 2:3. The anodic oxide layer was shown to be amorphous. but the structure irradiated with electron beam resulted in the transformation into crystalline structure of $${\gamma}$-Al_2$$O_3$ . From a comparison of the impedance results and the capacitance variation to investigate the ef- fects of sulfuric acid addition to the etching bath of hydrochloric acid, the EIS techinque could be useful to analyze the capacitance variation.

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Identification and Pathogenicity of Colletotrichum Species Causing Anthracnose of Korean Radish (Rhaphanus sativus) in Korea (무 탄저병을 일으키는 Colletotrichum속의 종 동정 및 병원성)

  • Choi, Hyo-Won;Kim, Jeomsoon;Hong, Sung Kee;Lee, Young Kee
    • The Korean Journal of Mycology
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    • v.47 no.4
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    • pp.393-406
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    • 2019
  • In August 2017, anthracnose symptoms were observed on the petioles and leaf veins of Korean radish (Rhaphanus sativus) in Hongcheon, Jeongseon, and Pyeongchang of the Gangwon province, Korea. Many grayish to dark-brown spots of 1-2 mm in diameter, appeared on the lower surface and leaf veins of the radish leaves. The spots gradually enlarged and coalesced to form dark-brown irregular lesions. Ten Colletotrichum isolates were obtained from the affected tissues of the Korean radish. Out of them, eight isolates were identified as C. higginsianum and two isolates were identified as C. truncatum based on morphological characteristics and multi-locus molecular phylogenetic analysis using the internal transcribed spacers and intervening 5.8S rDNA (ITS), partial beta-tubulin gene (TUB2), partial actin gene (ACT), and partial chitin synthase-1 gene (CHS1). The pathogenicity test was carried out on wounded and unwounded Korean radish (cv. Siraegimu and Osarimu), and Chinese cabbage (cv. Chuno and Smart) by inoculating with a spore suspension. All isolates except one C. truncatum isolate developed typical symptoms on both wounded and unwounded Korean radish. In Chinese cabbage, only the plants inoculated with C. higginsianum isolates developed symptoms regardless of the wound. This is the first report of anthracnose caused by C. truncatum on Korean radish in Korea.

THE PHYSCIAL PORPERTIES OFY Y2O3-CONTAINING GLASS INFILTRATED ALUMINA CORE MADE BY PRESSURELESS POWDER PACKING METHOD (무가압 분말충전 알루미나에 이트리아를 함유한 붕규산염 유리를 침투시킨 코아 도재의 물성)

  • Whang, Seung-Woo;Lee, Keun-Woo
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.1
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    • pp.221-243
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    • 1997
  • The objective of this study was to characterize the mechanical properties of $Y_{2}O_{3}$-containing glass infiltrated ceramic core material, which was made by pressureless powder packing method. A pure alumina powder with a grain size of about $4{\mu}m$ was packed without pressure is silicon mold to form a bar shaped sample, and applied PVA solution as a binder. Samples were sinterd at $1350^{\circ}C$ for 1 hour. After cooling, $Y_{2}O_{3}$-containing glass($SiO_{2},\;Y_{2}O_{3},\;B_{2}O_{3},\;Al_{2}O_{3}$, ect) was infiltrated to the sinterd samples at $1300^{\circ}C$ for 2 hours and cooled. Six different proportions $Y_{2}O_{3}$ of were used to know the effect of the mismatch of the thermal expansion coefficient between alumina powder and glass. The samples were ground to $3{\times}3{\times}30$ mm size and polished with $1{\mu}m$ diamond paste. Flexural strength, fracture toughness, hardness and other physical properties were obtained, and the fractured surface was examined with SEM and EPMA. Ten samples of each group were tested and compared with In-Ceram(tm) core materials of same size made in dental laboratory. The results were as follows : 1. The flexural strengths of group 1 and 3 were significantly not different with that of In-Ceram, but other experimental groups were lower than In-Ceram. 2. The shrinkage rate of samples was 0.42% after first firing, and 0.45% after glass infiltration. Total shrinkage rate was 0.87%. 3. After first firing, porosity rate of experimental groups was 50%, compared with 22.25% of In-Ceram. After glass infiltration, porosity rate of experimental groups was 2%, and 1% in In-Ceram. 4. There was no statistical difference in hardness between two materials tested, but in fracture toughness, group 2 and 3 were higher than In-Ceram. 5. The thermal expansion coefficients of experimental groups were varied to $4.51-5.35{\times}10^{-6}/^{\circ}C$ according to glass composition, also the flexural strengths of samples were varied. 6. In a view of SEM, many microparticles about $0.5{\mu}m$ diameter and $4{\mu}m$ diameter were observed in In-Ceram. But in experimental group, the size of most particles was about $4{\mu}m$, and a little microparticles was observed. The results obtained in this study showed that the mismatch of the thermal expansion coefficients between alumina powder and infiltrated glass affect the flexural strength of alumin/glass composite. The $Y_{2}O_{3}$-containing glass infiltrated ceramic core made by powder packing method will takes less time and cost with sufficient flexural strength similar to all ceramic crown made with slip casting technique.

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Ovipositional Characteristics of the Ussur Brown Katydid, Paratlanticus ussuriensis (Orthoptera: Tettigoniidae) (갈색여치(Paratlanticus ussuriensis)의 산란 특성)

  • Bang, Hea-Son;Na, Young-Eun;Han, Min-Su;Kim, Myung-Hyun;Roh, Kee-An;Lee, Jung-Taek
    • Korean Journal of Environmental Agriculture
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    • v.27 no.3
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    • pp.274-278
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    • 2008
  • Paratlanticus ussuriensis oviposited from early July to mid-September under laboratory condition. A female laid on average 145 eggs during the period of reproduction and over 54% of the eggs were laid within 2 weeks after the first laying. The average depth of egg-laying in soil was 19.4 mm under surface. The average major axis of an egg was 5.7 mm and the minor axis was 2.0 mm. Just before hatching, the egg swelled about twice the weight of a newly laid. In tests of ovipositional preference in different types of media, more eggs were laid in soil than in vermiculite or in $Oasis^{(R)}$ floral form. Females also prefer shaded places in the field for reproduction, away from sunshine. In terms of the strategy for egg survival, adult moves to the hill-side adjacent to orchard farm to find a proper place for their egg laying and its survival in winter.

Characteristics of Trigeminal Evoked Potential and It's Pathway in the Rat (백서에서 삼차신경 유발전위의 특성과 경로 분석)

  • Kim, Se-Hyuk;Zhao, Chun-Zhi;Kwon, Oh-Kyoo;Lee, Bae-Hwan;Park, Yong-Gou;Chung, Sang-Sup
    • Journal of Korean Neurosurgical Society
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    • v.29 no.8
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    • pp.985-994
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    • 2000
  • Objective : There are some advantages of trigeminal evoked potential(TEP) recording compared to other somatosensory evoked potential(SSEP) recordings. The trigeminal sensory pathway has a pure sensory nerve branch, a broader receptive field in cerebral cortex, and a shorter pathway. Despite these advantages, there is little agreement as to what constitutes a normal response and what wave forms truly characterize the intraoperative TEP. This study presents the normative data of TEP recorded on the epidural surface of the rat with a platinum ball electrode. Materials & Methods : Under general anesthesia with urethane, the adult Sprague-Dawley male rats(300-350g) were given electrical stimulation with two stainless steel electrodes which were inserted into the subcutaneous layer of the area around whiskers. A reference electrode was positioned in the temporalis muscle ipsilateral to the recording site. Results : TEPs were recorded in the Par I area of somatosensory cortex and recorded most apparently on the point of 2mm posterior from the bregma and 6mm lateral from the midline. The typical wave form consisted of 5 peaks (N1-P1-N2-P2-N3 according to emerging order, upward negativity). Each latency to corresponding peaks was not influenced by the different intensities of stimulation, especially from 1 to 5mA. Average latencies of 5 peaks were in the following order ; 7.7, 11.1, 15, 22.3, 29.4ms. There was also no significant difference between latencies before and after administration of muscle relaxant(pancuronium). For the electrophysiological localization of recorded waves, the action potential of a single unit was recorded with glass microelectrode(filled with 2M NaCl, $3-5M{\Omega}$) in the thalamus of rat. A sharp wave was recorded in the VPM nucleus, in which the latency was shorter than that of N1. This suggests that all 5 peaks were generated by neural activities in the suprathalamic pathway. Conclusion : In terms of recording near-field potentials, our data also suggests that TEP in the rat may be superior to other SSEPs. In overall, these results may afford normative data for the studies of supratentorial lesions such as hydrocephalus or cerebral ischemia which can have an influence on near-field potentials.

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Occurrence and Genesis of Obsidian in Gombawi Welded Tuff, Ulleung Island, Korea (울릉도 곰바위용결응회암 내 흑요암의 산출특징과 성인)

  • Im, Ji Hyeon;Choo, Chang Oh
    • Economic and Environmental Geology
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    • v.50 no.2
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    • pp.105-116
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    • 2017
  • The purpose of this study is to provide the information on genesis of obsidian occurring in the southwestern part of Ulleung Island, Korea, and to discuss its implications for volcanic activity through volcanological and mineralogical properties of obsidian. Obsidian occurs locally at the lower part of the Gombawi welded tuff, showing various complex textures and flow banding. Though obsidian is mostly homogeneous, it is closely associated with alkali feldspar phenocrysts, reddish tuff, and greyish trachyte fragments. The obsidian occurs as wavy, lenticular blocks or lamination composed of fragments. Cooling fractures developed on obsidian glass are characterized by perlitic cracks, orbicular or spherical cracks, indicating that obsidian rapidly quenched to form an amorphous silica-rich phase. It is evident that hydration took place preferentially at the outer rim relative to the core of obsidian, forming alteration rinds. The glassy matrix of obsidian includes euhedral alkali feldspars, diopside, biotite, ilmenite, and iron oxides. Microlites in glassy obsidian are composed mainly of alkali feldspars and ilmenite. Quantitative analysis by EPMA on the obsidian glass part shows trachytic composition with high iron content of 3 wt.%. Accordingly, obsidian formed with complex textures under a rapid cooling condition on surface ground, with slight rheomorphism. Such results might be induced by collapse of lava dome or caldera, which produced the block-and-ash flow deposit and the transportation into valley while keeping high temperatures.

Review of the CO2 Geological Storage Using Nanoparticle-stabilized CO2 Foam (나노입자기반 CO2 폼을 이용한 CO2 지중저장에 대한 기술적 고찰)

  • Son, Han Am
    • Economic and Environmental Geology
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    • v.53 no.2
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    • pp.213-220
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    • 2020
  • When CO2 foam is injected into the saline aquifer, the relative permeability of CO2 decreases and its viscosity increases, thereby reducing mobility in porous media and ultimately improving CO2 storge with enhanced sweep efficiency. In general, surfactants were used to fabricate CO2 foam. Recently, nanoparticles have been used to form stable foam than surfactant. This paper introduces CO2 storage technology using nanoparticle stabilized CO2 foam. If the surface of the hydrophilic nanoparticles is partially modified into a CO2-philic portion, the particles have an affinity for CO2 and water, thus forming a stable CO2 foam even in deep saline aquifers under high temperature and high salinity conditions, thereby it can be stored in the pores of the rock. In terms of economics, injection method using nanopaticle-stabilized CO2 foam is more expensive than the conventional CO2 injection, but it is estimated that it will have price competitiveness because the injection efficiency is improved. From an environmental point of view, it is possible to inject chemical substances such as surfactants and nanomaterials into aquifers or reservoirs for specific purposes such as pollutant removal and oil production. However, some studies have shown that nanoparticles and surfactants are toxic to aquatic animals, so environmentally proven substances should be used. Therefore, further research and development will be needed to study the production and injection of nanoparticle-stabilized CO2 foam that are environmentally safe and economically reasonable.

Effects of N-/C-Terminal Extra Tags on the Optimal Reaction Conditions, Activity, and Quaternary Structure of Bacillus thuringiensis Glucose 1-Dehydrogenase

  • Hyun, Jeongwoo;Abigail, Maria;Choo, Jin Woo;Ryu, Jin;Kim, Hyung Kwoun
    • Journal of Microbiology and Biotechnology
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    • v.26 no.10
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    • pp.1708-1716
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    • 2016
  • Glucose dehydrogenase (GDH) is an oxidoreductase enzyme and is used as a biocatalyst to regenerate NAD(P)H in reductase-mediated chiral synthesis reactions. In this study, the glucose 1-dehydrogenase B gene (gdhB) was cloned from Bacillus thuringiensis subsp. kurstaki, and wild-type (GDH-BTWT) and His-tagged (GDH-BTN-His, GDH-BTC-His) enzymes were produced in Escherichia coli BL21 (DE3). All enzymes were produced in the soluble forms from E. coli. GDH-BTWT and GDH-BTN-His showed high specific enzymatic activities of 6.6 U/mg and 5.5 U/mg, respectively, whereas GDH-BTC-His showed a very low specific enzymatic activity of 0.020 U/mg. These results suggest that the intact C-terminal carboxyl group is important for GDH-BT activity. GDH-BTWT was stable up to 65℃, whereas GDH-BTN-His and GDH-BTC-His were stable up to 45℃. Gel permeation chromatography showed that GDH-BTWT is a dimer, whereas GDH-BTN-His and GDH-BTC-His are monomeric. These results suggest that the intact N- and C-termini are required for GDH-BT to maintain thermostability and to form its dimer structure. The homology model of the GDH-BTWT single subunit was constructed based on the crystal structure of Bacillus megaterium GDH (PDB ID 3AY6), showing that GDH-BTWT has a Rossmann fold structure with its N- and C-termini located on the subunit surface, which suggests that His-tagging affected the native dimer structure. GDH-BTWT and GDH-BTN-His regenerated NADPH in a yeast reductase-mediated chiral synthesis reaction, suggesting that these enzymes can be used as catalysts in fine-chemical and pharmaceutical industries.

Aluminum Powder Metallurgy Current Status, Recent Research and Future Directions

  • Schaffer, Graham
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2001.11a
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    • pp.7-7
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    • 2001
  • The increasing interest in light weight materials coupled to the need for cost -effective processing have combined to create a significant opportunity for aluminum P/M. particularly in the automotive industry in order to reduce fuel emissions and improve fuel economy at affordable prices. Additional potential markets for Al PIM parts include hand tools. Where moving parts against gravity represents a challenge; and office machinery, where reciprocating forces are important. Aluminum PIM adds light weight, high compressibility. low sintering temperatures. easy machinability and good corrosion resistance to all advantages of conventional iron bm;ed P/rv1. Current commercial alloys are pre-mixed of either the AI-Si-Mg or AL-Cu-Mg-Si type and contain 1.5% ethylene bis-stearamide as an internal lubricant. The powder is compacted in closed dies at pressure of 200-500Mpa and sintered in nitrogen at temperatures between $580~630^{\circ}C$ in continuous muffle furnace. For some applications no further processing is required. although most applications require one or more secondary operations such as sizing and finishing. These sccondary operations improve the dimension. properties or appearance of the finished part. Aluminum is often considered difficult to sinter because of the presence of a stable surface oxide film. Removal of the oxide in iron and copper based is usually achieved through the use of reducing atmospheres. such as hydrogen or dissociated ammonia. In aluminum. this occurs in the solid st,lte through the partial reduction of the aluminum by magncsium to form spinel. This exposcs the underlying metal and facilitates sintering. It has recently been shown that < 0.2% Mg is all that is required. It is noteworthy that most aluminum pre-mixes contain at least 0.5% Mg. The sintering of aluminum alloys can be further enhanced by selective microalloying. Just 100ppm pf tin chnnges the liquid phase sintering kinetics of the 2xxx alloys to produce a tensile strength of 375Mpa. an increilse of nearly 20% over the unmodified alloy. The ductility is unnffected. A similar but different effect occurs by the addition of 100 ppm of Pb to 7xxx alloys. The lend changes the wetting characteristics of the sintering liquid which serves to increase the tensile strength to 440 Mpa. a 40% increase over unmodified aIloys. Current research is predominantly aimed at the development of metal matrix composites. which have a high specific modulus. good wear resistance and a tailorable coefficient of thermal expnnsion. By controlling particle clustering and by engineering the ceramic/matrix interface in order to enhance sintering. very attractive properties can be achicved in the ns-sintered state. I\t an ils-sintered density ilpproaching 99%. these new experimental alloys hnve a modulus of 130 Gpa and an ultimate tensile strength of 212 Mpa in the T4 temper. In contest. unreinforcecl aluminum has a modulus of just 70 Gpa.

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A Study on Ventilation System of Underground Low-Intermediate Radioactive Waste Repository (지하 동굴식 중-저준위 방사성 폐기물 처분장의 환기시스템 고찰)

  • Kim, Young-Min;Kwon, O-Sang;Yoon, Chan-Hoon;Kwon, Sang-Ki;Kim, Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.65-78
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    • 2007
  • The pollutants (Rn, CH, CO, HS, radioactive gas from radiolysis) were generated from the process of construction and operation of underground repository, and after disposal of low-intermediate radioactive waste inside there must be controlled by a ventilation system to distribute them in area where enough air is supported. Therefore, a suitable technical approach is needed especially at an underground repository that is equipped with many entry tunnels, storage tunnels, exhaust-blowing tunnels, and vertical shafts in complicated network form. For the technical approach of such a ventilation system, WIPP (Waste Isolation Pilot Plant) in U. S and SFR (Slutforvar for Reaktorafall) low-intermediate radioactive waste repository in Sweden were selected as the models, for calculating the required air quantity, organizing a ventilation network considering cross section, length, surface roughness of the air passage, and describing a calculation of resistance of each circuit. Based on these procedures, a best suited ventilation system was completed with designing proper capacity of fans and operating plan of vertical shafts. As a result of comparing the two repositories based on the geometry dimensions and ventilation facility equipment operation, more parallel circuit as in WIPP, brought decrease in resistance for entire system leading to reduce of operating costs, and the larger cross-sectional area of the SFR, the greater the percentage of disposal capacity. Accordingly, the mixture of parallel circuit of WIPP repository for reducing resistance and SFR repository formation for enlargement of disposal capacity would be the most rational and efficient ventilation system.

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