• Title/Summary/Keyword: surface degradation

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Thermal degradation properties of blue emitting phosphor particles prepared by the spray pyrolysis for PDP (분무열분해공정에서 제조된 PDP용 청색형광체의 열화특성)

  • Kang, Yun-Chan;Lee, Dong-Youl;Park, Hee-Dong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1060-1062
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    • 2002
  • Spherical and dense BAM phosphor particles were prepared by spray pyrolysis. The key idea of dense BAM particles is to lead gelation in droplets, which was successfully achieved by using the aluminum polycation as the precursor solution for the spray pyrolysis. The BAM phosphor particles prepared by spraying the aluminum polycation solution have completely spherical shape and dense structure. When directly applied to make phosphor film on the glass by the screen-printing method, the prepared spherical BAM phosphor particles showed better packing density and surface morphology than that of commercial one, which has irregular shape and large particle size. It was also found that the thermal degradation in the photoluminescence intensity for dense and spherical BAM particles was less than that of commercial one.

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Preparation of Graphene-BiOCl/Fe3O4 Nanocomposites and Their Use as Photocatalysts for Organic Dyes Degradation

  • Zhang, Fuyong;Ko, Weon Bae
    • Elastomers and Composites
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    • v.52 no.1
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    • pp.9-16
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    • 2017
  • Graphene-$BiOCl/Fe_3O_4$ nanocomposites were synthesized from $BiOCl/Fe_3O_4$ and graphene in an electric furnace operating at $700^{\circ}C$ for 12 h. The nanocomposite surface morphology and crystal structure were characterized by scanning electron microscopy and X-ray diffraction. The produced graphene-$BiOCl/Fe_3O_4$ nanocomposites acted as efficient heterogeneous photocatalysts for the degradation of organic dyes, as confirmed by UV-vis spectrophotometry.

Effects of Rock Weathering on the Degradation of Engineering Properties (암반풍화도에 따른 지질공학적 특성 저감효과)

  • Lee Chang-Sup;Cho Taechin
    • Tunnel and Underground Space
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    • v.15 no.6 s.59
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    • pp.411-424
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    • 2005
  • Weathering is defined as a process by which surface rock, once formed in the deep ground, is broken down and altered to keep the equilibrium with the ambient environment. In this study granitic rock samples of different weathering grades were collected in the field and the microscopic observation, X-ray diffraction analysis, electron microscopic observation, chemical analysis, and rock property tests were carried out. Formation of secondary minerals, especially clay minerals, by weathering was identified and the mechanism for the change of engineering properties such as rock strength degradation was analyzed. Tunnel model test, Failure behaviour, Shallow tunnel, Unsupproted tunnel length.

A Study on the Environmental Degradation Factors and the Required Performance of the Waterproofing Materials Applied to Underground Structures in Residential Apartment Buildings- Survey Centered- (공동주택 지하구조물에 적용되는 방수재의 환경적 열화요인과 부위별 필요성능에 관한 연구-설문조사를 중심으로-)

  • An, Ki-Won;Kang, Hyo-Jin;Oh, Kyu Hwan;Kim, Soo-Yeon;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.213-214
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    • 2017
  • In this study, a survey was conducted to investigate the environmental degradation factors of specific areas in residential apartment underground structures an'd the required performance attributes for waterproofing material. Based on the survey, it was concluded that joint displacement of concrete is the highest cause for problems, and the required performance was determined to high wet surface adhesion performance for waterproofing materials.

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Development of the Advanced NDI Technique Using an Alternating Current : the Evaluation of surface crack and blind surface crack and the detection of defects in a field component (교류전류를 이용한 새로운 비파괴탐상법의 개발;표면결함과 이면결함의 평가 및 실기 부재의 결함 검출)

  • Kim. H.;Lim, J.K.
    • Journal of Welding and Joining
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    • v.13 no.2
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    • pp.42-52
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    • 1995
  • In the evaluation of aging degradation on the structural materials based on the fracture mechanics, the detection and size prediction of defect are very important. Aiming at nondestructive detection and size prediction ol defect with high accuracy and resolution, therefore, an lnduced Current Focusing Potential Drop(ICFPD) technique has been developed. The principle of this technique is to induce a focusing current at an exploratory region by an induction wire flowing an alternating current(AC) that is a constant ampere and frequency. Defects are assessed with the potential drops that are measured the induced current on the surface of metallic material by the potential pick-up pins. In this study, the lCFPD technique was applied for evaluating the location and size of the surface crack and blind crack made in plate specimens, and also for detecting the defects existing in valve, a field component, that were developed by SCC etc. during the service. The results of this present study show that surface crack and blind crack are able to defect with potential drop. these cracks are distinguished with the distribution of potential drop, and the crack depths can be estimated with each normalized potential drop that are parameters estimating the depth of each type crack. In the field component, the defects estimated by experiment result correspond with those in the cutting face of the measuring point within a higher sensitivity.

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Electrochemical modification of the porosity and zeta potential of montmorillonitic soft rock

  • Wang, Dong;Kang, Tianhe;Han, Wenmei;Liu, Zhiping;Chai, Zhaoyun
    • Geomechanics and Engineering
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    • v.2 no.3
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    • pp.191-202
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    • 2010
  • The porosity (including the specific surface area and pore volume-diameter distribution) of montmorillonitic soft rock (MSR) was studied experimentally with an electrochemical treatment, based on which the change in porosity was further analyzed from the perspective of its electrokinetic potential (${\zeta}$ potential) and the isoelectric point of the electric double layer on the surface of the soft rock particles. The variation between the ${\zeta}$ potential and porosity was summarized, and used to demonstrate that the properties of softening, degradation in water, swelling, and disintegration of MSR can be modified by electrochemical treatment. The following conclusions were drawn. The specific surface area and total pore volume decreased, whereas the average pore diameter increased after electrochemical modification. The reduction in the specific surface area indicates a reduction in the dispersibility and swelling-shrinking of the clay minerals. After modification, the ${\zeta}$ potential of the soft rock was positive in the anodic zone, there was no isoelectric point, and the rock had lost its properties of softening, degradation in water, swelling, and disintegration. The ${\zeta}$ potential increased in the intermediate and cathodic zones, the isoelectric point was reduced or unchanged, and the rock properties are reduced. When the ${\zeta}$ potential is increased, the specific surface area and the total pore volume were reduced according to the negative exponent law, and the average pore diameter increased according to the exponent law.

Pre-Penetration Behavior of Botryosphaeria dothidea on Apple Fruits

  • Kim, Ki-Woo;Park, Eun-Woo;Ahn, Kyng-Ku
    • The Plant Pathology Journal
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    • v.15 no.4
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    • pp.223-227
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    • 1999
  • Pre-penetration behavior of Boytryosphaeria dothidea on apple fruits was investigated with scanning electron microscopy. Once conidia were deposited on the fruit surface, they germainted and produced germ tubes from one or both ends of the conidia. Germ tubes grew over the fruit surface and entered the fruits through lenticels or surface cracks formed naturally. Germ tubes of the fungus also appeared to penetrated the fruits directly with or without forming appressoria. Globose appressoria were frequently formed at the tip of germ tubes on the fruit surface, where no lenticels or surface cracks were found. The conidia collapsed and became flattened to the fruit surface after appressorial formation. Cuticles of fruit surface underneath appressoria and tips of some germ tubes were evidently altered, indicating possibility of direct penetration of the fungus by enzymatic degradation of the cuticle layers. This the first report on the formation of appressoria by B. dothidea.

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Surface Passivation Method for GaN UV Photodetectors Using Oxygen Annealing Treatment

  • Lee, Chang-Ju;Park, Hongsik
    • Journal of Sensor Science and Technology
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    • v.25 no.4
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    • pp.252-256
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    • 2016
  • Epitaxially grown GaN layers have a high surface state density, which typically results in a surface leakage current and a photoresponse in undesirable wavelengths in GaN optoelectronic devices. Surface passivation is, therefore, an important process necessary to prevent performance degradation of GaN UV photodetectors. In this study, we propose oxygen-enhanced thermal treatment as a simple surface passivation process without capping layers. The GaN UV photodetector fabricated using a thermal annealing process exhibits improved electrical and photoresponsive characteristics such as a reduced dark current and an enhanced photoresponsive current and UV-to-visible rejection ratio. The results of this study show that the proposed surface passivation method would be useful to enhance the reliability of GaN-based optoelectronic devices.

Fatigue Behavior of Catenary Wires by Environments Degradation (환경열화에 의한 가선재의 피로거동)

  • 김용기;장세기
    • Journal of the Korean Society for Railway
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    • v.7 no.1
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    • pp.14-19
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    • 2004
  • The effect of surface damage on fatigue properties of catenary wires were investigated to estimate their service lift. As surface defects of the wires caused by surface corrosion increase, surface roughness gets worse, and as roughness increases, it is easy for moisture coming from rain and dew to be condensed around uneven parts of the surface. The condensed moisture causes a locally severe corrosion which leads to damage of the wires. Corrosion of catenaty wires can make their actual lifetime shorter than that originally designed. The amount of decrease was more prominent as environmental conditions became more corrosive. They are also vibrated with some amplitude everytime pantographs touch contact line. The frequent cyclic load on the wire may result in a fatigue fracture. Surface damage by corrosion can make formation of crack initiation at fatigue. In the present study, the fatigue life of the used wire was measured 35 to 50% compared with that of new one in average.

Photocatalytic Oxidation of Humic Acid by various commerical TiO2: A Comparative Study (부식산의 광촉매 산화 공정에 도입된 여러 종류의 상용 TiO2 비교연구)

  • Mun, Kyung-Suk;Kim, Da-Hee;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.21-26
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    • 2001
  • In this study, the effects of crystalinity, composition and particle size of $TiO_2$ catalysts on the degradations of humic acid in aqueous solution was assessed using the commercially avaliable $TiO_2$ particles. Photocatalytic oxidations of humic acid (HA, Aldrich Co.) solution were carried out in case of adding different types of $TiO_2$ catalysts and their decomposition efficiencies were analyzed with respect to pH, DOC and UV absorbances values for the HA solutions and compared one another. The experimental results showed that $TiO_2$ particles(Degussa P-25) mixed with anataze and rutile gave the highest degradation efficiencies, respectively and much lower degradation efficiency in $TiO_2$ paticles of rutile only type. In comparing among ST series of anataze types, it was observed that the degradation efficiencies generally were increased with increasing $TiO_2$ contents and surface area of the particles. Higher degradation efficiency of HA was also found in zeolite type(D-TZ) of $TiO_2$ paticles compared with hydroxyapatite type (D-TH) of $TiO_2$ particles.

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