• Title/Summary/Keyword: surface degradation

Search Result 1,509, Processing Time 0.027 seconds

Degradation of GaAs HBT induced by instability of base surface recombination states (베이스 표면재결합상태의 불안정에 의한 GaAs HBT의 열화)

  • 김덕영;최재훈;김도현;송정근
    • Journal of the Korean Institute of Telematics and Electronics D
    • /
    • v.35D no.3
    • /
    • pp.11-17
    • /
    • 1998
  • Although GaAs HBTs are very attractive for high power amplifier because of their power handling capablity, they can't be actively commercialized due to the degradation of current gain occured in hihg current operation. In this paper we analyzed the type of current gain degradation of GaAs HBTs under high constant current stress, and identified the mechanism by using two dimensional numerical simulation. The cause of degradation was found out to be the variation of surface recombination states at the interface between GaAs extrinstic base and the nitride passivating the surface of base. The energy radiated from recombination of carriers in bulk as well as near the surface is estimated to activate the change of the surface states.

  • PDF

Analyses on the Increment of Surface Hydrophobicity of Epoxy Composites by Thermal Treatment (열철리에 따른 Epoxy 복합재료의 표면 소수성증가에 관한 해석)

  • Lim, Kyung-Bum;Lee, Beak-Su;Chung, Mu-Yong;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.50 no.4
    • /
    • pp.153-160
    • /
    • 2001
  • In order to analyze the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to high temperature. Then, the degradation process was evaluated by comparing contact angle, surface potential, surface resistivity, and XPS. The experimental results showed that the amount of weight loss, contact angle, surface potential and surface resistivity increased up to 200 $^{\circ}C$ as a function of temperature. These phenomena show the existence of hydrophobic surface. With the change to the hydrophobic surface and the electrical potential and resistivity on FRP surface increased. In XPS to analyze surface chemical structures, the increased hydrophobicity in thermal increase of unsaturated double bond in carbon chains. Aslo, thermal treatment caused the discoloration on the point of treated surface. These phenomena were attributed to the generations of ether group.

  • PDF

SURFACE DEGRADATION OF GALLIUM-ALLOYS DURING TOOTH BRUSHING IN VITRO

  • Lee, Seok-Hyung
    • Journal of Dental Rehabilitation and Applied Science
    • /
    • v.19 no.4
    • /
    • pp.309-315
    • /
    • 2003
  • When the exposure surface of restoration is brushed with various toothpaste in the mouth, wear or undesirable surface deposit of restoration can occur. Surface change of gallium alloys according to brushing and toothpaste may directly affect oral hygiene. The aim of this study was to evaluate the surface alterations of Gallium alloys during tooth brushing with different prophylactic agents. Two gallium-alloys and an amalgam as a control were investigated. Without and with brushing were applied with three kinds of prophylactic agents on the sample for 0, 1, 5, 10, 60 and 360 minutes. At each time interval, surface roughness was recorded by a profilometer and some pictures were taken by a SEM. All results were analyzed by the one-way ANOVA, followed by Tukey multiple comparisons and the simple linear regression analysis. The results indicate that gallium alloys are more susceptible to surface degradation during tooth brushing than amalgam with respect to the specific prophylactic agent used.

Study on Degradation Rates of Biodegradable Polymers by Stereochemistry (입체화학을 이용한 생분해성 고분자의 분해속도에 관한 연구)

  • Park, Chan-Young;Choi, Yong-Hae;Lee, Won-Ki
    • Journal of Environmental Science International
    • /
    • v.18 no.7
    • /
    • pp.797-802
    • /
    • 2009
  • To control degradation rate of biodegradable poly(lactide)s (PLA), the stereochemical PLAs with different ratios of d-lactide and l-lactide units were synthesized by the ring open polymerization and the their degradation kinetics were measured by a Langmuir film balance. The alkaline (pH=11) degradation of poly(l-lactide) (l-PLA) monolayer showed the faster rate at a surface pressure of 4 mN/m in the ranges from to 0 to 7 mN/m. However, the enzymatic degradation of l-PLA with Proteinase K did not occur until 4 mN/m. Above a constant surface pressure of 4 mN/m, the degradation rate was increased with a constant surface pressure. These behaviors might be attributed to the difference in the contacted area with degradation medium: alkaline ions need small contact area with l-PLA while enzymes require much bigger one to be activated due to different medium sizes. The stereochmical PLA monolayers showed that the alkaline degradation was increased with their optical impurities while the enzymatic one was inversed. These results could be explained by the decrease of crystallinity with the optical impurity and the inactivity of enzyme to d-LA unit.

A Study on the Surface Degradation Properties of Epoxy / Glass fiber Treated with Ultraviolet Rays (자외선 처리된 Epoxy/Glass Fiber의 표면 열화 특성에 관한 연구)

  • Lee, Baek-Su;Lee, Deok-Chul
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.48 no.2
    • /
    • pp.86-91
    • /
    • 1999
  • In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. As irradiation energy are increased, the surface properties were steeply decreased in the range of 300[nm]. But the measured values within the scope of400[nm]∼440[nm] showed a increase as compared with the untreated ones. Also, fromthe result of ESCA spectrum, it was confirmed plenty of oxygen groups on the spot showing the maximum decrease of surface properties and the existence of ether groups on the surface of coloring phase. We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.

  • PDF

Evaluation of Corrosion Degradation Characteristics of Turbine Blade Material Using Backward Radiated Ultrasound (후방복사된 초음파를 이용한 터빈 블레이드 재료의 부식 열화특성 평가)

  • Song, Sung-Jin;Kim, Young-H.;Bae, Dong-Ho;Jung, Min-Ho;Kwon, Sung-Duk
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.26 no.11
    • /
    • pp.2322-2327
    • /
    • 2002
  • The corrosion degradation characteristics of the 12Cr alloy steel, which is widely used in fossil power plants as a turbine blade material, are evaluated nondestructively by use of the backward radiated Rayleigh surface wave. In order to evaluate corrosion degradation characteristics, we constructed automated system for the backward radiation, and the frequency dependency of the Rayleigh surface wave is investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in the specimens. The velocity of the surface wave decrease as the increase of the aging time in the backward radiation profile, which seems to result from the increase of the effective degrading layer thickness. And, amplitude of the surface wave increase as the aging time, which seems to result from the increase of the intergranular corrosion. The result observed in this study demonstrates high potential of the backward radiated ultrasound as a tool for the nondestructive evaluation of the corrosion degradation characteristics of the aged materials.

Surface Modification and Enzymatic Degradation of Microbial Polyesters by Plasma Treatments (플라즈마를 이용한 미생물합성 폴리에스테르의 표면개질과 효소분해성)

  • Kim, Jun;Lee, Won-Ki;Ryou, Jin-Ho;Ha, Chang-Sik
    • Journal of Adhesion and Interface
    • /
    • v.7 no.2
    • /
    • pp.19-25
    • /
    • 2006
  • Since the enzymatic degradation of microbial poly(hydroxylalkanoate)s (PHAs), such as poly[(R)-3-hydroxybutyrate] and poly[(R)-3-hydroxybutyrate-co-3-hydroxyvalerate] initially occurs by a surface erosion process, their degradation behaviors can be controlled by the change of surface property. In order to control the rate of enzymatic degradation, plasma modification technique was applied to change the surface property of microbial PHAs. The surface hydrophobic and hydrophilic properties of PHA films were introduced by $CF_3H$ and $O_2$ plasma exposures, respectively. The enzymatic degradation was carried out at $37^{\circ}C$ in 0.1 M potassium phosphate buffer (pH 7.4) in the presence of an extracellular PHB depolymerase purified from Alcaligenes facalis T1. The results showed that the significant retardation of initial enzymatic erosion of $CF_3H$ plasma-treated PHAs was observed due to the hydrophobicity and the enzyme inactivity of the fluorinated surface layers while the erosion rate of $O_2$ plasma-treated PHAs was not accelerated.

  • PDF

Methodology to Simultaneously Optimize the Inlet Ozone Concentration to Oxidize NO and Relative Humidity Composition for the $NO_x$ Degradation using Soil Bio-filter

  • Cho, Ki-Chul;Hwang, Kyung-Chul
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.24 no.E2
    • /
    • pp.83-91
    • /
    • 2008
  • This work investigated the methodology to simultaneously optimize the ozone and relative humidity composition for the $NO_x$ degradation using soil biofilter. Experiments were made as a function of inlet ozone concentration ($0{\sim}1,770\;ppb$) and relative humidity ($38{\sim}81%$). Factorial design ($2^2+3$) and response surface methodology by central composite designs were used to examine the role of two factors and optimal response condition on $NO_x$ degradation. It was found that a second-order response surface model can properly interpret the experimental data with an $R^2$-value of 0.9730 and F-value of 71.83, based on which the maximum $NO_x$ degradation was predicted up to 92.8% within our experimental conditions.

A Study on the Characteristics of Surface Degradation & Degradation-Mechanism in UV Treated FRP (자외선 파장에 따른 FRP의 표면 열화특성 및 열화메커니즘에 관한 연구)

  • Lee, B.S.;Lim, K.B.;Na, D.G.;Chung, M.Y.;Chung, E.N.;You, D.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
    • /
    • 1998.11c
    • /
    • pp.813-815
    • /
    • 1998
  • In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. Finally, We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.

  • PDF

Partial Discharge Diagnosis of Thermal Degradated PVC Cable (열열화된 PVC 케이블의 부분방전 진단)

  • Song, Ki-Tae;Lee, Sung-Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.24 no.3
    • /
    • pp.208-214
    • /
    • 2011
  • In this thesis, the partial discharge according to applied voltage and variations of cross-sectional area and length of the conductor related to general condition for using cable was measured in order to study degradation diagnosis for 2-Core cable of the PVC insulator used in industrial fields for other safety installations. Also the thermal degradation conditions under various installation circumstances of cables were studied by assuming degradation conditions with each different degradation rate (50%, 67%, 100%) such as variation in degradated temperature, thermal exposure time, normal state, partially degradated state and overall degradated state for thermal degradation diagnosis. The quantity of electric discharge (V-Q) according to applied voltage was measured for measurement of inception voltage and extinction voltage. The quantity of electric discharge and the number of electric discharge (Q-N) were measured with applied voltage kept constantly. In addition, pictures were taken using SEM (scanning electron microscope) to compare the surface of external insulator to degradated state of internal insulator according to thermal degradation temperature and also compare the surface of external insulator to degradated surface state of internal insulator according exposure time of cables to thermal stress.