• Title/Summary/Keyword: surface and interface

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A Study on Space Charge of Organic Pentacene/metal Interface (유기물 Pentacene 박막과 금속 계면에서의 Space Charge 연구)

  • Yoon, Young-Woon;Babajayan, Arsen;Lee, Hoo-Neung;Kim, Song-Hui;Lee, Kie-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.1
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    • pp.41-46
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    • 2007
  • Surface potential properties at the interface of pentacene thin films on gold (Au) and aluminum (Al) surfaces were investigated by using a near-field scanning microwave microprobe (NSMM). The surface potential formed across the pentacene film was observed by measuring the microwave reflection coefficient $S_{11}$ and compared with the result of a Kelvin-probe method. The obtained reflection coefficient ${\Delta}S_{11}$ of the pentacene thin films on Al was decreased as the pentacene film thickness increased due to the increased accumulation of negative space charges, while for Au ${\Delta}S_{11}$ was essentially constant.

Controlled Plasma Treatment for Edge Contacts of Graphene (그래핀의 엣지 접합 (Edge Contact)을 위한 플라즈마 처리 연구)

  • Yue, Dewu;Ra, Chang-Ho;Liu, Xiaochi;Daeyeong, Daeyeong;Yu, Won-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.293-293
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    • 2014
  • The applicability of graphene has been demonstrated in the electronic fields. But, high performance of graphene is limited by the contact resistance (Rc) at the metal-graphene interface. Recently, Rc was found to be improved by forming edge-contacted graphene via theoretical simulation. Based on the differences between the surface and edge contacts at the M-G interface, we demonstrate "edge-contacted" graphene through the use of a controlled plasma processing technique that generates the edge structure of the bond and significantly reduces the contact resistance. The contact resistance attained by using pre-plasma processing was of $270{\Omega}{\cdot}{\mu}m$. Mechanisms of pre-plasma process leading to low Rc was revealed by SEM and Raman spectroscopy. In the end, controlled pre-plasma processing enabled to fabricate CVD-graphene field effect transistors with an enhanced adhesion and improved carrier mobility.

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Effects of Corrosion Behavior on Failure of Co-Cured Single Lap Joints Subjected to Cyclic Tensile Loads (피로하중이 가해지는 외면겹치기 동시경화조인트의 파괴에 미치는 부식의 영향)

  • Shin, Kum-Cheol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.3
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    • pp.315-321
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    • 2010
  • Co-cured single lap joints under cyclic tensile loads fail initially at the tip of the interface corner between the two adherents. The failure mechanism is complex because it is related to corrosion fatigue. Corrosion behavior at the interface affects the failure of the joints because corrosion deteriorates fatigue resistance. In this study, we clarified the cause of interfacial corrosion in co-cured single lap joints under cyclic tensile loads. The failure mechanism was also analyzed by observing the failed surfaces of specimens and the stress distribution along the interface. The surface roughness at the interface and the stacking sequence of the composite adherent were examined to investigate their effects on failure of the joint.

EFFECT OF COBALT-CHROMIUM ALLOY SURFACE TREATMENT WHEN BONDING WITH 4-META/MMA-TBB RESIN (Cobalt-Chromium 합금의 표면처리가 4-META/MMA-TBB 레진과의 접착에 미치는 영향)

  • Jin, Jae-Sik;Kim, Kyo-Han;Lee, Cheong-Hee;Jo, Kwang-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.4
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    • pp.510-525
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    • 2000
  • The effects of pretreatment of Co-Cr alloy, including two adhesive primers that contain either MDP or MAC-10, and silicoating on the bond The result sobtained as follows; o Strength of 4-META/MMA-TBB resin were investigated using FT-IR, SEM, and EDAX. o In the SEM observation of surface morphologies, the sandblasted specimen exibited a very rough surface, whereas the surfaces of the two groups primed with either MDP or MAC-10 were covered with a layer of primer, and the surface morphology of the silicoated specimen remained almost the same after sandblasting. o Before the thermocycling tests, the group treated with MDP demonstrated the highest mean tensile bond strength and the sandblasted group showed the lowest bond strength. o After 20,000 thermocyling, the mean tensile bond strength of the sandblasted group exhibited a 50% reduction in bond strength, while the others showed a $20\sim30%$ reduction. o Observation of the metal-resin interface revealed that in all groups the resin permeated the rough surface formed by sandblasting thereby producing a mechanical bond between the metal and the resin. It was also found that thermocycling resulted in a gap formation at the metal-resin interface of the specimens, and the sandblasted group exhibited a larger gap width than the other groups. o In fracture mode, all specimens indicated a cohesive fracture within the resin before thermocycling. However, thermocyling produced adhesive failure at the edge of the resin-metal interface in most specimens. The sandblasted group, which exhibited the lowest bond strength after thormocycling, also demonstrated the largest area of adhesive failure.

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Effect Evaluation of Hole Defects in Adhesive on SIF of Interface Crack (접착층내 결함이 계면균열의 응력확대계수에 미치는 영향 평가)

  • Hyun, Cheol-Seung;Heo, Sung-Pil;Yang, Won-Ho;Ryu, Myung-Hae
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.299-303
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    • 2001
  • Adherend-adhesive interface failure will occur on a macroscale when surface preparation or material quality are poor. It is well known that the stress singularity occurs at the edges of interface between the adhernds and the adhesive, and that crack will initiate from these positions. Also if bubbles are created and remained in the adhesive layer during the bonding process, the stress concentrates around these hole defects. In this paper, the effects of the hole defects on the SIF of interface crack were examined. From results, SIF increased with the hole defects near the interface crack and increased with an decreae in the upper adherend thickness, an increase in the center adhesive thickness.

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Determination of the Optical Functions of Various Liquids by Rotating Compensator Multichannel Spectroscopic Ellipsometry

  • Bang, Kyung-Yoon;Lee, Seung-Hyun;Oh, Hye-Keun;An, Il-Sin;Lee, Hai-Won
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.947-951
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    • 2005
  • Rotating compensator multichannel spectroscopic ellipsometry has been employed to determine the optical functions of various liquids used in chemistry. We attempted three different measurement configurations: (1) air-liquid interface, (2) prism-liquid interface, and (3) liquid-sample interface. In prism-liquid interface, we found that the prism surface had roughness and it should be considered in analysis for accurate results. In liquidsample interface, we had much higher reflection, better sensitivity, and less limitation compared to the other two configurations when crystalline silicon was used as reference sample. We discuss the merit of each configuration and present the optical functions of various liquids. Also we demonstrate Bruggeman effective medium theory to determine the optical properties of mixed liquid.

A STUDY ON AN INTERFACE CAPTURING METHOD APPLICABLE TO UNSTRUCTURED MESHES FOR THE ANALYSIS OF FREE SURFACE FLOW (자유표면유동 해석을 위한 비정렬격자계에 적합한 경계면포착법 연구)

  • Myong, H.K.;Kim, J.E.
    • Journal of computational fluids engineering
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    • v.11 no.4 s.35
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    • pp.14-19
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    • 2006
  • A conservative finite-volume method for computing 3-D flow with an unstructured cell-centered method has been extended to free surface flows or two-fluid systems with topologically complex interfaces. It is accomplished by implementing the high resolution method(CICSAM) by Ubbink(1997) for the accurate capturing of fluid interfaces on unstructured meshes, which is based on the finite-volume technique and is fully conservative. The calculated results with the present method are compared to show the ease and accuracy with available numerical and experimental results reported in the literature.

Development of a Solver for 3-D Flows with Free Surface using the Finite Volume Method on Unstructured Grids (비정렬 격자 유한체적법을 이용한 삼차원 자유표면 유동 해석 코드의 개발)

  • Yim, Joong-Hyuck;Baek, Je-Hyun
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.910-915
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    • 2003
  • A Navier-Stokes equation solver for incompressible viscous flows with free surface is developed and tested. This is based upon a fractional time step method and a non-staggered finite volume formulation for unstructured meshes. For time advancement scheme, Adams -Bashforth method for convective term and Crank-Nicolson method for diffusive term are applied. The interface between two fluids with different fluid properties is tracked with Piecewise Linear Interface Calculation(PLIC) Volume-of-Fluid(VOF) methods. Computational results are presented for some test problems: the broken dam, the sloshing in a rectangular tank, the filling of a cylindrical tank.

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Interfacial Adhesion of Silk/PLA Biocomposites by Plasma Surface Treatment (플라즈마 표면처리에 의한 Silk/PLA 바이오복합재료의 계면접착)

  • Chu, Bo Young;Kwon, Mi Yeon;Lee, Seung Goo;Cho, Donghwan;Park, Won Ho;Han, Seong Ok
    • Journal of Adhesion and Interface
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    • v.5 no.4
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    • pp.9-16
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    • 2004
  • Silk fibers were subjected to argon and ethylene plasma treatments in order to improve the interfacial adhesion with polylactic acid (PLA). After the plasma surface treatment, the surface morphology and surface adhesion of silk fibers to the PLA resin were largely changed. Various plasma treatment conditions were used in this work: 10, 25, 50, 100 and 150 W of electric power, 1, 3, 5, 7 and 10 minutes of treatment time, and 10 and 50 sccm of a gas flow rate. The interfacial shear strength of plasma-treated Silk/PLA biocomposites was measured by a single fiber micro-droplet debonding test method. The result provided an optimal plasma treatment condition to obtain the improved interfacial adhesion in the Silk/PLA biocomposites.

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DEVELOPMENT OF HYPER INTERFACIAL BONDING TECHNIQUE FOR ULTRA-FONE GRAINED STEELS

  • Kazutoshi Nishimoto;Kazuyoshi Saida;Jeong, Bo-young;Kohriyama, Shin-ichi
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.776-780
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    • 2002
  • This paper describes the concept and the characteristics of hyper interfacial bonding developed as a new concept joining process for UFG (ultra-fine grained) steel. Hyper interfacial bonding process is characterized by instantaneous surface melting bonding which involves a series of steps, namely, surface heating by high frequency induction, the rapid removing of heating coil and joining by pressing specimens. UFG steels used in this study have the average grain size of 1.25 ${\mu}{\textrm}{m}$. The surface of specimen can be rapidly heated up and melted within 0.2s. Temperature gradient near heated surface is relatively steep, and peak temperature drastically fell down to about 1100K at the depth of 2~3mm away from the heated surface of specimen. Bainite is observed near bond interface, and also M-A (martensite-austenite) islands are observed in HAZ. Grain size increases with increasing heating power, however, the grain size in bonded zone can be restrained under 11 ${\mu}{\textrm}{m}$. Hardened zone is limited to near bond interface, and the maximum hardness is Hv350~Hv390.

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