• 제목/요약/키워드: surface and interface

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The effect of surface treatment on interface formation between pentacene and polymer dielectrics

  • Han, Seung-Jin;Kim, Jae-Hoon;Park, Yong-Sup;Back, Kyu-Ha;Kim, Gi-Heon;Hong, Sa-Hwan;Kim, Dal-Hyun;Kim, Jeong-Won
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1415-1418
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    • 2007
  • Electronic and structural properties of the interfaces formed by pentacene deposited on a polymer-based dielectrics are investigated by electron spectroscopy, atomic force microscopy, and water contact angle measurement. There is strong influence of surface treatment of the polymer dielectrics on the energy level alignment and the surface topography upon the pentacene deposition.

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CdSe 나노입자의 합성과 광학 특징 (Synthesis and Optically Characterization of CdSe Nanocrystal)

  • 김찬영;김성현;정대혁
    • 통합자연과학논문집
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    • 제1권3호
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    • pp.250-253
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    • 2008
  • New issues arise as to surface characterization, quantification and interface formation. Surface and interface control of CdSe nanocrystal systems, one of the most studied and useful nanostructures. Semiconductor quantum dots (QDs) have been the subject of much interest for both fundamental reseach and technical applications in recent years, due mainly to their strong size dependent properties and excellent chemical processibility. In this dissertation, the synthesis of CdSe quantum dots were synthesized by pyrolysis of high-temperature organometallic reagents. In order to modify the size and quality of quantum dots, we controlled the growth temperature and the relative amount of precursors to be injected into the coordinating solvent. Moreover, an effective surface passivation of monodisperse nanocrystals was achieved by overcoating them with a higher-band-gap material. Synthesized CdSe quantum dots were studied to evaluate the optical, electronic and structural properties using UV-absorption, and photoluminescence measurement.

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Surface Micelle Formation of Polystyrene-b-Poly(2-vinyl pyridine) Diblock Copolymer at Air-Water Interface

  • Park, Myunghoon;Bonghoon Chung;Byungok Chun;Taihyun Chang
    • Macromolecular Research
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    • 제12권1호
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    • pp.127-133
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    • 2004
  • We have studied the surface micelle formation of polystyrene-b-poly(2-vinyl pyridine) (PS-b-P2VP) at the air-water interface. A series of four PS-b-P2VPs were synthesized by anionic polymerization, keeping the PS block length constant (28 kg/㏖) and varying the P2VP block length (1, 11, 28, or 59 kg/㏖). The surface pressure-area ($\pi$-A) isotherms were measured and the surface morphology was studied by atomic force microscopy (AFM) after Langmuir-Blodgett film deposition onto silicon wafers. At low surface pressure, the hydrophobic PS blocks aggregate to form pancake-like micelle cores and the hydrophilic P2VP block chains spread on the water surface to form a corona-like monolayer. The surface area occupied by a block copolymer is proportional to the molecular weight of the P2VP block and identical to the surface area occupied by a homo-P2VP. It indicates that the entire surface is covered by the P2VP monolayer and the PS micelle cores lie on the P2VP monolayer. As the surface pressure is increased, the $\pi$-A isotherm shows a transition region where the surface pressure does not change much with the film compression. In this transition region, which displays high compressibility, the P2VP blocks restructure from the monolayer and spread at the air-water interface. After the transition, the Langmuir film becomes much less compressible. In this high-surface-pressure regime, the PS cores cover practically the entire surface area, as observed by AFM and the limiting area of the film. All the diblock copolymers formed circular micelles, except for the block copolymer having a very short P2VP block (1 kg/㏖), which formed large, non-uniform PS aggregates. By mixing with the block copolymer having a longer P2VP block (11 kg/㏖), we observed rod-shaped micelles, which indicates that the morphology of the surfaces micelles can be controlled by adjusting the average composition of block copolymers.

Effects of $N_2/H_2$ plasma treatments on enhancement of neuronal cell affinity on single-walled carbon nanotube paper scaffolds

  • Yoon, Ok-Ja;Lee, Hyun-Jung;Jang, Yeong-Mi;Kim, Hyun-Woo;Lee, Won-Bok;Kim, Sung-Su;Lee, Nae-Eung
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.393-393
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    • 2010
  • The biocompatibility of materials used for biomedical applications depends on chemical composition, mechanical stiffness, surface energy, and roughness. The plasma treatment and etching process is a very important technology in the biomedical fields due to possibility of controlling the surface chemistry and properties of materials. In this work, $N_2/H_2$ plasma were treated on single-walled carbon nanotubes (SWCNTs) paper and characterization of treated SWCNTs paper was carried out. Also we investigated neurite outgrowth from SH-SY5Y on treated SWCNTs paper. The results indicated that $N_2/H_2$ plasma-modified SWCNTs paper enhanced neuronal cell adhesion, viability, neurite outgrowth and branching in vitro and exerted a positive role on the health of neural cells.

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FVM과 반무한체 해석을 이용한 표면온도예측에 관한 연구 (A Study for Estimation of the Surface Temperature Rise Using the FVM and Semi-Infinite Solid Analysis)

  • 김태완;이상돈;조용주
    • Tribology and Lubricants
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    • 제18권6호
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    • pp.389-395
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    • 2002
  • The surface temperature at the interface of bodies in a sliding contact is one of the most important factors influencing the behavior of machine components. The calculation of the surface temperature at a sliding contact interface has been an interesting and important subject for tribologist. Temperature analyses were usually performed under the consideration contacted two bodies as semi-infinite. But the analysis was difficulty in being applied to finite body and considering the boundary condition. In this study, contact temperature rise of two finite bodies and surfaces due to frictional heating under the rectangular and the circular sliding contact is calculated. Heat partition factor is calculated using semi-infinite solid analysis and the temperature of the finite bodies is calculated using FVM. It will be shown that Most frictional heat in the fore part of contact region for sliding direction is conducted into body that has a moving heat source and the site of the maximum temperature rise moves to the opposite direction of sliding during sliding.

Bioactivity of Calcium Phosphate Ceramic Coatings on Metallic Implants

  • Kim, Cheol-Sang;Ducheyne, P.
    • 대한의용생체공학회:의공학회지
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    • 제11권1호
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    • pp.5-12
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    • 1990
  • Calcium phosphate ceramics have been applied intensively to orthopaedic and dental implants by virtue of their osteoconductive nature. In an attempt to enhance the bone implant intergrity and Eta utility, these ceramics are deposited onto the porous surface of metallic implants. The coating procedure and the ensuing phase transformations of the ceramic alter the mechanical properties and surface chemistry of the ceramic layers as well as those of the substrate. These structural and compositional differences are directly related to the interaction mechanisms at the surface-active ceramicbone interface. Material and processing induced influences on dissolution, electrokinetic behavior, ceramic-metallic substrate interface and boRe growth enhancement are presented.

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$TiSi_2$의 상전이에 미치는 박막의 두께 및 기판의 방위의 영향 (The Effects of Ti Film Thicknesses and Si Substrate Orientations on Phase Transition of Tisi$_2$)

  • 윤강중;전형탁
    • 한국재료학회지
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    • 제5권7호
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    • pp.820-828
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    • 1995
  • 초청정 Si 기판위에 Ti을 증착하여 형성시킨 Ti-silicide의 상전이와 각상의 표면 및 계면형상을 Ti 증착두께, 열처리 온도, 기판의 방위에 따라 조사하였다. 초 고진공 챔버에서 각각 400$\AA$ 및 200$\AA$의 Ti를 50$0^{\circ}C$부터 90$0^{\circ}C$까지 10$0^{\circ}C$간격으로 가열되어 있는 Si(100) 및 Si(111) 기판에 증착하여 Ti-silicide를 형성하였다. 형성된 Ti-silicide를 XRD, SEM, TEM으로 상전이와 각상의 표면 및 계면 형상을 관찰하였다. 관찰결과 C49에서 C54상으로의 상전이 온도는 $650^{\circ}C$정도이었고, 기판의 방위와 박막의 증착 두께에 따라 상전이 온도의 변화가 관찰되었으며, 이 상전이 온도의 변화를 표면에너지와 체적에너지에 기초를 둔 고찰을 통해 설명하였다. 그리고 C49상은 증착한 박막에서의 Si 원자의 비균질한 확산 특성으로 인해 거친 계면을 나타내고 있으나, C54상은 비교적 균질한 계면을 나타내고 있으며 응집화에 의해 island가 형성된 것이 관찰되었다.

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에폭시 매입금구 표면거칠기에 따른 전기적, 기계적 특성 연구 (A Study on Mechanical and Electrical Properties at Interfaces Between Epoxy and ifs Molded Metal)

  • 김수연;하영길;이성진;김영성;박완기;김성진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.226-229
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    • 1999
  • Epoxy compound has been used as insulation material in electrical equipment for a long time because of its excellent electrical, mechanical and chemical properties. Nowdays, becoming higher voltage system, the properties of interface between epoxy and metal insert become more important. The breakdown voltage of epoxy compound for electric material is variable according to the surface roughness of metal insert. Generally, with metal insert sanding, the adhesion strength is enhanced and the breakdown strength is reduced. But in this study, we knew that the adhesion strength became enhanced but the breakdown strength didn\`t reduced with metal insert sanding. So in this study sanding. So in this study, we suggest the optimum interface condition by adjusting the surface roughness.

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장년층의 시각적 특성과 선호도를 고려한 휴대폰의 디스플레이 설계에 관한 연구: 컨조인트 분석과 반응표면분석을 활용하여 (A Study on Designing Mobile Phone Display in Consideration of Elder People's Optical Characteristics and Preferences: Using Conjoint Analysis and Response Surface Method)

  • 이성훈;신용식;박용길
    • 정보통신설비학회논문지
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    • 제4권1호
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    • pp.23-29
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    • 2005
  • This study is about designing mobile phone display in consideration of elder people's preferences by reason of their optical weakness. The research is closely connected with designing user-friendly interface by considering user characteristics. The criteria for first experiment are font sizes, font types, line spacing and background colors. With the experiment result, relative importance of each attribute and subjective preference are investigated by conjoint analysis. Secondly, an optimal display design for elder people is presented by response surface method on the basis of the result of conjoint analysis, other statistical analyses, and user interviews.

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Improvement in Interfacial Performances of Silicone Rubber by Oxygen Plasma Treatment

  • Lee, Ki-Taek;Seo, Yu-Jin;Huh, Chang-Su
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.232-233
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    • 2005
  • The Surface of semi-conductive silicone rubber was treated by oxygen plasma to improve adhesion and electric performance in joints between insulating and semi-conductive silicone materials. Surface characterizations were assessed using contact angle measurement and Fourier transform infrared spectroscope (FTIR). Adhesion level was understood from T-peel tests between plasma treated semi-conductive and insulating material. Electrical breakdown strength was measured to understand the charge of electrical performance. From the results, the oxygen plasma treatment produces a significant increase in function group of containing oxygen which can be mainly ascribed to the creation of carbonyl groups on the silicone surface from the strength were improved. Therefore it is concluded then plasma treatment leads to decrease voids originating form poor adhesive, and the improve the adhesion in silicone interface. So we could obtain higher electrical design level of silicone material used for electrical apparatus using oxygen plasma treatment.

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