• 제목/요약/키워드: surface alteration

검색결과 199건 처리시간 0.025초

Effect of rock mineralogy on mortar expansion

  • Karaman, Kadir;Bakhytzhan, Aknur
    • Geomechanics and Engineering
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    • 제20권3호
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    • pp.233-241
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    • 2020
  • Alkali-silica reaction (ASR) is among one of the most important damaging mechanisms in concrete, depending primarily on aggregates which contain reactive minerals. However, expansion in concrete may not directly relate to the reactive minerals. This study aims to investigate the influence of ASR and the expansion of mortar bars depending on aggregate type containing various components such as quartz, clay minerals (montmorillonite and kaolinite) and micas (muscovite and biotite). In this study, the accelerated mortar bar tests (AMBT) were performed in two conditions (mortar bars in the same and sole NaOH solutions). Petrographic thin section studies, X-ray diffraction (XRD) analysis (Rietveld method), scanning electron microscopy (SEM) and chemical analyses were carried out. This study showed that quartzite bars led to increase in expansion values of mortar bars in diabase-1 and andesite when these were in the same NaOH solution. However, three samples (basalt, quartzite and claystone) were found having ASR expansion based on the AMBT when the special molds were used for each sample. SEM study revealed that samples which exhibit highest expansions according to AMBT had a generally rough surface and acicular microstructures in or around the micro-cracks. Basalt and quartzite showed more variable in major oxides than those of other samples based on the chemical analyses, SEM studies and AMBT. This study revealed that the highest expansions were observed to source not only from reactive aggregates but also from alteration products (silicification, chloritization, sericitization and argillisation), phyllosilicates (muscovite, biotite and vermiculite) and clays (montmorillonite and kaolinite).

영남지역 고령토-납석 광상의 성인 연구 (Genesis of Kaolin-Pyrophyllite Deposits in the Youngnam Area)

  • 상기남
    • 자원환경지질
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    • 제25권2호
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    • pp.101-114
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    • 1992
  • Occurrences of many kaolin-pyrophyllite deposits in the Youngnam area is related to the Late Cretaceous volcanic rocks, which are widely distributed through southern part from Tongnae-Yangsan to Miryang-Wolsung. The mode of occurrence and genesis of the kaolin-pyrophyllite deposits related to the volcanism was studied. This area is covered by andesitic rocks, rhyolite and rhyolitic welded tuff in ascending order. Lower most andesitic part is almost fresh. The altered rocks in the rhyolitic welded tuff can be classified into the following zones: silicified, pyrophyllite-kaolin, and argillic zone from the center part of ore deposit. The clay deposits occur as irregular massive, layer and funnel type about 5~20 m in width and is accompanied by thin diaspore bed outside of ore shoot. The clays chiefly consist of kaolinite, sericite, pyrophyllite, a little amount of diaspore, alunite, dumortierite, corundum and pyrite. The process of kaolinization-pyrophyllitization has a close relation to a local acidic hydrothermal solution originated from granitic rocks. Acidic hydothermal alteration occurrs mainly in the rhyolitic welded tuff. Initial solution containing $H_2S$ and others was oxidized near the surface and formed hydrothermal sulfuric acid solution.

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Characterisation and Durability of a Vitrified Wasteform for Simulated Chrompik III Waste

  • Walling, Sam A.;Gardner, Laura J.;Pang, H.K. Celine;Mann, Colleen;Corkhill, Claire L.;Mikusova, Alexandra;Lichvar, Peter;Hyatt, Neil C.
    • 방사성폐기물학회지
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    • 제19권3호
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    • pp.339-352
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    • 2021
  • Legacy waste from the decommissioned A-1 nuclear power plant in the Slovak Republic is scheduled for immobilisation within a tailored alkali borosilicate glass formulation, as part of ongoing site cleanup. The aqueous durability and characterisation of a simulant glass wasteform for Chrompik III legacy waste, was investigated, including dissolution experiments up to 112 days (90℃, ASTM Type 1 water). The wasteform was an amorphous, light green glassy product, with no observed phase separation or crystalline inclusions. Aqueous leach testing revealed a suitably durable product over the timescale investigated, comparing positively to other simulant nuclear waste glasses and vitreous products tested under similar conditions. Iron and titanium rich precipitates were observed to form at the surface of monolithic samples during leaching, with the formation of an alkali deficient alteration layer behind these at later ages. Overall this glass appears to perform well, and in line with expectations for this chemistry, although longer-term testing would be required to predict overall durability. This work will contribute to developing confidence in the disposability of vitrified Chrompik legacy wastes.

Iterative-R: A reliability-based calibration framework of response modification factor for steel frames

  • Soleimani-Babakamali, Mohammad Hesam;Nasrollahzadeh, Kourosh;Moghadam, Amin
    • Steel and Composite Structures
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    • 제42권1호
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    • pp.59-74
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    • 2022
  • This study introduces a general reliability-based, performance-based design framework to design frames regarding their uncertainties and user-defined design goals. The Iterative-R method extracted from the main framework can designate a proper R (i.e., response modification factor) satisfying the design goal regarding target reliability index and pre-defined probability of collapse. The proposed methodology is based on FEMA P-695 and can be used for all systems that FEMA P-695 applies. To exemplify the method, multiple three-dimensional, four-story steel special moment-resisting frames are considered. Closed-form relationships are fitted between frames' responses and the modeling parameters. Those fits are used to construct limit state functions to apply reliability analysis methods for design safety assessment and the selection of proper R. The frameworks' unique feature is to consider arbitrarily defined probability density functions of frames' modeling parameters with an insignificant analysis burden. This characteristic enables the alteration in those parameters' distributions to meet the design goal. Furthermore, with sensitivity analysis, the most impactful parameters are identifiable for possible improvements to meet the design goal. In the studied examples, it is revealed that a proper R for frames with different levels of uncertainties could be significantly different from suggested values in design codes, alarming the importance of considering the stochastic behavior of elements' nonlinear behavior.

Hydroxyapatite 피막 처리된 임프란트에 대한 여러가지 기계적 표면처리방법이 임프란트 표면조도 및 성상에 미치는 영향 (EFFECT OF VARIOUS MECHANICAL TREATMENTS OF HYDROXYAPATITE-COATED IMPLANT SURFACES)

  • 양경란;정오철;이재목;서조영
    • Journal of Periodontal and Implant Science
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    • 제24권1호
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    • pp.131-143
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    • 1994
  • 구강내 노출된 임프란트를 건강한 상태로 유지하기 위해서는 임프란트 매식체 표면을 처치하여 주위조직과 잘 적합할 수 있는 표면구조를 만들어 주어야 한다. 실패한 임프란트의 처리방법으로 구연산이나 air-abrasive system과 같은 여러 가지 방법이 소개 되었으나 HA 피막 처치된 임프란트와 같은 거친 표면이 구강내로 노출된 경우에는 구연산이나 air-abrasive system을 이용한 표면 처리방법을 세균독소 제거에는 효과적이나 HA 피막 처리된 매식체의 거친 표면 제거는 어렵기 때문에 계속되는 치태침착을 방지하기에는 효과적이지 못하므로 세균독소를 제거하는 한편 표면성상을 변화시키지 않고 평활한 표면을 만들기 위한 처리방법들을 알아보고자 하였다. IMZ사에서 제작한 HA 피막 처리된 disc에 high speed diamond bur, low speed diamond bur, stone bur, rubber point, jetpolisher를 처치하고 표면평활도를 알아보기 위하여 표면조도측정 및 주사전자현미경으로 표면상태를 관찰하고 표면성분 변화 유무를 알아보기 위하여 EDX를 이용하여 표면성분을 분석한 결과 다음과 같은 결과를 얻었다. 각 시편에 대한 표면조도 측정 결과는 실험 I군 $2.11{\mu}m$, 실험 II군 $4.17{\mu}m$, 실험 III군 $7.28{\mu}m$, 실험 IV군 $8.61{\mu}m$, 실험 V군 $39.44{\mu}m$의 최대높이값을 나타내므로써, I, II, III, IV, V군 순으로 표면이 평활하게 나타났다. 주사전자현미경 관찰에서는 실험 I군은 비교적 평활한 면을 보였고, 실험 II군은 HA 입자가 거의 삭제되었으나 잔존하는 일부의 HA 입자로 인하여 I군보다 약간 거친 표면을 보였다. 실험 III군과 IV군은 삭제되지 않고 잔존하는 HA 입자가 많아 거친 양상을 보였으며 실험 V군인 HA 피막 처리된 면의 경우는 깊은 홈과 돌출된 부분을 가진 매우 불규칙한 표면 구조를 보였다. 시편의 단면 관찰에서는 실험 I군은 균일한 면을 보였으며 실험 III군과 IV군에서는 삭제되지 않고 잔존하는 다량의 HA 입자로 인해 거친 표면을 보였으나 HA 피막의 두께는 상당량 감소되어 나타났다. 또한 실험 II군과 I군과 유사한 양상을 보였다. 실험 V군의 경우는 일정하지는 않지만 약 $40{\mu}m$의 두께를 보였다. EDX에 의한 표면성분 분석 결과, 삭제가 가장 우수한 실험 II군에서는 calcium과 phosphorus가 소량 나타났고, 삭제가 완전하지 않은 실험 III, IV군에서는 calcium peak와 phosphorus peak를 보였다. 모든 군에 나타난 aluminum은 제조과정 중의 혼입으로 사료된다. 모든 실험군에서 titanium, aluminum, calcium, phosphorus 이외의 다른 성분은 나타나지 않았다.

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우리나라 주상절리에 대한 연구 전략 (Research Strategy on Columnar Joint in South Korea)

  • 안건상
    • 한국지구과학회지
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    • 제35권7호
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    • pp.501-517
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    • 2014
  • 주상절리에 관한 최근 연구를 살펴본 결과, 우리나라에 분포하는 주상절리를 이해하고, 활용하기 위한 연구 방향은 다음과 같다; 칼러네이드와 엔테블러춰의 기하학적 형태, 형성 메커니즘과 패턴의 변화, 수평단면과 내부 구조, 주상절리 상하부의 판상절리, 전분 혼합액의 건조실험, 절리 형성에 대한 수치 모델 및 컴퓨터 그래픽 활용, 화산암의 산출 상태에 따른 주상절리 형태와 크기, 모암의 암석학적 및 광물학적 연구. 이와 더불어 지표에 노출된 후의 변질, 풍화작용의 결과로 만들어진 너덜겅, 토르, 타포니 등과 같은 2차적인 경관에 대한 기재도 필요하다. 이 연구는 우리나라 주상절리와 신생대 용암류를 해석하는 중요한 역할을 할 것이다. 또한 연구 성과는 지질관광의 활성화와 지질학습장 측면에서 활용도가 높을 것이다.

패션전문점의 실내공간 디자인 이미지 유형과 구성요소 분석연구 -자체브랜드 복합 패션전문점을 중심으로- (An Analytical Study on the Types of Interior Space Design mage and Consisting Elements in the Fashion Specialty Store - Focused on the complex Fashion Specialty Store in own brand -)

  • 최상헌;최홍복
    • 한국실내디자인학회논문집
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    • 제15호
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    • pp.3-16
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    • 1998
  • Fashion specialty store is based on one theme called "Fashion", to pursue originality of facilities in one concept from merchandising, environmental planning and facilities management and satisfy consumer's urge quantitatively as well as qualitative]y also congreqation of characteristic space, distingtion from commor store, not only selling goods but also jointly owned funtiona] space such as information and culture. So this research. with the importance of image. to present the basic information of interior design, study on the analyzing the type of image and the factor of composition focused on the complex fashion specialty store in own brand. Ana]yzing thr type of image with preliminary research and the first and second questionnair, with this make a comparision between the factor of composition and image. The conclusion was summertized as follows : '||'&'||'#8226; Firstly, the interior image of complex fashion specialty store in own brand divided into ;) different images, Such as :VIodern, Semi Classic. Hi-Tech Ylodern, Natural. and casual image '||'&'||'#8226; Secondly, according to the factor of composition is as follows, Such as Architecture, Surface. Furniture, Lighting and Display, the factor of composition is as follows : Architectura] factor divided into vertical. horizental. flexibility and exterior, Surface : material. and main color, Furniture : form and material. Lighting : lighting fixture and genera] lighting system, and Display: window and interior display . '||'&'||'#8226; Third]y, make a comparision of image. simple and feminine with Hi-Tech, Semi-Classic toward natural. complicated, feminine. and Low-Tech, Hi Tech ~.Iodern image, toward modem. natural. simple feel and somehow feminine. Natrual image, toward modem. natura], simple, and Hi Tech, Casual image toward modm, simple, and Hi Tech. '||'&'||'#8226; Fourthly, with builaing up new space, alteration infashion specialty store focused on the customers seiling space with rest and resources, also huge character is found in fashion specialty store

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Evaluation of flux stabilisation using Bio-UF membrane filter on KZN Rivers, South Africa

  • Thoola, Maipato I.;Rathilal, Sudesh;Pillay, Lingam V.
    • Membrane and Water Treatment
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    • 제7권4호
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    • pp.313-325
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    • 2016
  • South Africa recognises piped water as the main source of safe drinking water supply. Remote areas do not have access to this resource and they rely solely on surface water for survival, which exposes them to waterborne diseases. Interim point of use solutions are not practiced due to their laboriousness and alteration of the taste. Bio-ultra low pressure driven membrane system has been noted to be able to produce stable fluxes after one week of operation; however, there is limited literature on South African waters. This study was conducted on three rivers namely; Umgeni, Umbilo and Tugela. Three laboratory systems were setup to evaluate the performance of the technology in terms of producing stable fluxes and water that is compliant with the WHO 2008 drinking water guideline with regards to turbidity, total coliforms and E.coli. The obtained flux rate trends were similar to those noted in literature where they are referred to as stable fluxes. However, when further comparing the obtained fluxes to the normal dead-end filtration curve, it was noted that both the Umbilo and Tugela Rivers responded similarly to a normal dead-end filtration curve. The Umgeni River was noted to produce flux rates which were higher than those obtainable under normal dead-end. It can be concluded that there was no stabilisation of flux noted. However, feed water with low E.coli and turbidity concentrations enhances the flux rates. The technology was noted to produce water of less than 1 NTU and 100% removal efficiency for E.coli and total coliforms.

CMP특성과 온도의 상호관계에 관한 연구 (A Study on the Correlation between Temperature and CMP Characteristics)

  • 권대희;김형재;정해도;이응숙;신영재
    • 한국정밀공학회지
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    • 제19권10호
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    • pp.156-162
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    • 2002
  • There are many factors affecting the results of CMP (Chemical Mechanical Polishing). Among them, the temperature is related to the removal rate and WIWNU (Within Wafer Non-Uniformity). In other words, the removal rate is proportional to the temperature and the variation of temperature distribution on a pad affects the non-uniformity within a wafer. In the former case, the active chemistry improves the rate of chemical reaction and the removal rate becomes better. But, there are not many advanced studies. In the latter case, a kinematical analysis between work-piece and pad can be obtained. And such result analysed from the mechanical aspect can be directly related to the temperature distribution on a pad affecting WIWNU. Meanwhile, the temperature change affects the quantities of both slurry and pad. The change of a pH value of the slurry chemistry due to a temperature variation affects the surface state of an abrasive particle and hence the agglomeration of abrasives happens above the certain temperature. And the pH alteration also affects the zeta potential of a pad surface and therefore the electrical force between pad and abrasive changes. Such results could affect the removal rate and etc. Moreover, the temperature changes the 1st and 2nd elastic moduli of a pad which are closely related to the removal rate and the WIWNU.

현대 패션 주얼리 디자인에 나타난 '경계 흐려짐' 현상 - 복식 및 신체와의 관계를 중심으로 - (A Study on the Blurring of Boundary Reflected in Contemporary Fashion Jewelry Design -Focused on the relationship between fashion jewelry and costume or fashion jewelry and body-)

  • 황유정;최정화
    • 한국의류산업학회지
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    • 제17권1호
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    • pp.11-21
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    • 2015
  • This study analyzed the expressive phenomenon of a blurred boundary in fashion jewelry focused on the relationship between fashion jewelry and costume or fashion jewelry and body. The method of this study was to analyze recent documentaries about jewelry theories in regards to 607 cases of fashion jewelry design in fashion books, fashion magazines, fashion internet sites from 2000 to 2014. The results were: First, phenomenon of blurred boundary between fashion jewelry and costume was expressed in a see-through wear form made of luxury material (gold and diamond) or paste material, a similar form (like fashion accessories made of crystal, bids, and gold chain), an integration of fashion accessories and jewelry, and an attached jewelry on fashion accessories. It reflected a rearrangement of conventional relationships, a blurred relation of function and meaning, dissolution of jewelry form stereotypes, jewelry styling, a harmony of function and decoration, and an alteration to the central role of a fashion image. Second, the phenomenon of a blurred boundary between fashion jewelry and body was expressed in a body organ wrapping, body surface adhesion and sculptural jewelry based on body pose. It reflected a separation from conventional space of jewelry expression, a realization of mystery and fantastic, an expression of new body surface and a blurred boundaries of fashion jewelry and body art. Aesthetic characteristics were analyzed into metaphor and integration by separation from the conventional relationship of fashion jewelry and costume or fashion jewelry and body.