• Title/Summary/Keyword: surface activation

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Activation and n-butane adsorption characteristics of palm char (야자각탄의 활성화와 n-butane 흡착특성)

  • 김인기;오한준
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.174-184
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    • 1997
  • Activated carbons were prepared from palm chars by steam activation. The effect of the activation temperature and time, steam concentration and flux on the n -butane adsorption properties were investigated on the basis of surface area, pore analysis and n-butane adsorption. The amount of n -butane adsorption increased with steam concentration and steam flux at higher activation temperature to the $900^{\circ}C$, however this tendancy on the activated carbons were not observed at the temperature above $900^{\circ}C$, It was shown that surface area was 978 $\textrm{m}^2$/g, average pore size was 9.3 $\AA$ and n-butane adsorption was 5.9 g /100ml in the activated carbons, prepared at $900^{\circ}C$, 185 minutes.

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Vortex relaxation for the surface barrier in 3D type-II superconductor (3차원 제2종 초전도체의 표면장벽에 대한 자속의 이완)

  • Kim, Gun-Cheol;Cheon, Mi-Yeon;Kim, Young-Cheol;Kim, Bong-Jun
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.262-265
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    • 1999
  • We report the activation energies which is calculated by adding a term being neglected usually, and magnetic relaxation effects for the surface barrier. The activation energies U at initial magnetization m (m$_{en}$ and m$_{ex}$) and equilibrium magnetization m$_{eq}$ are nearly similar to those of Burlachkov, but the m dependence of the activation energy U is remarkably different. The relaxation effects, which were determined by the m dependence of the activation energies U, are nonlinear for vortex entry, but linear at the initial stage and nonlinear at m(Int) ${\simeq}$ m$_{eq}$ for vortex exit. During relaxation process, the vortex entry at m = m$_{en}$ is faster than the vortex exit at m = m$_{ex}$ by about factor 90. The vortex exit at m = m$_{eq}$ is faster than one at m = m$_{ex}$ by about factor 1.3

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Adsorption Characteristics of Activated Carbon Prepared From Waste Citrus Peels by NaOH Activation (NaOH 활성화법으로 제조한 폐감귤박 활성탄의 흡착특성)

  • Kang, Kyung-Ho;Kam, Sang-Kyu;Lee, Song-Woo;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.16 no.11
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    • pp.1279-1285
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    • 2007
  • The activated carbon was prepared from waste citrus peels using NaOH. With the increase of NaOH ratio, iodine adsorptivity and specific surface area of the activated carbon prepared were increased, but activation yield was decreased. The optimal condition of activation was at 300% NaOH and $700^{\circ}C$ for 1.5 hr. For the activated carbon produced under optimal condition, iodine adsorptivity was 1,006 mg/g, specific surface area was $1,356 m^2/g$, and average pore diameter was $20{\sim}25{\AA}$. From the adsorption experiment for benzene vapor in fixed bed reactor, it was found that the adsorption capacity of activated carbon prepared from waste citrus peel was higher than that of activated carbon purchased from Calgon company. This result implied that the activated carbon prepared from waste citrus peel could be used for gas phase adsorption.

ESTIMATION OF ALUMINUM AND ARGON ACTIVATION SOURCES IN THE HANARO COOLANT

  • Jun, Byung-Jin;Lee, Byung-Chul;Kim, Myung-Seop
    • Nuclear Engineering and Technology
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    • v.42 no.4
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    • pp.434-441
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    • 2010
  • The activation products of aluminum and argon are key radionuclides for operational and environmental radiological safety during the normal operation of open-tank-in-pool type research reactors using aluminum-clad fuels. Their activities measured in the primary coolant and pool surface water of HANARO have been consistent. We estimated their sources from the measured activities and then compared these values with their production rates obtained by a core calculation. For each aluminum activation product, an equivalent aluminum thickness (EAT) in which its production rate is identical to its release rate into the coolant is determined. For the argon activation calculation, the saturated argon concentration in the water at the temperature of the pool surface is assumed. The EATs are 5680, 266 and 1.2 nm, respectively, for Na-24, Mg-27 and Al-28, which are much larger than the flight lengths of the respective recoil nuclides. These values coincide with the water solubility levels and with the half-lives. The EAT for Na-24 is similar to the average oxide layer thickness (OLT) of fuel cladding as well; hence, the majority of them in the oxide layer may be released to the coolant. However, while the average OLT clearly increases with the fuel burn-up during an operation cycle, its effect on the pool-top radiation is not distinguishable. The source of Ar-41 is in good agreement with the calculated reaction rate of Ar-40 dissolved in the coolant.

The Effect of Center of Pressure Displacement and Muscle Activation Onset during Expected and Unexpected Sudden Upper Limb Loading in Subjects with Low Back Pain and Healthy Subjects (예측된 그리고 예측되진 않은 갑작스런 상지로의 부하 적용시 요통 환자와 정상인의 압력 중심 이동 및 근활성 개시에 미치는 영향)

  • Chae, Yun-Won
    • The Journal of Korean Physical Therapy
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    • v.18 no.4
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    • pp.51-60
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    • 2006
  • Purpose: This study was to compare the effect of center of pressure(COP) displacement and muscle activation onset during expected and unexpected sudden limb loading in subjects with low back pain and healthy control subjects. Most studies of COP displacement and muscle activation onset on postural task focused on sudden trunk loading or gross limb movements. Investigation of the COP displacement and muscle activation onset during expected and unexpected sudden upper limb loading deserves similar attention. Methods: For this study, 14 subjects with low back pain and 12 healthy control subjects are participated. Force plate and surface EMG measures were used to determine COP displacement and muscle activation onset under expected and unexpected sudden upper limb loading. Results: COP displacement and muscle activation onset under unexpected sudden upper limb loading were similar in subjects with low back pain and healthy control subjects. However, COP displacement and muscle activation onset under expected sudden upper limb loading were shortened in healthy control subject but not among the subjects with low back pain. Conclusion: The results provide evidence for impaired feed-forward control in subjects with low back pain.

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A Study on the Effect of Pre-treatment on the Formation of Nitriding Layer by Post Plasma (포스트 플라즈마를 이용한 질화의 질화층 형성에 미치는 전처리의 영향에 대한 연구)

  • Moon, Kyoung Il;Byun, Sang Mo;Cho, Yong Ki;Kim, Sang Gweon;Kim, Sung Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.1
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    • pp.24-28
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    • 2005
  • New post plasma nitriding can achieve a high uniformity that have been difficult in DC nitriding and have a high productivity comparable to gas nitriding. However, it has not a enough high nitriding potential for a rapid nitriding, because surface activation or ion etching in the general plasma nitriding cannot be expected. Thus, in this study, the effects of pre-treatments with oxidation and reduction gas have been investigated to improve the nitriding kinetics of post plasma nitriding. An effective pre-treatment consisting of oxidation and reduction resulted in the increase of surface energy of STD 11. This induced the surface hardness and the effective nitriding depth of STD 11. It is thought that the increase of the surface energy and the surface area with pre-treatment promote the nucleation of nitriding layer.

Electrochemical Characteristics of Dental Implant in the Various Simulated Body Fluid and Artificial Saliva (다양한 유사체액과 인공타액에서 치과용 임플란트의 전기화학적 특성)

  • Kim, T.H.;Park, G.H.;Son, M.K.;Kim, W.G.;Jang, S.H.;Choe, H.C.
    • Journal of the Korean institute of surface engineering
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    • v.41 no.5
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    • pp.226-231
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    • 2008
  • Titanium and its alloy have been widely used in dental implant and orthopedic prostheses. Electrochemical characteristics of dental implant in the various simulated body fluids have been researched by using electrochemical methods. Ti-6Al-4V alloy implant was used for corrosion test in 0.9% NaCl, artificial saliva and simulated body fluids. The surface morphology was observed using scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX). The electrochemical stability was investigated using potentiosat (EG&G Co, 263A). The corrosion surface was observed using scanning electron microscopy (SEM). From the results of potentiodynamic test in various solution, the current density of implant tested in SBF and AS solution was lower than that of implant tested in 0.9% NaCl solution. From the results of passive film stability test, the variation of current density at constant 250 mV showed the consistent with time in the case of implant tested in SBF and AS solution, whereas, the current density at constant 250mV in the case of implant tested in 0.9% NaCl solution showed higher compared to SBF and AS solution as time increased. From the results of cyclic potentiodynamic test, the pitting potential and |$E_{pit}\;-\;E_{corr}$| of implant tested in SBF and AS solution were higher than those of implant tested in 0.9% NaCl solution.

Preparations of PAN-based Activated Carbon Nanofiber Web Electrode by Electrostatic Spinning and Their Applications to EDLC (정전방사에 의한 PAN계 활성화 탄소 나노섬유 전극 제조와 EDLC 응용)

  • Kim, Chan;Kim, Jong-Sang;Lee, Wan-Jin;Kim, Hyung-Sup;Edie, Dan D.;Yang, Kap-Seung
    • Journal of the Korean Electrochemical Society
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    • v.5 no.3
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    • pp.117-124
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    • 2002
  • Poly(acrylonitrile)(PAN) solutions in dimethylformamide(DMF) were electrospun to prepare webs consisting of 400nm ultra-fine fibers. The webs were oxidatively stabilized, activated by steam and resulted to be activated carbon fibers(ACFs). The specific surface area was $800\~1230 m^2/g$, which showed a trend of a decrease of the surface area with an increase in activation temperature, showing opposite behavior to the other ACFs. The activation energy of the stabilized fibers for the steam activation was determined as 29.2 kJ/mol to be relatively low indicating the easier activation than that of other carbonized fibers. The ACF webs were characterized by pore size and specific surface uea which would be related to the specific capacitance of the electrical double layer capacitor (EDLC). The specific capacitances measured were 27 F/g, 25 F/g, 22 F/g at the respective activation temperature of $700^{circ}C,\;750^{\circ}C\;800^{\circ}C$, showing similar trend with the specific surface area i.e., the higher activation temperature was, the lower specific capacitance resulted.

Several imageries classification with EEG

  • Choi, Kyoung-Ho;Jung, Sung-Jae;Kim, Il-Hwan
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.450-452
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    • 2004
  • Every movement, perception and thought we perform is associated with distinct neural activation patterns. Neurons in the brain communicate with each other by sending electrical impulses that produce currents. These currents give rise to electrical fields that can be measured outside the head. It shows some variation on the electroencephalographic signals. In recent devices, the EEG signals measured from head surface are a sum of all the momentary brain activation. With these EEG signals, it is difficult to distinguish the patterns correlated with a certain event from the signals. However, the system must discriminate some patterns with some events especially for any kind of device as a brain control interface system. In this experiment, the sensory-motor cortex of humans has been extensively studied. Activation related to several movements on both sides of the sensory-motor cortices in imaginary. The activation patterns during imagination of several movements resemble the activation patterns during preparation of movements. The result represents the system based on the optimal filters discriminated at least 60% of mental imageries.

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Oxidation Kinetics of Carbon Fibers

  • Roh, Jae-Seung
    • Carbon letters
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    • v.6 no.1
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    • pp.1-5
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    • 2005
  • Isotropic pitch based carbon fibers were exposed to isothermal oxidation in carbon dioxide gas to study the activation kinetics under the temperature of 800~$1100^{\circ}C$. The kinetic equation $f=1-{\exp}(-at^b)$ was introduced and the constant b was obtained in the range of 0.92~1.25. It was shown that the activated carbon fiber shows the highly specific surface area (SSA) when the constant b comes close to 1. The activation kinetics were evaluated by the reaction-controlling regime (RCR) according to changes of the apparent activation energy with changes of the conversion. It was observed that the activation energies increase from 47.6 to 51.2 kcal/mole with the conversion increasing from 0.2 to 0.8. It was found that the pores of the activated carbon fiber under the chemical reaction were developed well through the fiber.

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