• 제목/요약/키워드: surface activation

검색결과 1,416건 처리시간 0.035초

XPS Studies of CO Adsorption on Polycrystalline Nickel Surface

  • Boo, Jin-Hyo;Ahn, Woon-Sun
    • Bulletin of the Korean Chemical Society
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    • 제9권6호
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    • pp.388-393
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    • 1988
  • The chemisorption of CO molecules on polycrystalline nickel surface has been studied by investigating the resulting chemisorbed species with the X-ray photoelectron spectroscopy at temperatures between 300K through 433K. It is found that the adsorbed CO molecules are dissociated by the simple C-O bond cleavage as well as by the disproportionation reaction at temperatures above 373K. The former type dissociation is more favored at low coverages and at elevated temperatures. The isotherms of CO chemisorption are obtained from the xps intensities of C 1s peaks, and then the activation energy of the dissociative adsorption is estimated as a function of the CO exposure. These activation energies are extrapolated to zero coverage to obtain the activation energy of chemisorption in which thermal C-O bond cleavage takes place. The value obtained is 38.1 kJ/mol.

Activation analysis of targets and lead in a lead slowing down spectrometer system

  • Lee, Yongdeok;Kim, Jeong Dong;Ahn, Seong Kyu;Park, Chang Je
    • Nuclear Engineering and Technology
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    • 제50권1호
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    • pp.182-189
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    • 2018
  • A neutron generation system was developed to induce fissile fission in a lead slowing down spectrometer (LSDS) system. The source neutron is one of the key factors for LSDS system work. The LSDS was developed to quantify the isotopic contents of fissile materials in spent nuclear fuel and recycled fuel. The source neutron is produced at a multilayered target by the (e,${\gamma}$)(${\gamma}$,n) reaction and slowed down at the lead medium. Activation analysis of the target materials is necessary to estimate the lifetime, durability, and safety of the target system. The CINDER90 code was used for the activation analysis, and it can involve three-dimensional geometry, position dependent neutron flux, and multigroup cross-section libraries. Several sensitivity calculations for a metal target with different geometries, materials, and coolants were done to achieve a high neutron generation rate and a low activation characteristic. Based on the results of the activation analysis, tantalum was chosen as a target material due to its better activation characteristics, and helium gas was suggested as a coolant. In addition, activation in a lead medium was performed. After a distance of 55 cm from the lead surface to the neutron incidence, the neutron intensity dramatically decreased; this result indicates very low activation.

A study on elemental mercury adsorption behaviors of nanoporous carbons with carbon dioxide activation

  • Bae, Kyong-Min;Park, Soo-Jin
    • Carbon letters
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    • 제15권4호
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    • pp.295-298
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    • 2014
  • In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs' pore structures and total pore volumes were analyzed by reference to $N_2$/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on their specific surface area and micropore fraction.

The Effects of Performing a One-legged Bridge with Hip Abduction and Unstable Surface on Trunk and Gluteal Muscle Activation in Healthy Adults

  • Bak, Jong-Woo;Cho, Min-Kwon;Chung, Yi-Jung
    • The Journal of Korean Physical Therapy
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    • 제28권3호
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    • pp.205-211
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    • 2016
  • Purpose: This study investigated the influence of muscle activity of the trunk and lower limb during a bridge exercise using a unstable surface and during one-legged bridge hip abduction in healthy adults. Methods: Nineteen healthy participated in this study (12 males and 7 females, aged $29.0{\pm}5.0$). The participants were instructed to perform the bridge exercises under six different conditions. Trunk and lower limb muscle activation, such as the erector spinae (ES), gluteus maximus (GM), external oblique (EO), and internal oblique (IO), was measured using surface electromyography. The six different bridge exercise conditions were conducted randomly. Data analysis was performed by using the mean scores after three trials of each condition. Results: On the ipsilateral side, muscle activity of the IO, EO, and ES during the hip abduction condition (Single-legged hip abduction bridge, Bridge with use of a ball and single-leg hip abduction, Bridge with use of a sling and single-leg hip abduction) was significantly higher than those during Unstable surface (Bridge with use of a ball, Bridge with use of a sling) and General bridging exercise (p<0.05). In the contralateral side, activities of the GM and EO during Single-legged hip abduction bridge, Bridge with use of a ball and single-leg hip abduction and Bridge with use of a sling and single-leg hip abduction was significantly higher than that during Bridge with use of a ball, Bridge with use of a sling and General bridging exercise (p<0.05). Conclusion: This study demonstrated that performing a bridge exercise with use of a sling and single-leg hip abduction had an effect on trunk and gluteal muscle activation. The findings of this study suggest that this training method can be clinically effective for unilateral training and for patients with hemiplegia.

필라테스 슈퍼맨 동작 시 탄성밴드 사용유무와 지면의 종류에 따른 근활성도 분석 (The Analysis of EMG According to Surface Type and Elastic Band Usage During the Pilates Superman Movement)

  • 손남정;이경옥
    • 한국운동역학회지
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    • 제25권2호
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    • pp.219-229
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    • 2015
  • Objective : The purpose of this study was to analyze EMG according to surface type and elastic band usage during the pilates Superman movement. Method : The subjects were 10 female university students with a mean age of 27. The independent variables were surface type (yoga mat, air filled equipment, elastic mat) and elastic band usage. In order to measure muscle activity, the Noraxon(USA) was used. Eight muscles (upper trapezius, lower trapezius, thoracic spine, lumbar spine, gluteus maximus, gluteus medius, biceps femoris, semitendinosus) activation were analyzed. For the statistical analysis, MANOVA, independent t-test and Scheffe test for the post-hoc via SPSS 20.0 was used. Results : The left and right upper trapezius muscle activities were significantly reduced when using the elastic bands. In addition gluteus medius muscle activities significantly increased with the elastic band as well. Conclusion : According to the usage of the elastic band and the different types of surfaces, different muscle groups were recruited. Elastic bands were found to have more activation on the gluteus medius muscle meanwhile there was less activation on the upper trapezius during the pilates Superman movement.

다중 기능성 그룹을 포함하는 마이크로포어 탄소의 합성 및 전기화학적 특성 (Synthesis of microporous carbons containing multi-functional groups and their electrochemical performance)

  • 김기석;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.94.2-94.2
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    • 2011
  • In this work, multi-functional groups, i.e., nitrogen and oxygen, contained microporous carbons (MF-MCs) were prepared by the one step carbonization of the poly(vinylidene chloride-co-acrylonitrile-co-methyl methacryalte) (PVDC-AN-MMA) without activation. The electrochemical performance of MF-MCs was investigated as a function of carbonization temperature. It was found that MF-MCs had a high specific surface area over $800m^2/g$ without additional activation, resulting from the micropore's formation by the release of chlorine groups. In addition, although functional groups decreased, specific surface area was increased with increasing carbonization temperature, leading to the enhanced electrochemical performance. The pore size of the carbon distributed mainly in small micropore of 1.5 to 2 nm, which was idal for aqueous electrolyte. Indeed, the unique microstructure features, i.e. high specific surface area and optimized pore size provided high energy storage capability of MF-MCs. These results indicated that the microporous features of MF-MCs lead to feasible electron transfer during charge/discharge duration and the presence of nitrogen and oxygen groups on the MF-MCs electrode led to a pseudocapacitive reaction.

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탄소섬유의 KOH 활성화와 휘발성 유기화합물(VOC)의 흡착특성 (Activation of Carbon Fibers by KOH and Adsorption Characteristics for VOC)

  • 장진석;김인기;임굉;조성준
    • 한국재료학회지
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    • 제9권4호
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    • pp.362-367
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    • 1999
  • We intended to make the activated carbon fibers which could separate, remove and recover the volatile organic compounds of benzene, toluene, acetone and methanol. Changing activation temperature and time, large specific surface area and narrow pore distribution could be obtained. The activated carbon fibers have large adsorption capacity and selectivility for those organic compounds. We characterized the adsorption capability of the activated carbon fibers for benzene, toluene, acetone and methanol by BET specific surface area and pore size and micropore volume measurements. In the result of activation, the maximum value of BET specific surface area of the fibers was $1100\m^2$/g at $800^{\circ}C$ for 60 minutes and $K_2$O was reduced actively in this condition. Their average pore size was 5.8~5.9$\AA$. The activated carbon fibers prepared in this work had high adsorption rate to saturation and the selectibility for the above organic compounds. The adsorbed amount of acetone and methanol(diameter of$ 4.3\AA$ and $4.4\AA$ respectively) which are smaller than micropore diameter in size was 43~49%, which was larger value than benzene and toluene(in the same diameter as $5.9\AA$).

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무전해 니켈 도금법을 이용한 고성능 도전사의 제조 (Fabrication of Highly Conductive Yarn using Electroless Nickel Plating)

  • 홍소야;이창환;김주용
    • 한국염색가공학회지
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    • 제22권1호
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    • pp.77-82
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    • 2010
  • Highly conductive yarn was successfully obtained using electroless nickel plating method with palladium activation. In the presence of palladium seed on surface of fibers as a catalyst, continuos nickel layer produced on surface of fibers by reducing $Ni${2+}$ ion in the electroless plating bath to $Ni^0$. It was found that the Pd-activation using $SnCl_2$ and $PdCl_2$ to deposit palladium seeds on the surface of fibers plays a key role in the subsequent electroless plating of nickel. It also found that electroless nickel plating on the fibers can induce the nickel-plated $ELEX^{(R)}$ fibers to improve the electrical conductivity of the fibers. The thickness of nickel coating layer on the Pd-activated $ELEX^{(R)}$ fibers and specific conductivity of the fiber were increased through electroless plating time. The temperature of nickel plating bath was very effective to enhance the nickel deposition rate.

변형막 식각 방법에 따른 탄화규소 쇼트키 다이오드의 전기적 특성 (Electrical characteristics of SiC schottky diodes treated by the various dry etch methods for a damaged surface)

  • 최영민;강인호;방욱;주성재;김상철;김남균;김성진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.232-233
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    • 2008
  • The 4H-SiC schottky diodes treated by the various dry etch methods were fabricated and electrically characterized. The post etch process including an Inductively Coupled Plasma(ICP) etch and a Neutron Beam Etch(NBE) was performed after a high-temperature activation annealing without graphite cap in order to eliminate the damaged surface generated during the activation annealing. The reverse leakage current of diode treated by ICP was 1/35 times lower than that of the diode without any post etch at the anode bias of -100V, while the reverse leakage current of diode treated by NBE was 1/44 times lower at the same bias.

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