• 제목/요약/키워드: supported metal

검색결과 361건 처리시간 0.023초

CO2 Reforming of Methane over Co-Pd/Al2O3 Catalysts

  • Itkulova, Sh. S.;Zhunusova, K.Z.;Zakumbaeva, G.D.
    • Bulletin of the Korean Chemical Society
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    • 제26권12호
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    • pp.2017-2020
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    • 2005
  • The supported bimetallic Co-containing catalysts promoted by the different amount of noble metal (Pd) have been studied in the dry reforming of methane. The activity, selectivity, stability and resistance to the carbon deposition of Co-Pd/$Al_2O_3$ catalysts depend on both the catalyst composition and process conditions. It has been observed that the Co-Pd/$Al_2O_3$ catalysts produce the various oxygenates from $CO_2$ + $CH_4$ at moderate pressures.

Top Electrode Engineering in Organic Light-Emitting Devices Formed by Soft Contact Lamination

  • Lee, Tae-Woo;Zaumseil, Jana;Bao, Zhenan;Hsu, Julia W.P.;Rogers, John A.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.348-351
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    • 2004
  • We describe a new approach for building organic light-emitting diodes (OLEDs), which is based on physical lamination (i.e. soft contact lamination (ScL)) of thin metal electrodes supported by an elastomeric layer (polydimethylsiloxane) against an electroluminescent organic. We find that the devices fabricated have much better performance than those constructed with conventional vacuum deposition process. In addition, the ScL is intrinsically compatible with the technique of soft lithograph so that it is easy to build patterned OLEDs with feature sizes into the nanometer regime.

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Supported Metal Oxides for Continuous Cat-alytic Wet Oxidation of TCE

  • 김문현;추광호
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2004년도 봄 학술발표회 발표논문집
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    • pp.40-45
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    • 2004
  • 액상 TCE 제거반응을 위한 Hetero-CWO 촉매들 중에서 $CoO_{x}$/$TiO_2$$CuO_{x}$/$TiO_2$가 상대적으로 유망한 것으로 보여졌으며, 특히 5% $CoO_{x}$/$TiO_2$ 촉매의 경우에 반응시간에 따른 활성추이는 TCE 제거반응에서 주요 역할을 할 수 있는 반응 활성점의 변화를 암시하고 있다. $FeO_{x}$ /$TiO_2$와 Fe-MFI 촉매상에서 TCE 제거반응에 대한 시간에 따른 활성거동으로부터 활성점의 redox cycle를 어떻게 제어하는가 하는 점이 매우 중요함을 알 수 있었으며, 촉매표면에서 이를 유지.증진시킬 수 있는 촉매 디자인 기법이 요구되었다.

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Purification and Characterization of Thiol-Specific Antioxidant Protein from Human Liver: A Mer5-Like Human Isoenzyme

  • Cha, Mee-Kyung;Kim, Il-Han
    • BMB Reports
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    • 제29권3호
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    • pp.236-240
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    • 1996
  • A 23-kDa molecular mass of antioxidant protein was purified from human liver. This protein exhibited the preventive effect against the inactivation of glutamine synthetase by a metal-catalyzed oxidation system. This antioxidant activity was supported by a thiol-reducing equivalent such as dithiothreitol in a similar manner to that of the 25-kDa thiol-specific antioxidant protein (TSA) from human red blood cells (HR). However, a thioredoxin-linked peroxidase activity of thiol-specific antioxidant protein of human liver (HLTSA) (0.91 ${\mu}mol/min/nmol$ of HLTSA) was much lower than that of thiol-specific antioxidant protein of human red blood cells (HRTSA) (16.4 ${\mu}mol/min/nmol$ of HRTSA). This HLTSA is also immnologically distinct from HRTSA Amino acid sequences of the three tryptic peptides (P1, P2, P3) of HLTSA were found to be completely homologous to segments of the known Mer5-like protein, which belongs to the known TSA family.

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신생산기술 실행과정상에 조직 적응노력의 효과성 분석

  • 이상곤;이진주
    • 한국경영과학회:학술대회논문집
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    • 대한산업공학회/한국경영과학회 1994년도 춘계공동학술대회논문집; 창원대학교; 08월 09일 Apr. 1994
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    • pp.627-632
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    • 1994
  • This study suggests the contingency framework understanding the implementation of NIMT and conducts empirical analysis using survey data. The main objectives of the thesis are as follows : (1) analyzing the relationship between adaptation requirements and organizational adaptation efforts. (2) analyzing the relationship between organizational adaptation efforts and implementation performance, and the moderating effect of the adaptation requirements. (3) analyzing the relationship between organizational adaptation efforts and organization characteristics(organization size, technical capability, top management support). A field study was undertaken to test the hypothesized relationships among adaptation efforts, adaptations requirements, organization characteristics, implementation performance. Data were collected from 52 NMT implementation projects of 45 machine tool, metal component firms. The emprical relflts indicated that adaptation requirrnents, organization characteristics were significantly related to organizational adaptation efforts and adaptation efforts can significantly improve implementation perfomance, but the moderating effect of adaptation requirements on adaptation efforts and implementation performance was not supported.

저NOx형 하니컴 촉매버너의 개발 (Development of a low NOx burner with honeycomb catalyst)

  • 서용석;박병식;강성규
    • 대한기계학회논문집B
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    • 제21권6호
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    • pp.822-829
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    • 1997
  • A catalytic burner was studied which can be used as a heater operated in medium temperature. Noble metal catalysts (Pd/NiO) were used, which were supported on alumina wash coated honeycomb. The maximum heat-resisting temperature of the catalyst is about 900.deg. C. Combustion efficiency of the catalytic burner reached more than 99.5 % at the excess air ratio above 1.25.NOx emissions were lower than 1.0 ppm at all operation conditions. The operation condition for a stable catalytic combustion was obtained. It was dependent on the catalyst thickness. The 30 mm thick catalyst showed the widest stable catalytic combustion region. Stable catalytic combustion region of 30 mm thick catalyst was the operation condition of excess air ratio 1.25 - 1.75 and heat flux 7 - 14 kcal/h center dot cm$^{2}$.

미세접촉인쇄기법을 이용한 다기능성 자기조립막 제작과 전자.생물소자로의 응용 (Fabrication of Multi-functional Self-Assembled Monolayers by Microcontact Printing and Their Application for Electronic and Biological Devices)

  • 최대근;유형균;양승만;조정대;이응숙
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.1021-1024
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    • 2003
  • In this work, we fabricated various 2D metallic and polymeric nanopatterns with the feature resolution of sub-micrometer scale by using the method of microcontact printing ($\mu$ P) based on soft lithography. Silicon masters for the micromolding were made by e-beam lithography. Composite poly(dimethylsiloxane) (PDMS) molds were composed of a thin, hard layer supported by soft PDMS layer. Finally, monodisperse metal or polymer particles could be obtained in the prepared pattern for the application of electronic devices.

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An analytical solution for bending and vibration responses of functionally graded beams with porosities

  • Zouatnia, Nafissa;Hadji, Lazreg;Kassoul, Amar
    • Wind and Structures
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    • 제25권4호
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    • pp.329-342
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    • 2017
  • This work presents a static and free vibration analysis of functionally graded metal-ceramic (FG) beams with considering porosities that may possibly occur inside the functionally graded materials (FGMs) during their fabrication. A new displacement field containing integrals is proposed which involves only three variables. Based on the suggested theory, the equations of motion are derived from Hamilton's principle. This theory involves only three unknown functions and accounts for parabolic distribution of transverse shear stress. In addition, the transverse shear stresses are vanished at the top and bottom surfaces of the beam. The Navier solution technique is adopted to derive analytical solutions for simply supported beams. The accuracy and effectiveness of proposed model are verified by comparison with previous research. A detailed numerical study is carried out to examine the influence of the deflections, stresses and natural frequencies on the bending and free vibration responses of functionally graded beams.

THERMAL PLASMA SYNTHESIS OF NANO-SIZED POWDERS

  • Seo, Jun-Ho;Hong, Bong-Guen
    • Nuclear Engineering and Technology
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    • 제44권1호
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    • pp.9-20
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    • 2012
  • A brief review on the thermal plasma synthesis of nano-sized powders is presented according to the application materials, such as, metals, ceramics, glasses, carbonaceous materials and other functional composites, such as, supported metal catalyst and core-shell structured nano materials. As widely adopted plasma sources available for thermal plasma synthesis of nanosized powders, three kinds of plasma torches, such as transferred and non-transferred DC and RF plasma torches, are introduced with the main features of each torch system. In the basis of the described torch features and the properties of suggested materials, application results including synthesis mechanism are reviewed in this paper.

CRT 텐션 마스크의 장력 이완 저감을 위한 연구 (A Study for Reducing Tension Loosening in CRT Tension Mask)

  • 정일섭
    • 한국정밀공학회지
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    • 제20권6호
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    • pp.214-221
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    • 2003
  • Tension mask assembly is positioned right behind the glass-made front panels of CRT type display devices. The frame-supported thin metal sheet contains numerous slits, through which electron beams are focused to enhance definition. Pretension is imposed on the masks, especially for enlarged flat screens, in order to avoid vibration due to acoustic or mechanical impact. High temperature assembly process subsequent to pretensioning, however, degenerates the creep resistance of common mask materials, and if tensile stress is high enough, tension on the mask may be loosened substantially due to creep deformation. In this study, the assembly is modeled as a combined structure of beams and wire array, and a numerical simulation is attempted for pretensioning followed by high temperature process. According to a model study, small amount of creep strain is likely to be generated, but its adverse influence is not negligible. Some structural modification measures to reduce the creep-induced tension loosening are proposed and evaluated. Also, optimal configuration of frame structure is sought for, which maintains high tension of masks and minimizes the possible creep of frame simultaneously.