• 제목/요약/키워드: supported

검색결과 10,413건 처리시간 0.037초

Synthesis and characterization of carbon doped TiO2 photocatalysts supported on stainless steel mesh by sol-gel method

  • Tijani, JO.;Fatoba, OO.;Totito, TC.;Roos, WD.;Petrik, LF.
    • Carbon letters
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    • 제22권
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    • pp.48-59
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    • 2017
  • This study synthesized pure anatase carbon doped $TiO_2$ photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/$TiCl_4$. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The XRD patterns showed that the supported $TiO_2$ nanocrystals are typically anatase, polycrystalline and body-centered tetragonal in structure. The EDS and XPS results complemented one another and confirmed the presence of carbon species in or on the $TiO_2$ layer, and the XPS data suggested the substitution of titanium in $TiO_2$ by carbon. Instead of using calcination, PAN pyrolysis was used to control the carbon content, and the mesoporosity was tailored by the applied temperature. The supported $TiO_2$ nanocrystals prepared by pyrolysis at 300, 350, and $400^{\circ}C$ for 3 h on a stainless steel mesh were actual supported carbon doped $TiO_2$ nanocrystals. Thus, $PAN/DMF/TiCl_4$ offers a facile, robust sol-gel related route for preparing supported carbon doped $TiO_2$ nanocomposites.

Acetone Enhancement of Cumene Hydroperoxide-supported Microsomal Cytochrome P450-dependent Benzo(a)pyrene Hydroxylation

  • Moon, Ja-Young;Lim, Heung-Bin;Sohn, Hyung-Ok;Lee, Young-Gu;Lee, Dong-Wook
    • BMB Reports
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    • 제32권3호
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    • pp.226-231
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    • 1999
  • In vitro effects of acetone on cytochrome P450 (P450)-dependent benzo(a)pyrene (B(a)P) hydroxylation supported by cumene hydroperoxide (CuOOH) or NADPH/$O_2 $ systems were studied using 3-methylcholanthrene-pretreated rat liver microsomes. The maximal rate of B(a)P hydroxylation at constant concentration ($80\;{\mu}M)$ of the substrate was observed in the presence of $30\;{\mu}M$ CuOOH. However, at concentrations higher than $30\;{\mu}M$ CuOOH the hydroxylation rates were rapidly decreased. In contrast to CuOOH, at a concentration of $200\;{\mu}M$ NADPH, B(a)P hydroxylation rate reached a plateau. At concentrations higher than $200\;{\mu}M$ NADPH, the rates of substrate hydroxylation were maintained at the maximal rate with no inhibition. Acetone at 1% (v/v) enhanced both CuOOH- and NADPH/$O_2$-supported B(a)P hydroxylation at the optimal concentrations of the cofactors. At concentrations higher than 1% (v/v) acetone, substrate hydroxylation was sterero specific under the support of these two cofactors; it was strongly enhanced with $30\;{\mu}M$ CuOOH, but rather inhibited in the $200\;{\mu}M$> NADPH/$0_2 $ system. The lipid peroxidation rate induced during CuOOH-supported P450-dependent B(a)P hydroxylation was increased as CuOOH concentrations were increased. Acetone in the concentration range of 2.5~7.5%(v/v) inhibited lipid peroxidation during CuOOH supported B(a)P hydroxylation. The finding that CuOOH-supported B(a)P hydroxylation is greatly enhanced by acetone suggests that acetone may contribute more to the activation of oxygen (for the insertion of oxygen into the substrate) in the presence of CuOOH than with NADPH/$O_2$. Acetone may also contribute to the partial inhibition of destruction of microsomal membranes by lipid peroxidation.

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가중치 워크플로우 소셜 네트워크의 사이중심도 분석방법 (A Betweenness Centrality Analysis Method in Valued Workflow-supported Social Networks)

  • 김미선;김광훈
    • 인터넷정보학회논문지
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    • 제17권1호
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    • pp.65-71
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    • 2016
  • 본 논문에서는 가중치 및 방향성 워크플로우 소셜네트워크의 사이중심도 분석방법과 그에 따른 알고리듬을 제안한다. 기존의 워크플로우 소셜네트워크는 워크플로우 모델을 구성하는 단위업무를 처리하는 과정에서 수행자들간의 업무전달관계 유무를 이진 소셜네트워크 모델로 표현한 것이다. 그러나, 워크플로우 기반 조직을 구성하는 수행자들간의 업무전달관계를 효과적으로 분석하기 위해서는 기존의 수행자들간의 관계유무를 기본으로 하는 이진 소셜네트워크 정보 뿐 만 아니라 수행자들간의 정량적 업무전달관계와 그 업무전달관계의 방향성 또한 효과적인 분석결과를 획득하는데 있어서 매우 중요한 요인이다. 결과적으로, 본 논문에서는 수행자 그룹의 효과적인 업무전달관계 분석을 수행하기 위하여 정량적 업무전달관계 수준과 그의 방향성을 고려한 가중치 및 방향성 워크플로우 소셜네트워크 개념과 수행자 그룹의 사이중심도 분석방법 및 알고리듬을 제안한다. 특히, 제안한 분석방법을 검증하기 위하여 기존의 이진 워크플로우 소셜네트워크에 대한 사이중심도 분석방법과 본 논문에서 제안한 가중치 및 방향성 워크플로우 소셜네트워크에 대한 사이중심도 분석방법을 특정 워크플로우 모델에 적용하여 그 분석결과를 비교한다.

중소기업의 정부지원 정보화정책 성과평가 시점 연구 (A Study on the Timeliness for Performance Evaluation of Government-supported Information Policies)

  • 김락상;오상영
    • 한국산학기술학회논문지
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    • 제10권4호
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    • pp.872-876
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    • 2009
  • 정부는 중소기업의 정보화를 촉진시키기 위하여 지난 수년간 여러 종류의 정책자금을 지원하였다. 정부가 지원하는 정보화 지원 자금의 성격은 대부분 무상 지원으로 중소기업에게는 좋은 기회가 되어 왔다. 또한 정부는 지원하는 정책의 결과에 대한 성과도 관리하고자 노력하고 있다. 본 연구는 정부가 그동안 지원한 정보화정책에 대한 평가를 어떠한 단계로 하는 것이 타당한지 실증적 연구를 하였다. 실증 연구는 상관분석을 실시하였으며 측정에 활용한 요인간의 상관관계 결과는 유의한 것으로 나타났다. 정보화지원 정책을 통한 성과평가 시점에 대한 결과는 조직전략 분야의 평가가 Step3(장기적), 내부 운영 분야의 평가는 Step2(중기적), 지원과정의 평가는 Step1(단기적)의 평가단계로 나타났다.

원자힘현미경을 이용한 지지 지질층의 특성규명 (Characterization of Supported Lipid Layers Using Atomic Force Microscopy)

  • 박진원
    • Korean Chemical Engineering Research
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    • 제47권4호
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    • pp.395-402
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    • 2009
  • 원자힘현미경은 초미세크기의 물리적 특성을 규명하기 위한 수단으로서 지지 지질층의 물리적특성 규명에 이용되어 왔다. 원자힘현미경이 출현하기 이전에는 초미세관점에서 지지 지질층에서 발생하는 물리적 현상의 관찰이 전무하였다. 이 현미경은 탐침바늘(Cantilever)로 표면을 주사(Scanning)함으로써 표면의 초미세 형상(Morphology)을 제공하고 표면에 접근(Approach)했다가 후퇴(Retraction)하는 탐침바늘의 거동을 모니터링함으로써 힘곡선(Force Curve)을 나타낼 수 있다. 형상 파악을 통해 지지 지질층의 구조와 막 단백질이 지질층의 구조에 미치는 영향을 밝히는 연구가 진행되어 왔으며, 힘곡선을 통하여 지지 지질층 표면 특성-기계적 정전기적 특성-에 대한 연구가 진행되었다. 본 총설에서는 원자힘현미경을 이용하여 현재까지 진행된 지지 지질층의 구조와 표면 특성 연구에 대하여 소개하고 향후 연구 진행 방향에 대하여 논의하고자 한다.

지지체의 변화에 따른 Ni-페라이트의 2단계 열화학 사이클 반응 특성에 관한 연구 (Two-Step Thermochemical Cycle with Supported $NiFe_2O_4$ for Hydrogen Production)

  • 김우진;강경수;김창희;조원철;강용;박주식
    • 한국수소및신에너지학회논문집
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    • 제19권6호
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    • pp.505-513
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    • 2008
  • The two-step thermochemical cycle was examined on the $CeO_2$, YSZ, and $ZrO_2$-supported $NiFe_2O_4$ to investigate the effects of support material addition. The supported $NiFe_2O_4$ was prepared by the aerial oxidation method. Thermal reduction was conducted at 1573K and 1523K while water-splitting was carried out at 1073K. Supporting $NiFe_2O_4$ on $CeO_2$, YSZ and $ZrO_2$ alleviated the high-temperature sintering of iron-oxide. As a result, the supported $NiFe_2O_4$ exhibited greater reactivity and repeatability in the water-splitting cycle as compared to the unsupported $NiFe_2O_4$. Especially, $ZrO_2$-supported $NiFe_2O_4$ showed better sintering inhibition effect than other supporting materials, but hydrogen production amount was decreased as cycle repeated. In case of $CeO_2$-supported $NiFe_2O_4$, improvement of hydrogen production was found when the thermal reduction was conducted at 1573K. It was deduced that redox reaction of $CeO_2$ activated above 1573K.

The Effect of Plank Exercises with Hip Abduction Using Sling on Trunk Muscle Activation in Healthy Adults

  • Bak, Jongwoo;Shim, Suyoung;Cho, Minkwon;Chung, Yijung
    • The Journal of Korean Physical Therapy
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    • 제29권3호
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    • pp.128-134
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    • 2017
  • Purpose: The purpose of this study is to investigate the effects of healthy persons performing a plank exercise with hip abduction and use of sling on trunk muscle activity. Methods: Twenty-three subjects participated in this study. Muscle activities of the multifidus, rectus abdominis, external oblique and internal oblique were assessed with electromyography (EMG) while the subjects performed 6 various types of plank exercises in random order. Results: There was a significant difference in multifidus and internal oblique on the supported side and the multifidus, external oblique, and internal oblique on the elevated side (p<0.05), and differences in plank methods were significantly higher in the multifidus, rectus abdominis, external oblique, internal oblique of the supported side and the rectus abdominis, external oblique and internal oblique on the elevated side (p<0.05). In addition, post-hoc analysis of the various plank methods showed that muscle activity was significantly higher during the general plank exercise compared with the knee-supported-in-sling plank exercises (p<0.05), and was significantly higher with the ankle-supported-in-sling plank exercises compared with the general plank exercise. Conclusion: There was greater trunk muscle activity with plank exercises performed with the ankle-supported-in-sling and hip abduction plank exercises compared with the general or knee-supported-in-sling plank exercises. Through this study, various plank exercises have been discovered that can be selected at different intensities for core muscle training purposes based on trunk muscle strength.

500W 급 연료극 지지체 평관형 고체산화물연료전지 스택의 운전 특성 (Operating Characteristics of Advanced 500W class Anode-supported Flat Tubular SOFC stack in KIER)

  • 임탁형;김관영;박재량;송락현;이승복;신동열
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2007년도 추계학술 발표회
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    • pp.193-198
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    • 2007
  • KIER has been developing the anode supported flat tubular SOFC stack for the intermediate temperature $(700{\sim}800^{\circ}C)$ operation. for this purpose, we have first fabricated anode supported flat tubular cells by the optimization between the current collecting method and the induction brazing process. After that we designed the compact fuel & air manifold by adopting the simulation technique to uniformly supply fuel & air gas and the unique seal & insulation method to make the more compact stack. For making stack, the prepared anode-supported flat tubular cells with effective electrode area of $90cm^2$ of connected in series with 12 modules, in which one module consists of two cells connected in parallel. The performance of stack in 3 % humidified $H_2$ and air at $800^{\circ}C$ shows maximum power of 507 W. Through these experiments, we obtained basic & advanced technology of the anode-supported flat tubular cell and established the proprietary concept of the anode-supported flat tubular SOFC stack in KIER.

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탄성적으로 지지된 철근콘크리트 선형판의 유한요소 해석 (Finite Element Analysis of the Reinforced Concrete Circular)

  • 조진구
    • 한국농공학회지
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    • 제35권1호
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    • pp.59-66
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    • 1993
  • Ring Sector Plate Supported by Elastic Beam Although all the reinforced concrete circular ring sector plates are elastically supported, it is conventional to simplify their supporting conditions as fixed or simply-supported ones assuming that their supporting beam has infinite stiffness. However, in order to obtain a precise solution, it should be required to consider the stiffness of their supporting beam. As a methodological improvement to the precise analysis, "Reinforced Concrete Model" previously developed by the author was applied to the structural analysis of the reinforced concrete circular ring sector plates with elastically supported beam. The results of analysis in the cases under various conditions of open angle, steel ratio, relative stiffness(EI/DL) between plate and supporting beam were summarized as follows ; 1.Although the effect of relative stiffness between plate and supporting beam varies depending on the magnitude of open angle, in general, it shows the largest when not more than 5.0 and negligible when not less than 10.0. Therefore, it would be considered as fixed supporting condition :in the case of its open angle of 0$^{\circ}$rectangular plates), its stiffness ratio being not less than 10.0 and in the other case of its open angle of 30$^{\circ}$, its stiffness ratio being not less than 5.0. 2.In the rectangular plates, the effect of steel ratio is considerable in no supporting condition, but neglible in the supporting condition. So, the effect of steel ratio should be negligible in the case of the elastically supported circular ring sector plates. 3.However, the effect of steel ratio is much more considerable in the case of the fixed supported circular plates, especially, when steel ratio being not more than 1.0% and stiffness ratio being smaller. So, the effect of steel ratio should be considered in the analysis of reinforced concreate circular ring sector plates with fixed conditions. 4.The effect of open angle is greater in the case of without-supporting beam conditions. However, in the other case of with-supporting beam conditions, the effect is a little bit when open angle of not more than 300 and negligible when open angle of not more than 30$^{\circ}$.

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