• Title/Summary/Keyword: supercritical carbondioxide

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Selective Extraction of Phospholipids from Soybeans with Mixture of Supercritical Carbondioxide and Ethanol (초임계 $CO_2$와 에탄올 혼합물에 의한 대두인지질의 선택적 추출)

  • Lee, Mi-Jin;Jeon, Young-Soo;Jeong, Noh-Hee;Jeang, Bu-Shik
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.233-239
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    • 2010
  • Supercritical carbondioxide is very effective in removing oils from a variety of seed matrices, devoid of any appreciable amount of phospholipid content. However, the limited solubility of phosphalipids in supercritical carbondioxide leaves behind a potentially valuable by-product in spent seed matrix. Any phospholipid extraction process from the spent matrix must maintain the structure and the quality of phospholipids and must be compatible with the end use of the seed protein meal an animal feed or for human consumption. An initial supercritical carbondioxide extraction of soybean flakes was performed at 32 MPa and $80^{\circ}C$ to extract the oils, leaving the phospholipids in the deflatted soybean flakes, A second step was performed on the defatted soybean flake using $X_{eth}$=0.10, Varying the pressure from 175 MPa to 70.6 MPa and temperature from $60^{\circ}C$ to $80^{\circ}C$. For all supercritical carbon dioxide/ethanol mixture extractions, a fraction rich in phospholipids was obtained. The fractions extracted from defatted soybean flakes were dried and them redissolved in chloroform before HPLC-ELSD analysis. Quantitative and qualitative analysis of phospholipids on soybean seeds, defatted soybean flake, and different extracted phospholipid fractions was carried out, to ascertain the effect of extraction pressure and temperature.

Supercritical Carbon Dioxide Extraction of Oil from Chlorella vulgaris (초임계 이산화탄소를 이용한 Chlorella vulgaris의 오일 추출)

  • Ryu, Jong-Hoon;Park, Mi-Ran;Lim, Gio-Bin
    • KSBB Journal
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    • v.26 no.5
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    • pp.453-458
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    • 2011
  • In this study, two different extraction techniques, organic solvent extraction and supercritical carbon dioxide ($SCCO_2$) extraction, were employed to evaluate the extraction efficiency of oil from Chlorella vulgaris. In the organic solvent extraction, the effects of various organic solvent on the extraction yield were investigated. The $SCCO_2$ extraction was carried out while varying such operating parameters as temperature, pressure, $SCCO_2$ flow rate, and cosolvent. About 4.9 wt% of oil was extracted from ground Chrollera vulgaris for 18 h when dichloromethane/methanol (2:1, v/v) was used as an extraction solvent. The oil yield of the $SCCO_2$ extraction was found to be very low (0.53 wt%) and to increase up to about 0.86 wt% with the addition of cosolvent.

Waste heat recovery of recirculated MCFC using supercritical carbon dioxide power cycle (초임계 이산화탄소 사이클을 이용한 연료 재순환 MCFC의 폐열회수)

  • Lee, Jae Yoon;Ahn, Ji Ho;Kim, Tong Seop
    • Plant Journal
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    • v.15 no.2
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    • pp.42-45
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    • 2019
  • The molten carbonate fuel cell has a high temperature of waste heat and can constitute a bottoming cycle to increase the efficiency. Previous study used a bottoming cycle as steam turbine cycle. In this study, we are going to replace the bottoming cycle with a supercritical carbon dioxide power cycle. The system power was compared to consider replacing the bottoming cycle. As a result, the power of the supercritical carbon dioxide power cycle at the present development stage is lower than that of the steam turbine cycle, but theoretically, the power can be larger than the steam turbine cycle. If the supercritical carbon dioxide power cycle improves the isentropic efficiency of the turbine by 89%, the isentropic efficiency of the compressor by 83%, and the effectiveness of the recuperator by 0.9, the power can be same to the steam turbine cycle.

Evaluation of Estrogenic Activity of Pumpkin Seed Extract using Recombinant Yeast Assay (재조합 효모를 이용한 호박씨 추출물의 에스트로겐 활성 평가)

  • Tahk, Hong-Min;Lee, Bog-Hieu;Rho, Sook-Nyung;Kim, Chun-Soo;Jung, Ji-Youn;Choi, Chang-Sun
    • Journal of Food Hygiene and Safety
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    • v.24 no.2
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    • pp.124-127
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    • 2009
  • The aim of this study is to evaluate the estrogenic activity of Cucurbita pepo seed extract which includes ${\beta}-sitosterol$ and other phytosterols. Sample was extracted from Cucurbita pepo seed by supercritical carbondioxide method and resuspended with ethanol. Estrogenic activity was measured by recombinant yeast assay which detects estrogenic activity using recombinant yeast with high level of estrogenic receptor. However, estrogenic activity of pumpkin seed extract was not found in this study. Based on this data, pumpkin seed extract will not cause estrogenic disturbance.

Adsorption Characteristics on Organic Solvents Diluted in Supercritical Carbondioxide Measured by Chromatography and IR Spectroscopy (적외분광법과 크로마토 측정기법을 이용한 초임계 이산화탄소 중에 희석시킨 유기용매의 흡착특성)

  • Jin, Do-Won;Kim, Young-Il;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.76-81
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    • 1998
  • Physical adsorption on a silica gel(pore size of 80 nm, particle size of $10{\mu}m$)has been studied for binary mixture of acetone diluted in $CO_2$ by use of a FTIR transmission technique and we have compared the result of FTIR transmission technique with that of a chromatographic technique. Measurements were made at 313.2 K and under pressures up to 15MPa. As the pressure increases from 0.1MPa, the IA(Integral Absorbance) of the hydrogen-bonded OH groups interacting with acetone and adsorbed amount by use of a chromatographic technique increases at first, and reaches a maximum at a pressure below the critical pressure of $CO_2$, and then the intensities decrease gradually with increasing pressure. It is found that the pressure dependency of the chromatographic isotherm is a little larger than that of spectroscopic isotherm in the supercritical fluid region. This difference might be attributable to the weaker van der Waals force and relatively stronger hydrogen-bonding force influencing the adsorption of acetone on the sllica gel. The unique spectroscopic characteristics of amine group which vibrational frequencies of hydroxyl groups on the silica gel surface shift downward to about $1300cm^{-1}$ were measured from experimental result of triethylamine diluted in $CO_2$ or $N_2$.

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