• Journal of the Korean Applied Science and Technology
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• v.30 no.4
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• pp.635-648
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• 2013

This study was carried out to investigate the emulsifying properties of surface-active substances from defatted rapeseed cake by supercritical $CO_2$ extraction. Based on the interfacial tension data, a supercritical fluid extract (SFE) with the lowest value of 14.16 mN/m was chosen for evaluation which was obtained from No. 2 extraction condition (150 bar, $65^{\circ}C$, 250 g). For emulsions with SFE, some physicochemical properties (i.e., fat globule size, creaming stability, zeta potential etc) were investigated according to changes in SFE concentration, pH, and NaCl addition in an emulsion. It was found that fat globule size was decreased with increasing SFE concentration in emulsion, with showing a critical value at 0.5 wt%, thereby resulting in less susceptibility to creaming behavior. The SFE emulsion also showed instability at acidic conditions (pH<7.0) as well as by NaCl addition. This was coincided with zeta potential data of emulsion. In addition, SSL (sodium stearoyl lactylate) found to be suitable as a co-surfactant, as it helped considerably in decreasing fat globule size in emulsions and its optimum concentration to be over 0.03 wt%, based on 0.1 wt% SFE in emulsion.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.121-126
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• 2008

The cooling heat transfer coefficient of $CO_2$ (R-744) in a horizontal and helically coiled tube was investigated experimentally. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater, evaporator and gas cooler (test section). The test section consists of a horizontal stainless steel tube and hellically coiled copper tube of 4.57 and 7.75 mm. The experiments were conducted at saturation temperature of 100 to $20^{\circ}C$, and mass flux of 200 to $500kg/m^2s$. The test results showed the variation of the heat transfer coefficient tended to decrease as cooling pressure of $CO_2$ increased. The heat transfer coefficient with respect to mass flux increased as mass flux increased. The experimental results were also compared with the existing correlations for the supercritical heat transfer coefficient, which generally underpredicted the measured data. However, the experimental data showed a relatively good agreement with the correlations of Pitla et al. except for the pseudo critical temperature.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.06a
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• pp.216-221
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• 2005

The heat transfer coefficient and pressure drop during gas cooling process of carbon dioxide in a helically coiled tube were investigated experimentally. The experiments were conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable speed pump, a mass flowmeter, a pre-heater, a gas cooler(test section) and an isothermal tank. The test section is a double pipe type heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus. It was made of a copper tube with the inner diameter of 4.85 [mm], the outer diameter of 6.35 [mm] and length of 10000 [mm]. The refrigerant mass fluxes were 200${\sim}$600 [kg/$m^2$s] and the average pressure varied from 7.5 [MPa] to 10.0 [MPa]. The main results were summarized as follows: The heat transfer coefficient of supercritical $CO_2$ increases, as the cooling pressure of gas cooler decreases. And the heat transfer coefficient increases with the increase of the refrigerant mass flux. The pressure drop decreases in increase of the gas cooler pressure and increases with increase the refrigerant mass flux.

• The Korean Journal of Food And Nutrition
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• v.36 no.4
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• pp.264-273
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• 2023

Physicochemical properties and storage stability of plant-based alternative meat prepared with low-fat soybean powder (LPAM) treated by supercritical-CO₂ and those of full-fat soybean powder (FPAM) were compared. Ash and crude protein contents were higher in LPAM than in FRAM. Water absorption capacity and oil absorption capacity were significantly higher in LPAM than in FPAM. Water binding capacity was higher in LPAM than in FPAM during a 20 days storage period at 5℃ and pH was significantly lower in LPAM than in FPAM after a 5~10 days storage period. Hardness, gumminess and chewiness significantly increased with the increase in the storage period, and the three were significantly higher in LPAM than in FPAM after 10 days and 20 days of storage. The acid value showed no remarkable difference according to the storage period in LPAM; however, it was significantly higher in FPAM than in LPAM after 20 days of storage. The peroxide value and TBA value were significantly increased according to the storage period, and were significantly lower iin LPAM than in FPAM during all the storage periods. Therefore, the use of low-fat soybean powder may be effective in improving oxidative stability during storage in the production of plant-based alternative meat.

• Nuclear Engineering and Technology
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• v.52 no.9
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• pp.2107-2118
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• 2020

The nuclear reactor coupled with supercritical carbon dioxide (S-CO₂) Brayton cycle has good prospects in generation IV reactors. Turbomachineries (turbine and compressor) are important work equipment in circulatory system, whose performances are critical to the efficiency of the energy conversion system. However, the sharp variations of S-CO₂ thermophysical properties make turbomachinery performances more complex than that of traditional working fluids. Meanwhile, almost no systematic analysis has considered the effects of turbomachinery efficiency under different conditions. In this paper, an in-house code was developed to realize the geometric design and performance prediction of S-CO₂ turbomachinery, and was coupled with systematic code for Brayton cycle characteristics analysis. The models and methodology adopted in calculation code were validated by experimental data. The effects of recompressed fraction, pressure and temperature on S-CO₂ recompression Brayton cycle were studied based on detailed design of turbomachinery. The results demonstrate that the recompressed fraction affects the turbomachinery characteristic by changing the mass flow and effects the system performance eventually. By contrast, the turbomachinery efficiency is insensitive to variation in pressure and temperature due to almost constant mass flow. In addition, the S-CO₂ thermophysical properties and the position of minimum temperature difference are significant influential factors of cyclic performance.

• Clean Technology
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• v.10 no.3
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• pp.149-158
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• 2004

Supercritical carbon dioxide is often promoted as an environmentally friendly solvent having useful properties for a wide range of technical and chemical processes. But the limited ability of $CO_2$ to dissolve polar or non-volatile compounds represents a major drawback in many processes, because the key components will often fail to form homogeneous solution under practical conditions. The design of $CO_2$ soluble ($CO_2$-philic) surfactant to aid this process is therefore paramount in these areas, which has advanced the "greening" of demanding yet important applications in dyeing, cleaning of fibers and texiles, polymerization and polymer processing, photoresist removal, electroplating, and chemical synthesis.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.4
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• pp.315-321
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• 2005

Supercritical carbon dioxide extraction was investigated as a method for removing lipids and bad flavor from tuna viscera. To find the optimum conditions, different experimental variables, such as pressure, temperature, flow rate of solvent and sample size, were evaluated for the effective removal of lipids and the undesirable smell. Ethanol was used as the entrainer, with a $3\%$ by vol $CO_2$ flow rate. By increasing the pressure at constant temperature, the efficiency of the lipid removal was improved and the protein was concentrated without denaturalization. The main fatty acids extracted from the tuna viscera were palmitic acid (16:0), heptadecanoic acid (17:1), oleic acid (18:1) and docosahexaenoic acid (22:6). The major amino acids in the tuna viscera treated by supercritical carbon dioxide were glutamic acid, leucine and lysine, and the free amino acids were L-proline, taurine and L-$\alpha$-aminoadipic acid.

• Korean Journal of Food Science and Technology
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• v.31 no.5
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• pp.1300-1307
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• 1999

Supercritical fluid extraction was applied to recycling triglyceride from used shortening. Used shortening and its fractions were analyzed with high performance size exclusion chromatography for their composition in triglycerides, polymer and low molecular weight compounds. Conjugated diene value and color of the fractions were also measured with a UV spectrophotometer and a colorimeter, respectively. Pressure and temperature ranges employed were $15{\sim}30$ MPa and $40{\sim}60^{\circ}C$, respectively. Concentration of fat in supercritical (SC) $CO_2$ ranged from $0.3\;X\;10^{-3}{\sim}7.4\;X10^{-3}(g\;fat/g\;CO_2)$. An exponential relation between concentration of fat in SC $CO_2$ and density was observed. Color of the extracts was light yellow which was very close to that of the fresh shortening. Low molecular weight compounds were preferentially concentrated in the initial fraction, while polymer was extracted in the final fraction. Conjugated diene value of the initial fractions was clearly lower than that of feed. It increased sharply as the polymer content in the fraction became significantly large.

• Korean Journal of Food Science and Technology
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• v.30 no.5
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• pp.1163-1168
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• 1998

Fish tissues were spiked with organophosphorus pesticides (OPPs), mixed with a celite as a drying agent, and dynamically extracted with pure $CO_2$ or modified $CO_2$ for 10 min at different extraction temperatures, pressures and $CO_2$ flow rates. Recoveries of OPPs spiked in jacopever increased with the decrease of extraction temperature and pressure, and decreased with the increase of $CO_2$ flow rates. Modified $CO_2$ extractions with 10% methylene chloride showed a slight increase in the recoveries over pure $CO_2$ extraction. Quantity of fish tissues had great effect on their extraction efficiencies. Recoveries of OPPs were $66.7{\sim}86.3%$ for jacopever, $56.2{\sim}79.2%$ for yellow tail, $57.6{\sim}77.8%$ for blanquillo, $84.2{\sim}96.3%$ for sardine, $74.6{\sim}83.6%$ for mackerel. Application of supercritical carbon dioxide extraction offers an attractive alternative to the use of organic solvents for extraction of pesticide residues from fish tissues.

• Journal of Welding and Joining
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• v.28 no.1
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• pp.41-46
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• 2010

The low alloy-steel material(1.0Cr-0.5Mo, SA213T12), which has widely been used for the waterwall tube in the conventional power plant, do not have enough creep rupture strength for waterwall tubes of the Ultra-supercritical(USC) boilers. According to this reason, the high-strength low alloy-steel(2.25Cr-1.0Mo, SA213T22) has newly been adopted for the waterwall tube in the USC boilers. This paper presents failure analysis on weld-joint of the waterwall tubes in USC boilers. Visual inspections were performed to find out the characteristics of the fracture. Additionally both microscopic characteristics and hardness test were carried out on failed tube samples. Failures seem to happen mainly because the welding process has not been conducted strictly.(preheating, P.W.H.T and so forth). Thus, this paper has the purpose to describe the main cause of the poor welding process and to explain how to prevent similar failures in those weld-joints.