• Journal of the Korean Institute of Gas
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• v.11 no.3
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• pp.44-48
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• 2007

The cooling heat transfer characteristics of supercritical $CO_2$ in a helical coil gas cooler on the change of coil diameters are experimentally investigated. The main components of the refrigerant loop are a receiver, a variable speed pump, a mass flow-meter, a pre-heater and a helical coil gas cooler (test section). The test sections are made of a copper tube which the inner diameter is 4.55 mm and the helical coil diameters are done of 26.75 mm and 41.35 mm. The mass fluxes of refrigerant are varied from 200 to 800 [$kg/m^2s$] and the inlet pressures of gas cooler are 7.5 to 10.0 (MPa). A gas cooler with helical coil diameter of 26.75 mm has larger heat transfer coefficient than that of 41.35 mm. Also, when compared with experimental data and published correlations avaliable, most of correlations are under-predicted, but Pitla published correlations avaliable, most of correlations are under-predicted, but Pitla et al.'s correlation shows a relatively good coincidence with the experimental data except the region of pseudo critical temperature.

• Journal of the Semiconductor & Display Technology
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• v.16 no.1
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• pp.22-28
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• 2017

The result of stripping process for the removal of the post etch/ash Photoresist (PR) residue on an aluminum patterned wafer by using supercritical $CO_2$ ($sc-CO_2$) mixture, was investigated by scanning of electron microscope (SEM) inspection of wafer, measuring the cloud points and visual observation of the state of $sc-CO_2$ mixtures. It was found that $sc-CO_2$ mixtures were made by mixing additives and $sc-CO_2$ should form homogeneous and transparent phase (HTP) in order to effectively and uniformly remove the post etch/ash PR residue on the aluminum patterned wafer using them. The additives were formulated by mixing and co-solvents like an amine compound and fluorosurfactants used as HTP agents, and the PR residue on the wafer were able to be rapidly and effectively removed using the $sc-CO_2$ mixture of HTP. The five kinds of additives were formulated by the recipe of mixing co-solvents and surfactants, which were able to remove PR residue on the wafer by mixing with $sc-CO_2$ at the stripping temperature range from 40 to $80^{\circ}C$. The five kinds of $sc-CO_2$ mixtures which were named as PR removers were made, which were able to form HTP within the above described stripping temperature. The cloud points of $sc-CO_2$ mixtures were measured to find correlation between them and HTP.

• Bulletin of Food Technology
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• v.18 no.4
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• pp.113-119
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• 2005

• Proceedings of the Korean Nuclear Society Conference
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• 2001.10a
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• pp.329.1-329
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• 2001

• Korean Journal of Acupuncture
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• v.37 no.2
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• pp.88-96
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• 2020

Objectives : The purpose of this study was to investigate the anti-oxidant and anti-aging effect of the seed of Euphorbia lathyris L. extracted by supercritical CO₂. Methods : Human dermal fibroblast cells dosed with the extract from Euphorbia lathyris L. were harvested and the intracellular proteome was analyzed to examine the expression of proteins related collagen synthesis pathway, metalloproteinases (MMPs), extracellular matrix (ECM)-cell interaction, cytokines, and antioxidant enzymes by 2-dimensional gel electrophoresis. Results : Fatty acid analysis of the extract from Euphorbia lathyris L. showed oleic acid was 84% and linoleic acid was 4.1%. Antioxidative effect was about 53% by beta carotene bleaching assay. In 2-dimensional polyacrylamide gel electrophoresis (2-D PAGE) analysis, fifteen protein changes in five mechanisms which were collagen synthesis pathway, MMPs, ECM-cell interaction, cytokines, and antioxidant enzymes were analyzed. Conclusions : This study suggests the supercritical extraction from the seed of Euphorbia lathyris L. could be used as anti-oxidant substances for pharmacopuncture.

• Clean Technology
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• v.13 no.2
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• pp.99-103
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• 2007

Pt/Nafion self-humidifying membranes for Polymer Electrolyte Membrane Fuel Cell (PEMFC) were synthesized via a supercritical-impregnation method. The Nafion 112 membranes were impregnated with Pt(II) acetylacetonate from a supercritical carbon dioxide ($scCO_2$) solution at $80^{\circ}C$ and 19.8 MPa. After the impregnation, the Pt-impregnated Nafion membrane was converted Pt deposited Nafion(Pt/Nafion) membrane by reducing agent, sodium borohydride ($NaBH_4$) under $50^{\circ}C$ and 2 hours. The prepared Pt/Nafion membranes were investigated by SEM, EDS and EPMA. The performance of the Pt/Nafion membranes was examined in PEMFC as a self-humidifying membrane. The cell performance of the Pt/Nafion membrane at $65^{\circ}C$ is better than that of Nafion 112.

• Clean Technology
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• v.14 no.1
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• pp.1-6
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• 2008

Removal of paraffin wax from a ceramic injection mold using supercritical $CO_2$ has been studied. The paraffin wax is used as a binder in the ceramic injection molding process. The effects of pressure, temperature and flow rate of supercritical $CO_2$ on the removal of the paraffin wax were investigated. The removal rates were measured with various flow rates of $CO_2$ in the range of 328.15 - 348.15 K and 15 - 30 MPa. The removal rate of paraffin wax increased as the pressure increased. In the effect of temperature, the paraffin wax was effectively removed over 329.15K (melting point of paraffin wax), however, the efffct of temperature was not significant when the temperature was further increased. The increase of $CO_2$ flow rate also affected the removal of paraffin wax. However, the effect of flow rate was not observed when the flow rate reached a certain value. Propane was used as a co solvent in order to remove the paraffin wax effectively. When the propane was added to the $CO_2$, the removal efficiency was improved. The paraffin wax was completely removed from the ceramic injection mold without any change in their shape and the structure.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.29 no.8
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• pp.408-418
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• 2017

Supercritical carbon dioxide ($sCO_2$) power system is emerging technology because of its high cycle efficiency and compactness. Meanwhile, PCHE (Printed Circuit Heat Exchanger) is gaining attention in $sCO_2$ power system technology because PCHE with high pressure-resistance and larger heat transfer surface per unit volume is fundamentally needed. Thermo-fluidic characteristics of $sCO_2$ in the micro channel of PCHE should be investigated. In this study, heat transfer characteristics of $sCO_2$ of various inlet conditions and cross-sectional shapes of single micro channel were investigated experimentally. Experiment was conducted at supercritical state of higher than critical temperature and pressure. Test sections were made of copper and hydraulic diameter was 1 mm. Convective heat transfer coefficients were measured according to each interval of the channel and pressure drop was also measured. Convective heat transfer coefficients from experimental data were compared with existing correlation. In this study, using measured data, a new empirical correlation to predict near critical region heat transfer coefficient is developed and suggested. Test results of single channel will be used for design of PCHE.

• Polymer(Korea)
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• v.37 no.6
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• pp.685-693
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• 2013

The foams of a poly(lactic acid) modified by the reactive compounding were produced with the batch foaming technique using supercritical $CO_2(scCO_2)$. Experiments were performed at $105{\sim}135^{\circ}C$ and 12~24 MPa. The blowing ratio and foam structure were significantly affected by changing the temperature and pressure conditions in the foaming process. The blowing ratio first increased with increasing foaming temperature and saturation pressure, reached a maximum and then decreased with a further increase in the foaming temperature and saturation pressure. Decreasing the rate of depressurization permitted a longer period of cell growth and therefore larger microcellular structures were obtained.

• Proceedings of the Korean Nuclear Society Conference
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• 2004.05a
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• pp.466.2-466.2
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• 2004