• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.05a
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• pp.366-369
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• 2003

High T$_{c}$ superconducting lines will be applied as key materials in the areas of power transmission line; magnetic levitation of vehicle; magnetic separation; magnetic energy storage and marine propulsion. A combination method of electrophoresis deposition and zone-melting for preparation of YBaCuO tape is proposed. The submicron particle powder of YBaCuO made by sol-gel method is used in the electrophoresis process. A 40~50${\mu}{\textrm}{m}$ thickness of YBaCuO film on Ag plate could be deposited in about three minutes. After deposition the film is rolled and heat treated in order to increase the density and the adhesion of the film to the Ag plate. Silver(Ag) and lead oxide(PbO) were added in the YBaCuO powder in order to reduce its melting point. The YBaCuO coating with controlled Ag and PbO contents was preliminarily zone-melted at about 945$^{\circ}C$.>.

• Progress in Superconductivity
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• v.4 no.2
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• pp.162-167
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• 2003

The critical current value of Bi-2223/Ag tape can be influenced by various factors. In particular, it was known that properties of precursor powders could affect the formation of Bi -2223 and grain growth rate of the same. Since, moistures and organic matters can easily contaminate the precursor powders of Bi-2223 tapes and degrade properties of superconductors, the precursor powders should be kept in optimal conditions to minimize contamination. In this study, the effect of moisture and organic matters has been investigated. A Bi-2223/Ag tape contaminated with a large amount of moisture and organic matter has been characterized by low critical current values and bubbling. It has been found that as the quantity of moisture increases, the Bi-2223 phases are formed at lower temperature and the amount of non-superconducting phase increases.

• 한국초전도학회:학술대회논문집
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• v.9
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• pp.329-333
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• 1999

The BSCCO 2223 Ag-sheathed tapes were prepared with spray dried precursor powders, which are of different starting condition. The J$_c$ in the short tapes varied from 24 kA/ cm$^2$ to 47 kA/ cm$^2$ at 77K and 0T. The largely improvement of J$_c$ in certain tape, which characterized with the large textured BSCCO 2223 grains, homogeneity of reactant and fewer tracks of second phases in final superconducting matrixes, could be due to optimization in the precursor powder.

• Journal of the Korean Ceramic Society
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• v.33 no.6
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• pp.718-724
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• 1996

Deformation mechanism map of Langdon-Mohammed type for YBa2Cu3O7-x superconducting ceramic was constructed by considering mechanisms of Nabarro-Herring Coble and powder-law creep and grain boundary sliding (GBS) with an accommodation by grain boundary diffusion. The map was found consistent with experi-mental results not only of the creep the also of the superplastic deformation. It showed the transition from interface reaction-controlled to the grain boundary diffusion-controlled GBS mechanism at about 1 ${\mu}{\textrm}{m}$ grain size and 100 MPa flow stress in agreement with the experimental results.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2000.02a
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• pp.3-5
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• 2000

Among the various processing techniques used in HTS wire fabrication, the PIP(Powder In Tube) method is currently one of the most promising for applications on an industrial scale. In this study, we have fabricated Bi-2223/Ag superconducting tapes using the modified PIT process, where several process factors were changed and improved, ie., powder packing, drawing, rolling and heat treatment. We obtained Bi-2223 tape that have high critical current, 46 a at 77.3 K, have high critical current, 46A at 77.3 K, self field although the tape was not pressed but only rolled. The critical current of 100m class long length tape was measured 21.6A at the same criterion. Besides, the critical current of Bi-2223/Ag tape was measured applying magnetic fields with different directions at various temperatures.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.8
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• pp.664-670
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• 1998

고순도의 Bi(Pb)-Sr-Ca-Gu-O 초전도 분말의 얻기 위하여 액상법의 하나인 이멀젼 건조방법이 응용되었다. 다양한 합성 변수 중 오일과 용액의 계면활설제의 혼합비율을 조정하여 고순도의 Bi(Pb)-Sr-Ca-Gu-O 초전도 분말을 성공적으로 얻을 수 있었다. 이 공정의 최적 혼합비율은 70:20:10이였다. 관측된 분말을 구형이었으며 마이크론 크기 이하의 균일한 크기를 보였다. 최적의 소결조건에 한에 $840^{\circ}C$ 50시간의 열처리를 통하여 거의 108K를 갖는 초전도 분말이 얻어졌다.

• Journal of information and communication convergence engineering
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• v.1 no.2
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• pp.63-66
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• 2003

High $T_c$ superconducting lines will be applied as key materials in the areas of power transmission line; magnetic levitation of vehicle; magnetic separation; magnetic energy storage and marine propulsion. A combination method of electrophoresis deposition and zone-melting for preparation of YBaCuO tape is proposed. The submicron particle powder of YBaCuO made by sol-gel method is used in the electrophoresis process. A 40∼50 ${\mu}\textrm{m}$ thickness of YBaCuO film on Ag plate could be deposited in about three minutes. After deposition the film is rolled and heat treated in order to increase the density and the adhesion of the film to the Ag plate. Silver(Ag) and lead oxide(PbO) were added in the YBaCuO powder in order to reduce its melting point. The YBaCuO coating with controlled Ag and PbO contents was preliminarily zone-melted at about $945^{\circ}C$.

• Progress in Superconductivity
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• v.10 no.1
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• pp.40-44
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• 2008

A combined process of a mechanical ball milling and liquid glycerin ($C_{3}H_{8}O_3$) treatment of boron (B) powder has been conducted to enhance the superconducting properties of $MgB_2$. The individual aims of the mechanical milling and the glycerin treatment were to reduce the grain size of the $MgB_2$ and to achieve homogeneous carbon (C) incorporation into the $MgB_2$, respectively. Four kinds of B powders of as-received, glycerin treated, 2 h milled, and 2 h milled + glycerin treated were prepared. $MgB_2$ bulks were fabricated by in situ process using the prepared B powders. The mechanical ball milling was effective for a grain refinement, and a lattice disorder was easily achieved by glycerin addition. It was found that the critical current density ($J_c$) values were enhanced in the samples with milled B or glycerin treated B only. In the $MgB_2$ bulk prepared with both milled and glycerin treated B, the $J_c$ was further increased due to a higher grain boundary density and a greater C substitution.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07a
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• pp.585-588
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• 2003

Bi-2223 superconducting wires were fabricated by stacking, drawing process with different precursor powders and different heat-treatment histories. The precursor powders were 2 kinds of Pb content. And a part of the tapes were experienced pre-annealing process which caused tetragonal structure of Bi-2212 phase to orthorhombic structure of it was during drawing process. We confirmed the transformation of Bi-2212 phase from tetragonal structure to orthorhombic structure and reduction of second phases. AC magnetization analysis were performed in order to investigate the fraction of Bi-2223 phase in Bi-2223/Ag HTS tape. The cross sections of 55 filaments and 61 filaments were investigated after rolled in order to understand deformation mechanism of superconducting cores. We could achieve best Ic of 70 A class at the Bi-2223/Ag tape using low Pb content of precursor powder and experienced pre-annealing process. AC magnetization analysis was useful to investigate the fraction of Bi-2223 phase in the Bi-2223/Ag tape.

• Journal of Powder Materials
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• v.9 no.5
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• pp.359-364
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• 2002

We report the structure, thermal and magnetic properties of a non-equilibrium $Al_{0.6}(Fe_{50}Cu_{50})_{0.4}$ alloy powder produced by rod milling and chemical leaching. An X-ray diffractometry(XRD), a transmission electron microscope(TEM), a differential scanning calorimeter(DSC), a vibrating sample magnetometer(VSM), and superconducting quantum interference device(SQUID) were utilized to characterize the as-milled and leaching specimens. The crystallite size reached a value of about 8.82 nm. In the DSC experiment, the peak temperatures and crystallization temperatures decreased with increasing milling time. The activation energy of crystallization is 200.5 kJ/mole for as-milled alloy powder. The intensities of the XRD peaks of as-milled powders associated with the bcc type $Al_{0.5}Fe_{0.5}$ structure formative at $350^{\circ}C$ sharply increase with increasing annealing temperature. Above $400^{\circ}C$, peaks alloted to $Al_{0.5}Fe_{0.5}$ and $Al_{5}Fe_{2}$ are observed. After annealing at $600^{\circ}C$ for 1h, the leached Ll specimen transformed into bcc $\alpha$-Fe and fcc Cu phases, accompanied by a change in the structural and magnetic properties. The saturation magnetization decreased with increasing milling time, and a value of about 8.42 emu/g was reached at 500 h of milling. The coercivity reached a maximum value of about 142.7 Oe after 500 h of milling. The magnetization of leached specimens as function of fields were higher at 5 K, and increased more sharply at 5 K than at 100 K.