• Bulletin of the Korean Chemical Society
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• v.33 no.1
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• pp.183-188
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• 2012

A blue phosphorescent $Ir(dfpypy)_3$ (dfpypy:fluorinated pyridine-pyridine ligand) complex with meridional configuration has been synthesized by newly developed effective method and its solid state structure and photoluminescence are characterized. For this complex, mer-$Ir(dfpypy)_3$, the glass-transition and decomposition temperatures appear at $160^{\circ}C$ and $384^{\circ}C$ respectively in TGA and DSC experiments, which indicates that this complex has high thermal stability. In a crystalline structure, an average Ir-C bond length of mer-$Ir(dfpypy)_3$ is slightly longer than that of fac-$Ir(dfpypy)_3$, which assumed to be due to the weak trans-influence. The absorption and emission spectra are observed more red-shifted in mer-$Ir(dfpypy)_3$ than fac-$Ir(dfpypy)_3$. In addition, the former is readily oxidized than the latter in electrochemical behavior.

• Journal of the Korean Ceramic Society
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• v.56 no.5
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• pp.453-460
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• 2019

To reduce residual pores of composites and obtain a dense matrix, SiC_f/SiC composites were fabricated by chemical vapor deposition (CVI) using SiC nanorods. SiC nanorods were uniformly grown in the thickness direction of the composite preform when the reaction pressure was maintained at 50 torr or 100 torr at 1,100℃. When SiC nanorods were grown, the densities of the composites were 2.57 ~ 2.65 g/㎤, higher than that of the composite density of 2.47 g/㎤ for non-growing of SiC nanorods under the same conditions; grown nanorods had uniform microstructure with reduced large pores between bundles. The flexural strength, fracture toughness and thermal conductivity (room temperature) of the SiC nanorod grown composites were 412 ~ 432 MPa, 13.79 ~ 14.94 MPa·m^1/2 and 11.51 ~11.89 W/m·K, which were increases of 30%, 25%, and 25% compared to the untreated composite, respectively.

• International Journal of High-Rise Buildings
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• v.10 no.2
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• pp.149-164
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• 2021

Most of high-rise buildings in Japan^*1 are structure with damping systems recently. The design procedure is performance-based design (PBD), which is based on the nonlinear response history procedure (NRHP) using 2 or 3-dimentional frame model. In addition, hysteretic property of steel plates or velocity-dependent property of viscous dampers are common practice for the damping system. However, for the selection of damping system, the easy dynamic analysis of recent date may lead the most of engineers to focus attention on the maximum response only without thinking how it shakes. By nature, the seismic design shall be to figure out the action of inertia forces by complex & dynamic loads including periodic and pulse-like characteristics, what we call seismic ground motion. And it shall be done under the dynamic condition. On the contrary, we engineers engineers have constructed the easy-to-use static loads and devoted ourselves to handle them. The structures with damping system shall be designed considering how the stiffness & damping to be applied to the structures against the inertia forces with the viewpoint of dynamic aspect. In this paper we reconsider the role of damping in vibration and give much thought to the basic of shake with damping from a standpoint of structural design. Then, we present some design examples based on them.

• Journal of the Korean institute of surface engineering
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• v.56 no.4
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• pp.265-272
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• 2023

Photoelectrochemical (PEC) water splitting is one of the promising methods for hydrogen production by solar energy. Iron oxide has been effectively investigated as a photoelectrode material for PEC water splitting due to its intrinsic property such as short minority carrier diffusion length. However, iron oxide has a low PEC efficiency owing to a high recombination rate between photoexcited electrons and holes. In this study, we synthesized nanoporous structured iron oxide by anodization to overcome the drawbacks and to increase surface area. The anodized iron oxide was annealed in Ar atmosphere with different purging times. In conclusion, the highest current density of 0.032 mA/cm² at 1.23 V vs. RHE was obtained with 60 s of pursing for iron oxide(Fe-60), which was 3 times higher in photocurrent density compared to iron oxide annealed with 600 s of pursing(Fe-600). The resistances and donor densities were also evaluated for all the anodized iron oxide by electrochemical impedance spectra and Mott-Schottky plot analysis.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.37 no.6
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• pp.563-570
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• 2019

Red tide has caused massive fish kills in Korean coastal waters with devastating economic loss in the aquaculture industry since 1995. Remote sensing technique has shown to be effective for the detection of red tide in wide areas, where the absorption property of red tide water plays a central role in understanding the red tide reflectance. This study analyzed the optical absorption property of sea waters dominated by the dinoflagellate specie of Alexandirum affine, off the Tongyeong area in August, 2017. Water samples collected from 20 stations in the ship-based campaign were measured for absorption by pigment, suspended solid, and dissolved organic matter, with the corresponding water quality variables such as chlorophyll concentration and total suspended solid. The analysis showed that Alexandrium-dominated water exhibits strong absorption in the spectral range below 400 nm unlike that of diatom-dominated waters, and greater fluctuations in the range of 400 nm - 500 nm. The packaging effect in pigment absorption was stronger in Alexandrium-dominated waters, and the exponent in the absorption by detritus and gelbstoff is disparate for diatom and Alexandrium. In the model for the detritus and gelbstoff absorption (a_dg(λ)=a_dg(λ₀)e^-s(λ-λ₀)), the optimal exponent coefficient(s) for the Alexandrium was close to 0.01 rather than to 0.015, which was commonly use for modelling diatom waters.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.1
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• pp.93-99
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• 2008

In this paper, we propose new modulation schemes using the conventional CACB modulation with constant amplitude property. Also the proposed modulation schemes supports high transmission data rate by increasing the spectral efficiency. In order to obtain the high spectral efficiency, the $Q^2$PSK and CA-$Q^2$PSK are used. We explain the simplest combining modulation scheme of CACB and $Q^2$PSK (i.e., CACB-$Q^2$PSK). However, this modulation scheme cannot support the constant amplitude property. Hence the first CACB-CA-$Q^2$PSK (or CACB-CA-$Q^2$PSK I) modulation scheme is proposed for the constant amplitude property. In the modulation scheme, the redundant constant amplitude encoding (spectral efficiency decrease) is required. Therefore, the second CACB-CA-$Q^2$PSK (or CACB-CA-$Q^2$PSK II) modulation scheme is proposed retaining the constant amplitude and the spectral efficiency. Computer simulations show that the proposed CACB-CA-$Q^2$PSK II is the efficient modulation scheme.

• Journal of Internet Computing and Services
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• v.9 no.1
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• pp.21-32
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• 2008

In this paper, we propose new modulation schemes using the conventional CACB (Constant Amplitude Coded Multicode Biorthogonal) modulation with constant amplitude property. Also the proposed modulation schemes supports high transmission data rate by increasing the spectral efficiency, In order to obtain the high spectral efficiency, the $Q^2$AM (Quadrature-Quadrature Amplitude Modulation) and CA-$Q^2$AM (Constant Amplitude-$Q^2$AM) are used. We explain the simplest combining modulation scheme of CACB and $Q^2$AM (i.e., CACB-$Q^2$AM). However, this modulation scheme cannot support the constant amplitude property. Hence the first CACB-CA-$Q^2$AM (or CACB-CA-$Q^2$AM I) modulation scheme is proposed for the constant amplitude property. In the modulation scheme, the redundant constant amplitude encoding (spectral efficiency decrease) is required. Therefore, the second CACB-CA-$Q^2$AM (or CACB-CA-$Q^2$AM II) modulation scheme is proposed retaining the constant amplitude and the spectral efficiency. Computer simulations show that the proposed CACB-CA-$Q^2$AM II is the efficient modulation scheme.

• Journal of the Korean Chemical Society
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• v.66 no.3
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• pp.185-193
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• 2022

The theoretical investigation has been performed to predict thermodynamic stability, density, detonation velocity, and detonation pressure of energetic salts produced by pairing of nitrogen-rich anions (tetrazine, oxadiazole etc.) and cations (NH₃OH⁺, NH₂NH₃⁺, CH₉N₆⁺, C₂H₆N₅⁺). All possible geometries and the binding energy for the trigger bond of energetic salts have been optimized at the B3LYP/cc-pVDZ level of theory. The detonation velocity and detonation pressure have been calculated using Kamlet-Jacobs equation, while enthalpy has been predicted at the G2MP2 level of theory. The predicted results reveal that the energetic salts including small sized NH₃OH⁺(1) and NH₂NH₃⁺(2) cations increase detonation property. And also the energetic salts including more amino group (-NH₂) such as CH₉N₆⁺(3) cation increase thermodynamic stability. These results provide basic information for the development the high energy density materials (HEDMs).

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.26 no.1
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• pp.1-7
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• 2016

RE : YAG ($RE=Nd^{3+}$, $Er^{3+}$) single crystals are laser diodes and generally grown by Czochralski method with controlling the various growth parameter. Since the defects occurred by temperature gradient or the rotation speed of solid-liquid growth interface act as the decline of crystal optical property during the growth procedure, crystalline quality improvement via defects analysis is necessary. The etch pit density (EPD) analysis was used to confirm the surface defect of grown RE : YAG single crystal and to select the area of transmission electron microscopy (TEM) analysis. Defects in the specimen produced by tripod polishing method such as buckling, rod shaped, bend contours by internal stress, segregation and others were observed by using 200 kV TEM and 300 kV FE-TEM.

• Korean Journal of Materials Research
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• v.20 no.7
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• pp.364-369
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• 2010

A $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor powder with stuffed tridymite structure was synthesized by glycine-nitrate combustion method. The luminescence, formation process and microstructure of the phosphor powder were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). The XRD patterns show that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was an amorphous phase. However, a crystalline $SrAl_2O_4 $ phase was formed by calcining at $1200^{\circ}C$ for 4h. From the SEM analysis, also, it was found that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was in irregular porous particles of about 50 ${\mu}m$, while the calcined phosphor was aggregated in spherical particles with radius of about 0.5 ${\mu}m$. The emission spectrum of as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor did not appear, due to the amorphous phase. However, the emission spectrum of the calcined phosphor was observed at 520 nm (2.384eV); it showed green emission peaking, in the range of 450~650 nm. The excitation spectrum of the $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor exhibits a maximum peak intensity at 360 nm (3.44eV) in the range of 250~480 nm. After the removal of the pulse Xe-lamp excitation (360 nm), also, the decay time for the emission spectrum was very slow, which shows the excellent longphosphorescent property of the phosphor, although the decay time decreased exponentially.