• Title/Summary/Keyword: sulfur-based

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Isolation of Hydrogen Evolution Photosynthetic Bacteria Rhodobacter sphaeroides KS 56 (수소 생성 광합성 세균 Rhodobacter sphaeroides KS 56 분리)

  • 이은숙;권애란
    • The Korean Journal of Food And Nutrition
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    • v.10 no.4
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    • pp.549-552
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    • 1997
  • A purple non-sulfur photosynthetic bacteria which evolved molecular hydrogen efficiently from glucose in the presence of low concentration of NH4+ under light illuminated anaerobic condition was isolated from mud samples in Korea. This bacteria was identified on Rhodobacter sphaeroides KS 56 based on the morphological, cultural and physiological characteristics.

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Strength Development of Sulfur-Polymer-Based Concrete Surface Protecting Agents Depending on Curing Condition and Hazard Assessment of Sulfur Polymers (유황폴리머를 활용한 콘크리트 표면보호재의 양생조건에 따른 강도 평가 및 유황폴리머의 유해성 평가)

  • Lee, Byung-Jae;Lee, Eue-Sung;Kim, Seung-Gu;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.1
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    • pp.139-146
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    • 2015
  • The amount of by-product from sulphur increases in domestic industrial facilities. However, the amount of its consumption is limited so that the amount of unused sulphur continues to increase. Therefore, in this study, the use sulfur polymer as the concrete surface protecting material was conducted. The compressive strength showed that as the substitution ratio of filler increased up to 40%, the compressive strength also increased. A high compressive strength was shown at the curing temperature of $40^{\circ}C$ (SS, FA) and $60^{\circ}C$ (OPC) according to the type of filler. The difference of compressive strength between air dry curing and water curing was insignificant so that there was no significant influence of moisture during curing process. The evaluation result of bond strength showed that the highest bond strength was shown at the air-dry condition of $40^{\circ}C$ regardless of type of filler. Bonding didn't occur properly during water curing in comparison to air dry curing. Also, in case of the specimen cured at $60^{\circ}C$, discoloration and hair cracks appeared due to the influence of temperature, and the highest bond strength was shown at the substitution ratio of 20% (SS, FA) and 30% (OPC) according to the type of filler. The releasing test result of harmful substance showed that no harmful substance was released, so there is no harmfulness in the surface protecting material using sulfur polymer. As a conclusion drawn in this study, it is most appropriate to substitute silica by approximately 20%, mix and cure at the air-dry condition of $40^{\circ}C$ in order to use sulfur polymer as the surface protecting material.

Effect of Flower and Fruit Thinner on Fruit Set and Fruit Quality of 'Gamhong' Apples (적화제 및 적과제가 '감홍' 사과의 착과와 과실 품질에 미치는 영향)

  • Yoo, Jingi;Kang, Bong Kook;Kim, Dae Hyun;Lee, Jinwook;Lee, Dong Hoon;Kweon, Hun-Joong;Choi, In Myung;Jung, Hee Young;Choung, Myoung-Gun;Choi, Dong Geun;Kang, In-Kyu
    • Horticultural Science & Technology
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    • v.34 no.1
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    • pp.24-31
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    • 2016
  • This study investigated the effects of flower and fruit thinning agents on fruit set and harvested fruit quality attributes in 'Gamhong' apples. Lime sulfur, MaxCel (1.9% BA), and Fruitone (3.5% NAA) were applied either at post-bloom or fruitlet stages to mature 'Gamhong/M.9' trees. In 2011, the numbers of fruits per cluster in terminal flowers were 1.74, 0.82, and 1.15 for the control, lime sulfur, and Maxcel (applied at 10-mm fruit stage) treatments, respectively. The percentages of single fruit per cluster were 36.0, 47.9, and 48.7% for the control, lime sulfur, and Maxcel (10 mm) treatments, respectively, while the percentages of clusters with three fruits per cluster were 22.9, 1.4, and 5.8%. In lateral flowers, fruit numbers per cluster were 1.20, 0.36, and 0.50 for the control, lime sulfur, and Maxcel (10 mm) treatments, respectively. In 2012, all the thinning treatments showed a positive effect on flower and fruit thinning, compared with the control. Moreover, the treatment with thinning agents did not affect fruit quality. Overall, the results suggest that a single application of flower or fruit thinning agents would be sufficient, rather than the mixed application of thinning agents, based on the observed decrease in fruit setting.

Copper Mineralization Around the Ohto Mountain in the Southeastern Part of Euiseong, Gyeongsangbug-Do, Republic of Korea (경북·의성 동남부 오토산 주변의 동광화작용)

  • Lee, Hyon Koo;Kim, Sang Jung;Yun, Hyesu;Song, Young Su;Kim, In-Soo
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.311-325
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    • 1993
  • The Ohto and Tohyun copper mine which are located 4 km southeast of Euiseong, Gyeongsangbukdo, Republic of Korea show various common geologic and mineralogic features. Both copper deposits are of hydrothermal-vein types, and associated with fracture system developed during formation of the Geumseong-san caldera in late Cretaceous age. According to structures and mineral assemblages, the mineralization processes have progressed in four stages: three hypogene mineralization stages and one supergene stage. Three hypogene stages are 1) stage I forming $N5{\sim}20^{\circ}E$ veins in the Ohto mine, 2) stage II building $N5^{\circ}W{\sim}N5^{\circ}E$ veins in the Tohyun mine, and 3) stage ill bringing $N80^{\circ}E$ veins which crosscut veins of the stage II. The vein ores consist mainly of pyrite, arsenopyrite, galena and chalcopyrite, minor or trace amounts of magnetite, hematite, pyrrhotite, stannite, bournonite, boulangerite, stibnite, galenobismutite, native bismuth, marcasite, geothite and malachite. The main gangue minerals are quartz and calcite. Wallrock is altered by sericitization, chloritization, pyritization, carbonitization and argillization. Arsenic and copper contents in arsenopyrite increase from stage I to stage III (from 31.28 to 33043 atom.% As) and (from 0.04 to 0040 atom.% Co). Going from stage I to stage III Fe and Mn contents in sphalerite decreases from 12.56 to 0.44 wt.% and from 0.24 to 0.01 wt.%, respectively. The compositional data of arsenopyrite in the early stage I indicate a temperature of $420{\sim}365^{\circ}C$ and sulfur fugacity of $10^{-6.5}{\sim}10^{-8.3}$ atm. Chalcopyrite and pyrrhotite assemblage suggest that Middle stage I was deposited at below $334^{\circ}C$. The compositional data of arsenopyrite in early stage II suggest a temperature range of $425{\sim}390^{\circ}C$ and sulfur fugacity codition of $10^{-6.4}{\sim}10^{-7.3}$ atm. Based on fluid inclusion the Middle stage II was regarded as to be deposited at $420{\sim}337^{\circ}C$ (Chi et al., 1989). Referring composition of sphalerite and stannite middle-late stage II seem to be deposited around $246^{\circ}C$ and $10^{-16.5}$ atm. sulfur fugacity. The ${\delta}^{34}S$ values of sulfide minerals in the Stage I, II, III range from 4.9 to 7.6%0 and indicate igneous ore fluid origin. Based on differences in mineral assemblages, chemical composition and chemical environments of Ohto and Tohyun mine its mineralization are considered to be formed at diffent mineralization ages and by different ore fluids.

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A Preliminary Study on Calculating Eruptive Volumes of Monogenetic Volcanoes and Volcanic Hazard Evaluation in Jeju Island (제주도 단성화산의 분화량 계산과 화산재해 평가에 대한 예비연구)

  • Ko, Bokyun;Yun, Sung-Hyo
    • The Journal of the Petrological Society of Korea
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    • v.25 no.2
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    • pp.143-149
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    • 2016
  • Eruptive volumes of three monogenetic volcanoes (Songaksan tuff ring, Biyangdo scoria cone, and Ilchulbong tuff cone) with the youngest eruption age are calculated using the model, applied to Auckland Volcanic Field in New Zealand, to investigate the volcanic eruption scale and to evaluate volcanic hazard of Jeju Island. Calculated eruptive volumes of the volcanoes are $24,987,557m^3$, $9,652,025m^3$, and $11,911,534m^3$, respectively, and the volumes include crater infill, tuff ring (tuff cone), scoria cone, and lava flow. Volcanic explosivity indices of Songaksan tuff ring, Biyangdo scoria cone, and Ilchulbong tuff cone are estimated based on the eruptive volumes to be 3, 2, and 3 respectively, and eruption type is Strombolian to Surtseyan. It is assumed that the amount of emitted sulfur dioxide gas is $2-8{\times}10^3kt/y$ according to the correlation between volcanic explosivity index and volcanic sulfur dioxide index. Recent age dating researches reveal evidences of several volcanic activities during the last 10,000 years indicating the possible volcanic eruption in Jeju Island in the near future. Therefore, it is necessary for appropriate researches regarding volcanic eruption of the island to be accomplished. In addition, establishment of the evaluation and preparation system for volcanic hazard based on the researches is required.

Influence of Reduction Atmosphere and Temperature on the Separability and Distribution Behavior of Fe from FeTiO3 via Sulfurization (고온 황화반응에 의한 FeTiO3로부터 Fe의 분리성과 분배거동에 미치는 환원/황화 분위기 및 온도의 영향)

  • Shin, Seung-Hwan;Kim, Sun-Joong
    • Resources Recycling
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    • v.28 no.3
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    • pp.45-52
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    • 2019
  • $TiO_2$ as a raw material for producing titanium can be produced by carbon reduction of natural ilmenite ores over 1823 K and acid leaching of the obtained titanium-rich slag. However, the conventional process can cause very high energy consumption and a large amount of leaching residues. In the present study, we proposed the sulfurization of $FeTiO_3$ with $Na_2SO_4$ at temperatures below 1573 K, which can separate Fe in $FeTiO_3$ as the FeS based sulfide phase and Ti as the $TiO_2-Na_2O$ based oxide phase. This study is a fundamental study for sulfurization of $FeTiO_3$ to investigate the influence of reducing atmosphere, reaction temperature and the sulfur/Fe ratio on the separability and distribution behaviors of of Fe, Ti, and Na between the oxide phase and the sulfurized phase. At 1573 K and carbon saturation condition, the Fe can be separated from $FeTiO_3$ as Fe-C-S metal and a part of FeS, and the concentration of Fe in oxide decreased to 4 mass% after sulfurization.

Evaluation of Antibacterial Property and Freshness Maintenance of Functional Hybrid Corrugated Board Used for Agricultural Products (농산물용 복합 골판지의 항균성 및 선도유지기능 평가)

  • Lee, Ji-Young;Kim, Chul-Hwan;Choi, Jae-Sung;Oh, Seok-Ju;Kim, Byeong-Ho;Lim, Gi-Baek;Kim, Sun-Young;Kim, Jun-Sik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.3
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    • pp.45-51
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    • 2013
  • We developed a new antibacterial material, a non-woven fabric, a sulfur solution, and a new adhesive system to manufacture a new type of functional hybrid corrugated board in previous studies. Based on experimental data, the prototypes of functional hybrid corrugated boards were manufactured and their physical properties and functionalities, including antibacterial property and the freshness maintenance of sweet persimmon, were measured in this study. The functional hybrid corrugated board could be manufactured in the actual process with linerboards, non-woven fabrics, and other materials without any troubles, and was strong enough to be used as a packaging box for agricultural products. The antibacterial property of the hybrid corrugated board showed a value high enough to eliminate bacteria, which could deteriorate the sweet persimmons. Based on appearance observations, weight loss and firmness measurements, the freshness of sweet persimmons in the functional hybrid corrugated board was maintained better than it was in the conventional corrugated board.

Emission Prediction from Naval Ship Main Propulsive Diesel Engine under Steady Navigation (정속항해 시 함정 주 추진 디젤엔진의 배기가스 배출량 예측)

  • Lee, Hyung-Min;Park, Rang-Eun
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.6
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    • pp.788-793
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    • 2012
  • This study was focused on the estimations of air pollutants, such as PM(Particulate matters), SOx(Sulfur Oxides), $CO_2$(Carbon diOxides) and NOx(Nitrogen Oxides), from a diesel propulsion engine installed on a naval vessel. Legislative and regulatory actions for exhaust emissions from ships are being strengthened in international communities and national governments to protect human health and the environment. In this context, various technologies have been developed from all of the nations of the world to meet strict standards. These regulations are based on commercial ship applications and according to size, but are not suitable for military naval vessels, which have much different engine operating conditions and hull architectures. Additionally, there is no international emission control system for military ships. Emission factors have been updated for commercial ship types from work at various research institutes; however, it is difficult to develop emission factors for military vessels because of their characteristics. In this paper, exhaust emissions from diesel engines installed on naval vessels under steady navigation condition were estimated with emission inventory methodology applied to ocean going vessels using fuel-based methods and fuel sulfur content analysis.

Al corrosion phenomena on the Al grain boundary after AlCu plasma etching (AlCu 플라즈마 식각후 Al 결정입계에서 Al 부식현상)

  • 김창일;권광호;윤선진;김상기;백규하;남기수
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.12
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    • pp.47-52
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    • 1996
  • Cl-based gas chemistry is generally used to etching for al alloy metallization. After the etching of Al alloy with Cl-based gas plasma, residual chlorine on Al alloy reacts with H$_{2}$O due to air exposure and results in Al corrosion. In this study, the corrosion phenomena of Al wer examined with XPS(X-ray photoelectron spectroscopy) and SEM (scanning electorn microscopy). It was confirmed that chlorine mainly existed at the grian boundary of Al alloy after plasma etching of Al alloy with cl-based gas chemistry and Al corrosion was largely generated at the grain boundary of Al alloy. And residual chlorine was passivated by sulfur and fluorine which were generated by SF$_{6}$ plasma. These effects of passivation reduced the Al corrosion due to air exposure.

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