• 제목/요약/키워드: sulfur compounds

검색결과 561건 처리시간 0.034초

Aryloxyallylthiopyridazine 유도체 합성 (Synthesis of Aryloxyallylthiopyridazine Derivatives)

  • 권순경;김미경
    • 약학회지
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    • 제46권2호
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    • pp.89-92
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    • 2002
  • Allylthio group of the sulfur compounds of garlic oil plays an important role for prevention and treatment of hepatic diseases induced by toxic substances or carbon tetrachloride. Thus allylthio group as pharmacologically active group was introduced into pyridazine heterocycle ring. Aryloxyallylthiopyridazine derivatives were synthesized and their hepatoprotective activities were screened in rat. The activities of these compounds were weaker than alkoxyallylthiopyridazine derivatives, which exhibit a superior hepatoprotective effect.

차량 내 미생물에 의해 생성되는 악취유발 화학물질의 분석 (Determination of Malodor-causing Chemicals Produced by Microorganisms Inside Automobile)

  • 박상준;김의용
    • KSBB Journal
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    • 제29권2호
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    • pp.118-123
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    • 2014
  • It was confirmed that malodor connected with an air-conditioner in an automobile is caused by microbial volatile organic compounds (MVOCs) produced by microorganisms getting into an air-conditioner when it is operating. Chemicals such as hydrogen sulfide, dimethyl sulfide, nbutyric acid, n-valeric acid, iso-valeric acid, n-octanol and toluene were detected above the odor threshold inside the automobile. The characteristics of a funky odor in the air blown into the automobile were due to detected sulfur compounds (hydrogen sulfide and dimethyl sulfide). Dimethyl sulfide was produced by microorganisms such as Aspergillus versicolor, Methylobacterium aquaticum, Herbaspirillum sp. and Acidovorax sp. In addition, the characteristics of a sour odor in the air blown into the automobile were due to detected organic acids (n-butyric acid, n-valeric acid and iso-valeric acid). N-valeric acid and iso-valeric acid were generated from Aspergillus versicolor, while iso-valeric acid was produced by Methylobacterium aquaticum. In addition, the odor intensity of the air blown into the automobile was affected by the concentration of detected sulfur compounds and organic acids. On the other hand, it is estimated that chemicals such as hydrogen sulfide, n-octanol and n-butyric acid detected in the air blown into the automobile were produced by non-identified species of microorganisms.

충주시 악취발생원으로부터 배출되는 악취원인물질 특성 분석 (Characterization of Odorous Elements from Emission Sources in Chungju)

  • 조병렬;조영민
    • 대한환경공학회지
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    • 제30권4호
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    • pp.415-422
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    • 2008
  • 충주시에 소재하는 주요 환경시설로부터 배출되는 악취성 물질의 배출특성을 주민 민원에 대한 설문과 정치형 시료채취기를 활용하여 조사하였다. 네 군데의 조사시설 가운데 분뇨처리장이 가장 높은 악취농도를 보여주었다. 악취성물질의 주요 성분은 황화합물, 트리메칠아민, 알데히드 등이었다. 음식물 쓰레기 처리공정은 황화합물과 알데히드를 많이 배출하였다. 도시하수처리장은 고농도의 알데히드를 배출하는 것으로 나타났다. 악취의 관능 수준은 기상여건에 따라 다양하였으며, 심야의 악취 강도가 주간보다 훨씬 심각하게 나타났다.

Development of Reaction Flavors with Enzymatic Hydrolysate of Krill Euphausia superba in Ramen Sauce

  • Kim, Ye-Joo;Park, Jin-Yong;Park, Hyun-Joo;Kim, Seon-Bong;Chun, Byung-Soo;Lee, Yang-Bong
    • Fisheries and Aquatic Sciences
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    • 제17권4호
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    • pp.403-408
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    • 2014
  • Antarctic krill Euphausia superba is an excellent potential source of food protein. We used enzymatic hydrolysate of Antarctic krill and 10 other precursors to seek the optimum krill reaction flavor and apply to ramen sauce. Krill concentrate and powder were compared by sensory evaluation. The krill powder performed better preference, and was added to ramen sauce, which itself performed better than a commercial shrimp flavored sauce. In total, 47 and 39 volatile compounds were identified from krill concentrate and powder, respectively. Both products contained many aldehydes and sulfur-containing compounds. The whisky flavor of aldehydes lowered the shrimp flavor of the krill concentrate. Sulfur-containing compounds were found in krill powder, confirming the results from sensory evaluation.

안산시 주거지역을 중심으로 한 환경대기 중 휘발성 유기화합물과 황계열 성분의 온라인 연속측정 연구 (On-line GC Analysis of Odorous VOC and S Gas Pollutant Levels in Ambient Air of a Residential Area at Ansan City, Korea)

  • 김기현;주도원;최여진;홍윤정;사재환;박종호;전의찬;최청렬;구윤서
    • 한국대기환경학회지
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    • 제21권1호
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    • pp.107-118
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    • 2005
  • In this study, the concentrations of major odorous compounds including reduced sulfur compounds (OMS, CS$_2$, and DMDS) and aromatic VOC (benzene, toluene, xylene, etc.) were measured continuously using an on-line GC analytical system. Our measurements were made from a residential area of Ansan sity during about two week period of October, 2004. The highest mean concentrations of Sand VOC were found as 56.9 pbb of DMS and 21.7 ppb of toluene, respectively. The results of this study generally show that the pollution levels for both types of chemicals are significant relative to previous measurement results reported from comparable sites, if the results are compared simply in terms of the magnitude of the measured concentration data. Moreover, when the relative importance of different compounds is compared in terms of the odor strength, it indicated that the contribution of reduced S compounds may be much more important than that of VOC in the study area.

Optimization of Cure System for the ESBR Silica WMB and BR Silica DMB Blend Compounds

  • Yu, Eunho;Kim, Woong;Ryu, Gyeongchan;Ahn, Byungkyu;Mun, Hyunsung;Hwang, Kiwon;Kim, Donghyuk;Kim, Wonho
    • Elastomers and Composites
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    • 제54권2호
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    • pp.97-104
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    • 2019
  • Emulsion styrene-butadiene rubber silica wet masterbatch (ESBR silica WMB) technology was studied to develop highly filled and highly dispersed silica compounds, involving the preparation of a composite by co-coagulating the modified silica and the rubber latex in a liquid phase. Previous studies have shown that when manufacturing ESBR silica WMB/Butadiene silica dry masterbatch (BR silica DMB) blend compounds, preparing BR silica dry masterbatch and mixing it with ESBR silica WMB gave excellent results. However, WMB still has the problem of lower crosslink density due to residual surfactants. Therefore, in this study, tetrabenzylthiuram disulfide (TBzTD) was added instead of diphenyl guanidine (DPG) in the ESBR silica WMB/BR silica DMB blend compounds and sulfur/CBS contents were increased to evaluate their cure characteristics, crosslink densities, mechanical properties, and dynamic viscoelastic properties. TBzTD was found to be more effective in increasing the crosslink density and to produce superior properties compared to DPG. In addition, with increasing sulfur/CBS contents, mechanical properties and rolling resistance were enhanced due to high crosslink density, but the abrasion resistance was not significantly changed because of the toughness.

제지공장의 폐재인 Sludge로 부터 합성 Board의 제조 (The Manufacturing of Composition Board Using Waste Sludge Discharged from Manufacturing Factory)

  • 이병근
    • Journal of the Korean Wood Science and Technology
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    • 제15권2호
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    • pp.99-104
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    • 1987
  • Fiber mats were made at various density levels, using fibers from papermill sludge, ricestraw and various mixtures of the two. The paper mill sludges were collected from Moorim Papermill Co, and Jeonjoo Papermill Co. They were soaked in the liquid sulfur compounds, sulfur-tall oil and sulfurpolyester compounds, and made into fiber-reinforced, sulfur-based composition board. Under optimum conditions of fiber mat preparation and saturation with molten sulfur and modified sulfur, the Young's moduls of the manufactured tiber-reinforced composition board are superior to those of conventional wood-based composition boards. For example, the moduli of elasticity of the composition board made from papermill sludge, with a density of 0.40gm/$cm^3$, were greater than 1,400,000psi as compared 800,000psi for high density hardboard(1.28gm/$cm^3$). The modulus of rupture of the best reinforced composition board manufactured was over 9000psi, comparable to 6000psi of high density hardboard. The proposed Bryant and Lee's theory, "Modified Rule of Mixtures" can be applicable to the nonoriented and short fibrous composition board, when it was modified from "Rule of Mixtures" established by Paul an Jones, and supplemented by Smith and Cox's theory, In the Bryant and Lee's theory of $E_c=\frac{1}{3}aE_fV_f+bE_mV_m$, the constants "a" and "b" for the composition boards made from papermill sludge and the mixtures of ricestraw and the sludge were identified to be in the ranges of 3.29~3.54 and -2.47~-2.80 respectively.

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