• Applied Chemistry for Engineering
• /
• v.8 no.3
• /
• pp.389-394
• /
• 1997

The distribution of impurity included in benzene layer crystal was explored in layer crystallization of cyclohexane and benzene mixtures. The influence of crystal growth rate on crystal purity was investigated. All experimental results for bezene-cyclohexane system obtained in layer crystallizer have been evaluated with the criterion of Wintermantel. The purity of crystal decreases with increasing degree of subcooling, decreasing feed concentration and increasing crystal growth rate. The crystal growth rate was a key parameter to determine the inclusion of impurity in crystals. The results obtained from runs performed at increasing crystallization time(i.e. crystal thickness) have clearly shown that migration of inclusions within crystal layer to the melt, leading to the removal of impurity occurs. The diffusion of impurity which takes place during the crystallization from the beginning, enhances a further purification of the crystal layer if that underwent a thermal gradient after growth of the layer crystal stops.

• Nuclear Engineering and Technology
• /
• v.24 no.3
• /
• pp.274-284
• /
• 1992

A 1/15-scale CREARE experiment, which simulates the thermal-hydraulic behavior in the reactor pressure vessel of a PWR during a hypothetical Loss Of Coolant Accident, has been analyzed using CATHARE code for the associated model assessment to represent the phenomenon. The key parameters examined in the CREARE experiment were known as ECC water injection rate. ECC water subcooling, system pressure, and steam flow rate coming out from the core bottom. The present CATHARE simulation, however, has been mainly focused on qualitative analysis of a countercurrent flow in the downcomer. The discrepancy of the simulation results with the experimental data is considered arising primarily from an inadequate numerical representation as well as an interfacial friction model. Accordingly it is suggested from the sensitivity studies that either multidimensional approach or further examination of momentum equations at a junction near a volume element in CATHARE be necessary in order to represent the phenomenon more realistically.

• Nuclear Engineering and Technology
• /
• v.41 no.9
• /
• pp.1143-1156
• /
• 2009

The SPACE code that is based on a multi-dimensional two-fluid, three-field model is under development for licensing purposes of pressurized water reactors in Korea. Among the participating research and industrial organizations, KAERI is in charge of developing the physical models and correlation packages for the constitutive equations. This paper introduces a developed wall-to-fluid heat transfer package for the SPACE code. The wall-to-fluid heat transfer package consists of twelve heat transfer subregions. For each sub-region, the models in the existing safety analysis codes and the leading models in literature have been peer reviewed in order to determine the best models which can easily be applicable to the SPACE code. Hence a wall-to-fluid heat transfer region selection map has been developed according to the non-condensable gas quality, void fraction, degree of subcooling, and wall temperature. Furthermore, a partitioning methodology which can take into account the split heat flux to the continuous liquid, entrained droplet, and vapor fields is proposed to comply fully with the three-field formulation of the SPACE code. The developed wall-to-fluid heat transfer package has been pre-tested by varying the independent parameters within the application range of the selected correlations. The smoothness between two adjacent heat transfer regimes has also been investigated. More detailed verification work on the developed wall-to-fluid heat transfer package will be carried out when the coupling of a hydraulic solver with the constitutive equations is brought to completion.

• Journal of the Korean Institute of Gas
• /
• v.24 no.6
• /
• pp.18-27
• /
• 2020

This study presents flow assurance analysis in subsea pipeline considering system availability of topside in LNG-FPSO. A hydrate management strategy was established, which consisted of PVCap experiments, system availability analysis of LNG-FPSO topside, hydrate risk analysis in the pipeline, and calculation of PVCap injection concentration. The experimental data required for the determination of PVCap injection concentration were obtained by measuring the hydrate induction time of PVCap at the subcooling temperatures of 6.1, 9.2, and 12.1℃. The availability of LNG-FPSO topside system for 20 years was 89.3%, and the longest downtime of 50 hours occurred 2.9 times per year. The subsea pipeline model for multiphase flow simulation was created using field geometry data. As a result of risk analysis of hydrate plugging using subsea pipeline model, hydrate was formed at the end of flowline in 23.2 hours under the condition of 50 hours shutdown. The injection concentration of PVCap was determined based on the PVCap experiment results. The hydrate plugging in subsea pipeline of LNG-FPSO can be completely prevented by injecting PVCap 0.25 wt% 2.9 times per year.

• Journal of Energy Engineering
• /
• v.27 no.4
• /
• pp.27-35
• /
• 2018

The passive containment cooling system (PCCS) has been designed to remove the released decay heat during the accident by means of the condensation heat transfer phenomenon to guarantee the safety of the nuclear power plant. The heat removal performance of the PCCS is mainly governed by the condensation heat transfer of the steam-air mixture. In this study, the heat removal performance of the PCCS was evaluated by using the MARS-KS code with a new empirical correlation for steam condensation in the presence of a noncondensable gas. A new empirical correlation implemented into the MARS-KS code was developed as a function of parameters that affect the condensation heat transfer coefficient, such as the pressure, the wall subcooling, the noncondensable gas mass fraction and the aspect ratio of the condenser tube. The empirical correlation was applied to the MARS-KS code to replace the default Colburn-Hougen model. The various thermal-hydraulic parameters during the operation of the PCCS follonwing a large-break loss-of-coolant-accident were analyzed. The transient pressure behavior inside the containment from the MARS-KS with the empirical correlation was compared with calculated with the Colburn-Hougen model.

• Nuclear Engineering and Technology
• /
• v.52 no.4
• /
• pp.721-733
• /
• 2020

In nuclear engineering, the occurrence of critical heat flux (CHF) is complicated for rod bundle, and it is much more difficult to predict the CHF when it is in natural circulation under motion condition. In this paper, the dryout-type CHF is investigated for the rod bundle in a natural circulation loop under rolling motion condition based on the coupled analysis of subchannel method, a one-dimensional system analysis method and a CHF mechanism model, namely the three-fluid model for annular flow. In order to consider the rolling effect of the natural circulation loop, the subchannel model is connected to the one-dimensional system code at the inlet and outlet of the rod bundle. The subchannel analysis provides the local thermal hydraulic parameters as input for the CHF mechanism model to calculate the occurrence of CHF. The rolling motion is modeled by additional motion forces in the momentum equation. First, the calculation methods of the natural circulation and CHF are validated by a published natural circulation experiment data and a CHF empirical correlation, respectively. Then, the CHF of the rod bundle in a natural circulation loop under both the stationary and rolling motion condition is predicted and analyzed. According to the calculation results, CHF under stationary condition is smaller than that under rolling motion condition. Besides, the CHF decreases with the increase of the rolling period and angular acceleration amplitude within the range of inlet subcooling and mass flux adopted in the current research. This paper can provide useful information for the prediction of CHF in natural circulation under motion condition, which is important for the nuclear reactor design improvement and safety analysis.

• Korean Chemical Engineering Research
• /
• v.43 no.5
• /
• pp.595-602
• /
• 2005

In order to purify diethylene glycol as main impurity included in p-dioxanone, SLE (solid-liquid equilibria) and mixture density on two components system of p-dioxanone and diethylene glycol were measured and a layered melt crystallization with seed has been applied. The SLE of p-dioxanone and diethylene glycol were a simple eutectic system and the temperature and PDX concentration at eutectic point were 0.08 and 246 K, respectively. Densities of their binary mixtures were well fitted by the best correlation equation, ${\rho}_l=0.405+1.361x+0.002T-0.004xT$. In the melt crystallization, the growth rate (G) was proportional to the 1.5th power of the subcooling degree. The effective distribution coefficient ($K_{eff}$) as the degree of impurity removal was observed to increase with increasing the growth rate and initial p-dioxanone concentration. And also, $K_{eff}$ was correlated with Z function using Wintermantel's model such as $K_{eef}=-0.0604+6.392{\times}Z$. Finally, PDX purity through the optimization of this process can be obtained over 99%.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.11
• /
• pp.6452-6457
• /
• 2014

R1234yf has been developed as an alternative refrigerant to R134a, which has been associated with global warming. The capillary tubes as expansion valves control the mass flow rate and balance system pressure in the refrigeration cycle. The present numerical model used the governing equations including the law of conservation of mass, momentum, and energy in a capillary tube. The mass flow rate of R1234yf decreased by 47.0% as the capillary tube length was increased from 1 to 4 m. As the inner diameter of the capillary tubes was changed from 1.3 to 1.7 mm, the mass flow rate of R134a and R1234yf increased by 117.9% and 121.0%, respectively. The mass flow rate of the R134a and R1234yf increased by 28.3% and 29.1% with subcooling increasing from 0 to $7^{\circ}C$. In addition, when the inlet temperature of the capillary tubes was changed from 35 to $60^{\circ}C$, the mass flow rate of R134a and R1234yf increased by 31.0% and 45.4%, respectively.

• Nuclear Engineering and Technology
• /
• v.18 no.4
• /
• pp.273-280
• /
• 1986

The purpose of this study is to obtain the experimental data of the forced flow dryout heat flux in a heat generating debris bed which simulates the degraded nuclear reactor core after severe accident. An experimental investigation has been conducted of dryout heat flux in an inductively heated bed of steel particles with upward forced flow rising coolant circulation system under atmospheric pressure. The present observations were mainly focused on the effects of coolant mass flux, particle size, bed height, and coolant subcooling on the dryout heat flux The data were obtained when carbon steel particles in the size distribution 1.5, 2.5, 3.0 and 4.0 mm were placed in a 55 mm ID Pyrex glass column and inductively heated by passing radio frequency current through a multiturn work coil encircling the column. Distilled water was supplied with variation of mass flux from 0 to 3.5 kg/$\textrm{cm}^2$ s as a coolant in the tests, while the bed height was selected as 55 mm and 110 mm. Inlet temperature of coolant varied by 2$0^{\circ}C$ and 8$0^{\circ}C$. The principal results of the tests are: (1) Dryout heat flux increases with increase of upward forcing mass flux and particle size; (2) The dryout heat flux at the zero mass flux obviously depends on the Particle size as Previous studies; (3) The forced flow dryout heat flux in the shallow bed is somewhat higher than that in the deep bed,

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.23 no.6
• /
• pp.449-469
• /
• 2011

This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering during 2010. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) Research trends of thermal and fluid engineering have been surveyed as groups of general thermal and fluid flow, fluid machinery, and new and renewable energy. Various topics were presented in the field of general thermal and fluid flow. Research issues mainly focused on the thermal reliability of axial fan and compressor in the field of fluid machinery. Studies on the design of ground source heat pump systems and solar chemical reactors were executed in the field of new and renewable energy. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer in thermoelectric cooling/power generation systems, combined heat and power systems, carbon nano fluid with PVP, channel filled with metal foam and smoke ventilation in a rescue station of a railroad tunnel. Also the studies on flow boiling of R123/oil mixture in a plain tube bundle and R410A charge amount in an air cooled mini-channel condenser were reported. In the area of industrial heat exchangers, researches on plate heat exchanger, shell and tube heat exchanger, enthalpy exchanger, micro channel PCHE were performed. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer in thermoelectric cooling/power generation systems, combined heat and power systems, carbon nano fluid with PVP, channel filled with metal foam and smoke ventilation in a rescue station of a railroad tunnel. Also the studies on flow boiling of R123/oil mixture in a plain tube bundle and R410A charge amount in an air cooled mini-channel condenser were reported. In the area of industrial heat exchangers, researches on plate heat exchanger, shell and tube heat exchanger, enthalpy exchanger, micro channel PCHE were performed. (3) Refrigeration systems with alternative refrigerants such as hydrocarbons, mixed refrigerants, and CO2 were studied. Performance improvement of refrigeration systems are tried applying various ideas of refrigerant subcooling, dual evaporator with hot gas bypass control and feedforward control. The hybrid solar systems combining the solar collection devices with absorption chillers or compression heat pumps are simulated and studied experimentally as well to improve the understanding and the feasibility for actual applications. (4) Research trend in the field of mechanical building facilities has been found to be mainly focused on field applications rather than performance improvements. Various studies on heating and cooling systems, HVAC facilities, indoor air environments and energy resources were carried to improve the maintenance and management of building service equipments. In the field of heating and cooling systems, papers on a transformer cooling system, a combined heat and power, a slab thermal storage and a heat pump were reported. In the field of HVAC facilities, papers on a cooling load, an ondol and a drying were presented. Also, studies on HVAC systems using unutilized indoor air environments and energy resources such as air curtains, bioviolence, cleanrooms, ventilation, district heating, landfill gas were studied. (5) In the field of architectural environment and energy, studies of various purposes were conducted such as indoor environment, building energy, renewable energy and green building. In particular, renewable energy and building energy-related researches have mainly been studied reflecting the global interest. In addition, many researches which related the domestic green building certification of school building were performed to improve the indoor environment of school.